Microwave-assisted Cannizzaro reaction—Optimisation of reaction conditions

The microwave-assisted Cannizzaro reaction was studied in order to develop fully reproducible synthetic protocols for transformation of aldehydes to carboxylic acid and alcohols. Optimised were the following process parameters: power, temperature, and time. Aromatic, heteroaromatic and aliphatic aldehydes were used in the studies. It was found that furfural, thiophene-2-carbaldehyde, pyridinecarboxaldehyde and aromatic aldehydes react under mild conditions, while 1-methyl-pyrrole-2-carboxaldehyde derivatives and aliphatic aldehydes require more drastic reaction conditions and a longer exposure time to microwave radiation.     

Low-Temperature TLC-MS of Essential Oils from Five Different Sage (Salvia) Species

JPC – Journal of Planar Chromatography – Modern TLC - In a previous paper we discussed the possibility of fractionating the essential oils of different sage species by low-temperature...     

Prediction of losses in the flow through the last stage of low‐pressure steam turbine

In this paper, the numerical modelling of the flow through the low‐pressure steam turbine last stage was presented. On the basis of predicted wet steam flow‐field, the aerodynamic as well as thermodynamic losses were estimated. For calculations of the wet steam steady flow‐field three numerical methods were employed. The first method was a streamline curvature method (SCM). The commercial CFD code (CFX‐TACflow) and an in‐house code, both solving the 3‐D RANS equations, were the next two methods. In the wet steam region, by means of all three methods, the equilibrium flow was modelled. Additionally, the in‐house CFD code was used for modelling of the non‐equilibrium steam condensing flow. In this work, the comparison of the cascade loss coefficient for stator and rotor and selected flow parameters for the stage were presented, compared and discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

High energy,large momentum transfer amplitudes: The sum of ladder diagrams inΦ 3 theory

We perform summation of ladder diagrams in the high energy, large momentum limit. This leads to new results for both perturbative and non-perturbative approaches. In particular, an explicit expression for any diagram's contribution is given, the non-perturbative form of asymptotically non-analytic terms is found and representation of amplitude as a series of Regge poles is presented.Supported in part by Polish Ministery of National Education, grant no. CPBP 01.03     

On anomalous diffusion of fractal clusters under certain realistic physical conditions

Summary Diffusion of a fractal cluster of dimensiond _f in a three-dimensional space is investigated. The diffusion process is assumed to be modelled by a standard parabolic diffusion equation, although a more general case represented by the Fokker-Planck-Kolmogoroff equation is also introduced. The mean-square displacement of the cluster mass centre is analysed and its anomalous behaviour is presented and critically discussed. The results obtained can be applied to describe some effects which may occur during the diffusion-limited cluster-cluster aggregation process, especially when the viscosity of the solvent is changed in time and/or a directed transport of clusters is present in the system. Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994.     

Angular Distribution of Hyperfine Magnetic Field in Fe3O4 and Fe66Ni34 from Mössbauer Polarimetry

Nuclear resonance studies of the two different types impurity doped potassium hexachloro-stannates, the isomorphic system such as (K–Rb)₂SnCl₆ and K₂(Sn–Re)Cl₆ and the nonisomorphic system K₂SnCl₆:Al³⁺ in the high temperature cubic phase revealed contrasting features with one the other characterized by static in the former and dynamic feature in the latter case respectively. The resonance spectra of the nonisomorphic system indicate additionally a sign of the local structural transition above the conventional structural phase transition temperature. This seems to be triggered by the ligand-deficient octahedral defects and can be explained in terms of the enhanced activity of the octahedral defects for the hindered rotation.