共查询到20条相似文献,搜索用时 32 毫秒
1.
Dong Zhou Anastasia Tkacheva Xiao Tang Bing Sun Devaraj Shanmukaraj Peng Li Fan Zhang Michel Armand Guoxiu Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(18):6062-6067
The low Coulombic efficiency and serious safety issues resulting from uncontrollable dendrite growth have severely impeded the practical applications of lithium (Li) metal anodes. Herein we report a stable quasi‐solid‐state Li metal battery by employing a hierarchical multifunctional polymer electrolyte (HMPE). This hybrid electrolyte was fabricated via in situ copolymerizing lithium 1‐[3‐(methacryloyloxy)propylsulfonyl]‐1‐(trifluoromethanesulfonyl)imide (LiMTFSI) and pentaerythritol tetraacrylate (PETEA) monomers in traditional liquid electrolyte, which is absorbed in a poly(3,3‐dimethylacrylic acid lithium) (PDAALi)‐coated glass fiber membrane. The well‐designed HMPE simultaneously exhibits high ionic conductivity (2.24×10?3 S cm?1 at 25 °C), near‐single ion conducting behavior (Li ion transference number of 0.75), good mechanical strength and remarkable suppression for Li dendrite growth. More intriguingly, the cation permselective HMPE efficiently prevents the migration of negatively charged iodine (I) species, which provides the as‐developed Li‐I batteries with high capacity and long cycling stability. 相似文献
2.
R. Blanga M. Goor L. Burstein Yu. Rosenberg A. Gladkich D. Logvinuk I. Shechtman D. Golodnitsky 《Journal of Solid State Electrochemistry》2016,20(12):3393-3404
Composite Li10SnP2S12 (LSPS)/polyethylene oxide (PEO) films, containing 25 to 50 % polymer, were electrophoretically deposited from acetone-based suspension and tested as possible candidates for polysulfide barriers in Li/S batteries. It was found by XRD and XPS tests that saturation of composite films by LiI salt, followed by prolonged annealing at 90 °C, diminishes the crystallinity of neat LSPS and results in the formation of a novel composite Li10+xIxSnP2S12 (LISPS)/P(EO)3/LiI solid electrolyte (x < 1). The high room-temperature ion conductivity of amorphous sulfide Li10+xIxSnP2S12 (0.1–0.3 mS cm?1) is restricted by slow ion transport via the polymer electrolyte (PE) imbedded in ceramics and grain boundaries between the PE and sulfide. Increase in polymer content and temperature improves total ion transport in the LISPS/PEO system. Conformal EPD coating of sulfur and lithium sulfide cathodes by the developed composite electrolyte increased the reversible capacity and Faradaic efficiency of the Li/S and Li/Li2S cells and enabled their operation at 60 °C. 相似文献
3.
Polymer electrolytes that have been developed for battery applications fall into two general classes, neat or “pure” polymer and plasticized or gel in which the polymer is combined with a conducting organic electrolyte. The polyethylene oxide (PEO) and its modifications are typical of the “pure” polymer electrolytes. They have poor conductivity at room temperatures, but at elevated temperatures, their conductivity is of the order of 10−3 to 10−4 S/cm. The PEO electrolytes have found application in the high temperature (>60°C) lithium metal anode battery systems. The high temperature necessary for good operation makes them unsuitable for use in small consumer appliances. The polymer electrolyte battery development activities have resulted in several high performance battery systems now just entering the market. Not all of the developments have resulted in commercial cell production. The commercialization activities of high performance lithium‐ion (Li‐Ion) batteries have been based on two general plastic polymer systems: poly‐vinylidene difluoride‐hexafluoropropylene copolymer (PVdF‐HFP) and polyacrylates. The polymer cells are expected to have advantages in manufacturing, flexibility, thin cell formats and lightweight packaging. Important parameters in PVdF gel electrolyte performance include the electrolyte type (combination of organic carbonates), temperature, and HFP copolymer content. Li‐Ion coin cells fabricated with a polyolefin separator with either liquid electrolyte or with the PVdF gel polymer electrolyte have equivalent performance. 相似文献
4.
