ANSYS CFX在哈根-泊肃叶方程教学实践中的应用

在对哈根-泊肃叶方程理论分析和推导的基础上,借助于ANSYS CFX进行流场的数值计算,获得速度场和剪切速率的分布以及壁面的剪切应力等多个物理量的分布以及较为直观的可视结果和可靠数据,进一步的提高了教学效果,促进了学生的理解能力与动手实践的兴趣。     

Integrated,reliable laser system for an 87Rb cold atom fountain clock

We designed, assembled, and tested a reliable laser system for ⁸⁷Rb cold atom fountain clocks. The laser system is divided into four modules according to function, which are convenient for installing, adjusting, maintaining, and replacing of the modules. In each functional module, all optical components are fixed on a baseplate with glue and screws, ensuring the system's structural stability. Mechanical stability was verified in a 6.11g RMS randomvibration test, where the change in output power before and after vibration was less than 5%. Thermal stability was realized by optimizing of the structure and appropriate selection of component materials of the modules through thermal simulation. In the laser splitting and output module, the change in laser power was less than 20% for each fiber in thermal cycles from 5 ℃ to 43 ℃. Finally, the functionality of the laser system was verified for a rubidium fountain clock.     

异腈氮杂配铜配合物的合成及光解水制氢性能

设计、合成了供电子性能的异腈二齿配体,可与铜(Ⅰ)和1,10-菲咯啉衍生物发生反应,形成一类异腈氮杂配铜光敏剂4a~4h,并在光解水制氢体系研究了其光催化活性。实验结果表明,2,2′-二异腈基二苯硫醚与2,9位具有取代基的菲咯啉形成的杂配铜配合物具有一定的光敏活性,光解水制氢TON达168。结合这类配合物的光物理性能和光电性能研究,对这类配合物作为光敏剂的构效关系及其内在机理进行了初步地解释与探讨。     

一种基于应力的双方向结构拓扑优化算法

基于传统的渐进结构优化方法，提出了一种基于应力的双方向渐进拓扑优化算法。该方法是对传统方法和目前的双方向法的改进和完善。算例表明该方法能避免目前的双方向法具有的解的振荡问题，具有更高的可靠性，能获得更佳的拓扑结构。     

Dark-matter pair production at the ILC in the littlest Higgs model with T-parity

In the littlest Higgs model with T-parity, the heavy photon (A_H) is supposed to be a possible dark matter (DM) candidate. The direct proof of the validity of this model is to produce the heavy photon at an accelerator. In this paper, we study the production rate of e~+ e~- → AH AH at the international e~+ e~- linear collider (ILC) in the littlest Higgs model with T-parity, and show the distributions of the transverse momenta of A H . The numerical results indicate that the heavy photon production rate could reach the 10~-1 fb level at some parameter space, so this could be a good chance to observe the heavy photon via the pair production process with high luminosity at the ILC (500 fb~-1). We know that DM is composed of weakly interacting massive particles, so the interactions with standard model particles are weak. How to detect heavy photons at a collider and distinguish them from other DM candidates are discussed in the final section of the paper.     

RbH2PO4不同相的铁电性和光学特性

利用第一性原理系统地研究了RbH2PO4晶格优化结构、总的和分的态密度、电荷密度分布。我们发现氧原子和Rb, H原子的杂化形成了两种离子群,在铁电相离子键和PO4四面体的耦合强度比顺电相更强。结果,通过P-O 和 H-O的距离改变电荷密度的再分布和PO4四面体的顺序旋转导致了铁电性的产生。两种类型粒子群的运动和自动成型畴壁导致了可以观测的焦热电流。     

铕(Ⅲ)-钙试剂络合物吸附波及其应用研究

用线性扫描极谱法研究了在氨-氯化铵缓冲体系中Eu(Ⅲ)-钙试剂络合物的极谱行为。在pH10.2的NH3-NH4Cl缓冲介质中,Eu(Ⅲ)-钙试剂络合物在-0.82V(vs.SCE)处有一灵敏的导数极谱波,其峰电流与Eu(Ⅲ)的浓度在1.0×10-7~8.0×10-6mol/L范围内呈线性关系,检出限为9.0×10-8mol/L。方法可用于试样中痕量铕的测定。本文还研究了极谱波的性质。     

OTPPTS对烯烃氢甲酰化反应的影响

 研究了水/有机两相体系中TPPTS(磺化三苯基膦)氧化为OTPPTS(氧化的TPPTS)对Rh/TPPTS催化烯烃氢甲酰化反应的影响. 结果表明,在己烯-1、辛烯-1和十二烯-1氢甲酰化反应中,当n(OTPPTS)/n(TPPTS)＜1时,对催化剂体系性能的影响较小,但当n(OTPPTS)/n(TPPTS)＞1时,将引起催化剂体系的活性、选择性和稳定性下降; 如果保持体系中TPPTS的含量一定,使n(TPPTS)/n(Rh)≥18,当n(OTPPTS)/n(Rh)＝20时,则对催化剂体系性能的影响不明显. 这说明生成的OTPPTS不是铑催化剂的毒物. TPPTS氧化为OTPPTS致使铑催化剂的活性和生成醛的选择性下降, 是由于TPPTS浓度的降低导致n(TPPTS)/n(Rh)值过低,使催化循环中各活性物种的平衡发生变化及铑配合物的稳定性变差所造成的结果.     

Numerical analysis of plasma arc physical characteristics under additional constraint of keyhole

The physical characteristics of a plasma arc affect the stability of the keyhole and weld pool directly during keyhole plasma arc welding(KPAW). There will be significant change for these characteristics because of the interaction between the keyhole weld pool and plasma arc after penetration. Therefore, in order to obtain the temperature field, flow field, and arc pressure of a plasma arc under the reaction of the keyhole, the physical model of a plasma arc with a pre-set keyhole was established. In addition, the tungsten and base metal were established into the calculated domain, which can reflect the effect of plasma arc to weld pool further. Based on magneto hydrodynamics and Maxwell equations, a two-dimensional steady state mathematical model was established. Considering the heat production of anode and cathode, the distribution of temperature field, flow field, welding current density, and plasma arc pressure were solved out by the finite difference method. From the calculated results, it is found that the plasma arc was compressed a second time by the keyhole. This additional constraint results in an obvious rise of the plasma arc pressure and flow velocity at the minimum diameter place of the keyhole, while the temperature field is impacted slightly. Finally, the observational and metallographic experiments are conducted, and the shapes of plasma arc and fusion line agree with the simulated results generally.     

Molecular dynamics simulations of the effects of sodium dodecyl sulfate on lipid bilayer

Molecular dynamics simulations have been performed on the fully hydrated lipid bilayer with different concentrations of sodium dodecyl sulfate(SDS). SDS can readily penetrate into the membrane. The insertion of SDS causes a decrease in the bilayer area and increases in the bilayer thickness and lipid tail order, when the fraction of SDS is less than 28%.Through calculating the binding energy, we confirm that the presence of SDS strengthens the interactions among the DPPC lipids, while SDS molecules act as intermedia. Both the strong hydrophilic interactions between sulfate and phosphocholine groups and the hydrophobic interactions between SDS and DPPC hydrocarbon chains contribute to the tight packing and ordered alignment of the lipids. These results are in good agreement with the experimental observations and provide atomic level information that complements the experiments.