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1.
O. V. Kuznetsova E. Yu. Fursova G. A. Letyagin G. V. Romanenko V. I. Ovcharenko 《Russian Chemical Bulletin》2018,67(7):1202-1205
Hydrolysis of [M4(hfac)4(MeO)4(MeOH)4] (М = Сo, Ni and hfac is hexafluoroacetylaceton ate) is a convenient way of obtaining polynuclear complexes [Ni7(hfac)6(OH)8(H2O)6]?2H2O, [Co12(hfac)10(OH)14(H2O)8]?2H2O?2MePh, [Co12(hfac)10(OH)14(H2O)4(Me2CO)4]?3PhMe, and [Co12(hfac)10(OH)14(H2O)6(Me2CO)2]?2H2O?2Me2CO, whose structures were confirmed by X-ray analysis. 相似文献
2.
Complexes of CrIII, MnII, ZnII & CdII with the polydentate carboxamide ligandN′, N′′-bis(3-carboxy-1-oxoprop-2-enyl) 2-Amino-N-arylbenzamidine (H2L) have been synthesized and characterized by elemental analyses, spectroscopic studies (Vibrational, electronic, ESR and
1H-NMR), magnetic susceptibility measurements, thermal studies and powder diffraction studies. The vibrational spectral data
are in agreement with coordination of amide and carboxylate oxygen of the ligands with the metal ions. The electronic spectra
indicates octahedral or tetrahedral geometry around the metal ions, has been supported by magnetic susceptibility measurements.
The results of electron spin resonance & 1H-NMR spectra have supported the results of other spectral techniques. Kinetic and thermodynamic parameters were computed
from the thermal data using Coats and Redfern method, which confirm first order kinetics. Powder diffraction determines the
cell parameters of the complexes. 相似文献
3.
E. Yu. Fursova O. V. Kuznetsova V. I. Ovcharenko G. V. Romanenko A. S. Bogomyakov M. A. Kiskin I. L. Eremenko 《Russian Chemical Bulletin》2007,56(9):1805-1808
A method was developed for the synthesis of mixed-metal heterospin compounds with the direct coordination of the nitroxide
fragment based on the replacement of acetonitrile molecules in the heterotrinuclear complex [Co2Gd(NO3)Piv6(CH3CN)2] with nitroxide molecules. The molecular and crystal structure of the heterospin mixed-ligand heterotrinuclear CoII, GdIII, CoII complex [Co2Gd(NO3)Piv6(NIT-Me)2], where NIT-Me is stable nitronyl nitroxide, was established. The magnetic properties of this complex were investigated in
the temperature range of 2–300 K. The coordination of nitroxide groups to CoII ions is responsible for strong exchange interactions between the unpaired electrons in the exchange clusters {>-·O-CoII}, resulting in the virtually complete spin coupling between each coordinated >N-·O group and one of the unpaired electrons
of each CoII ion at temperatures below 200 K.
Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1742–1745, September, 2007. 相似文献
4.
Saeedeh Hashemian 《Russian Journal of Inorganic Chemistry》2011,56(3):397-401
The imidazol side group of histidine has two nitrogen atoms capable of being protonated or participating in metal binding.
Hence, histidine can take on various metal-bound and protonated forms in proteins. Because of its variable structural state,
histidine often functions as a key amino acid residue in enzymatic reactions. Ab initio (HF and MP2) calculations were done
in modeling the cation (H+, Li+, Na+, K+, Mg2+, Ca2+) interaction with side chain of histidine. The region selectivity of metal ion complexation is controlled by the affinity
of the side of attack. In the imidazol unite of histidine the ring nitrogen has much higher metal ion (as well as proton)
affinity. The complexation energies with the model systems decrease in the following order: Mg2+ > Ca2+ > Li+ > Na+ > K+. The variation of the bond lengths and the extent of charge transfer upon complexation correlate well with the computed interaction
energies. 相似文献
5.
