共查询到20条相似文献,搜索用时 31 毫秒
1.
The geometry, frequency and intensity of the vibrational bands of 8-hydroxyquinoline and its 5,7-dichloro, 5,7-dibromo, 5,7-diiodo
and 5,7-dinitro derivatives were obtained by the density functional theory (DFT) calculations with Becke3-Lee-Parr (B3LYP)
functional and 6-31G* basis set. The effects of chloride, bromide, iodide and nitro substituent on the vibrational frequencies
of 8-hydroxyquinoline have been investigated. The assignments have been proposed with aid of the results of normal coordinate
analysis. The observed and calculated spectra are found to be in good agreement.
相似文献
2.
Cory C. Pye 《Central European Journal of Chemistry》2011,9(4):567-571
A geometry and SCF convergence study of Hartree-Fock calculations using the 6-31G* basis set is carried out on the set of
all possible diatomic molecules formed from atoms with Z≤36. The utility of Hartree-Fock calculations using the smaller STO-3G
basis set to improve the convergence behavior is demonstrated.
相似文献
3.
Tsonko Kolev Bojidarka B. Koleva Michael Spiteller 《Central European Journal of Chemistry》2008,6(3):393-399
The applications of linear-polarized IR-spectroscopy to oriented colloid suspensions in a nematic host are demonstrated with
croconic and rhodizonic acids. The experimental IR vibrational assignments of the solid-state of both neutral compounds are
presented. Assignments are supported by theoretical quantum chemical calculations and vibrational analysis at the DFT level
of theoretical approximation with the 6-311++G** basis set.
相似文献
4.
Fluorescence spectroscopy and circular dichroism (CD) spectroscopy were used to investigate the interaction of coumarin-3-carboxylic
acid with human serum albumin (HSA) and bovine serum albumin (BSA) under physiological conditions in a buffer solution of
pH 7.4.
相似文献
5.
Bingcheng Yang Feifang Zhang Xinmiao Liang 《Central European Journal of Chemistry》2012,10(3):472-479
This review summarizes the development of capillary ion chromatography (CIC) over approximately the last 5 years. It mainly
focuses on the technologic aspects of several key components associated with CIC, including micropump, microscale electrodialytic
eluent generator, microscale suppressor and the detector.
相似文献
6.
This paper describes the preparation and characterization of poly(ethyl cyanoacrylate) colloidal particles loaded with the
organic fluorophore Rhodamine 6G. We studied the physicochemical properties of the colloidal particles: morphology, size-distribution,
ζ-potential, fluorescent properties and photobleaching upon UV-light illumination. The properties of the obtained colloidal
particles, as well as the dye loading efficiency, were found to depend on the concentrations of ethyl cyanoacrylate monomer
and Rhodamine 6G in the polymerization medium. The fluorophore release from the colloidal particles in aqueous buffer is also
studied.
相似文献
7.
Dimitra Giasafaki Athanassios Bourlinos Georgia Charalambopoulou Athanassios Stubos Theodore Steriotis 《Central European Journal of Chemistry》2011,9(5):948-952
Metal-carbon composites have shown considerable hydrogen storage potential at room temperature. In the present work the behaviour
of two different Pd amalgam doped carbon substrates, namely a carbogenic foam and a mildly oxidised ordered mesoporous carbon,
are compared on the basis of their hydrogen sorption properties at 77 and 298 K and low pressures, aiming to investigate the
effect of surface on the storage capacity. In both cases, the introduction of alloy nanoparticles leads to an improvement
of the hydrogen uptake with respect to pure carbons. This effect is significant for the carbogenic foam however small for
the ordered carbon.
相似文献
8.
