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壳聚糖在二氯乙酸中的溶致液晶性 总被引:6,自引:0,他引:6
制备了不同脱乙酰度和分子量在1-3 ~15-1 ×105 范围内的壳聚糖样品,并用傅里叶变换红外光谱法(FTIR)和粘度法进行了表征.借助偏光显微镜研究了不同壳聚糖样品在二氯乙酸中的液晶相转变和液晶状态.实验结果表明,分子量在105 ~106 范围内的增大使壳聚糖形成液晶相的临界浓度( C* ) 略有降低;脱乙酰度在70 ~90 % 范围内,对C* 的影响基本可以忽略.临界浓度的实验值与根据Khokhlov Semenov Odijk 理论预示的值比较一致,说明蠕虫链模型可以很好地描述壳聚糖分子链在二氯乙酸中的溶致液晶行为. 相似文献
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在PH4.50的0.05mol/LHAc-NaAc介质中,研究了钼(Ⅵ)-邻菲络啉的极谱行为。钼(Ⅵ)-邻菲络啉配合物在2.5次分极谱仪上于-0.50V,-0.67V处产生两个吸附还原波,后者的峰峰值epp与钼(Ⅵ)浓度在2.0*10^-8-8.0*10^-6mol/L范围内呈线性关系。 相似文献
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蒙脱土修饰电极上某些神经递质的电化学行为 总被引:7,自引:0,他引:7
采用不同电化学方法对神经递质多巴胺(DA)在蒙脱土修饰电极上的行为进行了研究,结果发现,蒙脱土修饰膜地DA有明显的富集作用。在PH7.4时,DA强烈地富集在蒙脱土膜内,并显示完成的伏安响应而抗坏血酸(AA)和DAR的代谢产物3,4-二羟基苯乙酸(DOPAC)则无任何响应。采用计时库仑法测定了DA在蒙脱土膜内的表观扩散系数为2.3×10^-9cm^2/s,并计算了异相速率常数为2.7×10^-6cm 相似文献
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用示波极谱研究了溶血素的溶血活性,在1/15molLNaHPO4-1.15mol.LKH2PO(pH=7.4)底液中活性溶血素有一灵敏的极谱阴极波,峰电位为-1.82V,峰高与溶血素活性在6.0*10^-6-5。3*10^-5unit.mL和5.3*10^-5-2。0*10^-3unit/mL范围内呈线性关系,根据不同药物对抗血清中溶血清形成的不同影响,建立了极谱法筛选免疫药物的新方法。本法简单, 相似文献
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催化褪色光度法测定痕量钴的研究 总被引:15,自引:2,他引:15
研究了在PH10.5的Na2B4O7-NaOH介质中,痕量钴(Ⅱ)对过氧化氢氧化桑色素初色反应的催化作用,建立了催化动力学光度法测定痕量钴的新方法。方法的线性范围为0-1.2μ/mL检出限为4.4*10^-18g/L。用于水和维生素B12中钴的测定,结果满意。 相似文献
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用鲁米诺-双氧水-铬(Ⅲ)化学发光体系结合巯基棉对As(Ⅲ)的富集分离,建立了快速的测定化探样品中痕量砷的新方法,检测线性范围为1.0*10^-4-1.0*10^1mg/L,检出限为3.4*10^-5mg/L。用于实际化探样吕测定,相对标准偏差为5.5^-9.0%。 相似文献
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HEPT类化合物的QSAR研究 总被引:3,自引:0,他引:3
为定量结构/活性相关性研究提取了量子化学参数,拓扑指数Am,分子连接性指数^mxt及疏水性常数,同时应用正交变换和最佳变量子集算法(Leaps-and-Bonds)进行了变量压缩和选择,进而实施了多元回归分析,并由此结果进行了HEPT类化合物(1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)-thymine derivatives)的结构/活性关系的理论解释,进行了人工神经网络法对于该类化合物的活性预测,其结构明显好于多元回归法。 相似文献
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Emma Hocker 《Macromolecular Symposia》2006,238(1):16-21
Sweden's famous warship, Vasa, sank on her maiden voyage in August 1628, and remained on the bottom of Stockholm harbour for 333 years. Raised in 1961, she became the first large-scale wooden object to be treated with polyethylene glycol (PEG). In the summer of 2000 a number of acidic salt precipitations were noticed on the surface of the ship and on wooden artefacts in the storerooms. An international research project has been established to look into the causes of this problem and suggest possible re-treatments. Meanwhile projects are underway to monitor movements in the ship, to build a better support system, and to replace the thousands of iron bolts holding the structure together, while a sophisticated new climate system has recently been installed in the museum. 相似文献
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通过在LS55型荧光-磷光-发光分光光度计上加装液滴产生及调节附件,采用计算机采集与分析处理数据,成功地研制了双通道液滴光化学传感装置.利用葡聚糖凝胶对复合维生素B中不同组分的选择性吸附来达到分离与同时检测的目的,并将其用于复合维生素B药片的分析,取得了满意的结果. 相似文献
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《Physics and Chemistry of Liquids》2012,50(5):671-677
Similarity of the extrusion curves of non-wetting liquid in a nanoporous medium with different initial fill volume fractions is observed experimentally. The similarity can be explained by the scaling of the interface energy and the self-similarity of the infinite percolation cluster of fluid-filled pores. Understanding the physical processes leading to the observed phenomena is a foundation for the development of high-performance devices for damping and energy storage on the basis of such heterogeneous systems. 相似文献
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David Briers Lieven De Cremer Guy Koeckelberghs Stijn Foerier Thierry Verbiest Celest Samyn 《Macromolecular rapid communications》2007,28(8):942-947
A new chromophore, C1 , based on a similar DπA‐structure as in the FTC ‐chromophore but with a hydroxyalkyl spacer perpendicular to the direction of the dipole moment was synthesized. Both chromophores and the CLD ‐chromophore were used to prepare high Tg nonlinear optical vinyl polymers. The influence of the position of the spacer on the DπA‐system on the NLO response of the resulting polymers was investigated.
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The content of the fine and ultrafine particles in the raw material results in difficulty of the separation, the loss of the valuable components and ecological contamination. Secondary using of the fine particles is impossible without their granulation. This problem has been solved by the agglomeration-in-liquid method.An agglomeration-in-liquid method is a process to produce agglomerates in a liquid phase from solid particles suspended in the liquid. The surface of solid particles and the binding liquid must be of identical polarity, but the continuous phase must be of the opposite polarity. The water solutions of the surfactant are the binding liquids or the organic liquids. 相似文献
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A. D. Alexadrov 《Colloid and polymer science》1994,272(2):181-183
The dependence of the critical supersaturation on the degree of the initial undersaturation has been analyzed in detail.This dependence is explained by means of the Richarch-Powell equation, taking into account the dependence of the -ratio upon the partial pressures of the inert gas and the liquid under investigation. 相似文献
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Bjørn Voigt 《Theoretical chemistry accounts》1973,31(4):289-295
A series of approximate LCAO-SCF methods intermediate between the INDO and the NDDO schemes is proposed. The suggestion is based upon the decomposition of integrals in multipole-multipole type interactions. 相似文献