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1.
NO和O2在Pt(110)面上吸附的TDS和PEEM研究   总被引:8,自引:1,他引:7  
采用热脱附和光电子发射普微镜研究了O2和NO在Pt(110)面上的吸附和共吸附。结果表明,室温条件下,NO在Pt(110)面上有端式和桥式两种不同的吸附方式。Pt(110)表面预吸附的原子态氧占据了NO进入了桥式吸附的活性粒,从而阻遏了NO在Pt表面发生解离反应必须经过的桥式吸附中间态的形式,进而降低了NO在Pt表面直接分散的能力。  相似文献   

2.
CuO/γ—Al2O3上NO吸附及其歧化反应的低温红外光谱研究   总被引:1,自引:0,他引:1  
伏义路 《分子催化》1998,12(2):101-106
应用原位低温红外光谱技术,研究了NO在氧化态和还原态CuO/γ-Al2O3催化剂上,从150℃到室温的吸附及其在表面上发生的反应。重点研究了歧化反应与温度的关系和歧化产物之-N2O在表面的吸附。  相似文献   

3.
利用X射线光电子能谱(XPS)和紫外光电子能谱(UPS)等表面分析方法,表征了甲酸和乙酸在ZrO2表面 的反应和吸附态。室温下,甲酸在ZrO2表面以HCOO-(a)的形态被吸附,部分HCOO-(a)进一步分解产生O~(2-)(a), HCO(a)和CH_x(a),加热有利于表面甲酸根的分解。乙酸在ZrO2表面的反应与甲酸相似。甲酸和乙酸在ZrO2表面 的吸附实质就是表面酸碱中和反应。  相似文献   

4.
NO^—2离子的光催化反应研究(Ⅱ)   总被引:1,自引:0,他引:1  
张贵彬  孙晓冬 《催化学报》1999,20(2):150-154
研究了NO^-2离子在TiO2表面的光催化反应,结果表明,体系pH值升高及Cr,Cl^-,SO^2-4离了的加入均对NO^-2离子在TiO2表面的暗态吸附产生抑制作用,而NO^-2在TiO2表面的光照反应转化率则随pH值的升高出现先减小后增大的总体变化趋势。  相似文献   

5.
应用量子化学从头算方法对NO在TiO2表面发生吸附的四种吸附模型进行了榴型优化,能量计算及Mulliken布居分析。计算结果表明,吸附模型M2-2是NO在TiO2表面发生吸附分解最为有利的模型。据此提出了NO在TiO2表面吸附分解形成N2O的可能机理,认为吸附NO发生该分解反应的反应势垒较自由NO大大降低,从而催化该反应的发生。该机理与实验的推测一致。  相似文献   

6.
李文  钟顺和 《分子催化》1994,8(3):163-172
利用红外光谱、程序升温脱附、程序升温表面反应和激光表面反应技术研究了固体NiSO_4表面上CO、H_2和C_2H_4的化学吸附性能及激光促进CO加氢合成乙烯的反应机理。实验结果表明:在硫酸镍固体表面上卧式吸附于S-O-Ni键S位和Ni位的CO是激光合成乙烯的有效吸附态;解离吸附于硫氧双键氧位上的H参与CO加氢反应;激光选择激发表面S-O键,通过能量传递和驰豫使卧式吸附态C=O键活化并与吸附态H反应生成CH_2物种和H_2O,继而邻近的CH_2结合形成产物C_2H_4。  相似文献   

7.
运用TP-FT-IR技术研究了CO、NO、NO+CO在负载型Cu-Fe-Ce-O(Ⅰ)和Cu-Fe-O(Ⅱ)催化剂上的吸附行为。研究表明,NO具有比CO更强的吸附能力,可与表面氧反应生成硝基、亚硝酸盐、硝酸盐等物种.在NO+CO反应过程中,在催化剂表面存在(CO.NO)*表面络合物(2400—2430cm ̄(-1))和NCO*(异氰酸盐)表面物种,其关系为:CO*+NO*→(CO.NO)*+*→NCO*+O*.在(Ⅱ)中加入铈,能提高CO在表面的吸附强度,使NCO*的稳定性下降,同时对NO在表面的吸附产生影响。根据研究的结果,提出了NO+CO在模型催化剂上的表面反应机理.  相似文献   

