基于顶空及SERS分子识别的薤与韭的挥发物研究

顶空及表面增强拉曼散射（SERS）分子识别技术应用于新鲜薤、韭的挥发性物质研究,直接测得了以纳米银溶胶作为基底的薤、韭的挥发物的 SERS 光谱,并与液态烯丙基甲基硫醚（allyl methyl sulfide）、1-丙硫醇（1-propanethiol）、二烯丙基二硫（diallyl disulfide）及三者中两两混合后的挥发物的SERS 谱进行比对。结果显示薤、韭的挥发物的SERS光谱重现性非常好;薤的挥发性物的SERS谱与液态烯丙基甲基硫醚和1-丙硫醇混合后的挥发物的SERS谱基本一致,薤的挥发物的SERS 谱中既有烯丙基甲基硫醚挥发物的SERS谱的特征峰：626和674 cm－1,又有1-丙硫醇挥发物的 SERS 谱的特征峰：702,893,1024,1085,1215,1320 cm－1;韭的挥发物的SERS谱与液态烯丙基甲基硫醚和二烯丙基二硫混合后的挥发物的SERS谱基本一致,韭的挥发物的SERS谱中既有烯丙基甲基硫醚挥发物的SERS谱的特征峰：674 cm－1,又有二烯丙基二硫挥发物的SERS谱的特征峰,407,577,716,1189,1291,1401 cm－1。说明薤的挥发物中含有烯丙基甲基硫醚和1-丙硫醇成分;韭的挥发物中含有烯丙基甲基硫醚和二烯丙基二硫成分;薤和韭的挥发物虽有所差异,但都含有烯丙基甲基硫醚成分。证明顶空技术结合SERS分子识别技术可用于直接对薤和韭的挥发物研究。该技术在常温下进行,能保证得到的挥发物即为植物所含物种的原始成分,通过与标样对比,可确定植物中挥发物的组成。     

基于顶空-SERS技术的不同产地、不同药源的薤白挥发物研究

将顶空技术与表面增强拉曼散射(SERS)技术结合,以纳米银溶胶作为基底获得了不同产地、不同药源的薤白挥发物的SERS光谱。实验表明不同产地的小根蒜挥发物SERS谱及藠头挥发物SERS谱的峰位峰形非常相似,且重复性好。所检测的植物样品挥发物的SERS谱在375、635、673、712、781、893、1025、1086、1222、1322、1629 cm-1附近的峰对应较好。与液态烯丙基甲基硫醚、1-丙硫醇及二者混合后的挥发物SERS谱进行比对,结果显示,小根蒜和藠头挥发物的SERS谱与液态烯丙基甲基硫醚和1-丙硫醇混合后的挥发物SERS谱基本一致;说明不同产地的小根蒜和楚雄地区藠头的挥发物中都含有烯丙基甲基硫醚和1-丙硫醇成分。说明顶空技术与SERS技术结合可直接用于新鲜薤白的挥发物研究。     

THE MULTIPLE EQUILIBRIA IN THE COUPLED ATMOSPHERE-OCEAN SYSTEM

In this paper, a topography forced quasi-geostrophic baroclinic model and an SST (sea surface temperature) equation are used to set up a simple coupled atmosphere-ocean model The large-scale ocean current is nearly the Sverdrup flow. Two basic processes are considered in this system, i. e. the SST as a thermal forcing drives the atmospheric circulation and the ocean current produced by the wind redistributes the SST. Highly truncating and multiple scale method are used to simplify the model and obtain a low dimensional dynamic system. In this part, the qualitative vector in the phase space of the system is analysed and two stable equilibria are obtained. These two kinds of equailibria may be used to explain some features of the long-range anomalies of circulation.     

