配位聚合物[Mn(4,4′-bpy)_(1.5)(H_2O)_3](ClO_4)·(4,4′-bpy)(L)·H_2O的水热合成和晶体结构(英文)

The title compound, [Mn(4,4'-bpy)1.5(H2O)3](ClO4)·(4,4'-bpy)(L)·H2O(1), where L=2,4,6-trimethylbenzoic acid, was synthesized and its crystal structure was determined by X-ray diffraction analysis. The crystal is of triclinic, space group P1 with a=2.929 9(6) nm, b=1.036 4(2) nm, c=8.222 0(1) nm, α=105.300(2)°, β=97.495(2)°, γ=91.118(2)°, V=1.884 0(4) nm3, Z=2, Mr=780.10, Dc=1.375 g·cm-3, μ=0.483 mm-1, F(000)=812, R=0.055 4, wR=0.135 2. The Mn atoms are octahedrally coordinated by three N atoms of three 4,4'-bipyridine ligands and three O atoms of water. The complex shows a one-dimensional chain structure bridged by water and 4,4'-bipyridine molecules. CCDC: 615707.     

Syntheses, Characterization and Crystal Structures of Two-dimensional 4,4′-Bipyridyl Lead Halides, PbI_2(4,4′-bpy) and PbBr_2(4,4′-bpy)

IntroductionLinear bidentate N,N′- donor complexes havebeen extensively used in recent years to obtain thepolymeric frameworks with potential applicationprospects in different areas of material sciences,such as electrical conductivity[1] ,magnetism[2 ] ,photomechanical behaviour[3 ] and catalysis[4～ 6] .Among them,4,4′- bipyridine( bpy) has beenproven to be able to form one- dimensional poly-mers[7] ,two- dimensional layers[4] ,and three- di-mensional frameworks exhibiting the interpene-tra…     

[Ag(4,4′-bpy)]~+及[Zn(phen)_2(H_2O)_2]~(2+)两种配合物的合成、结构与荧光性质

用水热法和溶液法分别合成了2个新的配合物{[Ag(4,4′-bpy)]·3-HSBA.H2O}n(1)和[Zn(phen)2(H2O)2]·(A-2,5-DSA)·3H2O(2)(3-HSBA=3-羧基苯磺酸根,A-2,5-DSA=苯氨-2,5-二磺酸根,4,4′-bpy=4,4′-联吡啶,phen=1,10-邻菲咯啉),用X-射线单晶衍射结构分析方法测定了其晶体结构。配合物1是一维链状结构。在1个不对称单元中包含1个[Ag(4,4′-bpy)]+阳离子,1个3-羧基苯磺酸根阴离子和1个晶格水分子。Ag髣离子与2个4,4′-联吡啶的2个氮原子配位。配合物2是单核结构。在1个不对称单元中包含1个[Zn(phen)2(H2O)2]2+阳离子,1个苯氨-2,5-二磺酸根阴离子和3个晶格水分子。Zn髤离子与2个1,10-邻菲咯啉的4个氮原子和2个水氧原子配位。配合物1和2中,配位阳离子、抗衡阴离子以及晶格水分子之间存在丰富的氢键,进而构筑成超分子网络结构。配合物的荧光均来自于配体的π-π*电子跃迁。     

氢键构筑的新颖微孔配位聚合物[Co_2(Hisor)_2·(4,4′-bpy)_2(H_2O)_2]·4,4′-bpy的合成与结构

近年来 ,微孔配位聚合物的研究越来越引起人们的重视 .与传统的微孔材料硅酸盐、硅铝酸盐、磷铝酸盐等相比 ,微孔配位聚合物具有独特的优势 :一方面 ,可以将金属离子所特有的磁学、光学、电学和氧化 -还原等特性引入所设计合成的配位聚合物中 ;另一方面 ,有机配体的多样性、可修饰性和与各种金属离子的不同组合 ,为设计合成尺寸可控、形状可控和性质可控的各种配位聚合物提供了可能 .因此 ,微孔配位聚合物在分子磁性、分子识别、信息储存、分离、催化和非线性光学等方面有着广泛的应用前景 .于是 ,设计和合成微孔配位聚合物成为当前具有挑战…     