Salt‐containing membranes based on polymethacrylates having poly(ethylene carbonate‐co‐ethylene oxide) side chains, as well as their blends with poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP), have been studied. Self‐supportive ion conductive membranes were prepared by casting films of methacrylate functional poly(ethylene carbonate‐co‐ethylene oxide) macromonomers containing lithium bis(trifluorosulfonyl)imide (LiTFSI) salt, followed by irradiation with UV‐light to polymerize the methacrylate units in situ. Homogenous electrolyte membranes based on the polymerized macromonomers showed a conductivity of 6.3 × 10?6 S cm?1 at 20 °C. The preparation of polymer blends, by the addition of PVDF‐HFP to the electrolytes, was found to greatly improve the mechanical properties. However, the addition led to an increase of the glass transition temperature (Tg) of the ion conductive phase by ~5 °C. The conductivity of the blend membranes was thus lower in relation to the corresponding homogeneous polymer electrolytes, and 2.5 × 10?6 S cm?1 was recorded for a membrane containing 10 wt % PVDF‐HFP at 20 °C. Increasing the salt concentration in the blend membranes was found to increase the Tg of the ion conductive component and decrease the propensity for the crystallization of the PVDF‐HFP component. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 79–90, 2007 相似文献
5.
Yutao Li Henghui Xu Po‐Hsiu Chien Nan Wu Sen Xin Leigang Xue Kyusung Park Yan‐Yan Hu John B. Goodenough 《Angewandte Chemie (International ed. in English)》2018,57(28):8587-8591
Solid‐oxide Li+ electrolytes of a rechargeable cell are generally sensitive to moisture in the air as H+ exchanges for the mobile Li+ of the electrolyte and forms insulating surface phases at the electrolyte interfaces and in the grain boundaries of a polycrystalline membrane. These surface phases dominate the total interfacial resistance of a conventional rechargeable cell with a solid–electrolyte separator. We report a new perovskite Li+ solid electrolyte, Li0.38Sr0.44Ta0.7Hf0.3O2.95F0.05, with a lithium‐ion conductivity of σLi=4.8×10?4 S cm?1 at 25 °C that does not react with water having 3≤pH≤14. The solid electrolyte with a thin Li+‐conducting polymer on its surface to prevent reduction of Ta5+ is wet by metallic lithium and provides low‐impedance dendrite‐free plating/stripping of a lithium anode. It is also stable upon contact with a composite polymer cathode. With this solid electrolyte, we demonstrate excellent cycling performance of an all‐solid‐state Li/LiFePO4 cell, a Li‐S cell with a polymer‐gel cathode, and a supercapacitor. 相似文献
6.
Shengjie Zhang Junhao Li Ningyi Jiang Xuqiu Li Sivakumar Pasupath Yanxiong Fang Quanbing Liu Dai Dang 《化学:亚洲杂志》2019,14(16):2810-2814
It is a very urgent and important task to improve the safety and high‐temperature performance of lithium/lithium‐ion batteries (LIBs). Here, a novel ionic liquid, 1‐(2‐ethoxyethyl)‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (PYR1(2o2)TFSI), was designed and synthesized, and then mixed with dimethyl carbonate (DMC) as appropriate solvent and LiTFSI lithium salt to produce an electrolyte with high ionic conductivity for safe LIBs. Various characterizations and tests show that the highly flexible ether group could markedly reduce the viscosity and provide coordination sites for Li‐ion, and the DMC could reduce the viscosity and effectively enhance the Li‐ion transport rate and transference number. The electrolyte exhibits excellent electrochemical performance in Li/LiFeO4 cells at room temperature as well as at a high temperature of 60 °C. More importantly, with the addition of DMC, the IL‐based electrolyte remains nonflammable and appropriate DMC can effectively inhibit the growth of lithium dendrites. Our present work may provide an attractive and promising strategy for high performance and safety of both lithium and lithium‐ion batteries. 相似文献
7.