瓷石和高岭土样品分类的研究

本文用Ｑ型聚类法对瓷石１３个样品，高岭土１９个样品进行分类研究，其分类结果对陶瓷工业生产有一定的指导意义。     

Single-to-Multiple Channel Wavelength Conversions and Tuning of Picosecond Pulses in Quasi-Phase-Matched Waveguides

We report the single-to-multiple channel wavelength conversions of 1.57-ps pulses based on cascaded secondharmonic generation and difference frequency generation in quasi-phase-matched periodically poled lithium hiebate waveguides. For single-to-single channel wavelength conversion, no external cavity laser is required with use of a fibre ring laser. The conversion efficiency is about -21.44 dB. The converted idler wavelength can be tuned from 1526.4nm to 1537.5nm as the lasing pump wavelength is varied from 1566.1 nm to 1555.0nm. By employing several input pumps, tunable single-to-dual and single-to-triple channel wavelength conversions are experimentally demonstrated.     

数字图像相关技术的综合算法及其在断裂力学中的应用

鉴于散斑图的随机噪声和相关搜索运算过程仍是当今影响相关图像技术所获结果精度与计算速度两大有待研究解决的主要问题,提出一种基于小波变换、序惯相似度检测和统计相关算法三者相结合的新算法。其基本原理是应用小波变换对变形前后的散斑图进行滤波平滑处理;利用序惯相似度检测算法进行粗搜索,找到可能的匹配点;在可能的匹配点应用统计相关法进行细搜索,最终找到匹配点的位置。基本实验、计算和应用表明,这种算法在消除噪声和提高运算速度等方面,取得了良好的效果。     

定量分析化学中极谱分析法的教学介绍

极谱分析法自从1920年海路夫斯基(J.Heyro-vsky)在捷克布拉格查礼大学研究滴汞电极上的电解作用起始到现在已有30多年的历史,在这些年代中由于伊耳克威斯(kovic)在1934年确定了扩散电流与浓度的数学有关系之后,而奠定了定量分析的基础。在1935年又由海路夫斯基同伊耳克威斯推出半波电位的特性,从而奠定了定性分析的基础。关于仪器方面的发展,最初由手工形式的装置即从记录电解、电压与电流关系的曲线后来改进到自动记录并通过照像来观察结果的仪器了。其后更配合阴极射线示波器的装置来进行分析工作。由于研究文献的日见增多,因此,在应用方面也就渐渐     

DYNAMIC INSTABILITY OF LARGE-SCALE SEA SURFACE TEMPERATURE (SST) DISTURBANCE AND THE FORMATION OF SEA SURFACE TEMPERATURE ANOMALY (SSTA)

This paper proposes that the formation of SSTA is a dynamic instability of large-scaleSST disturbance. Using a linear coupled air-sea model, in which the baroclinic atmosphere isdivided into two levels and the ocean is a mixture layer and a deep water layer, we obtainphysical conditions as well as spatial and temporal seales for the growing of SST disturbance.The major factors for the growing of SST disturbance include Sverdrup transportation, heatexchange between mixture layer and deep water, and modulation effect of clouds on solarradiations. The main horizontal scales of growing SST disturbance range from 3000 to 6000km and its temporal scales are several months. even soveral years. On the basis of thesetheoretical results, the causes for the formation of SSTA are also discussed.     

多元线性回归方程的平面图示

随着科学技术的不断地发展,多元线性回归分析方法广泛地为人们所采用,因此,如果能将其回归方程图示出来,那是很有意义的.伹疑难的是,多元线性回归方程所对应的是多维空间内的回归超平面,而实验数据在同一空间内却对应着一个点集,因而能否作图,能作怎样的图,这些问题长期来还未曾获得解决.     

PERIODIC AND NONPERIODIC OSCILLATIONS OF NONLINEAR ATMOSPHERIC WAVES FORCED BY PERIODIC THERMAL FORCING——SYSTEM WITHOUT DISSIPATION

In this paper, a baroclinic stable system with periodic forcing is used to discuss the dynamics of wave amplitude near the resonant forcing instability.In the first part, the linear resonant condition and weakly nonlinear resonant problem are analysed and two distinct periodic solutions with larger and smaller amplitudes are solved respectively for system without dissipation. When external forcing varies between the existence domains for these two kinds of periodic solution, nonperiodic oscillation appears, i.e. the so-called "chaos" phenomenon.