全文获取类型
收费全文 | 8260篇 |
免费 | 1102篇 |
国内免费 | 928篇 |
专业分类
化学 | 2315篇 |
晶体学 | 128篇 |
力学 | 980篇 |
综合类 | 180篇 |
数学 | 2927篇 |
物理学 | 3760篇 |
出版年
2024年 | 12篇 |
2023年 | 80篇 |
2022年 | 157篇 |
2021年 | 223篇 |
2020年 | 244篇 |
2019年 | 186篇 |
2018年 | 223篇 |
2017年 | 299篇 |
2016年 | 328篇 |
2015年 | 254篇 |
2014年 | 423篇 |
2013年 | 683篇 |
2012年 | 434篇 |
2011年 | 541篇 |
2010年 | 467篇 |
2009年 | 540篇 |
2008年 | 556篇 |
2007年 | 529篇 |
2006年 | 530篇 |
2005年 | 429篇 |
2004年 | 355篇 |
2003年 | 375篇 |
2002年 | 317篇 |
2001年 | 281篇 |
2000年 | 274篇 |
1999年 | 231篇 |
1998年 | 181篇 |
1997年 | 182篇 |
1996年 | 155篇 |
1995年 | 162篇 |
1994年 | 104篇 |
1993年 | 85篇 |
1992年 | 64篇 |
1991年 | 51篇 |
1990年 | 54篇 |
1989年 | 45篇 |
1988年 | 40篇 |
1987年 | 31篇 |
1986年 | 22篇 |
1985年 | 28篇 |
1984年 | 32篇 |
1983年 | 6篇 |
1982年 | 23篇 |
1981年 | 17篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 5篇 |
1975年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
This paper is concerned with the Cauchy problem on the Boltzmann equation without angular cutoff assumption for hard potential in the whole space. When the initial data is a small perturbation of a global Maxwellian, the global existence of solution to this problem is proved in unweighted Sobolev spaces with . But if we want to obtain the optimal temporal decay estimates, we need to add the velocity weight function, in this case the global existence and the optimal temporal decay estimate of the Boltzmann equation are all established. Meanwhile, we further gain a more accurate energy estimate, which can guarantee the validity of the assumption in Chen et al. (0000). 相似文献
2.
Herein, we report an addition to the toolbox for the monitoring and quantification of the hydrolytic decay of pentose-1-phosphates, which are known to be elusive and difficult to quantify. This communication describes how apparent equilibrium shifts of a nucleoside phosphorolysis reaction can be employed to calculate hydrolytic loss of pentose-1-phosphates based on the measurement of post-hydrolysis equilibrium concentrations of a nucleoside and a nucleobase. To demonstrate this approach, we assessed the stability of the relatively stable ribose-1-phosphate at 98 °C and found half-lives of 1.8–11.7 h depending on the medium pH. This approach can be extended to other sugar phosphates and related reaction systems to quantify the stability of UV-inactive and hard-to-detect reaction products and intermediates. 相似文献
3.
4.
Benni Du 《Molecular physics》2020,118(2)
Kinetics and mechanism of the gas-phase reaction of CH3C(O)OCH(CH3)CH2OCH3 (MPA) with OH radicals in the presence of O2 and NO have been investigated theoretically by performing a high and reliable level of theory, viz., CCSD(T)/6-311?+?G(d,p)//BH&HLYP/6-311++G(d,p)?+?0.9335×ZPE. The calculations predict that the H-abstraction from the ?CH2?O? position of MPA is the most facile channel, which leads to the formation of the corresponding alkoxy radicals CH3C(O)OCH(CH3)C(O ?)HOCH3 under atmospheric conditions. This activated radicals CH3C(O)OCH(CH3)C(O ?)HOCH3 will undergo further rearrangement, fragmentation and oxidative reactions and predominantly leads to the formation of various products (methyl formate HC(O)OCH3 and acetic anhydride CH3C(O)OC(O)CH3). In the presence of water, acetic anhydride can convert into acetic acid CH3C(O)OH via the hydrolysis reaction. The calculated total rate constants over the temperature range 263–372?K are used to derive a negative activation energy (Ea= ?5.88 kJ/mol) and an pre-exponential factor (A?=?1.78×10?12 cm3 molecule?1 s?1). The obtained Arrhenius parameters presented here are in strong agreement with the experimental values. Moreover, the temperature dependence of the total rate constant over a temperature range of 263?1000?K can be described by k?=?5.60 × 10?14×(T/298?K)3.4×exp(1725.7?K/T) cm3 molecule?1 s?1. 相似文献
5.
