空心球壳型V2O5的制备研究

无机空心微球含可容纳大量客体的中空部分,具有比表面积大、密度小、表面渗透能力强、稳定性好等特点,在化学、生物、材料科学和光电领域均有重要的应用,如控制释放胶囊(药物、颜料、化妆品、油墨)、催化剂及催化剂载体、分离材料、声学隔音材料以及电子学元件等。[1-3]空心球壳材料的制备方法通常有喷雾干燥法,乳液法[4],模板合成法[5]。近年来以胶体粒子为模板合成空心材料引起了人们的高度重视,其中聚苯乙烯微球(PSt)由于其形貌规整,粒径均一而被广泛用作形成空心结构的有机模板[6]。通过对锂离子电池正极材料的广泛研究,发现空心球壳型…     

银在浸出黄铜矿中的催化作用

本文研究了用Fe_2(SO_4)_3、MnO_2、FeCl_3、CuCl_2等浸出黄铜矿时Ag~ 的作用。Ag~ 在氯化物溶液中不起催化作用。但在酸性Fe_2(SO_4)_3及MnO_2溶液中可使反应速率常数提高200倍,文中导出了在Ag~ 催化作用下硫酸高铁浸出黄铜矿的动力学方程。确定了速率控制步骤是离子通过产物硫层的扩散过程,活化能为35.7kJ/mol。探讨了银催化浸出黄铜矿的反应机理。     

自负载吡啶双亚胺酸酯钒(Ⅲ)催化剂的合成及催化乙烯聚合

合成了一系列自负载吡啶双亚胺酸酯钒(Ⅲ)催化剂(V(Ⅲ)),并通过傅里叶变换红外光谱仪(FTIR)、元素分析及核磁共振波谱仪(NMR)等技术手段对配合物进行了表征。 在倍半乙基氯化铝(EASC)活化下,V(Ⅲ)催化剂对乙烯聚合表现出很高的催化活性(7.2~12.1 g/(mol·h·Pa)),且自负载基团的链长对催化剂的活性及所得聚合物的性质影响较小。 同时,该类V催化剂催化乙烯与1-己烯共聚合性能良好,得到高相对分子质量(高达68.1×10³)的聚合物。 所得聚合物经扫描电子显微镜(SEM)表征,其微观结构为片层叠加结构。     

空间平均的角度散斑相关粗糙度测量模拟研究

角度散斑相关是一种不受表面粗糙度轮廓的间距特性影响的粗糙度幅度参量测量方法,它的数学模型通常建立在集平均的基础上。通过模拟计算随机粗糙表面的远场散斑场,以散斑图面上的空间平均代替常规的集平均来计算角度散斑相关系数,并应用集平均的数学模型反演粗糙度参量。结果证实了这种空间平均角度散斑相关粗糙度测量方法的有效性,在同一表面只需对少数个区域进行测量并对测得的粗糙度参量取平均,即可获得足够的测量精度。对于Rq大于2.0μm的表面,测量相对误差小于15%。根据最佳测量条件,该方法适用于大粗糙度表面。     

Feng混沌系统参数识别及自适应模糊控制器的反步设计

设计了参数观测器,对Feng混沌系统中未知参数进行识别.采用反步控制方法,在存在输入扰动项的情况下,构造模糊自适应控制器控制Feng混沌系统.模糊逻辑系统用来逼近反步控制方法中出现的未知、非线性且结构复杂的函数.和传统的反步控制方法相比,本文采用的控制器结构简单,易于实现.仿真的结果验证了本文控制方法的有效性.     

非对易空间的三模谐振子能谱

在非对易空间中,用不变本征算符方法(IEO),对非耦合、坐标耦合、动量耦合三种三模谐振子系统能谱进行求解,并将求解结果与一般对易空间的能谱进行比较分析.通过比较发现,当非对易参数为零时,所求能级差还原到了与普通空间相对应的一般量子系统哈密顿量能级差,验证了推导结果的正确性;同时讨论了耦合系数对非对易空间能谱的影响. 关键词： 不变本征算符 非对易空间 三模谐振子能谱 能级差     

180°进气弯管安装角度对离心压气机的性能影响

针对车用涡轮增压器压气机进口广泛采用弯管的现实,有必要评估弯管导流进气对离心压气机性能的影响,为发动机进气管道的优化提供参考。本文对离心压气机进口接入直管和多种不同安装角度的180°弯管展开实验和数值研究。研究结果表明:弯管进气使压气机性能下降,其性能下降程度与弯管的周向安装位置有关,而且这种影响随流量增加而增大;叶轮进口的流场结构受进气管道导流、叶轮势流和下游蜗壳周向不对称性共同作用,其对应的总压畸变形态改变了叶轮进气条件,导致压气机性能不同程度下降。     

