Photoinduced Electron Transfer between N,N,N′,N′-Tetra-(p-methylphenyl)-4,4-diamino-1,1′-diphenyl Ether (TPDAE) and Fullerenes (C_(60)/C_(70)) by Laser Flash Photolysis

Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｐｈｏｔｏｉｎｄｕｃｅｄｅｌｅｃｔｒｏｎｔｒａｎｓｆｅｒ (ＰＥＴ)ｉｓｏｎｅｏｆｔｈｅｍｏｓｔｉｎｔｅｒｅｓｔｉｎｇｆｅａｔｕｒｅｓｏｆｄｏｎｏｒ ａｃｃｅｐｔｏｒｓｙｓｔｅｍｓｆｏｒｔｈｅｄｅｓｉｇｎａｎｄｔｈｅｃｏｎｓｔｒｕｃｔｉｏｎｏｆａｒｔｉｆｉｃｉａｌｍｏｌｅｃｕｌａｒｄｅｖｉｃｅｓｆｏｒｅｎｅｒｇｙｃｏｎｖｅｒｓｉｏｎａｎｄｉｎｆｏｒｍａｔｉｏｎｐｒｏｃｅｓｓｉｎｇｗｈｉｃｈｈａｖｅａｎｕｍｂｅｒｏｆｐｏｔｅｎｔｉａｌｌｙｉｎｔｒｉｇｕｉｎｇａｐｐｌｉｃａｔ…     

Axially Dissymmetric Chiral (R)-N,N′-Bis(2-hydroxy-3,5-di-tert-butyl-arylmethyl)-1,1′-binaphthalene-2,2′-diamine as Chiral Ligands in the Reaction of Diethylzinc to Aldehydes

ＩｎｔｒｏｄｕｃｔｉｏｎＡｘｉａｌｌｙｄｉｓｓｙｍｍｅｔｒｉｃ 1,1′ ｂｉｎａｐｈｔｈｙｌａｎｄ 1,1′ ｂｉ ｐｈｅｎｙｌｌｉｇａｎｄｓｂｅａｒｉｎｇｔｗｏｉｄｅｎｔｉｃａｌｇｒｏｕｐｓｉｎｔｈｅ 2 ,2′ ｐｏｓｉｔｉｏｎｈａｖｅｐｒｏｖｅｄｔｏｂｅｒｅｍａｒｋａｂｌｙｕｓｅｆｕｌｉｎｅｎａｎｔｉｏｓｅ ｌｅｃｔｉｖｅｃａｔａｌｙｓｉｓ ,ｗｉｔｈｏｐｔｉｃａｌｙｉｅｌｄｓｃｌｏｓｅｔｏ 10 0 %ｅｎａｎ ｔｉｏｍｅｒｉｃｅｘｃｅｓｓ (ｅｅ)ｏｂｔａｉｎｅｄｉｎｓｅｖｅｒａｌｐｒｅｐａｒａｔｉｖｅｌｙｉｍ ｐ…     

Synthesis of (+) or (-)-2-(8′-Diphenylphosphino-1′-naphthyl)oxazoline Ligands and Their Application in Pd-Catalyzed Allylic Alkylation Reaction

ＩｎｔｒｏｄｕｃｔｉｏｎＷｉｔｈｔｈｅｆａｍｏｕｓＤＩＯＰｌｉｇａｎｄ ,ＫａｇａｎｉｎｔｒｏｄｕｃｅｄｔｈｅｉｍｐｏｒｔａｎｔｃｏｎｃｅｐｔｏｆＣ2 ｓｙｍｍｅｔｒｙｉｎｌｉｇａｎｄｄｅｓｉｇｎ .1Ｈｏｗｅｖｅｒ ,ｉｔｉｓｎｏｔａｌｗａｙｓｔｒｕｅｔｈａｔａＣ2 ｓｙｍｍｅｔｒｉｃｌｉｇａｎｄｓｈｏｕｌｄｎｅｃｅｓｓａｒｉｌｙｂｅｓｕｐｅｒｉｏｒｔｏａｎｏｎ ｓｙｍｍｅｔｒｉｃｃｏｕｎ ｔｅｒｐａｒｔ .Ｔｒａｎｓｉｔｉｏｎｍｅｔａｌ ｃａｔａｌｙｚｅｄａｌｌｙｌｉｃａｌｋｙｌａｔｉｏｎｖｉａｓｙｍｍｅ…     

催化酯化新进展(英)

