Congresses,Conferences, Symposia,Meetings, and Seminars in the Field of Chemical Sciences Held in 1995–1996

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Congresses, Conferences, Symposia, Meetings, and Seminars in the Field of Chemical Sciences Held in 1995–1996     

Congresses,conferences, symposia,meetings, and seminars in the field of chemical sciences held in 1995–1996

Information

Congresses, conferences, symposia, meetings, and seminars in the field of chemical sciences held in 1995–1996     

Congresses,Conferences, Symposia,Meetings, and Seminars in the Field of Chemical Sciences held in 1995–1996

Information

Congresses, Conferences, Symposia, Meetings, and Seminars in the Field of Chemical Sciences held in 1995–1996     

Congresses,Conferences, Symposia,Meetings, and Seminars in the field of chemical sciences held in 1995–1996

Information

Congresses, Conferences, Symposia, Meetings, and Seminars in the field of chemical sciences held in 1995–1996     

Congresses,conferences, symposia,meetings, and seminars in the field of chemical sciences held in 1995–1996

Information Congresses, Conferences, Symposia, Workshops, and Seminars in the Field of Chemical Sciences Held with Participation of the Russian Academy of Sciences

II International Symposium Chromatography and spectroscopy in analysis of environmental objects and toxicology     

Permo-Triassic Magnetostratigraphy in Wulong Area, Sichuan, China

The Permo-Triassic boundary in Wulong area, Sichuan Province, South China lies in a continuous marine carbonate succession with abundant fossil records. Two well-exposed sections were sampled for magnetostratigraphic studies. The experimental results of rock magnetism reveal that the samples from the Triassic limestones contain only magnetites among which 70% are multi-domain. The ChRM direction is carried by remaining 30% of single-domain magnetite. The Permian limestone samples are dominated by single-domain to superparamagnetic magnetites with little ChRM direction due to their fine-grained texture. Nevertheless, the polarity determination is still possible based on the NRM vector changes during thermal demagnetization. A Permo-Triassic polarity profile in Wulong area is established in the paper, and a tentative correlation with other known profiles is pursued. The authors suggest that the Illawarra reversal starts at the upper part of Wujiapingian, while some normal polarity events may exist in the     

A Smart,Autocatalytic, DNAzyme Biocircuit for in Vivo,Amplified, MicroRNA Imaging

DNAzymes have been recognized as promising transducing agents for visualizing endogenous biomarkers, but their inefficient intracellular delivery and limited amplification capacity (including insufficient cofactor supply) preclude their extensive biological application. Herein, an autocatalytic DNAzyme (ACD) biocircuit is constructed for amplified microRNA imaging in vivo based on a hybridization chain reaction (HCR) and DNAzyme biocatalysis, sustained by a honeycomb MnO₂ nanosponge (hMNS). The hMNS not only delivers DNA probes, but also supplies Mn²⁺ as a DNAzyme cofactor and magnetic resonance imaging (MRI) agent. Through the subsequent cross-activation of HCR and DNAzyme amplicons, the ACD amplifies the limited signal resulting from miRNA recognition. The hMNS/ACD system was used to image microRNA in vivo, thus demonstrating its great promise in cancer diagnosis.     

Congresses,Conferences, Symposia,Meetings, and Seminars held in 1993–1994

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Congresses, Conferences, Symposia, Meetings, and Seminars held in 1993–1994     

Congresses,conferences, symposia,meetings, and seminars held in 1993–1994

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Congresses, conferences, symposia, meetings, and seminars held in 1993–1994     

α-Halo Ketones in C-, N-, O-, and S-Alkylation Reactions

The review summarizes and analyzes both theoretical aspects and practical applications of C-, N-, O-, and S-alkylation with -halo ketones of aliphatic, alicyclic, aromatic, and heterocyclic compounds. Some reactions of -halo ketones with difunctional nucleophiles are also discussed.     

Arsenspuren in Wolfram, Molybd?n und in einigen anderen Metallen

Ohne Zusammenfassung     

Conformation and chiral effects in α,β,α-tripeptides

Short α,β,α-tripeptides comprising a central chiral trisubstituted β(2,2,3)*-amino acid residue form unusual γ-turns and δ-turns in CDCl(3) and DMSO-d(6) solutions but do not form β-turns. Thermal coefficients of backbone amide protons, 2D-NMR spectra, and molecular modeling revealed that these motifs were strongly dependent on the configuration (chiral effect) of the central β-amino acid residue within the triad. Accordingly, SSS tripeptides adopted an intraresidual γ-turn like (C6) arrangement in the central β-amino acid, whereas SRS diastereomers preferred an extended δ-turn (C9) conformation. A different SRS-stabilizing bias was observed in the crystal structures of the same compounds, which shared the extended δ-turn (C9) found in solution, but incorporated an additional extended β-turn (C11) to form an overlapped double turn motif.     