Chih‐Hao Tsao Mitsuru Ueda Ping‐Lin Kuo 《Journal of polymer science. Part A, Polymer chemistry》2016,54(3):352-358
A new method to prepare the polymer electrolytes for lithium‐ion batteries is proposed. The polymer electrolytes were prepared by reacting poly(phosphazene)s (MEEPP) having 2‐(2‐methoxyethoxy)ethoxy and 2‐(phenoxy)ethoxy units with 2,4,6‐tris[bis(methoxymethyl)amino]‐1,3,5‐triazine (CYMEL) as a cross‐linking agent. This method is simple and reliable for controlling the cross‐linking extent, thereby providing a straightforward way to produce a flexible polymer electrolyte membrane. The 6 mol % cross‐linked polymer electrolyte (ethylene oxide unit (EO)/Li = 24:1) exhibited a maximum ionic conductivity of 5.36 × 10?5 S cm?1 at 100 °C. The 7Li linewidths of solid‐state static NMR showed that the ionic conductivity was strongly related to polymer segment motion. Moreover, the electrochemical stability of the MEEPP polymer electrolytes increased with an increasing extent of cross‐linking, the highest oxidation voltage of which reached as high as 7.0 V. Moreover, phenoxy‐containing polyphosphazenes are very useful model polymers to study the relationship between the polymer flexibility; that is, the cross‐linking extent and the mobility of metal ions. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 352–358 相似文献
8.
Hsien‐Wei Chen Chun‐Yi Chiu Feng‐Chih Chang 《Journal of Polymer Science.Polymer Physics》2002,40(13):1342-1353
This study demonstrates that adding clay that was organically modified by dimethyldioctadecylammonium chloride (DDAC) and d2000 surfactants increases the ionic conductivity of polymeric electrolyte. A.C. impedance, differential scanning calorimetric (DSC), and Fourier transform infrared (FTIR) studies revealed that the silicate layers strongly interact with the dopant salt lithium perchlorate (LiClO4) within a poly(ethylene oxide) (PEO)/clay/LiClO4 system. DSC characterization verified that the addition of a small amount of the organic clay reduces the glass‐transition temperature of PEO as a result of the interaction between the negative charge in the clay and the lithium cation. Additionally, the strength of such a specific interaction depends on the extent of PEO intercalation. With respect to the interaction between the silicate layer and the lithium cation, three types of complexes are assumed. In complex I, lithium cation is distributed within the PEO phase. In complex II, lithium cation resides in an PEO/exfoliated‐clay environment. In complex III, the lithium cation is located in PEO/agglomerated‐clay domains. More clay favors complex III over complexes II and I, reducing the interaction between the silicate layers and the lithium cations because of strong self‐aggregation among the silicate layers. Notably, the (PEO)8LiClO4/DDAC‐modified clay (DDAC‐mClay) composition can form a nanocomposite electrolyte with high ionic conductivity (8 × 10?5 S/cm) at room temperature. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 1342–1353, 2002 相似文献
9.
Zhuoran Ao Prof. Youlan Zou Haiyan Zou Yuxing Huang Nantao Chen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(34):e202200543
Despite the high specific capacity of Li−S battery, shuttle effect of lithium polysulfides (LiPSs) and safety issue pose a great challenge to realize its commercial application. Replacing liquid electrolyte with poly (ethylene oxide) (PEO) -based solid-state electrolyte is considered as a promising method to boost the safety, but the shuttle effect of LiPSs cannot be completely eliminated. In this work, a new kind of double-layer PEO-based polymer electrolyte is designed to restrict the LiPSs. The layer next to cathode consists of PEO and poly(vinylpyrrolidone) (PVP). The other layer consists of PEO. PVP with abundant of amide groups has been proved to have strong affinity to LiPSs. The strong interaction between LiPSs and carbonyl groups in amide is verified by Attenuated Total Reflection-Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy tests. As a result, the assembled Li−S battery exhibits a specific capacity of 1100 mAh g−1 and capacity retention of 347 mAh g−1 after 200 cycles at 60 °C and 0.05 C, while the capacity retention of the battery without PVP-blended PEO electrolyte remains only 27 % at the same conditions. 相似文献
10.