酯化是一经典的有机合成反应,随着肽合成的进展,在此领域已做了大量的研究工作。介绍了一些新的酯化有机催化剂如： Ｎ , Ｎ ′ Ｄｉｃｙｃｌｏｈ ｅｘｙｌｃａｒｂｏｄｉｉｍ ｉｄｅ, ４ｄｉｍ ｅｔｈｙｌａｍ ｉｎ ｏｐ ｙｒｉｄｉｎ ｅ, Ｂｉｓ［４（ ２, ２ｄｉｍ ｅｔｈｙｌ１, ３ｄｉｏｘｏｌｙｌ）ｍ ｅｔｈｙ ］ ｃａｒｂｏｄｉｉｍ ｉｄｅ, ｂｅｎｚｏｔｒｉａｚｏｌｙｌ Ｎ ｏｘｙｔｒｉｓｏｉｍ ｅｔｈｙｌａｍ ｉｎｏｐｈｏｓｐｈｏｎｉｕｍ 和 ２ｅｔｈ ｏｘ ｙ１（ｅｔｈ ｏｘｙｃａｒｂｏｎｙｌ）１,２ｄｉｈｙｄｒｏｑｕ ｉｎｏｌｉｎ ｅ。参考文献 ２０ 篇。     

Synthesis and Crystal Structure of a Novel Hydrogen-Bonded Three-Dimensional Polymer [Zn(1,4-benzenedicarboxylate)-(pyridine)·H_2O]_n

ＩｎｔｒｏｄｕｃｔｉｏｎＤｅｓｉｇｎａｎｄｓｙｎｔｈｅｓｅｓｏｆｎｏｖｅｌｓｕｐｒａｍｏｌｅｃｕｌａｒｃｏｍ ｐｌｅｘｅｓｗｉｔｈｕｎｕｓｕａｌａｎｄｔａｉｌｏｒａｂｌｅｓｔｒｕｃｔｕｒｅｓａｒｅｆｕｎｄａ ｍｅｎｔａｌｓｔｅｐｓｉｎｄｉｓｃｏｖｅｒｙａｎｄｆａｂｒｉｃａｔｉｏｎｏｆｖａｒｉｏｕｓｔｅｃｈ ｎｏｌｏｇｉｃａｌｌｙｕｓｅｆｕｌｆｕｎｃｔｉｏｎａｌｓｕｐｒａｍｏｌｅｃｕｌａｒｄｅｖｉｃｅｓ .1 3Ｒｅｃｅｎｔｌｙ ,ｃｏｎｓｉｄｅｒａｂｌｅｅｆｆｏｒｔｓｈａｖｅｂｅｅｎｄｅｖｏｔｅｄｔｏｃｒ…     

New Chiral Ligand N-Toluenesulfonyl-2,2′-dimethoxy-6,6′-diaminobiphenyl for Catalytic Asymmetric Transfer Hydrogenation of Ketones

Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｏｐｔｉｃａｌｌｙａｃｔｉｖｅｓｅｃｏｎｄａｒｙａｌｃｏｈｏｌｓａｒｅｕｓｅｆｕｌｂｕｉｌｄ ｉｎｇｂｌｏｃｋｓｆｏｒｐｈａｒｍａｃｅｕｔｉｃａｌｓ ,ａｇｒｏｃｈｅｍｉｃａｌｓａｓｗｅｌｌａｓｏｔｈｅｒｍａｔｅｒｉａｌｓ .1Ａｖａｒｉｅｔｙｏｆａｓｙｍｍｅｔｒｉｃｃａｔａｌｙｔｉｃｒｅａｃ ｔｉｏｎｓｈａｖｅｂｅｅｎｄｅｖｅｌｏｐｅｄｆｏｒｐｒｅｐａｒｉｎｇｓｕｃｈｉｍｐｏｒｔａｎｔｓｅｃｏｎｄａｒｙａｌｃｏｈｏｌｓ .2 Ｉｎａｄｄｉｔｉｏｎｔｏｓｔｒａｉｇｈｔｆｏｒｗａ…     

