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1.
用表面增强拉曼散射光谱(SERS)和时间分辨SERS光谱(TRSERS)等技术首次研究了烯丙基硫脲(ATU)在HClO4、H2SO4和HNO3介质中与无机阴离子在银电极上的电化学共吸附行为.提出ATU很可能以S端与银电极表面形成化学吸附键,仲氨基相对伯氨基距离表面较近,整个分子偏向烯丙基一侧倾斜吸附在表面上.ClO-4、SO2-4和NO-3等弱吸附无机阴离子均能被ATU诱导共吸附在其质子化了的仲氨基上,这3种无机阴离子被ATU诱导共吸附的强弱顺序是ClO-4>SO2-4>NO-3.被诱导共吸附的无机阴离子对ATU在电极表面的化学吸附起到稳定剂的作用,有利于ATU在电极表面形成致密的吸附层  相似文献   

2.
H2O2参与的电化学振荡反应长期以来倍受人们的关注[1,2,3],文献[1]报道了Ag电极在H2O2-HClO4水溶液中的电势振荡现象;文献[2]报道了Pt电极H2O2-H2SO4体系在控电流条件下的电势振荡,其实验的H2O2浓度范围为0.02~0....  相似文献   

3.
负载型La0.8Sr0.2CoO3燃烧催化剂的载体效应   总被引:6,自引:1,他引:5  
贾美林  沈岳年 《分子催化》2000,14(4):265-269
负载型La0.8Sr0.2CoO3/β-A)催化剂,由于钴离子在不太高的温度下易和载体γ-AI2O3作用形成CoAl2O4尖晶石或在尖晶石,因而不能有效地成为CO、HC化合物完全氧化的催化剂,采用XRD、BET、DTA、TG和二甲苯完全氧化催化活性测试等手段,研究了CoAl2O4的形成过程,可以认为这是一个放热、释氧而失重的过程,并伴有晶胞的稍微增大,若在γ-AI2O3表面涂数一层以MgAl2O4  相似文献   

4.
本文在HClO4介质中,用循环伏安法电化学制备了聚邻苯二胺修饰膜电极,探讨了该聚合膜与Ni^2+的配合及其影响因素,关对配合后的膜电极进行了电化学研究。  相似文献   

5.
本文在HClO4 介质中,用循环伏安法电化学制备了聚邻苯二胺修饰膜电极,探讨了该聚合膜与Ni2+ 的配合及其影响因素,并对配合后的膜电极进行了电化学研究。  相似文献   

6.
利用色谱微反联用技术对负载钯催化剂上甲醇、甲醛的深度氧化进行了较全面的研究。结果表明:Pd/Al2O3催化剂对甲醇氧化具有很高的转化效率和一定的深度氧化活性。以(NH4)2PdCl4为浸渍液、还原气氛下焙烧所得的0.1%Pd/γAl2O3性能最好,当进气O2/CH3OH比为6、并无CO存在时,其T50、T95分别为90℃、200℃,生成甲醛的最高转化率为17%左右。另外,反应原料气组分如O2、CO等也将严重影响Pd/γAl2O3对甲醇氧化的活性及选择性。  相似文献   

7.
以新型阴离子载体S-烷基双硫腙,制备了FeCl^-4阴离子选择性电极,研究了电极的性能,确定了亚硝酸催化氧化Fe^2+的最佳反应条件,在4mol/L NaCl-0.2mol/L HCl介质中反应50min时以尿素终止,反应生成的Fe(Ⅲ)以FeCl^-4选择电极电位法测定。间接测定NO^-2。线性范围为15-350μg/LNO^-2,检出限为8μg/L。该法应用于雪水和水样中亚硝酸根的测定,结果与光度法一致。  相似文献   