Huijun Yang Cheng Guo Jiahang Chen Ahmad Naveed Jun Yang Yanna Nuli Jiulin Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(3):801-805
Safety concerns pose a significant challenge for the large‐scale employment of lithium–sulfur batteries. Extremely flammable conventional electrolytes and dendritic lithium deposition cause severe safety issues. Now, an intrinsic flame‐retardant (IFR) electrolyte is presented consisting of 1.1 m lithium bis(fluorosulfonyl)imide in a solvent mixture of flame‐retardant triethyl phosphate and high flashpoint solvent 1,1,2,2‐tetrafluoroethyl‐2,2,3,3‐tetrafluoropropyl (1:3, v/v) for safe lithium–sulfur (Li?S) batteries. This electrolyte exhibits favorable flame‐retardant properties and high reversibility of the lithium metal anode (Coulombic efficiency >99 %). This IFR electrolyte enables stable lithium plating/stripping behavior with micro‐sized and dense‐packing lithium deposition at high temperatures. When coupled with a sulfurized pyrolyzed poly(acrylonitrile) cathode, Li?S batteries deliver a high composite capacity (840.1 mAh g?1) and high sulfur utilization of 95.6 %. 相似文献
11.
A 3D Nanostructured Hydrogel‐Framework‐Derived High‐Performance Composite Polymer Lithium‐Ion Electrolyte 下载免费PDF全文
Jiwoong Bae Dr. Yutao Li Dr. Jun Zhang Xingyi Zhou Dr. Fei Zhao Dr. Ye Shi Prof. John B. Goodenough Prof. Guihua Yu 《Angewandte Chemie (International ed. in English)》2018,57(8):2096-2100
Solid‐state electrolytes have emerged as a promising alternative to existing liquid electrolytes for next generation Li‐ion batteries for better safety and stability. Of various types of solid electrolytes, composite polymer electrolytes exhibit acceptable Li‐ion conductivity due to the interaction between nanofillers and polymer. Nevertheless, the agglomeration of nanofillers at high concentration has been a major obstacle for improving Li‐ion conductivity. In this study, we designed a three‐dimensional (3D) nanostructured hydrogel‐derived Li0.35La0.55TiO3 (LLTO) framework, which was used as a 3D nanofiller for high‐performance composite polymer Li‐ion electrolyte. The systematic percolation study revealed that the pre‐percolating structure of LLTO framework improved Li‐ion conductivity to 8.8×10?5 S cm?1 at room temperature. 相似文献
12.
Paula C. Barbosa Luísa C. Rodrigues Maria Manuela Silva Michael J. Smith Prudência B. Valente Alexandra Gonçalves Elvira Fortunato 《先进技术聚合物》2011,22(12):1753-1759
Solid polymer electrolyte (SPE) systems based on interpenetrating blends of poly(ethylene oxide‐co‐propylene oxide) and poly(methyl methacrylate) host matrices, with lithium perchlorate as guest salt, were prepared. These electrolytes were presented as free‐standing films, and their thermal and electrochemical properties were characterized by conductivity and electrochemical stability measurements. The properties of the interpenetrating blends of poly(ethylene oxide‐co‐propylene oxide) and poly(methyl methacrylate) host matrices as the electrolyte component of a solid‐state electrochromic device are reported and the results obtained suggest that this electrolyte provides an encouraging performance in this application. The most conducting electrolyte composition of this SPE system is the formulation designated as SPE2‐0PC (5.01 × 10?4 S cm?1 at about 57°C). The lowest decomposition temperature was registered with the SPE6‐15PC composition (233°C). The average transmittance in the visible region of the spectrum was above 41% for all the samples analyzed. After coloration the device assembled with 71 wt% PC presented an average transmittance of 15.71% and an optical density at 550 nm of 0.61. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
13.
Silicone‐urethane membranes for lithium batteries. Part 1. Moisture‐cured poly(siloxane‐urethane‐urea) elastomers containing polyethylene oxide (PEO) segments – synthesis and characterization as potential membrane materials 下载免费PDF全文
Poly(siloxane‐urethane‐urea) elastomers containing both polysiloxane and polyethylene oxide (PEO) segments in the polymer chain were obtained by moisture‐curing of NCO‐terminated poly(siloxane‐urethane) prepolymers synthesized from isophorone diisocyanate and mixtures of polyoxyethylene diols and polysiloxane diols with various molecular weights. Mechanical properties of the moisture‐cured films and their swelling ability in solvent mixtures commonly used in lithium batteries were investigated, and it was found that they were greatly influenced by PEO content in the polymer. PEO content in the polymer was also found to affect very much the electric conductivity of the films after immersion in lithium salt solution in ethylene carbonate–dimethyl carbonate solvent mixture. At high contents of PEO in the polymer chain specific conductivities of the films in a range of 10?3, Scm?1 could be achieved at room temperature. Based on the results of Scanning Electron Microscopy with X‐ray Analysis (SEM/EDS) investigations and wide‐angle X‐ray scattering and small‐angle X‐ray scattering studies, it could be anticipated that the reason for good conductivity of the films might be their specific supramolecular structure that potentially facilitated lithium ion mobility. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
14.
