全文获取类型
收费全文 | 1946篇 |
免费 | 160篇 |
国内免费 | 307篇 |
专业分类
化学 | 1298篇 |
晶体学 | 14篇 |
力学 | 77篇 |
综合类 | 15篇 |
数学 | 91篇 |
物理学 | 918篇 |
出版年
2024年 | 1篇 |
2023年 | 18篇 |
2022年 | 16篇 |
2021年 | 34篇 |
2020年 | 52篇 |
2019年 | 38篇 |
2018年 | 35篇 |
2017年 | 61篇 |
2016年 | 73篇 |
2015年 | 60篇 |
2014年 | 107篇 |
2013年 | 147篇 |
2012年 | 117篇 |
2011年 | 153篇 |
2010年 | 102篇 |
2009年 | 141篇 |
2008年 | 145篇 |
2007年 | 159篇 |
2006年 | 120篇 |
2005年 | 98篇 |
2004年 | 71篇 |
2003年 | 78篇 |
2002年 | 69篇 |
2001年 | 48篇 |
2000年 | 70篇 |
1999年 | 53篇 |
1998年 | 57篇 |
1997年 | 56篇 |
1996年 | 32篇 |
1995年 | 23篇 |
1994年 | 27篇 |
1993年 | 36篇 |
1992年 | 31篇 |
1991年 | 16篇 |
1990年 | 6篇 |
1989年 | 12篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 7篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 9篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 3篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2413条查询结果,搜索用时 15 毫秒
1.
Jinke Bai Linfeng Wang Wenyong Chen Xiao Jin Qinghua Li Yuxiao Wang Xueru Zhang Yinglin Song 《Particle & Particle Systems Characterization》2020,37(8):2000115
Device grade quantum dots (QDs) require QDs ensembles to retain their original superior optical properties as in solution. QDs with thick shells are proven effective in suppressing the inter-dot interaction and preserving the emission properties for QDs solids. However, lattice strain–induced defects may form as the shell grows thicker, resulting in a notable photoluminescence quenching. Herein, a well-type CdxZn1−xS/CdSe/CdyZn1−yS QDs is proposed, where ternary alloys CdZnS are adopted to match the lattice parameter of intermediate CdSe by separately adjusting the x and y parameters. The resultant thick-shell Cd0.5Zn0.5S/CdSe/Cd0.73Zn0.27S QDs reveal nonblinking properties with a high PL QY of 99% in solution and 87% in film. The optimized quantum dot light-emitting diodes (QLEDs) exhibit a luminance of 31547.5 cd m−2 at the external quantum efficiency maximum of 21.2% under a bias of 4.0 V. The shell thickness shows great impact on the degradation of the devices. The T50 lifetime of the QLEDs with 11.2 nm QDs reaches 251 493 h, which is much higher than that of 6.5 and 8.4 nm QDs counterparts. The performances of the well-type thick-shell QLEDs are comparable to state-of-the-art devices, suggesting that this type of QDs is a promising candidate for efficient optoelectronic devices. 相似文献
2.
3.
Paramagnetic pyrroline and 1,2,3,6-tetrahydropyridine derivatives of BODIPY and their diamagnetic analogs have been synthesized and characterized as novel redox double sensor and cation sensitive reagents. 相似文献
4.
The association of complex formation with static quenching in CT systems was investigated. Evaluation of the data made evident
that the inner filter effect must be allowed for. Time-resolved and temperature-dependent stationary measurements of fluorescence
led to the separation of dynamic and static quenching components. The static quenching constant is discussed with respect
to the equilibrium constant of complex formation determined by absorption spectroscopy. 相似文献
5.
Modified Stern-Volmer equation is obeyed by bovine serum albumin (BSA)-iodide system showing selective quenching of tryptophanyl
fluorescence of BSA. The fraction of accessible protein fluorescence is 0.56 and the effective Stern-Volmer constant is 290
M-1 at pH 7.4 in 0.005 M phosphate buffer at 25°C. Collisional quenching is operative both in the BSA -I−1 system and the model system, tryptophan-I−1. It is supported by the observed relationship between the ratio of quenching rate constants (k
q
) and diffusion coefficients and alsok
q
with bulk viscosity. 相似文献
6.
7.
J.L. Shui 《Applied Surface Science》2006,253(5):2379-2385
Spongy-like reticular structure is a unique morphology fabricated by electrostatic spray deposition (ESD) technique. The effects of solvent, substrate temperature, precursor feeding rate, static electric field strength, and deposition time on tailoring the reticular structure were investigated. Scanning electron microscopy was used to observe the film morphology. MnOx or LiMn2O4 were selected as the model materials. It is found that in addition to the conventional solvent butyl carbitol, other kinds of solvents such as ethylene glycol and propylene glycol can also be used to obtain reticular films at a suitable substrate temperature. Porous films with a low cross-linking degree pore structure can be prepared by increasing precursor feeding rate or decreasing substrate temperature. Increasing the deposition time or the electric field strength helps to obtain reticular films with more homogeneous pore size distribution. In addition, the addition of a high boiling-point solvent in mixed alcohol solvent results in the increase of proper substrate temperature. It is concluded that the fluidity of the spray droplets on the surface of a hot substrate is an important factor to form a reticular film. 相似文献
8.
Applied Biochemistry and Biotechnology - 相似文献
9.
We have studied the characteristic features of carbazole phosphorescence quenching by benzophenone in toluene at 77 K. We
have shown that the decrease in the relative phosphorescence intensity for carbazole (energy donor) by a greater factor than
we see for the relative change in its decay time is due to the fact that a change in the phosphorescence decay time occurs
only for carbazole molecules participating in triplet-triplet energy transfer, while the substantial decrease in the phosphorescence
intensity for carbazole with no change in the phosphorescence decay time is connected with quenching of its singlet states.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 554–556, July–August, 2006. 相似文献
10.
偏硅酸钙中Pr3+的4f5d态的光谱特性及Pr3+→Gd3+的能量传递 总被引:2,自引:0,他引:2
合成了高效发射UV光的CaSiO3:Pr^3 新型荧光体,研究了室温下Pr^3 的4f5d态的发射和激发光谱,Pr^3 的4f5d态的最低子能级向4f^2组态的^3H4,^3H6和^1G4能级跃迁产生UV发射,并不伴随有4f-4f能级跃迁的可见光发射。Pr^3 的浓度猝灭是由于辐射和无辐射能量传递造成的,同时,在CaSiO3中,存在Pr^3 →Cd^3 的能量传递,探讨了其能量传递特性。 相似文献