8.
低温煤焦油电解加氢性能的研究   总被引:11,自引:2,他引:9  
对电极材料、溶剂种类、支持电解质种类等的选择、低温煤焦油在间歇式卫离电解槽中,以铅板为阴极,、铂丝为阳极,以DMF=C2H3OH-H2O-Bu4NBr为电解体系,电解后可得到较争孤加氢效果,当DMF:C2H5OH=2:3(体积比),「H2O」=2.5mol/l,「Bu4NBr」=0.50mol/l,T=306K,电解电位为-2.2V,电解后的焦油中氢含量可提高0.84%,H/C原子比可增加0.15  相似文献   

9.
β—苯胺基苯丙酮在铁电极上吸附动力学的研究   总被引:2,自引:0,他引:2  
汪的华  卜宪章 《电化学》1998,4(1):37-41
用计时电流法研究了0.5mol/L H2SO4溶液中β-苯胺基苯丙酮,卤素离子在铁电极上的吸附动力学行为以及Cl^-对PAP吸,脱附速度的影响,求得了吸,脱附速度常数ka,kd和吸附自由能参数f值。结果表明,当PAP发生化学吸附时,ka比kd约大2个数量级,吸附粒子间存在吸引力。  相似文献   

10.
讨论了meso四苯基卟啉(H2TPP)吸附在AgCl溶胶表面的吸收光谱。实验表明,当pH=2.0~6.0时,H2TPP吸附于AgCl溶胶表面以卟啉二酸H4TPP2+存在;当pH=6.75~11.0时,H2TPP吸附于AgCl溶胶表面发生络合反应,生成二价银络合物Ag(Ⅱ)TPP,并且络合反应的速率随pH值的增大而加快。  相似文献   

11.
The spectral-polarization characteristics of absorption and phosphorescence of molecules of the initial form of nitro-substituted indolinospirobenzothiopyran were studied in oriented polyethylene films and in solutions with different polarity. An oscillator model of the electron transitions responsible for the formation of absorption and luminescence spectra was suggested. It was established that the principal differences in the spectral and photophysical properties of the compound studied and its oxygen-containing analog are associated with the fact that the electronegativity of the S atom is lower than that of the O atom. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1143–1146, June, 1997.  相似文献   

12.
非那雄胺能抑制5α-还原酶的活性,明显降低二氢睾酮水平,是一种治疗良性前列腺增生的有效药品。该合成工艺以甾烯酮酸为原料,将其与氯化亚砜反应,无须分离即与叔丁胺反应得17β-酰胺化合物,再氧化开环,环合,氢化,脱氢合成了非那雄胺。经元素分析、IR、1HNMR、13CNMR、MS分析表征了其结构。该法无须使用昂贵的2,2-二吡啶二硫化物和剧毒药品苯亚硒酸酐,且以乙酸铵代替氨气,降低了对设备的要求和腐蚀,更适用于工业生产。  相似文献   

13.
翟宗玺  刘树深  夏树屏 《化学学报》1990,48(10):946-950
用氧化镁氯化镁水溶液制备了8水合氯氧化镁[nMg(OH)2·MgCl2·8H2O], 并测定了其在盐酸中的溶解热, 实验结果表明, 氯氧化镁溶解热与n值呈线性关系, 根据溶解热求出5Mg(OH)2·MgCl2·8H2O和3Mg(OH)2·MgCl2·8H2O的生成热分别为-7727.1和5888.1kJ·mol^1^-。  相似文献   

14.
Two vanilloids, (5E)-8-(4-hydroxy-3-methoxyphenyl)oct-5-en-4-one (1) and 4-[3-hydroxydecyl]-2-methoxyphenol (2), isolated from the dried seeds of Grains of Paradise (Aframomum melegueta), were synthesized; the latter compound was made as the S-enantiomer and the material derived from the seeds was found to be a 1:1.7 mixture of the R and S isomers. The synthetic route used should allow the preparation of analogs having extended alkyl chains and consequently different lipophilicity, and 3, a homolog of 2, was also prepared.  相似文献   

15.