Marin Ayranov Dorothea Schumann 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(3):649-654
The station for pions cancer therapy was operated at PSI from 1980 to 1992. After a cooling time of 12 years it’s made of
copper beam dump was cut and samples were taken for analytical purposes. The sampling collected about 500 g of high active
copper chips that can be used for separation of exotic radionuclides. The analyses by gamma spectrometry, LSC and AMS showed
main nuclides present to be 60Co, 54Mn, 22Na, 65Zn, 26Al, 53Mn, 59Ni, 63Ni, 55Fe and 60Fe and 44Ti with a daughter nuclide 44Sc. In the frame of ERAWAST project a procedure combining selective precipitation and ion exchange for the separation of the
rare radionuclides from the copper beam dump was developed. The proposed separation procedure is easy for remote controlled
implementation in a hot cell. The ion exchange separation of Ni, Al, Mg, Ti and Fe was complete and high decontamination factors
for copper and cobalt were achieved. Based on the developed procedure a remotely controlled system for separation of exotic
radionuclides from the copper chips was set up. The full scale system was installed in a hot cell where high activity levels
can be handled. In order to evaluate the reliability and functionality of the system extensive tests have been done. During
the test period 13.86 g in total of the proton irradiated copper beam dump were processed for separation of 26Al, 59Ni, 53Mn, 44Ti and 60Fe. The results showed that the system was operational and the radionuclide separation was selective with high chemical yield.
The procedure manages as well the generated liquid wastes containing high level of 60Co activity. 相似文献
6.
Isothermal titration calorimetry has been used to determine the stoichiometry, formation constants and thermodynamic parameters
(ΔG
o, ΔH, ΔS) for the formation of the citrate complexes with the Mn2+, Co2+, Ni2+ and Zn2+ ions. The measurements were run in Cacodylate, Pipes and Mes buffer solutions with a pH of 6, at 298.15 K. A constant ionic
strength of 100 mM was maintained with NaClO4. The influence of a metal ion on its interaction energy with the citrate ions and the stability of the resulting complexes
have been discussed. 相似文献
7.
Chang Heon Lee Moo Yul Suh Kwang Yong Jee Won Ho Kim 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(1):187-194
A sequential separation procedure has been developed for the determination of 99Tc, 94Nb, 55Fe, 90Sr and 59/63Ni in various radioactive wastes generated from nuclear power plants. Ion exchange and extraction chromatography were adopted
for individual separation of the radionuclides. Precipitation was supplementarily utilized for both purification of the individual
radionuclides and preparation of the radionuclide sources for use in a radioactivity measurement. The chromatographic separation
behavior of the radionuclides both from the sample matrix metals and from one another was investigated using stable metals,
Re (as a surrogate of 99Tc), Nb, Fe, Sr and Ni. The validity of the procedure for reliability and applicability was evaluated by measuring the recovery
of the metal carriers added to synthetic radioactive waste solutions. The recoveries by the chromatographic separation were
in the range of 84.8 to 102.2% with 2s of less than 8.6%, the recoveries by the precipitation being in the range of 84.3 to 97.3% with 2s of less than 10.9%. 相似文献
8.
B. Bartoś E. Kowalska A. Bilewicz G. Skarnemark 《Journal of Radioanalytical and Nuclear Chemistry》2009,279(2):655-657
103mRh is a very promising radionuclide for Auger electron therapy due to its very low photon/electron ratio. The goal of the
present work was the elaboration a method for production of large quantities of 103mRh for generator system. It was found that the combination of solvent extraction with evaporation of 103RuO4 followed by decomposition of H5IO6 makes it possible to produce 103mRh of high radionuclidic and chemical purity. 相似文献
9.
Guo-Zhang Huang Ze-Yu Ruan Jie-Yu Zheng Jie-Yi Wu Yan-Cong Chen Quan-Wen Li Muhammad Nadeem Akhtar Jun-Liang Liu Ming-Liang Tong 《中国科学:化学(英文版)》2018,61(11):1399-1404
Single-molecule magnets (SMMs) are regarded as promising candidates for ultrahigh-density storage, quantum information processing and molecular spintronics. It is a crucial challenge for chemists to modulate magnetic dynamics of SMMs. Here, we successfully synthesized two 3d-4f polynuclear compounds [Co2Dy(TTTTCl)2(MeOH)]NO3·3MeOH (1) and [Co2Dy(TTTTCl)2 (MeOH)][Co(HTTTTCl)](NO3)2·2.5MeOH·2H2O (2), where H3TTTTCl=2,2′,2′′-(((nitrilotris(ethane-2,1-diyl)) tris(azanediyl)) tris(methylene))tris-(4-chlorophenol). On applying the approach by co-crystallization of bulky diamagnetic moiety, the effective energy barrier enhances from 401 K (1) to 536 K (2), which are both among the highest d-f heterometallic SMMs. 相似文献
10.