Synthesis and Crystal Structure of [Cu(phen)_2(SO_4)(H_2O)]·0.5C_4H_4O_4·7H_2O

1INTRODUCTION The construction of metal-organic coordination polymers based on covalent interactions[1]or supra-molecular contacts such as hydrogen-bonding and/orπ-πinteractions)[2]is now of great interest not only due to the enormous variety of intriguing structural topologies themselves,but also to their unexpected physical and chemical properties for potential prac-tical applications as functional materials.Many N-containing ligands,such as4,4?-bipyridine,2,2?-bi-pyridine and1,10-phen…     

Synthesis and Crystal Structure of a Two-dimensional Framework Supramolecular Complex [Mn(phen)(DPZDA)(H_2O)]·2H_2O

1INTRODUCTION Crystal engineering has captured the interest of re-searchers these years[1,2].Especially,supramolecular chemistry based on weak interactions(hydrogen bond,π-πstacking,C–H···O interaction,ion-πinter-action and hydrophobic interaction,et al.)is one of the most hottest studying fields[3～5].So far,in this field,intensive endeavors have been paid to the synthesis of novel functional complexes possessing catalysis,non-linear optical property,magnetism and molecular recog…     

[Cu_2(Gly-GlyO)_2(4,4′-bpy)(OH)_2]·10H_2O配合物的合成、晶体结构和分子结构研究

合成了以４，４′－ｂｐｙ为中继基、Ｇｌｙ－ＧｌｙＯ为螯环的新型双核铜配合物．经Ｘ射线单晶结构分析确定该配位化合物晶体的化学式为［（Ｈ２ＮＣＨ２ＣＯＮＨＣＨ２ＣＯＯ）Ｃｕ（ＯＨ）（Ｃ１０Ｈ８Ｎ２）Ｃｕ（ＯＨ）－（Ｈ２ＮＣＨ２ＣＯＮＨＣＨ２ＣＯＯ）］·１０Ｈ２Ｏ．晶体属三斜晶系，Ｐ１空间群，晶胞参数ａ＝０．７１２４（２）ｎｍ，ｂ＝１．１４０５（１０）ｎｍ，ｃ＝１．１４３４（１０）ｎｍ，α＝６７．５５°，β＝７９．０２°，γ＝７７．９７°，Ｖ＝０．８３４（３）ｎｍ３，Ｚ＝１．最终一致性因子Ｒ为０．０７２７．     

Syntheses and Crystal Structures of [Na(H_2O)](C_(17)H_(13)O_6SO_3)·2H_2O and [Ni(H_2O)_6](C_(17)H_(13)O_6SO_3)_2·4H_2O

Introduction Flavonoids exist widely in edible plants, and have pharmacological activity. They played a major role in the successful medical treatments at ancient times, and their uses have been persevered up to now.1-3 Flavonoid sulfates were found in a large number of plant species. They occupy an important position in the field of natu-ral products chemistry since they provide structures consisted of organic and inorganic components. The pharmacological assay revealed that flavonoid sulfat…     

Hydrothermal Synthesis, Crystal Structure and Fluorescence Property of a Novel Coordination Polymer [Eu_2(C_6H_8O_4)_3(H_2O)_2]_n·n(4,4′-bpy)

1UINTRODCTIONAtpresentthefluorescentmaterialsusedaremostlyinorganicororganicmicromolecularlumine-scentmaterialsthatareeasilyattenuatedinsunlight.Thereforepeopleintendtostudythepolymerflu-orescentmaterialscontainingrare-earthionsduetotheirgoodfluorescenthomochromepropertyandhighluminescentintensity.Inrecentyearswidestudieshavebeenperformed[1～10]tosearchforlu-minescentmaterialswithfineluminescentproper-tiesatlowprice.Asfortherare-earthcoordinationpolymer,agreatnumberofinvestigationsaremain…     

Syntheses, Characterization and Crystal Structures of Two-dimensional 4,4＇-Bipyridyl Lead Halides, PbI2 （4,4＇-bpy） and PbBr2 （4,4＇-bpy）

Two-dimensional 4,4-bipyridyllead halides, Pbl2 (4,4‘-bpy) (1) and PbBr2 ( 4,4‘-bpy ) (2), were synthesized. The structures were determined by means of X-ray single crystal diffraction. The structure shows a distorted octahedral configuration with six-coordinated central lead atoms. In crystals 1 and 2, the molecules are packed in a two-dimensional network structure through bridging halide atoms and 4,4‘-bipyridine ligands between the adjacent lead atoms.