共查询到10条相似文献,搜索用时 46 毫秒
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建立了电感耦合等离子体光谱测定镍基高温合金中硅、锰、磷元素的方法,优化了试样前处理方法,对前处理所用酸的酸度进行不同比例试验,确定了仪器测量条件及分析谱线.在一定浓度范围内,各元素的浓度与谱线强度呈线性关系,相关系数大于0.9999.加标回收率为93.3%~106.7%,测定结果的相对标准偏差小于3.0%(n=10).... 相似文献
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《Journal of Coordination Chemistry》2012,65(2-3):207-215
Abstract A new manganese(III) complex [HimH][Mn(sal)2(imH)2]CH3OH (sal = salicylate, C7H4O3 2-; imH = imidazole, C3H4N2; [HimH]+ = imidazole cation (C3H5N2) has been prepared and characterized by X-ray analysis and magnetic measurements. The compound crystallizes in the monoclinic space group P2 1 with a = 9.931(2), b = 10.237(1), c = 12.926(7) Å, β = 102.740° and Z = 2. The structure has been refined to R = 0.030 and Rw = 0.031. The Mn(III) ion has elongated octahedral coordination with mutually trans imidazoles occupying axial sites. The equatorial plane is defined by four O atoms of two salicylates. Each [HimH]+ cation (imidazolium) is associated with two complex anions through hydrogen bonds as an imidazolium bridge. The variable temperature magnetic susceptibility for the complex in the temperature range 77-300 K has been interpreted in terms of a single-ion zero-field splitting model with a molecular field term correction. The values obtained for D, g. and zj' are -6.93 cm?1, 2.00 and -0.90 cm?1. 相似文献
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Sang Y.-L. Lin X.-S. Zou L.-F. Jin R.-F. Zhang X.-H. Liu Y.-H. 《Journal of Structural Chemistry》2022,63(6):956-963
Journal of Structural Chemistry - Two mononuclear nickel(II) complexes, [Ni(L1)2] (1) and [Ni(L2)2] (2), where L1 and L2 are the anions of 4-methylbenzoic acid (1-pyridin-2-ylmethylidene)hydrazide... 相似文献
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鲍根德 《中国科学B辑(英文版)》1989,(7)
Study shows that the reduction of iron (Fe~(3+)) and manganese (Mn~(4+)) in modern sedi-ments and the diffusive flux of the Mn~(2+) from the pore water into the overlying waterare mainly controlled by bacteria, and the distribution of the bacteria is believed to beaffected strongly by the sedimentary environment. It is the diffusive fluxes between Fe~(2+)and Mn~(2+) that lead to the separation of iron and manganese in the modern sediment at theChangjiang Mouth and near the shore. The level of the separation decreases with theincrease of the overlying water salinity and increases from the surface to the depth. Thismechanism has given a new explanation why manganese is concentrated in sediments onthe oceanic floor of ferromanganese-rich nodules. 相似文献
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SAPO-5分子筛中硅的取代及其性能研究 总被引:3,自引:1,他引:3
本文采用三乙胺为模板剂,用水热法合成不同含硅量的SAPO-5分子筛,并用X射线衍射、扫描电镜、电子探针分析、真空重量吸附等方法对其进行了表征,结果表明硅已进入了骨架,硅同晶非等比取代磷和铝,并且分子筛的孔道是畅通的。 用微型反应器测定了AlPO4-5及不同量硅取代的SAPO-5分子筛上的异丙苯裂解和邻二甲苯异构化催化反应,结果表明Si引入了催化活性很低的磷酸铝骨架后使其催化活性明显增加,进一步证实了硅是同晶非等比取代磷和铝,因而使分子筛骨架带负电性。 硅进入磷酸铝分子筛骨架的SAPO-5分子筛经红外光谱实验发现不仅具有表面羟基,而且都是酸性羟基。吸附吡啶后的红外光谱结果表明SAPO-5上同时存在B酸和L酸中心,B酸中心数目随着硅含量的增加而增加。 相似文献
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