共查询到20条相似文献,搜索用时 140 毫秒
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裉色光度法测定SO^2—3的研究 总被引:4,自引:0,他引:4
本文研究了SO^2-3褪色碱蓝6B的反应,在pH5.2Ac-NaAc缓冲介质中,SO^2-3浓度在0.39-12mg/L范围内符合比尔定律,仅Fe^3+,Ni^2+,Cr^3+干扰测定,用于食品中SO^2-3的测定,结果令人满意。 相似文献
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偶合反应化学发光法测定痕量银的研究——K4Fe(CN)6—Luminol体系 总被引:5,自引:0,他引:5
将Ag(I)催化K4Fe(CN)6的水合反应与Luminol同Cu(CN)^2-4的化学发光反应相偶合,建立起一种新的灵敏测定痕量银的化学发光分析法,在所研究的优化条件下,该法测定银的选择性较好,检测限达到4.0×10^-13g/mLAg线性浓度范围为1.0×10^-12~1.0×10^-6g/mLAg对4×10^-11g/mLAg(I)溶液连续11次测定的RSD≤3.5%,用于环境水和岩矿中银的 相似文献
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新银盐光度法测定磷酸氢钙中的微量砷 总被引:5,自引:0,他引:5
以硝酸银-乙酸-聚忆烯醇-乙醇作为砷化氢吸收液,Zn-KI-SnCl2为还原体系的新银盐光度法测定了磷酸氢钼中的微量砷。As^2-含量在0-7.5μg/5mL范围内服从比耳定律。应用于磷酸氢钙样品中As呈测定,回收率96-103%,方法检出限为2.88×10^-6g/L,RSD为0.94-5.50%,测定结果与标准方法基本一致。 相似文献
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催化动力学光度法测定痕量苯酚 总被引:5,自引:0,他引:5
研究了在硫酸介质中苯酚对I^-1催化Ce^4+-As(Ⅲ)反应的抑制作用及其动力学条件。建立了用催化动力这光度法测定痕量苯酚的新方法,结果表明,在0.001mol/LCe(SO4)2,0.00125mol/L,As2O3,0.01mg/L,KI,0.0125mol/L,H2SO4和0.13%(w/v)NaCl溶液中测定苯酚,其表面摩尔吸光系数为2.1×10^5L.mol^-1.cm^-1,线性范围 相似文献
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大黄酚在0.15mol/L HAc-NaAc(pH4.9)底液中,出现一灵敏的示波极谱导数峰,峰电位为-0.45V(vs,SCE),峰电流与大黄酚浓度在2.0×10^-7-5.0×10^-6mol/L范围内成线性关系,检测限为2.0×10^-6mol/L。用于生药大黄中大黄酚的测定,回收率为92.4%-108.4%。用多种电化学手段研究体系的电化学行为,测得电极反应电子数n=2。体系具有吸附性,并 相似文献
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抑制动力学分析法测定痕量铈 总被引:11,自引:0,他引:11
1引言研究了铈(Ⅲ)阻抑H2O2氧化水杨基荧光酮(SAF)褪色的反应。反应对铈(Ⅲ)为一级反应,表观活化能为28.75kJ/mol。据此建立了测定痕量铈的动力学分析法。测定条件为:SAF:4.0x10-5mol/L,H2O2:0.010%,NaOH:2.0x10-2mol/L,50℃。线性范围0.04~0.44mg/L,检测限为0.02mg/L。当溶液中的铈含量为0.16mg/L时,3~8倍量的轻稀土,5~11倍量的重稀土及同倍量铀和钍不干扰测定。2实验部分2.1试剂和仪器铈(Ⅲ)标准溶液:20… 相似文献
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锡钨杂多酸—耐尔蓝光度法测定纳克量易 总被引:1,自引:0,他引:1
本文报道一个光度法测定纳克量锡的新方法,在聚乙烯醇(PVA)存在下锡与钨酸盐和耐尔蓝(NB)反应形成离子缔合物,离子缔合物的最大吸收位于580nm,表现摩尔吸光系数ε值2.95×10^7L·mol^-1·cm^-1。服从比耳定律范围0-2.0μg/L,检出限(3σ)0.083μg/L,对2.0μg/L锡测定的RSD为21.42%,离子缔合物至少稳定72h。考察了40多种共存离子的影响,大多数常见元 相似文献
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N-四氢苯并噻唑亚胺Schiff碱的化学发光测定 总被引:3,自引:0,他引:3
新合成的噻唑类Schiff碱N-2(2-四氢苯并噻唑)-2-羟基苯甲亚胺及类似化合物与Ce^4+反应可产生微弱的化学发光,使用增敏剂奎宁可使发光显著增强,研究其发光反应动力学曲线、荧光光谱、化学发光光谱以及Schiff碱与Ce^4+混合前后紫外可见吸收光谱的变化,确定子发生反应的官能团,讨论了发光反应的机理。考察了奎宁存在下Schiff碱与Ce^4+化学发光反应条件及共存物质对发光强度的影响,建立了流动注射化学发光测定Schiff碱的方法。该法线性范围为2.0*10^-7-1.0*10^-4mol/L检出限为8.0*10^-8mol/L,化学发光测定Schiff碱的方法,该法线性范围为2.0*10^-7-1.0*10^-4mol/L,检出限为8.0*10^-8mol/L,对2.0*10^-6mol/L噻唑类Sdi 相似文献
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建立了氨基酸同位素稀释液相色谱-串联质谱法准确测定合成肽段绝对含量的方法。实验中对合成肽段的纯度进行了表征,色谱纯度表征结果为99%以上,质谱纯度为90%以上。在肽段溶液中加入13C标记的氨基酸后进行酸溶液水解时间的优化,水解后的氨基酸直接经液相色谱分离和质谱检测,结果表明肽段中的被测氨基酸在150 ℃、6 mol/L HCl溶液水解4~6 h就可以达到水解平衡。每个肽段选择两个或两个以上的被测氨基酸,测得随机选择的5种合成肽段的绝对含量为62.07%~88.18%,测定结果的相对标准偏差小于8%,相对误差小于5%,均满足定量要求。除常用的被测氨基酸苯丙氨酸、缬氨酸、异亮氨酸外,还考察了选择赖氨酸和精氨酸作为被测氨基酸的可行性,实验结果表明增加精氨酸为被测氨基酸是可行的,从而进一步增加了方法的普适性。该方法的建立避免了色谱法定量时氨基酸衍生化处理带来的副反应影响及操作繁琐等问题,提高了肽段含量测定的准确度和精密度,为肽段含量的准确测定提供了一种新的方法。 相似文献
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The conductivities of binary mixtures of glycerine and water were measured at 20°C by means of a transient method. The equation
describing the correlation between concentration and thermal conductivity was determined. The equation can be used for determining
concentrations in mixtures. The results show that (1) the error in the determination of the molar concentration of water in
mixtures is less than 1%, (2) the time of measurement is 1 s, (3) this method can be used for on-line analysis in production