Jin Wang Gang Huang Kai Chen Xin‐Bo Zhang 《Angewandte Chemie (International ed. in English)》2020,59(24):9382-9387
The limited triple‐phase boundaries (TPBs) in solid‐state cathodes (SSCs) and high resistance imposed by solid electrolytes (SEs) make the achievement of high‐performance all‐solid‐state lithium‐oxygen (ASS Li‐O2) batteries a challenge. Herein, an adjustable‐porosity plastic crystal electrolyte (PCE) has been fabricated by employing a thermally induced phase separation (TIPS) technique to overcome the above tricky issues. The SSC produced through the in‐situ introduction of the porous PCE on the surface of the active material, facilitates the simultaneous transfer of Li+/e?, as well as ensures fast flow of O2, forming continuous and abundant TPBs. The high Li+ conductivity, softness, and adhesion of the dense PCE significantly reduce the battery resistance to 115 Ω. As a result, the ASS Li‐O2 battery based on this adjustable‐porosity PCE exhibits superior performances with high specific capacity (5963 mAh g?1), good rate capability, and stable cycling life up to 130 cycles at 32 °C. This novel design and exciting results could open a new avenue for ASS Li‐O2 batteries. 相似文献
15.
Yan Wen Fang Lian Yan Ren Hong‐Yan Guan 《Journal of Polymer Science.Polymer Physics》2014,52(8):572-577
Polyvinyl formal (PVFM)‐based dense polymer membranes with nano‐Al2O3 doping are prepared via phase inversion method. The membranes and also their performances as gel polymer electrolytes (GPEs) for lithium ion battery are studied by field emission scanning electron microscope, X‐ray diffraction, differential scanning calorimetry, mechanical strength test, electrolyte uptake test, electrochemical impedance spectroscopy, cyclic voltammetry, and charge–discharge test. The polymer membrane with 3 wt % nano‐Al2O3 doping shows the improved mechanical strength of 12.16 MPa and electrolyte uptake of 431.25% compared with 10.47 MPa and 310.59% of the undoped sample, respectively. The membrane absorbs and swells liquid electrolyte to form stable GPE with ionic conductivity of 4.92 × 10?4 S cm?1 at room temperature, which is higher than 1.77 × 10?4 S cm?1 of GPE from the undoped membrane. Moreover, the Al2O3‐modified membrane supporting GPE exhibits wide electrochemical stability window of 1.2–4.8 V (vs. Li/Li+) and good compatibility with LiFePO4 electrode, which implies Al2O3‐modified PVFM‐based GPE to be a promising candidate for lithium ion batteries. © 2014 Wiley Periodicals, Inc. J. Polym. Sci. Part B: Polym. Phys. 2014 , 52, 572–577 相似文献
16.
Ye Lin Feng Zeng‐Guo Zhao Yu‐Mei Wu Feng Chen Shi Wang Guo‐Qing 《Journal of polymer science. Part A, Polymer chemistry》2006,44(11):3650-3665
A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF3·Et2O as initiator through cationic ring‐opening polymerization. The evidence from 1H and 13C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10?5 S/cm at room temperature and 6.3 × 10?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006 相似文献
17.
Poly(acetyl ethylene oxide acrylate‐co‐vinyl acetate) (P(AEOA‐VAc)) was synthesized and used as a host for lithium perchlorate to prepare an all solid polymer electrolyte. Introduction of carbonyl groups into the copolymer increased ionic conductivity. All solid polymer electrolytes based on P(AEOA‐VAc) at 14.3 wt% VAc with 12wt% LiClO4 showed conductivity as high as 1.2 × 10?4 S cm?1 at room temperature. The temperature dependence of the ionic conductivity followed the VTF behavior, indicating that the ion transport was related to segmental movement of the polymer. FTIR was used to investigate the effect of the carbonyl group on ionic conductivity. The interaction between the lithium salt and carbonyl groups accelerated the dissociation of the lithium salt and thus resulted in a maximum ionic conductivity at a salt concentration higher than pure PAEO‐salts system. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
18.