The First Total Synthesis of 4,4′-Biisofraxidin

Ｉｎｔｒｏｄｕｃｔｉｏｎ　　 4 ,4′ Ｂｉｉｓｏｆｒａｘｉｄｉｎ (1) ,ａｎｅｗｂｉｓｃｏｕｍａｒｉｎ ,1ｗａｓｉｓｏｌａｔｅｄｂｙＷａｎｃｈａｉＤｅ Ｅｋｎａｍｋｕｌａｎｄｈｉｓｃｏ ｗｏｒｋｅｒｓｆｒｏｍｔｈｅｒｏｏｔｃｕｌｔｕｒｅｓｏｆｉｍｐａｔｉｅｎｓｂａｌｓａｍｉｎａＬ . (Ｂａｌ ｓａｍｉｎａｃｅａｅ) ,ｗｈｉｃｈｈａｓｌｏｎｇｂｅｅｎｕｓｅｄｉｎＴｈａｉｌａｎｄａｓａｔｒａｄｉｔｉｏｎａｌｆｏｌｋｍｅｄｉｃｉｎｅ .ＴｈｅｌｅａｖｅｓｏｆＢａｌｓａｍｉｎａｃｅａｅａｒｅｕｓｕａｌｌｙｕｓｅｄｆ…     

一维链状配位聚合物[Co(imbz)_2(H_2O)_2]_n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构(英文)

０ＩｎｔｒｏｄｕｃｔｉｏｎＮｕｍｅｒｏｕｓｕｎｉｑｕｅｆｒａｍｅｗｏｒｋｓｈａｖｅｂｅｅｎｒｅｐｏｒｔｅｄｂｙａｓｓｅｍｂｌｙｏｆｒａｔｉｏｎａｌｄｅｓｉｇｎｅｄｏｒｇａｎｉｃｌｉｇ-ａｎｄｓｗｉｔｈｍｅｔａｌｉｏｎｓｏｖｅｒｔｈｅｐａｓｔｄｅｃａｄｅ１～３．Ｉｔｉｓｋｎｏｗｎｔｈａｔｂｏｔｈｉｍｉｄａｚｏｌｅａｎｄｃａｒｂｏｘｙｌａｔｅａｒｅｆｕｎｃｔｉｏｎａｌｇｒｏｕｐｓｆｏｒｃｏｏｒｄｉｎａｔｉｏｎｔｏｔｒａｎｓｉｔｉｏｎｍｅｔａｌｉｏｎｓｔｏｆｏｒｍｃｏｍｐｌｅｘｅｓ４～６．Ｈｏｗｅｖｅ…     

Synthesis and Quantum Chemistry Studies of (R)-N-(Propionylthiazolidine-2-thione-4-methoxycarbonyl)germanium Sesquioxide

ＳｙｎｔｈｅｓｉｓａｎｄＱｕａｎｔｕｍＣｈｅｍｉｓｔｒｙＳｔｕｄｉｅｓｏｆ（Ｒ）┐Ｎ┐（Ｐｒｏｐｉｏｎｙｌｔｈｉａｚｏｌｉｄｉｎｅ┐２┐ｔｈｉｏｎｅ┐４┐ｍｅｔｈｏｘｙｃａｒｂｏｎｙｌ）ｇｅｒｍａｎｉｕｍＳｅｓｑｕｉｏｘｉｄｅ＊ＬＩＹｅ－ｚｈｉ＊＊，...     

Synthesis, Structure and Noncovalent Interactions of Palladium(II) Complexes with N-Benzoyl-β-phenylalaninate Dianion and Aromatic Diimine

Ｉｎｔｒｏｄｕｃｔｉｏｎ　　Ｎｏｎ ｃｏｖａｌｅｎｔｉｎｔｅｒａｃｔｉｏｎｓｈａｖｅａｂｉｇｉｎｆｌｕｅｎｃｅｏｎｔｈｅｃｏｎｆｏｒｍａｔｉｏｎａｌｏｒｇａｎｉｚａｔｉｏｎｏｆｔｈｅｂｉｏｍｏｌｅｃｕｌｅｓｗｈｉｃｈｉｓｒｅｓｐｏｎｓｉｂｌｅｆｏｒｔｈｅｒｅｇｉｏ ａｎｄｓｔｅｒｅｏ ｓｐｅｃｉｆｉｃｉｔｙｏｆｖａｒｉｏｕｓｂｉｏｌｏｇｉｃａｌｐｒｏｃｅｓｓｅｓ .1Ａｍｏｎｇｔｈｅｓｅｉｎｔｅｒａｃｔｉｏｎｓ ,ｔｈｅｉｎ ｔｒａｍｏｌｅｃｕｌａｒｓｔａｃｋｉｎｇｉｎｔｅｒａｃｔｉｏｎｂｅｔｗｅｅｎｓ…     

Crystal and Molecular Structure of Bis-N,N’(dithiodi-2,1-phennylene)benzamide

１ＩＮＴＲＯＤＵＣＴＩＯＮＢｉｓ Ｎ,Ｎ’（ｄｉｔｈｉｏｄｉ ２,１ ｐｈｅｎｎｙｌｅｎｅ）ｂｅｎｚａｍｉｄｅｈａｓｂｅｅｎｗｉｄｅｌｙｕｓｅｄｉｎｐｒｏ ｃｅｓｉｎｇｏｆｒｕｂｂｅｒａｓｐｅｐｔｉｚｅｒｆｏｒｐｒｏｄｕｃｉｎｇｆｒｅｅｒａｄｉｃａｌ...     