真空辅助法合成Fe_3(PO_4)_2·8H_2O及对LiFePO_4/C结构、形貌和电化学性能的影响(英文)

采用了一种真空辅助沉淀法制备Fe3(PO4)2·8H2O,并以此进一步合成粒径尺寸在400 nm左右LiFePO4颗粒.研究了Fe3(PO4)2·8H2O对于磷酸铁锂的形貌、结构、电化学性能的影响.X射线衍射(XRD)结果表明,真空辅助制备的Fe3(PO4)2·8H2O具有高纯度,以此制备的LiFePO4具有高结晶度和纯度.扫描电子显微镜(SEM)结果表明,真空辅助制备的Fe3(PO4)2·8H2O具有未完全发育的颗粒,以此制备的LiFePO4均匀无硬团聚.透射电子显微镜(TEM)结果显示真空辅助制备的LiFePO4包覆一层均匀的碳.真空制备的LiFePO4显示了优异的电化学性能,在1C、10C、20C倍率下的容量分别为140、113、100 mAh·g-1.真空制备的LiFePO4的循环伏安曲线显示了小的极化电压和尖锐的氧化峰.充放电平台曲线表明真空对LiFePO4高倍率性能起到重要作用.电化学阻抗谱(EIS)计算结果显示,真空和非真空制备的LiFePO4的锂离子扩散系数分别为1.42×10-13和4.22×10-14cm2·s-1,说明真空辅助能够提高LiFePO4的扩散系数.     

Mechanical properties an undercut evaluated resonance test and of silicon nanobeams with by combining the dynamic finite element analysis

Mechanical properties of silicon nanobeams are of prime importance in nanoelectromechanical system applications. A numerical experimental method of determining resonant frequencies and Young＇s modulus of nanobeams by combining finite element analysis and frequency response tests based on an electrostatic excitation and visual detection by using a laser Doppler vibrometer is presented in this paper. Silicon nanobeam test structures are fabricated from silicon-oninsulator wafers by using a standard lithography and anisotropic wet etching release process, which inevitably generates the undercut of the nanobeam clamping. In conjunction with three-dimensional finite element numerical simulations incorporating the geometric undercut, dynamic resonance tests reveal that the undercut significantly reduces resonant frequencies of nanobeams due to the fact that it effectively increases the nanobeam length by a correct value △L, which is a key parameter that is correlated with deviations in the resonant frequencies predicted from the ideal Euler-Bernoulli beam theory and experimentally measured data. By using a least-square fit expression including △L, we finally extract Young＇s modulus from the measured resonance frequency versus effective length dependency and find that Young＇s modulus of a silicon nanobeam with 200-nm thickness is close to that of bulk silicon. This result supports that the finite size effect due to the surface effect does not play a role in the mechanical elastic behaviour of silicon nanobeams with thickness larger than 200 nm.     

Mechanical properties of silicon nanobeams with an undercut evaluated by combining the dynamic resonance test and finite element analysis

Mechanical properties of silicon nanobeams are of prime importance in nanoelectromechanical system applications.A numerical experimental method of determining resonant frequencies and Young’s modulus of nanobeams by combining finite element analysis and frequency response tests based on an electrostatic excitation and visual detection by using a laser Doppler vibrometer is presented in this paper.Silicon nanobeam test structures are fabricated from silicon-oninsulator wafers by using a standard lithography and anisotropic wet etching release process,which inevitably generates the undercut of the nanobeam clamping.In conjunction with three-dimensional finite element numerical simulations incorporating the geometric undercut,dynamic resonance tests reveal that the undercut significantly reduces resonant frequencies of nanobeams due to the fact that it effectively increases the nanobeam length by a correct value △L,which is a key parameter that is correlated with deviations in the resonant frequencies predicted from the ideal Euler-Bernoulli beam theory and experimentally measured data.By using a least-square fit expression including △L,we finally extract Young’s modulus from the measured resonance frequency versus effective length dependency and find that Young’s modulus of a silicon nanobeam with 200-nm thickness is close to that of bulk silicon.This result supports that the finite size effect due to the surface effect does not play a role in the mechanical elastic behaviour of silicon nanobeams with thickness larger than 200 nm.