A Sulfur Heterocyclic Quinone Cathode and a Multifunctional Binder for a High‐Performance Rechargeable Lithium‐Ion Battery 下载免费PDF全文
Dr. Ting Ma Dr. Qing Zhao Dr. Jianbin Wang Dr. Zeng Pan Prof. Jun Chen 《Angewandte Chemie (International ed. in English)》2016,55(22):6428-6432
We report a rational design of a sulfur heterocyclic quinone (dibenzo[b,i]thianthrene‐5,7,12,14‐tetraone=DTT) used as a cathode (uptake of four lithium ions to form Li4DTT) and a conductive polymer [poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)=PEDOT:PSS) used as a binder for a high‐performance rechargeable lithium‐ion battery. Because of the reduced energy level of the lowest unoccupied molecular orbital (LUMO) caused by the introduced S atoms, the initial Li‐ion intercalation potential of DTT is 2.89 V, which is 0.3 V higher than that of its carbon analog. Meanwhile, there is a noncovalent interaction between DTT and PEDOT:PSS, which remarkably suppressed the dissolution and enhanced the conductivity of DTT, thus leading to the great improvement of the electrochemical performance. The DTT cathode with the PEDOT:PSS binder displays a long‐term cycling stability (292 mAh g?1 for the first cycle, 266 mAh g?1 after 200 cycles at 0.1 C) and a high rate capability (220 mAh g?1 at 1 C). This design strategy based on a noncovalent interaction is very effective for the application of small organic molecules as the cathode of rechargeable lithium‐ion batteries. 相似文献
19.
Tomoyuki Ohta Shinji Takeoka Eishun Tsuchida Han Yu Feng Zheng Sheng Fu Yun Pu Wang 《先进技术聚合物》1992,3(8):433-436
Ion-conductive polymer which shows an ionic conductivity (σi) of 1.4 × 10?4S/cm at 25°C when mixed with LiClO4 (molar ratio in Li/OE = 0.05) was used as a separator of electrodes in a lithium secondary battery. The effect of high ionic conductivity on the performance of the battery was studied. The polymer structure was and the cathode was comprised of poly(1,3,4-thiadiazole disulfide), graphite powder and the polymer electrolyte. The cell [(?)Li/polymer electrolyte/graphite–poly(disulfide) (+)] had an open circuit voltage (Voc) of 3.25 V, a plateau voltage of 2.75 V, a discharge density (id) of 0.05 mA/cm2 with the cathode utilization of 63%, and achieved over several tens of cycles at 25°C. 相似文献
20.
Zhiming Li Jiangong Wei Feng Shan Jun Yang Xinling Wang 《Journal of Polymer Science.Polymer Physics》2008,46(7):751-758
Poly(methyl methacrylate) (PMMA) was anchored to multiporous poly(vinylidine fluoride) (PVDF) surface via electron beam preirradiation grafting technique to prepare PVDF/PMMA brushes. The conformation of the PVDF/PMMA brushes was verified through Attenuated total reflection‐Fourier transform infra red spectroscopy (ATR‐FTIR), energy dispersive X‐ray spectroscopy (EDX), and scanning electron microscopy (SEM). Thermal stability of PVDF/PMMA brushes was characterized by thermo gravimetric analysis (TGA). The degradation of PVDF/PMMA brushes showed a two‐step pattern. PVDF/PMMA brushes membrane could be used as polymer electrolyte in lithium‐ion rechargeable batteries after it was activated by uptaking 1 M LiPF6/EC‐DMC (ethylene carbonate/dimethyl carbonate; EC:DMC = 1:1 by volume) electrolyte solution. The activated membrane showed high ionic conductivity, 6.1 × 10?3 S cm?1 at room temperature, and a good electrochemical stability up to 5.0 V. The excellent performances of multiporous PVDF‐g‐PMMA membranes suggest that they are suitable for application in high‐performance lithium‐ion batteries. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 751–758, 2008 相似文献