Yingchun Wu Haipeng Li Xuecheng Wu Gérard Gréhan Lutz Mädler Cyril Crua 《Proceedings of the Combustion Institute》2019,37(3):3211-3218
Droplet evaporation characterization, although of great significance, is still challenging. The recently developed phase rainbow refractometry (PRR) is proposed as an approach to measuring the droplet temperature, size as well as evaporation rate simultaneously, and is applied to a single flowing n-heptane droplet produced by a droplet-on-demand generator. The changes of droplet temperature and evaporation rate after a transient spark heating are reflected in the time-resolved PRR image. Results show that droplet evaporation rate increases with temperature, from ?1.28 m2/s at atmospheric 293 K to a range of (?1.5, ?8) m2/s when heated to (294, 315) K, agreeing well with the Maxwell and Stefan–Fuchs model predictions. Uncertainty analysis suggests that the main source is the indeterminate gradient inside droplet, resulting in an underestimation of droplet temperature and evaporation rate. With the demonstration on simultaneous measurements of droplet refractive index as well as droplet transient and local evaporation rate in this work, PRR is a promising tool to investigate single droplet evaporation in real engine conditions. 相似文献
6.
7.
《Physics letters. A》2019,383(17):2090-2092
In this paper, we have used Monte Carlo (MC) method to simulate and study the temperature and doping effects on the electric conductivity of fullerene (C60). The results show that the band gap has reduced by the doping and the charge carrier transport is facilitated from valence band to conduction band by the temperature where is touched a 300 K. In this case, the conductivity reached a value of . The electric conductivity of C60 can increase by the triphenylmethane dye crystal violet (CV) alkali metal to reach at 303 K. Our results of MC simulation have a good agreement with those extracted from literature [10], [33]. 相似文献
8.
In this paper, we consider a viscoelastic wave equation of variable coefficients in the presence of past history with nonlinear damping and delay in the internal feedback and dynamic boundary conditions. Under suitable assumptions, we establish an explicit and general decay rate result without imposing restrictive assumption on the behavior of the relaxation function at infinity by Riemannian geometry method and Lyapunov functional method. 相似文献
9.
The large deviation principle (LDP) which has been effectively used in queueing analysis is the sample path LDP, the LDP in a function space endowed with the uniform topology. Chang [5] has shown that in the discrete-time G/D/1 queueing system under the FIFO discipline, the departure process satisfies the sample path LDP if so does the arrival process. In this paper, we consider arrival processes satisfying the LDP in a space of measures endowed with the weak* topology (Lynch and Sethuraman [12]) which holds under a weaker condition. It is shown that in the queueing system mentioned above, the departure processes still satisfies the sample path LDP. Our result thus covers arrival processes which can be ruled out in the work of Chang [5]. The result is then applied to obtain the exponential decay rate of the queue length probability in an intree network as was obtained by Chang [5], who considered the arrival process satisfying the sample path LDP. 相似文献
10.
We inquire into the time evolution of quantum systems associated with pseudo-or quasi-Hermitian Hamiltonians. We obtain, in
the pseudo-Hermitian case, a generalized Liouville-von Neumann equation for closed systems. We show that quantum systems with
quasi-Hermitian Hamiltonians admit the proper interpretation in terms of open quantum system and derive a generalized Lindblad-Kossakowski
equation. Finally, we extend such formalism to the study of decaying systems.
Partially supported by PRIN “Sintesi”. 相似文献