Dimitrios C. Xarchoulakos Konstantina Kehagia Nikolaos Kallithrakas-Kontos Constantinos Potiriadis 《Journal of Radioanalytical and Nuclear Chemistry》2017,312(2):285-292
For the first time, a radiological study for the dissolved 238U, 234U, 210Pb and 210Po was held in major Greek rivers across the country. 234U/238U activity ratios are above one in all samples and 210Po/210Pb activity ratios are respectively below the unit indicating the disequilibrium in the samples. Quite satisfactory correlations were observed among 234U and 238U as well as among 210Po and 210Pb values. Uranium isotopes were separated by ion exchange and electroplated on stainless steel plates. 210Po was spontaneously deposited on nickel plates, while 210Pb was indirectly determined through the ingrowth of 210Po. The sources were measured by a-spectrometry. 相似文献
11.
S. Pommé E. García-Toraño G. Sibbens S. Richter R. Wellum A. Stolarz A. Alonso 《Journal of Radioanalytical and Nuclear Chemistry》2008,277(1):207-210
High-resolution alpha-particle spectrometry was performed on three uranium materials enriched in 235U. Besides the 235U peaks, separate peaks belonging to impurity traces of 234U could be quantified. Relying on the isotopic composition of the uranium, as determined by mass spectrometry, the ratio of
the half-lives of 238U and 235U was determined via the activity ratio of 234U and 235U in the materials. As an intermediate link, the 234U/238U half-life ratio was taken from published mass spectrometric analyses of ‘secular equilibrium’ uranium material. The resulting
half-life ratio T
1/2(238U)/T
1/2(235U) = 6.351±0.031 is in agreement with the commonly adopted half-life values determined by Jaffey et al. 相似文献
12.
D. A. Haas S. R. Biegalski K. M. Foltz Biegalski 《Journal of Radioanalytical and Nuclear Chemistry》2008,277(3):561-565
In support of the Comprehensive Nuclear-Test-Ban Treaty (CTBT), improvements have been made to the model of the Automated
Radioxenon Sampler/Analyzer (ARSA) β-γ coincidence detector for radioxenon monitoring. MCNPX is used to simulate the detector
response for all the electrons and photons emitted from 131mXe, 133Xe, 133mXe, 135Xe, and 137Cs signals. A MatLab code was written to incorporate the MCNPX results in the calculation of β-γ coincidence spectra. These
will aid in the development of the Spectral Deconvolution Analysis Tool (SDAT)1 and to calibrate β-γ coincidence systems. The models developed for this work include improvements over previous models in
their ability to address Compton scattering in the β-cell, and the β-distribution offset in the 31 keV γ-ray region for 133Xe. 相似文献
13.
We have investigated the presence of foreign ions into the bulk structure and the external surfaces of aragonite using periodic
ab-initio methods. Four cations isovalent to Ca2+ were studied: Mg2+, Sr2+, Ba2+ and Zn2+. The calculations were performed at structures (bulk, surface) that contain four and eight CaCO3 units. Our results, at the Hartree-Fock level, show that the incorporation of those ions into aragonite depends strongly
on their size. Mg2+ and Zn2+, due to their smaller size, can substitute Ca2+ ions in the crystal lattice while the incorporation of Sr2+ and Ba2+ into aragonite is energetically less favoured. Examination of the [011], [110] and [001] surfaces of aragonite revealed that
the surface incorporation reduces the energetic cost for the larger ions. These systems provide challenging examples for most
shape analysis methods applied in Mathematical Chemistry. 相似文献
14.
A. D. Sajeniouk 《Journal of Radioanalytical and Nuclear Chemistry》2005,264(2):337-342
15.
Claudia Landstetter Christian Katzlberger 《Journal of Radioanalytical and Nuclear Chemistry》2009,282(2):467-471
Screening measurements for 3H, 226Ra, 222Rn and 238U in ground water were performed within a ground- and drinking water project in Austria. The aim of this project is to get
an overview of the distribution of natural radionuclide activity concentration levels in ground water bodies. In some cases
this water is used for drinking water abstraction. In this paper methods and results of the screening measurements are presented.
Regions with high activity concentrations were identified and in these regions further investigation for 228Ra, 210Pb and 210Po will be conducted. 相似文献
16.