8.
魏绪明  吴凯 《分子催化》1994,8(6):437-442
用紫外光电子能谱(UPS)和俄歇电子能谱(AES)对碳氧共存的多晶铑表面及CO、O_2、C_2H_4在该表面上的吸附进行了研究,发现铑表面上共存的表面碳和表面氧存在相互作用,由于表面氧的存在,外来吸附物如CO、O_2、C_2H_4等可以覆盖在表面碳上面,使表面碳占据表面位抑制其它物种吸附的屏蔽效应消失。该表面具有氧化性,可以把吸附的乙烯氧化。  相似文献   

9.
Cu—Fe—Ce—O/γ— Al2O3催化CO+NO反应的TP—FT—IR研究   总被引:2,自引:0,他引:2  
运用TP-FT-IR技术研究了CO、NO、NO+CO在负载型Cu-Fe-Ce-O(Ⅰ)和Cu-Fe-O(Ⅱ)催化剂上的吸附行为。研究表明,NO具有比CO更强的吸附能力,可与表面氧反应生成硝基、亚硝酸盐、硝酸盐等物种。在NO+CO反应过程中,在催化剂表面存在(CO.NO)*表面络合物(2400-2430cm^-1)和NCO*(异氰酸盐)表面物种,其关系为:CO*+NO*→(CO.NO)*+*→NCO  相似文献   

10.
CO2部分氧化乙烷制乙烯Pd—Cu/MoO3—SiO2催化剂的研究   总被引:7,自引:0,他引:7  
李青  钟顺和 《应用化学》1998,15(6):49-52
用化学吸附-红外光谱、化学吸附-程序升温脱附(TPD)和微型反应技术研究了Pd-Cu/MoO3-SiO2(MoSO)催化剂对CO2和乙烷的吸附活化和部分氧化反应性能.结果表明,乙烷以C—H键中的H吸附于MoSO载体表面MoO键的端基氧上;Pd-Cu/MoSO催化剂对CO2有良好的化学吸附活化性能,CO2的吸附除有线式吸附态和剪式吸附态外,还有一种新的卧式吸附态;Pd-Cu/MoSO催化剂的晶格氧参与了化学反应.探讨了在Pd-Cu/MoSO催化剂上CO2的部分氧化乙烷反应机理  相似文献   

11.
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.  相似文献   

12.
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.  相似文献   

13.
The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.  相似文献   

14.
Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields.  相似文献   

15.
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.  相似文献   

16.
An efficient approach to the synthesis of highly congested di, penta and hexacyclic pyrazoles as well as imidazole fragment containing novel heterocyclic molecule has been developed through a carbanion induced transformation of suitably functionalized 2H-pyran-2-ones, benzo[h]chromene and thiochromeno[4,3-b]pyrans. Due to the presence of fluorescence, we report their prime application metal sensor as off/on switching in ferric ions.  相似文献   

17.
A new and simple synthesis of novel N-protected methyl 5-substituted-4-hydroxypyrrole-3-carboxylates, which exist in equilibrium with their 4-oxo tautomers, has been developed in two steps starting from N-protected α-amino acids. The key intermediates are enaminones, which can also be isolated, characterized, and used for the construction of other functionalized heterocycles, before they spontaneously decompose to pyrrole products. 4-Hydroxypyrroles are prone to partial aerial oxidation but can be efficiently alkylated or reduced to stable polysubstituted pyrrolidine derivatives.  相似文献   

18.
The chemoselectivity in the intramolecular CH insertion of various diazosulfonamides has been experimentally studied. The results reveal that the aliphatic 1,4-, 1,5-, or 1,6-C(sp3)?H insertions of diazosulfonamides are not accessible, while the aromatic 1,5-C(sp2)?H insertion can be realized specifically by adjusting the diazo-adjacent group. In addition, the general chemoselectivities in the intramolecular CH insertions of diazosulfonyl compounds are summarized. Generally, diazosulfones undergo both aromatic 1,5-C(sp2)?H and aliphatic 1,5- and 1,6-C(sp3)?H insertions, while diazosulfonates undergo aliphatic 1,5- and 1,6-C(sp3)?H insertions. However, diazosulfonamides only undergo aromatic 1,5-C(sp2)?H insertion.  相似文献   

19.
Zhanhui Yang  Shiyi Yang  Jiaxi Xu 《Tetrahedron》2017,73(23):3240-3248
Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.  相似文献   

20.
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