Syntheses and Magnetic Properties of Cu（Ⅱ）－RE（Ⅲ） Heterobinuclear Complexes with N，N′－Bis（3－carboxyisalicylidene）－trimethylenediamine

ＳｙｎｔｈｅｓｅｓａｎｄＭａｇｎｅｔｉｃＰｒｏｐｅｒｔｉｅｓｏｆＣｕ（Ⅱ）－ＲＥ（Ⅲ）ＨｅｔｅｒｏｂｉｎｕｃｌｅａｒＣｏｍｐｌｅｘｅｓｗｉｔｈＮ，Ｎ′－Ｂｉｓ（３－ｃａｒｂｏｘｙｉｓａｌｉｃｙｌｉｄｅｎｅ）－ｔｒｉｍｅｔｈｙｌｅｎｅｄｉａｍｉｎｅＴＡ...     

Synthesis and Crystal Structure of a New Praseodymium(Ⅲ)-Copper(Ⅱ) Polymeric Complex:〔Pr_2Cu_3(L~1)_6〕_n(H_2L~1=NH｛CH_2COOH｝_2)

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｓｙｎｔｈｅｓｉｓｏｆｐｏｌｙｎｕｃｌｅａｒｃｏｐｐｅｒ ｌａｎｔｈａｎｏｉｄｃｏｍｐｌｅｘｅｓｉｓｏｆｓｐｅｃｉａｌｉｎｔｅｒｅｓｔｆｏｒｓｅｖ ｅｒａｌｒｅａｓｏｎｓ〔１－４〕．Ｔｈｅｓｅｃｏｍｐｌｅｘｅｓａｒｅｉｍ...     

N,N,N′,N′-四丁基丙二酰胺萃取Yb(Ⅲ)的研究

取代酰胺类萃取剂易合成、分解产物易除去可用于萃取铀 (Ⅳ )、钍 (Ⅳ ) [1 - 4 ] ,但对高放废液中共存稀土元素的萃取研究较少[5] 。本文在以前研究工作的基础上[6] ,进一步探讨了TBMA萃取Yb(Ⅲ )的性能。1　实验部分1 1　试剂和仪器试剂均为AR级。TBMA由实验室合成 ,减压蒸馏提纯 ,经元素分析、红外光谱等检验产品为目标产物 ,纯度高于 98%。FTS 1 65红外光谱仪 (美国Bio Rad公司 ) ,75 2分光光度计 (上海分析仪器总厂 ) ,PHS 2C精密数显酸度计 (上海伟业仪器厂 ) ,恒温康氏振荡器 (实验室改装 )。1 2　实验准确称量 1 970 3g…     

N，N，N′，N′-四丁基丙二酰胺从硝酸盐介质中萃取铈(Ⅲ)

Study on the extraction and separation of rare earth with new extractants is important in the rare earth chemistry and nuclear reprocessing. In this work， the extraction of Ce(Ⅲ) with N，N，N′，N′-tetrabutylmalonamide (TBMA) in toluene from nitrate media has been investigated. The effect of the concentration of nitric acid， TBMA and salt-ing-out agent (LiNO₃) and also the temperature on the distribution ratios was examined. The stoichiometries of the extracted complexes were determined to be Ce(NO₃)₃·3TBMA and Ce(NO₃)₃·4TBMA， respectively. The ap-parent extraction constants and the enthalpy of the extraction were calculated based on the extraction data， which are logK_ex1=3.97， logK_ex2=4.75 and Δ_rH_m^?=-31.25kJ·mol^-1， respectively. The IR spectra of the loaded organic phase supported the suggested extraction mechanism.     