Quantitative analysis of geraniol,nerol, linalool,and α-terpineol in wine

A mixture of [(2)H(7)]-geraniol, [(2)H(7)]-nerol, [(2)H(7)]-linalool and [(2)H(7)]-alpha-terpineol was prepared for use as internal standards in a rapid and accurate analytical method, employing gas chromatography-mass spectrometry (GC/MS), to determine the concentration of geraniol, nerol, linalool and alpha-terpineol in wine. The method avoids the possible formation, degradation and interconversion of these compounds during their analysis.     

Efficient Stereoselective Synthesis of C,O,S,N-Glycosides in High Yield

The Koenig-Knorr method is still the most useful method for the synthesis of glycosides thoughpartly inherent disadvantages of this method could not be overcome. Recently Schmidt et al. reportedthat glycosyl trichloroacetimidates can be used to synthesize C, O and S-glycosides stereoselectively inhigh yield under mild reaction conditions.     

Zur Wasserbestimmung- in Glycerin, Margarine, ?len und Fetten

Ohne Zusammenfassung     

Dehydration reactions in water. Brønsted Acid-surfactant-combined catalyst for ester,ether, thioether,and dithioacetal formation in water

Dehydration reactions in water have been realized by a surfactant-type catalyst, dodecylbenzenesulfonic acid (DBSA). These reactions include dehydrative esterification, etherification, thioetherification, and dithioacetalization. In these reactions, DBSA and substrates form emulsion droplets whose interior is hydrophobic enough to exclude water molecules generated during the reactions. Detailed studies on the esterification revealed that the yields of esters were affected by temperature, amounts of DBSA used, and the substrates. Esters were obtained in high yields for highly hydrophobic substrates. On the basis of the difference in hydrophobicity of the substrates, unique selective esterification and etherification in water were attained. Furthermore, chemospecific, three-component reactions under DBSA-catalyzed conditions were also found to proceed smoothly. This work not only may lead to environmentally benign systems but also will provide a new aspect of organic chemistry in water.     

Kristallchemische Untersuchungen in Systemen (Ti,Nb, Ta,Mo, W)−(As,Sb)

Zusammenfassung Legierungen aus den Systemen Mo–As und W–As werden röntgenographisch untersucht. Die Kristallstrukturen von MoAs und Mo₅As₄ werden bestimmt. MoAs kristallisiert im B31-Typ, Mo₅As₄ und die dazu isotypen Verbindungen (Ti_0,4W_0,6)₅As₄; Nb₅Sb₄ und Ta₅Sb₄ gehören zu einer Ti₅Te₄-artigen Struktur.     

Hydrogen Balmer α line behavior in Laser-Induced Breakdown Spectroscopy depth scans of Au,Cu, Mn,Pb targets in air

The behavior of hydrogen spectral emission of the plasmas obtained by Laser-Induced Breakdown Spectroscopy (LIBS) measurement of four metal targets (Au, Cu, Mn, Pb) in air was investigated. The plasma was produced by a pulsed Nd:YAG laser emitting in the fundamental wavelength. A systematic study of the spatial-integrated plasma emission obtained by an in-depth scanning of the target was performed for each metal, both in single pulse and collinear double-pulse configurations. Further, a spatial-resolved analysis of the emission of plasma produced on the Al target by a single laser pulse was performed, in order to describe the spatial distribution of emitters deriving from the target and air elements. The line intensities of the main plasma components (target metal, nitrogen, oxygen and hydrogen) were measured in both experimental conditions. Results show that the hydrogen line intensity varies greatly as a function of the metal considered, and exhibits a marked decrease after the first laser shots. However, differently from emission lines due to surface impurities, the hydrogen line intensity reaches a constant level deep inside the target. The spatial-resolved measurements indicate that hydrogen atoms in the plasma mainly derive from the target surface and, only at a minor extent, from the dissociation of molecular hydrogen present in the surrounding air. These findings show that the calculation of plasma electron number density through the measurement of the Stark broadening of hydrogen Balmer α line is possible also in depth scanning measurements.