共查询到19条相似文献,搜索用时 62 毫秒
1.
CuAl水滑石的合成及其催化活性 总被引:1,自引:0,他引:1
以Cu(NO3)2.6(H2O)和A l(NO3)3.9(H2O)为原料,NaOH和Na2CO3为沉淀剂,通过低过饱和共沉淀法合成了CuAl系列的碳酸根型水滑石,其结构经XRD,IR及TG-DTA表征。于55℃焙烧24 h后发现其复合氧化物对乙醇催化脱水、脱氢反应有一定的活性。 相似文献
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铜锰铝水滑石的合成、表征及衍生复合氧化物酸碱催化活性研究 总被引:1,自引:0,他引:1
采用低过饱和共沉淀法合成了铜锰铝不同摩尔投料比的碳酸根型水滑石,通过XRD、IR、TG-DTA等手段对样品进行测试和表征。X-衍射结果显示,其M2 /M3 摩尔投料比为2-4得到的水滑石为较满意构型。红外的结果进一步证实了碳酸根离子柱撑CuMnA l水滑石的成功合成,热重-差热分析结果显示随M2 /M3 比的增加,水滑石热稳定性减弱。经焙烧后,发现其复合氧化物催化活性随着Cu含量的增加而增大,随着Mn含量的增加对乙醛的选择性增大,可达到91.6%。 相似文献
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以Co(NO3)2.6(H2O)、Mg(NO3)2.6(H2O)和Fe(NO3)3.9(H2O)为原料,以NaOH和Na2CO3为沉淀剂采用低过饱和共沉淀法合成了CoMgFe系列的碳酸根水滑石,通过XRD,IR,TG-DTA,等手段对样品进行测试和表征,X-衍射结果显示,其M2 /M3 投料物质的量比为2-4得到的水滑石为理想构型。经焙烧后,发现其复合氧化物对乙醇催化脱水、脱氢反应有一定的活性。 相似文献
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水滑石(Layered Double Hydroxides,简称LDHs)是一类具有层状结构的阴离子型粘土[1],其结构类似于水镁石,化学通式为x/n ·mH2O ,其中M2+和M3+分别代表层板上占据八面体氢氧化物中心位置的二价和三价金属离子,An-为层间阴离子.以半径相似的二价、三价过渡金属阳离子部分或全部取代Mg、Al可合成多种二元、三元甚至四元水滑石类化合物HTLcs(Hydrotalcite-like compounds);将较大的阴离子基团(如杂多阴离子等) 引入层间则可合成柱撑水滑. 相似文献
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杂多酸柱水滑石的合成及其上烯烃烷基化反应 总被引:7,自引:0,他引:7
Layered double hydroxides (LDHs) pillared with heteropolyoxo-metalate have been synthesized via both restructuring of hydrotalcite-like compounds and direct anion exchange under microwave field. LDHs and their derivatives are both found to be efficiency for alkylation of iso-butane and butene with a higher butene conversion and selectivity towards C_8~o. 相似文献
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钴铜铝水滑石类化合物的合成及其催化氧化对甲酚:Ⅰ.水滑石的合成及 … 总被引:1,自引:1,他引:0
用共沉淀法合成了以钴为主的水滑石型化合物,用XRD,IR等对其及热分解产物进行了表征。结果表明,水滑石经过焙烧,逐渐失去层间的H2O,OH^=和CO^2-3,转化成尖晶石结构。比表面积测定和CO2-TPD结果表明,焙烧温度和产物的Co:Cu比对表面积和碱性均有明显的影响。 相似文献
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采用共沉淀水热法制备了镍铝铈三元复合层状氢氧化物.详细探讨了合成体系pH值、Ce/Al比及陈化条件对合成产物物相的影响;通过XRD,ICP,TG-DTA手段研究了合成物物相、组成及热行为.考察了以合成物为前驱体经焙烧后转化为镍铝铈复合金属氧化物在催化消除NO反应中的应用.实验结果表明,合成镍铝铈三元复合层状氢氧化物的适宜条件是:M2 /M3 =2,Ce/Al=0.07~0.75,pH=5.5~6.9,水热处理条件为110℃,5 h;在pH=5.5~6.9条件下,合成原料配比不同,产物物相相同,但组成不同;合成物热稳定性较差,在T=100~400℃之间,层间吸附水及层间平衡阴离子NO3-脱去,转化为复合氧化物,将此氧化物应用于NO消除反应中,表现出高的低温活性,400℃进行反应,NO转化率达95%,N2选择性几乎100%. 相似文献
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The coprecipitation method was used to prepare a series of different oxides (CuO: 0, 5%, 10%, 15%, 20%, 30% and 40%) derived from Cu substituted Mg/Al mixed anionic clay precursors (hydrotalcites) at the ratio of M2+/M3+ =3. In order to study influences of Cu and Mg content upon the performance of these materials, such characterization techniques as X-ray diffraction, thermogravimetrical analysis, differential scanning calorimetry, temperature programmed reaction and Fourier transform infrared reflectance spectra, were used. The results showed that complete structure of hydrotalcite precursors could be formed when CuO≤30%. When CuO≥40%, Cu(OH)2 phase appeared. Homogeneous composite oxides can be obtained by high temperature calcination at CuO≤20%. When CuO>20%, CuO phase was isolated. The content of Cu and Mg had significant influences on thermal stability of materials. The reduction ability of materials was related to calcination temperatures and material composition. 相似文献
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Donia A. M. Radwan N. R. E. Atia A. A. 《Journal of Thermal Analysis and Calorimetry》2000,61(1):249-261
Mixed oxides were prepared by the thermal decomposition of the oxalates of cobalt(II) and copper(II) coprecipitated from aqueous
solution or made by mechanical mixing. The compositions and structures of the oxides were confirmed by means of TG and X-ray
powder diffraction spectroscopy. The catalytic behaviour of the oxides obtained was studied by using the decomposition of
H2O2 as a model reaction. The results were compared with those on the oxides produced from the thermal decomposition of mechanically
mixed oxalates. The catalytic activities of the mixed oxides were found to be lower than that of pure cobalt oxide, but higher