S. Osaki S. Sugihara Y. Maeda T. Osaki 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(1):135-140
Depth distribution of atmospheric 210Pb and 7Be and 90Sr and 137Cs fission products was measured in two types of aeolian soils (desert dust and volcanic ash), irrigated paddy soil and strongly
acidic soil. The depth dependence of 210Pb, 7Be and 137Cs show that these radionuclides have been diffused as solid soil particles in surface soil layers. In aeolian soil layers,
about 50% of 90Sr were diffused in surface soil layer and the remaining 50% had penetrated to deeper layers. The half of the fission particles
containing 90Sr were shown to have decomposed over the past 35 years. 相似文献
17.
Matthias J. Brunnermeier Stefanie A. K. Schmied Robert Schupfner 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(3):1285-1290
The period of date of death of an elephant can be assessed by analyzing four different radionuclides, 14C, 90Sr, 228Th and 232Th in its ivory. These nuclides are supposed to have variing concentrations at different parts of a tusk. The reason is the
procedure of growth which takes place at the butt-site of a tusk. Therefore the site of sampling could have a big influence
on the assessed date of death. However, to find out if the position of sampling is important a complete tusk was analyzed
regarding the distribution of these nuclides. Results show that the concentration activity of 14C and 228Th varies in different parts of a tusk. The activity concentration of 90Sr is very similar in all analyzed parts. The conclusion is that sampling at the butt of a tusk is recommended for age assessment. 相似文献
18.
S. K. Aggarwal D. Alamelu P. M. Shah N. N. Mirashi 《Journal of Radioanalytical and Nuclear Chemistry》2007,273(3):771-774
Determination of 241Am/243Am ratios is required for vanous purposes including assay of Am by isotope dilution techniques. Alpha-spectrometry on electrodeposited
sources is a preferred technique for this determination. However, there is an inherent problem of tail contribution which
necessitates the use of suitable algorithms to account for the same. Recently, in the frame of a Coordinated Research Program
(CRP) of the International Atomic Energy Agency (IAEA), WinALPHA software has been developed which is a combination of an
asymmetrical Gaussian for the main part of the peak and a low energy function. Therefore, it was of interest to compare the
use of this algorithm with the routinely used method, in our laboratory, based on geometric progression (G. P.) decrease.
Since, there are no reference materials available commercially for 241Am/243Am ratios, synthetic mixtures covening a wide range (0.3 to 2.0) of 241Am/243Am α-activity ratios were used and un-ignited electrodeposited sources were prepared for α-spectrometry. The α-spectra obtained using PIPS detector, were evaluated using the two algonthms The 241Am/243Am α-activity ratios obtained were also compared with those determined by thermal ionization mass spectrometry (TIMS). An agreement
of about 1% was obtained in the 241Am/243Am ratios determined by the two methods and also by using the two algorithms for α-spectrum evaluation. 相似文献
19.
The scanning transmission ion microscope (STIM) has been used to determine the intracellular mass of human cultured cells. A 4He+ microbeam of 2.0 MeV energy was chosen to obtain enhanced ion-energy-loss sensitivity through the micron-thick freeze-dried cells. Local sample mass calculation, based on energy-loss conversion by use of appropriate matrix stopping powers, was performed by use of dedicated software. The method was validated with epoxy resin sections and polymer foil as analogues of biological samples in the range of (intra)cellular thickness, 150 to 3000 nm. STIM analysis resulted in less than 5% error in mass determination. 4He+ energy-loss micro-spectrometry was performed on freeze-dried human ovarian cancer cells, the mean areal mass obtained was 120 microg cm(-2) (200 microg cm(-2) in the nucleus and 250 microg cm(-2) in nucleoli). This method is particularly useful for mass normalization of X-ray fluorescence yields resulting from particle-induced X-ray emission microanalysis (micro-PIXE). When performed successively these two ion-beam micro-analytical methods enable the mapping of true element concentrations within single cells. 相似文献
20.
M. A. Kiskin A. A. Sidorov G. G. Aleksandrov Yu. G. Shvedenkov V. N. Ikorskii V. M. Novotortsev I. L. Eremenko I. I. Moiseev 《Russian Chemical Bulletin》2005,54(9):2211-2214
The interaction of [K2FeIII
4(O)2(OOCCMe3)10(HOOCCMe3)2(H2O)2]n with 2-pyridinecarboxaldehyde results in a mixed-valence complex FeIIFeIII
3(μ3-O)2(μ2-OOCCMe3)7L2··2.5MeCN·3H2O (L = 2-NC5H4COOH0.75K0.25). The structure of the complex was established by X-ray analysis. The magnetic properties of the complex were studied.
Dedicated to Academician A. L. Buchachenko on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2145–2148, September, 2005. 相似文献