Markku R. Sundberg Rolf Å. M. Uggla Reijo J. Sillanpää Krzysztof K. Zborowski Angel Sánchez-González Jorma K. T. Matikainen Seppo A. A. Kaltia Tapio A. Hase 《Central European Journal of Chemistry》2010,8(3):486-493
Chromium trioxide forms an adduct with zwitterionic quinolinic acid. The structure of the product was found to be (quinolinium-3-carboxylato-O)trioxidochromium(VI), determined by single-crystal X-ray diffraction methods. To evaluate the bonding properties of the compound,
its structure was optimized at the B3LYP/6-311G* level of theory. The electronic characteristics were investigated by topological
methods applied to the total charge density in various model compounds including the title compound, title compound with a
HF molecule presenting a hydrogen bonding and anionic moiety. Calculated aromaticity indices indicate that the quinolinic
rings tend to conserve their degree of aromaticity against hydrogen bonding. However, when there is hydrogen bonding involving
an N-H bond or when the quinolinium zwitterion is deprotonated, there are clear changes in the interaction between chromium
trioxide and the quinolinic moiety.
相似文献
9.
Mi?osz Mi?tkiewski Beata Powa?a Bartosz Staniszewski Maciej Kubicki W?odzimierz Urbaniak Cezary Pietraszuk 《Central European Journal of Chemistry》2011,9(4):728-736
Selected β-diketones bearing unsaturated derivatives have been demonstrated to undergo homo-metathesis and cross-metathesis with selected
olefins in the presence of Grubbs catalysts. The reactions led to respective homo- and cross-metathesis products mainly with
good yields and selectivities.
相似文献
10.
This article describes the simple hydrodehalogenation of halogenated anilines and their derivatives by the action of Raney
aluminium-nickel alloy in aqueous alkaline solution at room temperature. The reaction course was monitored by means of 1H
nuclear magnetic resonance (NMR) spectroscopy and GC-MS spectra.
相似文献
11.
Mažvydas Mackevičius Feliksas Ivanauskas Aivaras Kareiva 《Central European Journal of Chemistry》2012,10(2):380-385
In our work, we present a method for estimation of the diffusion and reaction rates of synthesis at high temperatures using
limited information from laboratory experiments, such as synthesis time and dimensions of reactants. Synthesis by sol-gel
and solid-state reactions is considered. The inverse modeling problem is solved for one- and two-dimensional models. Explicit
formulas for the diffusion coefficient and reaction rate as functions of temperature are obtained. The activation energies
are calculated, and the lower bounds of diffusion and reaction rates are estimated, thus obtaining conditions for occurrence
of synthesis.
相似文献
12.
Available quantitative data of the reactivity of organosilicon compounds were subjected to correlation analysis. As an alternative
to the carbon chemistry values, the scale of steric constants E
S
(Si) can be used for organosilicon compounds and the inductive effect is best expressed by two terms, involving the parameter
of electronegativity of substituents. Alkyl substituents contribute to the reactivity exclusively through their steric effects,
steric and polar effects in silicon compounds are additive and the resonance effect is insignificant. The correlation analysis
can be employed in investigations of organosilicon reactions along with other methods.
相似文献
13.
Jadwiga Jasińska Beata Krzyżyńska Mieczysław Kozłowski 《Central European Journal of Chemistry》2011,9(5):925-931
Activated carbons containing different surface functionalities have been investigated as catalysts in conversion reactions
of ethanol and methanol. These carbon materials were prepared from Polish brown coal by chemical activation with potassium
hydroxide and modified by the oxidation or reaction with ammonia or chlorine. The main process upon ethanol decomposition
was its dehydrogenation, while in the process of methanol decomposition only a few samples were catalytically active, and
the only product was dimethyl ether (a product of dehydration).
相似文献
14.
Dariusz Wyrzykowski Michał Wera Artur Sikorski Dagmara Jacewicz Lech Chmurzyński 《Central European Journal of Chemistry》2011,9(6):1096-1101
The crystal structure of 2-methylpyridinium tetrachloroferrate(III) was determined. The iron cation is tetracoordinated by
chloride anions, and it adopts a slightly distorted tetrahedral coordination with three angles smaller, two almost equal and
one larger than the tetrahedral. The compound is isostructural with its 3-, and 4-methylpyridinium analogues. The thermal
properties of 2-, 3- and 4-methylpyridinium tetrachloroferrates(III) have been studied using TG and DSC techniques. The compounds
exhibit a high stability in the melt.