The heats of detonation of 20 simple high explosives and explosive mixtures were determined by means of an adiabatic detonation calorimeter designed by the authors. The results indicated that the performance of the instrument was reliable and the experimental data were very accurate. For explosive mixtures, there was a linear accumulative relationship between the heats of detonation of the explosive mixture and its components. Accordingly, the heats of detonation of explosive mixtures could be calculated directly from the heats of detonation of simple explosives and the characteristic heats of other components. The experiments showed that the gold or brass shell of the cylindrical charge could be substituted by a thick-walled porcelain shell, which had the advantage of cheapness.

  相似文献   

16.
Cotton cellulose was swollen in a sodium hydroxide solution and carboxymethylated by a two-bath method for different periods of time for each process. The kinetics of acid hydrolysis and the crystallinity of the swollen and carboxymethylated samples were measured. The proportion of broken bonds, rate constants for hydrolysis, and permeability of cellulose to hydrolyzing agents were calculated. The susceptibility of glycosidic linkages to acid hydrolysis was improved by carboxymethylation more than by swelling in alkali. The increased accessibility of carboxymethylcellulose to acid was regarded as a consequence of increased intra-and intercrystalline swelling and of the glycosidic bonds' weakness caused by the electron-attracting carboxymethyl group on the C-6 position.  相似文献   

17.
In this review, the research of the author in the field of colloidal systems is summarized. The factors influencing colloidal stability are systematized and analyzed. Examples are presented to illustrate the practical utilization of the theory of stability of colloids and thin films.This review was prepared on the basis of the works of the author, which were awarded the State Premium for 1991 in the field of science and technology, chemistry section.Institute of Physical Chemistry, Russian Academy of Sciences, 117915 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 8, pp. 1708–1717, August, 1992.  相似文献   

18.
Main hydration products of two cement pastes, i.e. CSH-gel, portlandite (P) (and specific surface S) were studied by static heating, and by SEM, TEM and XRD, as a function of cement strength (C-33 and C-43) hydration time (th) and subsequent hydration in water vapour.Total change in mass on hydration and air drying, Mo, increased with strength of cement paste and with hydration time. Content of water escaping at 110 to 220°C, defined as water bound with low energy, mainly interlayer and hydrate water, was independent on cement strength but its content increased with (th). Content of chemically bound (zeolitic) water in CSH-gel, escaping at 220-400°C, was slightly dependent on strength and increased with (th). It was possibly derived from the dehydroxylation of CSH-gel and AFm phase. Portlandite water, escaping at 400-500°C, was independent on cement strength and was higher on longer hydration. Large P crystals were formed in the weaker cement paste C-33. Smaller crystals were formed in C-43 but they increased with (th). Carbonate formated on contact with air (calcite, vaterite and aragonite), decomposed in cement at 600-700oC. It was high in pastes C-33(1 month) and C-43(1 month), i.e. 5.7 and 3.3%, respectively; it was less than 1% after 6 hydration months (low sensitivity to carbonation) in agreement with the XRD study showing carbonates in the air dry paste (1month), and its absence on prolonged hydration (6 months) and on acetone treatment. Water vapour treatment of (6 months) pastes or wetting-drying increased this sensitivity.Nanosized P-crystals, detected by TEM, could contribute to the cement strength; carbonate was observed on the rims of gel clusters.This revised version was published online in November 2005 with corrections to the Cover Date.  相似文献   

19.
20.
The aim of the presented work was the investigation of thermal oxidation of ilmenite in static air atmosphere. The investigations were carried out by use of a derivatograph (MOM, Hungary). The changes of crystallographic structure of investigated samples were identified by X-ray diffractometry on Philips PW-1710 diffractometer. In temperature above 500°C appears structure of hematite Fe2O3. On the basis of the thermogravimetric measurements, the contracting area and contracting volume models were found as the best fitting experimental data. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

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