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1.
K_3Sb_3P_2O_(14)·5H_2O的水热合成与表征 总被引:2,自引:0,他引:2
利用水热晶化法合成了磷锑酸钾K3Sb3P2O14·5H2O,并通过XRD、31PMASNMR、IR、DTA-TG及组成分析等多种手段对其进行了表征。该化合物属六方晶系,晶胞参数为:a=0.71377nm,b=0.71377nm,c=3.08047nm,α=90°,β=90°,γ=120°,具有层状结构,钾离子具有可交换性。 相似文献
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张子学 《广东微量元素科学》1995,2(4):46-51
采用二次饱和-D最优设计的方法,研究Sr(NO3)2(x1)、KH2PO4(x2)和Na2B4O7·10H2O(x3)叶面喷施对秦油2号油菜的产量效应,获得回归方程:y=247.485+7.0048x1+2.29244x2—9.82646x3—0.2535x1x2—13.8524x1x3:—3.37475x2x3+27.0575X21—16.3036x22—8.7678x23结果表明St(NO3)2。有明显的增产作用.x1x3的交互作用(效应)最大.通过计算机模拟.其最佳因子组合为Sr(NO3),0.1%、KH2PO40.3%和硼砂0.01%,预计产量可达296.46kg/667m2. 相似文献
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在具有K2NiF4型结构的Sm2-xSrxNiO4(x=0.4,0.5,0.6,0.8,1.0,1.2,1.4,1.5)化合物上进行了CO催化还原NO的研究。结果表明,低温、低Sr^2+取借代量与高温、高Sr^2+取代量的反应途径不同,这可从化合物的结构、化合物中金属-氧键的标准生成焓的总和、NO还原的表现活化能及化合物上O2的脱附行为等得到解释。 相似文献
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制得了二丁胺甲基膦酸-亚磷酸氢锆Zr(HPO3)2-x.(O3PCH2NBu2).H2O(x=0.8,0.6,0.5,0.4,0.35),用溴化苄季铵化,得部分季铵化产物,溴化苄基二丁铵甲基膦酸-二丁胺甲基膦酸-亚磷酸氢锆Zr(HPO3)2-x.(O3PCH2NBu2)x-y.(O3PCH2N^+Bu2.CH2Ph.Br^-).H2O(y<x),用作相转移催化剂,对液/液或固/固/液相转移催化的取 相似文献
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用水热合成出系列化合物MSn2(PO4)3(M=Na,K,NH4),该化合物具有NASICON型三维骨架结构,测得其晶胞参数为:(1)NaSn2(PO4)3,a=0.852692)nm,c=2.247(4)nm;(2)KSn2(PO4)3,a=0.8366(1)nm,c=2.356(4)nm;(3)NH4Sn2(PO4)3,a=0\8330(1)nm,c=2\390(5)nm.热分析结果表明,在较 相似文献
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用固相法合成了Pr_(2-x)Sr_xNiO_(4±δ)(0.0≤x≤1.0)系列K_2NiF_4型化合物,研究了其结构,红外光谱,电磁性质。当0.0≤x<0.1和x=1.0时以正交晶系结晶;当0.1≤x<1.0时以四方晶系结晶;Ni离子平均价态在+2至+3价之间。当x值较小时,样品中含有过量的氧。NiO_6八面体中Ni ̄(3+)的Jahn-Teller畸变引起c/a值在x=0.5处出现极大,在77~250K之间,样品磁性质符合居里-外斯定律,并表现出反铁磁相互作用。电学性质的变化可以理解为Ni ̄(3+)离子电子组态由:变至的结果 相似文献
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纳米晶材料SrMgxTi1-xO3的合成与表征 总被引:3,自引:1,他引:2
采用硬脂酸法合成纳米晶SrMgxTi1-xO3(x=0.1-0.5)材料,用DTA,TG,XRD,IR,XPS和TEM进行表征,结果表明,粉末粒径d随SrMgxTi1-xO3中镁含量、烧结温度和烧结时间的改变而变化;烧结所产生的粉末粒度分布均匀,大小适中;Mg^2+部分替SrTiO3的Ti^4+后,O的1s光谱随着Mg^2+含量的不同而发生变化。 相似文献
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采用X光光电子能谱(XPS)及曲线拟合手段对硫化态K-MoO_3/Al_2O_3合成醇催化剂进行了研究,分别考察负载量及硫化前不同条件预处理对催化剂表面的S、Mo组分的物种形式及各物种相对含量的影响,以及表面不同组分的相对组成。结果表明,根据其电子结合能变化,S组分可区分为SO_4 ̄(2-)、SO_3、S ̄0、S_2 ̄(2-)、MoS_2、MoS_(2-x)等六种存在形式不同的物种;Mo组分可区分为Mo ̄(6+)、Mo ̄(5+)、MoS_(2+x)、MOS_2、MOS_(2-x)等五种存在形式不同的物种。MoO_3/Al_2O_3.重量比为0.03的样品,Mo组分硫化还原不完全,表面S、Mo组分均以多种物种形式并存,MoO_3/Al_2O_3比增加至0.08和0.24后,表面S、Mo组分中MOS_2物种形式所占比例有所增加,样品的硫化还原也较彻底,但负载量增加至MoO_3/Al_2O_3比为0.35后,表面存在较多的S ̄(6+)物种和Mo ̄(6+)、Mo(5+)物种,同时K组分在表面富集。对MoO_3/Al_2O_3比为0.24,样品硫化前不同条件预处理的研究表明,该样品与水蒸汽接触对其表面结构影响很大,与水蒸汽接触后再硫化,其表 相似文献
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用X射线衍微法测定了由η^5-MeO2CC5H4(CO)3MoNa和〔(η^5-MeO2CC5H4)(CO)2W〕Fe-(CO)3Co(CO)3(μ3-S)的等瓣置换反应所生成的手性簇合物-〔(η^5-MeO2CC5H4)(CO)2Mo〕-〔(η^5-MeO2CC5H4)(CO)2W〕Fe(CO)3(μ3-S)的分子结构及晶体结构。晶体属P1空间群,晶胞参数a=0.87162(5)nm,b=0.8 相似文献
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D. J. Harris E. R. Lee C. S. Siegel I. R. Davison C. B. Jackson R. D. Brown 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4)
Abstract Two routes are described for the synthesis of pharmaceutical grade phospholipids at the multi-kilogram scale. 相似文献
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Mohamed E. Khalifa 《合成通讯》2020,50(17):2590-2616
Abstract Thiophenes are a highly important group of heterocycles and have been of great interest to researchers due to their various reactivities. Many synthetic strategies are used to generate functionalized thiophene derivatives. Several reactions are described, depending on the reactivity of the substituents attached to the thiophene nucleus toward different nucleophiles to yield the versatile thiophene products. Many diverse applications have been utilized for thiophenes from medicinal chemistry to material science. 相似文献