than that of copper oxide. This result was interpreted in terms of the relative standard reduction potential of the catalyst
as compared with that of H2O2. The catalytic activity of the mixed oxides obtained from the coprecipitate was found to be lower than that of the oxides
obtained from the mechanical mixture at the same temperature. As the temperature of preparation was increased, the catalytic
activities of the oxides obtained decreased. This was attributed to the solid-solid interactions, which gave a new phase with
lower catalytic activity than those of the interacting phases.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Ye Lwin Abu Bakar Mohamad Zahira Yaakob Wan Ramli Wan Daud 《Reaction Kinetics and Catalysis Letters》2000,70(2):303-310
A series of Cu/Al catalysts, containing different proportions of copper and aluminium, have been prepared by coprecipitation using metal nitrate precursors and Na2CO3. The dried precipitate catalyst precursors were characterized by X-ray diffraction (XRD) to show the presence of Cu-Al binary hydrotalcite-like phase. The dried precipitates were calcined at 873 K for 3 h. The calcined catalysts were characterized by XRD and temperature-programmed reduction (TPR) methods to show the presence of unidentified mixed oxides. The results showed that the extent of metal-support interaction increased with copper loading due to the mixed oxides formed from the hydrotalcite-type phase during calcination. High dispersion of the mixed metal oxides was indicated by comparison with similar studies on Cu-Al catalysts, prepared by similar methods, whose precursors showed no hydrotalcite formation. 相似文献
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采用共沉淀法合成了钴系尖晶石型Co0.5 M0.5 Co2O4(M=Mg、Zn、Ce)复合氧化物催化剂,考察了其对甲烷催化燃烧反应的催化活性,并运用FT-IR、XRD、BET及H2-TPR等技术对催化剂进行了表征.实验结果表明,Co0.5 Ce0.5 Co2 O4催化剂有较高的催化活性,与CoO. 5Mg0.5 Co2 O4和Co0.5Zn0.5Co2 O4催化剂相比,Co0.5 Ce0.5Co2 O4催化剂有较高的晶格畸变率、较大的比表面积和孔容、较小的晶粒度、较强的氧活动性和较低的甲烷催化燃烧表观活化能. 相似文献
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高分子金属催化剂的性能,不仅与金属离子的种类有关,而且与高分子配体的结构有关。作者在以SiO_2负载的聚苯乙烯马来酸酐共聚物的苯胺氨解产物——钯单金属高分子催化剂(P—C_6H_5NH·Pd) 中引入少量的第一过渡金属离子,形成双金属高分子金属催化剂(P-C_6H_5NH·Pd·M)。研究结果表明,由于第一过渡金属离子的引入,使单金属高分子催化剂的催化加氢性能(活性、选择性和稳定性)得到了改善。而且发现,第一过渡金属离子的助催化作用与它的晶体场稳定化能(Crystal Field Stablization Energy,CFSE)有关。 相似文献
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Catalytic activities exerted by the lanthanide oxides Ln2O3 (Ln=La, Sm, Gd and Dy) (0.25 mol%) on the thermal decomposition of barium perchlorate were studied gasometrically at 718 K. The
α vs. t plot for the salt alone displays (i) initial gas evolution (ii) an induction period, (iii) a short acceleratory stage and
(iv) a long decay stage. For the mixtures with Ln2O3, phenomena (i) and (ii) are not observed. Ln2O3 enhances the rate of reaction in both the acceleratory and the decay stage, and increases the fraction decomposed, α, in
the sequence La2O3>Gd2O3>Sm2O3,>Dy2O3.
The influence of Dy2O3 (0.25–2.0 mol%) on the decomposition of Ba(ClO4)2 at 718 K indicates that such admixture facilitates the process and the effect increases with increasing concentration.
The salt alone and the mixtures decompose through the same stages in the temperature range 703–733 K as at 718 K. The data
on both types of samples fit well to the Prout-Tompkins and the Avrami-Erofeev mechanism, suggesting that nucleation takes
place in a chain-branching manner and that the two-dimensional growth of the nuclei occurs during the process. Admixture enhances
the rate of reaction marked without affecting the energy of activation
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This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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层状前体镁铁水滑石及磁性材料的制备及表征 总被引:4,自引:0,他引:4
本文提出了利用镁铁水滑石作为磁性材料前体再经高温焙烧制备尖晶石型铁氧体的思路,深入研究了水滑石的制备工艺及结构性能并初步探讨了其焙烧后的磁学性能。由共沉淀法合成了Mg/Fe摩尔比为2,3,4,6的镁铁水滑石,XRD结果表明随镁铁比增大、晶化温度的升高及晶化时间的延长,水滑石的晶体结构规整性增强;热重-差热结果显示镁铁水滑石的分解有两个过程,随着镁铁比增大,水滑石的热稳定性提高。高温焙烧后的镁铁水滑石具有较好的磁学性能。 相似文献