相似文献
15.
An alternative procedure for the calculation of highly excited vibrational levels in S0 formaldehyde was developed to apply
to larger molecules. It is based on a new set of symmetrized vibrational valence coordinates. The fully symmetrized vibrational
kinetic energy operator is derived in these coordinates using the Handy expression [Molec. Phys. 61, 207 (1987)]. The potential
energy surface is expressed as a fully symmetrized quartic expansion in the coordinates. We have performed ab initio electronic computations using GAMESS to obtain all force constants of the S0 formaldehyde quartic force field. Our large
scale vibrational calculations are based on a fully symmetrized vibrational basis set, in product form. The vibrational levels
are calculated one by one using an artificial intelligence search/selection procedure and subsequent Lanczos iteration, providing
access to extremely high vibrational energies. In this work special attention has been given to the CH stretch system by calculating
the energies up to the fifth CH stretch overtone at ∼16000 cm−1, but the method has also been tested on two highly excited combination levels including other lower frequency modes.
相似文献
16.
Mehdi Ghandi Parham Asgari Abuzar Taheri Alireza Abbasi 《Central European Journal of Chemistry》2010,8(4):899-905
One-pot, three-component condensation of 2-hydroxybenzaldehyde derivatives, primary amines with alkyl isocyanides is reported.
N-alkyl-2-(2-hydroxyphenyl)-2-iminoacetamide derivatives are generated presumably via the preliminary formation of N, N′-disubstituted benzo[b]furan-2,3-diamines and subsequent oxidation with molecular oxygen.
相似文献
17.
Badamtsetseg Soyollkham Pavel Valášek Miroslav Fišera Vlastimil Fic Vlastimil Kubáň Ignác Hoza 《Central European Journal of Chemistry》2011,9(4):677-687
Wine samples (Grüner Veltliner (GV) and Zweigelt (ZW) from four different geographical regions of Austria and Czech Republic) were analyzed to determine their total phenolic content
(TPC) by applying the Folin-Ciocalteau method, total antioxidant activity (TAA) by FRAP (ferric reducing antioxidant power)
and DPPH (1,1-diphenyl-2-picryl-hydrazyl) assays, and to identify and quantify eleven phenolic compounds using a HPLC/UV-VIS
method.
相似文献
18.
(Z/E)-1-(2-Methoxyaryl)-1-phenylpropenes have been prepared in good yields by heating a mixture of a phenolic substrate, cinnamyl
chloride, tetramethylammonium chloride and K2CO3 in polyethyleneglycol at 180°C. The one-pot synthesis proceeds through four discrete reaction steps: alkylation of the
phenol with cinnamyl chloride, Claisen rearrangement, O-methylation and double-bond migration. The configuration of one crystalline product was determined using a single-crystal
X-ray diffraction analysis. The thermodynamic and structural features of the products were evaluated using computational chemistry
techniques.
相似文献
19.
Nikolai N. Kolesnikov Elena B. Borisenko Dmitrii N. Borisenko Boris A. Gnesin 《Central European Journal of Chemistry》2011,9(4):619-623
In the present study newly produced semiconductor ceramic nanopowder materials made of CdTe and Cd1−xZnxTe (CZT) are considered. Common features and differences in microstructures, phase transformations, grain growth and properties
of the ceramic materials of the binary and ternary compositions are studied.
相似文献
20.
Irena Baranowska Sylwia Magiera Jacek Baranowski 《Central European Journal of Chemistry》2011,9(6):972-981
The aim of this paper is to optimize and validate a high performance liquid chromatography (HPLC) method for separation and
quantification of five isoflavones. A statistical central composite design was used to separate all peaks. These multivariate
procedures were efficient in determining the optimal separation condition using resolution, capacity factor, asymmetry and
number of theoretical plates.
相似文献