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Divergent strategy in natural product synthesis allows the comprehensive synthesis of family natural products. Efficient formulation of this idea requires the biosynthetic/biosynthesis-inspired insight toward the well-orchestrated design of a pluripotent late-stage intermediate, in concomitant with the applicability of the intermediates for versatile transformations. This digest focuses on the actual applications of those strategies in natural product synthesis with an emphasis on the recipes for the choice of the common intermediates. 相似文献
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Jakob Ewald Rasmussen Marcello Massimo Boccia John Nielsen Claude Taillefumier Sophie Faure Thomas Hjelmgaard 《Tetrahedron letters》2014
A facile and expedient route to the synthesis of arylopeptoid oligomers (N-alkylated aminomethyl benz-amides) using semi-automated microwave-assisted solid-phase synthesis is presented. The synthesis was optimized for the incorporation of side chains derived from sterically hindered or unreactive amines and both ortho- and para-substituted arylo-backbones. By utilizing this optimized protocol a complex nonameric arylopeptoid was synthesized in less than 11 h, featuring a novel alternating ortho-, meta-, and para-substituted backbone pattern and a variety of chemically diverse and challenging side chains. 相似文献
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Takaaki Matsubara Dr. Keisuke Takahashi Dr. Jun Ishihara Prof. Dr. Susumi Hatakeyama 《Angewandte Chemie (International ed. in English)》2014,53(3):757-760
The first asymmetric total synthesis of (?)‐ophiodilactone A and (?)‐ophiodilactone B, isolated from the ophiuroid (Ophiocoma scolopendrina), is reported. The key features of the synthesis include the highly stereocontrolled construction of the structurally congested γ‐lactone/δ‐lactone skeleton through an asymmetric epoxidation, diastereoselective iodolactonization, and intramolecular epoxide‐opening with a carboxylic acid, and biomimetic radical cyclization of ophiodilactone A to ophiodilactone B. 相似文献
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Donglin Fu Xuemin Rao Jinyi Xu Genzoh Tanabe Osamu Muraoka Xiaoming Wu Weijia Xie 《Tetrahedron letters》2018,59(30):2876-2879
The first total syntheses of naturally occurring cyclodepsipeptides Hikiamides A–C are described. The key linear pentapeptide precursors, prepared efficiently via Fmoc-solid-phase synthesis, were cyclized in dilute solution to provide the target Hikiamides A–C. The structures of the synthetic Hikiamides A–C were characterized by NMR and HRMS spectroscopy which were in agreement with those of natural products. 相似文献
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Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents—Synthesis of (−)‐Lardolure and Siphonarienal 下载免费PDF全文
Varvara Morozova Juri Skotnitzki Dr. Kohei Moriya Prof. Dr. Konstantin Karaghiosoff Prof. Dr. Paul Knochel 《Angewandte Chemie (International ed. in English)》2018,57(19):5516-5519
Optically enriched secondary alkyl iodides were converted into secondary alkyllithium and secondary alkylcopper compounds with very high retention of configuration. Quenching with various electrophiles, including chiral epoxides, provided a range of chiral molecules with high enantiomeric purity (>90 % ee). This method has been applied in an iterative fashion in the total synthesis of (?)‐lardolure in 13 steps and 5.4 % overall yield (>99 % ee, dr>99:1) and siphonarienal in 15 steps and 5.6 % overall yield (>99 % ee, dr>99:1) starting from commercially available ethyl (R)‐3‐hydroxybutyrate (>99 % ee). 相似文献
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Solid-phase organic synthesis is a rapidly expanding area of synthetic chemistry that is being widely exploited in the search for new medicinally important compounds using combinatorial techniques. In recent decades, a large number of reports related to solid-phase synthesis of heterocycles have appeared because of the wide variety of their biological activity. In this review, we report the important role of solid-phase synthesis in the synthesis of nitrogen containing six-membered ring heterocycles. 相似文献