Synthesis and Structure of Copper(Ⅱ) Complex [Cu(C_5H_5N)_2(H_2O)(C_6H_5COO)_2]

1　ＩＮＴＲＯＤＵＣＴＩＯＮＣｅｒｔａｉｎｃｏｐｐｅｒｃｏｍｐｌｅｘｅｓｈａｖｅｂｅｅｎｓｈｏｗｎｔｏｈａｖｅｕｎｕｓｕａｌｃｈｅｍｉｃａｌｐｒｏｐｅｒｔｉｅｓｓｕｃｈａｓｏｘｙｇｅｎｔｒａｎｓｆｅｒ,ｏｘｉｄａｔｉｖｅａｄｄｉｔｉｏｎａｎｄｈｏｍｏｇｅｎｏｕｓｃａｔａｌｙｔｉｃｈｙｄｒｏｇｅｎａｔｉｏｎ[1].Ｏｘｉｄａｔｉｖｅａｄｄｉｔｉｏｎｒｅａｃｔｉｏｎｓａｒｅｋｅｙｓｔｅｐｓｉｎｔｈｅａｃｔｉｖａｔｉｏｎｏｆσｂｏｎｄｓｉｎａｇｒｅａｔｎｕｍｂｅｒｏｆｃａｔａｌｙｔｉｃｐｒｏｃｅｓｓ.Ｃｏｐ…     

Synthesis and Crystal Structure of the Derivative of β-elemene C_(20)H_(33)N·Cl_3CCOOH

１ＩＮＴＲＯＤＵＣＴＩＯＮβ ｅｌｅｍｅｎｅ,ａｓｅｓｑｕｉｔｅｒｐｅｎｏｉｄｃｏｍｐｏｕｎｄ,ｉｓａｎａｔｕｒａｌｐｒｏｄｕｃｔｉｓｏｌａｔｅｄｆｒｏｍｅｓｅｎ ｔｉａｌｏｉｌｃｏｎｔａｉｎｅｄｉｎｔｈｅｒｏｏｔａｎｄｓｔｅｍｏｆＣｈｉｎｅｓｅｈｅ...     

N,N′-二(十二烷基)乙二胺二乙酸萃取汞的研究

研究了N ,N′ 二 (十二烷基 )乙二胺二乙酸 (简写为H2 R2 Y)的氯仿溶液对汞 (Ⅱ )的萃取行为。考察了酸度、萃取剂浓度、相比及温度等因素对萃取率的影响 ;用电导法及摩尔比法测得萃合物的摩尔比为 1∶1 ;测定了新试剂H2 R2 Y对Hg2 与Fe3 、Co2 、Ni2 、Zn2 、Cr3 、Mn2 等金属离子的分离效果 ;并根据分配比与温度的关系求出了萃取反应的ΔH0 、ΔS0 、ΔG0 和lgKex值 ,该萃取反应为放热反应。     

Bis(ortho-)chelated Monoanionic Bisphosphinoaryl Ruthenium(II) Complexes: Synthesis, Characterization and Reactivity

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｉｎｔｅｒａｃｔｉｏｎｏｆｂｉｓｐｈｏｓｐｈｉｎｅｓｗｉｔｈ (ｔｒａｎｓｉｔｉｏｎ)ｍｅｔａｌｓｉｓａｆａｓｃｉｎａｔｉｎｇｆｉｅｌｄｆｒｏｍｔｈｅｃｏｏｒｄｉｎａｔｉｏｎｃｈｅｍｉｓｔ’ｓｐｏｉｎｔｏｆｖｉｅｗ .Ａｗｉｄｅａｒｒａｙｏｆｍｏｎｏ ａｎｄｍｕｌｔｉ ｍｅｔａｌｌｉｃｃｉｓ η2 Ｐ ,Ｐ′ｃｏｏｒｄｉｎａｔｅｄｃｏｍｐｌｅｘｅｓａｒｅｆｏｒｍｅｄｉｎｗｈｉｃｈａｖａｒｉｅｔｙｏｆｃｏｏｒｄｉｎａｔｉｏｎｍｏｄｅｓｉｓｅｎ ｃｏｕｎｔｅｒｅｄ .Ｔｈｅｃｈｅｌａ…     

N,N′-二(十二烷基)乙二胺二乙酸萃取分离铜

研究了N,N′-二(十二烷基)乙二胺二乙酸的氯仿溶液对铜的萃取行为,考察了初始水相酸度、萃取剂浓度及温度对Cu(Ⅱ)萃取率的影响. 结果表明,在pH≥6条件下对Cu(Ⅱ)有很高的萃取率,且在一定范围内随萃取剂浓度增大和温度升高萃取率均增大;用摩尔比法和电导法测得萃合物中Cu2+与萃取剂的摩尔比为1∶1;控制pH=6能使Cu(Ⅱ)与常见过渡金属离子Fe(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、 Zn(Ⅱ)、Mn(Ⅱ)得到分离.