control.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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Summary Based on the ratio of two apparent heights and an empirical correction factor, a method is presented for quantitation of peak
areas of severely overlapped pairs. This method can be applied to a wide range of area ratios and peak asymmetries, provided
there exists a clear and precise valley-except for shoulder peaks. The relative errors of the first peak are usually within
±3% and theoretical relative error limits are −7.0% to +5.5%. Peak asymmetry of a severely overlapped pair can be determined
using the ratio of the front half-width to the rear half-width at 10% peak height of an overlapping profile. The asymmetry
so determined is an apparent one and the relative errors are −4% to +5.3% for peaks with 90% relative valley, depending on
area ratio, degree of overlap and asymmetry. An empirical area equation for the first peak involving area ratio, asymmetry,
resolution and the area measured by a perpendicular drop algorithm is also developed. 相似文献
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Solid samples can be analysed as without a prior decomposition step, if they are pulverized and then embedded in a thin layer of a cold-setting polymer. This method is very appropriate for materials which are difficult to decompose or which can be easily contaminated. The sample components are evenly distributed in a thin layer, which improves considerably the signal-tonoise-ratio, and this leads to a decrease of the limits of detection. The reproducibility of the method was tested with cobalt oxide and yttrium oxide and also a mixture of these with silver oxide and manganese dioxide. Between 20 and 60 ng of these elements can be determined without difficulty, with a precision of ± 2–4%. The correlation coefficients found for the calibration graphs were between 0.994 and 0.999. 相似文献
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建立血液中甲卡西酮快速溶剂萃取(ASE)-气相色谱/质谱(GC/ MS)分析的新方法. 通过优化 ASE 的萃取条件(溶剂、温度及时间),对血液中的甲卡西酮进行有效提取,之后用 GC/ MS 进行定性、定量分析. 方法检出限为0. 02 mg / L,定量限为0. 1 mg / L. 血液中甲卡西酮在0. 5、1. 0 和2. 0 mg / L 3 个添加水平的平均回收率在96. 70% ~99. 27%之间,甲卡西酮在0. 1 ~ 50 mg / L 的浓度范围内线性良好. 方法快速、简便、高效且操作自动化,适用于血液中甲卡西酮的检验鉴定. 相似文献
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《Analytical letters》2012,45(4):763-775
Abstract A simple and sensitive spectrophotometric method is described for determination of amoxicillin. The method is based on a nucleophilic substitution reaction to measure the pink compound produced by the reaction of amoxicillin with sodium 1,2‐naphthoquinone‐4‐sulfonate in pH 9.00 buffer solution. The stoichiometric ratio of the compound is 1:1, and its maximum absorption wavelength is at 468 nm, ε=3.91×103 L · mol?1 · cm?1. The Beer's law is obeyed in the range of 0.8–120 µg · mL?1 of amoxicillin. The linear regression equation is A=0.041239+0.22128 C, with 0.9994 of a linear regression correlation coefficient. The detection limit is 2.0 µg · mL?1, and average recovery is over 98.5%. This paper further optimizes the determination of amoxcillin compared to the previous methods, and the kinetic property and reaction mechanism are studied intensively. This proposed method has been successfully applied to the determination of amoxicillin in tablets and capsules. The results obtained by this method agreed well with those by the official method high pressure liquid chromatography (HPLC). 相似文献