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针对无机化学传统教学模式的不足,构建了无机化学微信平台。介绍了构建平台必需的微信公众号和微信群的建立过程和方法。分析了无机化学微信平台在教学中的实践效果,弥补了传统教学中的不足。讨论了无机化学微信平台的积极作用,提高了教师教学水平和学生的学习能力,达到了师生双赢的目的。 相似文献
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自20世纪初期,德国化学家EmilFischer首先合成了甘氨酸二肽片段,并第一次提出“peptide”(多肽)这一名词,多肽化学的研究已经历了100多年的发展.1953年,Vigneand小组首次完成了生物活性肽催产素的合成,并因此于1955年获得了诺贝尔化学奖.1963年,Merrifield提出了多肽固相合成法,并发明了第一台多肽自动合成仪,大大简化了多肽合成的流程、提高了合成的效率,从而促使多肽化学实现了飞跃式发展,Merrifield也因此获得了1984年诺贝尔化学奖.1965年,我国科学家完成了牛结晶胰岛素的合成, 相似文献
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环取代基对金属化聚苯胺衍生物膜修饰电极性能的影响 总被引:1,自引:0,他引:1
通过比较聚2,5-二甲氧基苯胺(PDMAn)、聚邻甲基苯胺(POT)和聚间氯苯胺(PmClAn)膜修饰电极的氧化还原电位、沉积在这3种聚合物上的铂微粒的表面形态与晶面取向以及异丙醇在分散Pt微粒的聚苯胺膜修饰电极上的氧化行为,从电子效应和立体效应探讨了聚合物电化学性质与环取代基的关系以及不同聚合基质对Pt沉积机理和有催化性能的影响,结果表明,在硫酸溶液中PDMAn膜修饰电极的氧化还原电位最负、POT次之、PmClAn最正,Pt在PDMAn和POT膜上的电沉积机理与在PmClAn膜上的不同,聚合物膜上沉积的Pt微粒呈现(200)晶面择优取向,其中POT膜上择优取向度最大,PDMAn次之,Pm-ClAn最小,异丙醇在金属化聚合物膜电极上的氧化电位取决于聚苯胺的本质,在POT膜修饰电极上异丙醇的电氧化主要发生在POT的活性电位区,而在PDMAn与PmClAn膜上的电氧化则主要发生在Pt上的氧化电位区,说明聚合物膜不仅作为Pt微粒的分散介质,而且本身有产生催化作用。 相似文献
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Wetting of a sessile droplet on structured or patterned surface can be found in a broad range of applications. The researchers have been promoted to keep working on the topic. The review is on the basis of the recent experimental advances on the sessile droplet wetting on the hydrophobic, hydrophilic, or combined hydrophobic and hydrophilic surfaces under isothermal conditions, and on heating or cooling substrates having nonisothermal conditions. More attention has been paid on the wetting configuration between the sessile droplet and the structured substrate; the research gap has been discussed on identifying the three-phase line shape. Further, the three-dimensional measurement for the sessile droplets on the patterned surfaces with focusing more on the contact line of sessile droplets might reveal new physical insights. This review targets at building a holistic overview on the sessile droplet wetting behaviors on the structured substrate in the past 2 years. 相似文献
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Satoshi Kubota Hiromasa Nishikiori Nobuaki Tanaka Morinobu Endo Tsuneo Fujii 《Journal of photochemistry and photobiology. A, Chemistry》2009,206(2-3):148-154
Pyrene crystals were grown on carbon nanofibers (CNFs) by dispersing pyrene polycrystals and CNFs in water during ultrasonic irradiation, and they were characterized by scanning electron microscopy, X-ray diffractometry (XRD) and spectroscopy. The XRD measurements indicated that the orientation and size of the pyrene crystals on the CNF aggregates were different from that of the added pyrene polycrystals. Based on the spectroscopic properties of the pyrene crystals on the CNFs, the pyrene crystals on the CNF aggregates and on the individual CNFs were determined to be polycrystals and single crystals, respectively. These results indicate that pyrene crystals are produced on the CNFs by recrystallization of the added pyrene polycrystals and their crystal states depend on the aggregation state of the CNFs. 相似文献
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本文主要综述有机化学在建立核酸的顺序测定法和自动顺序仪,在破译遗传密码,在建立核酸片段的化学合成方法,固相合成法及DNA合成仪的设计,在合成许多有生物活力的核酸分子,在发展并完善遗传工程以及新近发现酶RNA(Ribozyme)等方面的卓越贡献。最后简要地展望有机化学将对生物学发展作出进一步贡献的几个方面。 相似文献
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Yiu‐Ting R. Lau Lu‐Tao Weng Kai‐Mo Ng Chi‐Ming Chan 《Surface and interface analysis : SIA》2010,42(9):1469-1475
The effect of film thickness on the structural conformation of the surfaces of the amorphous state, edge‐on lamellae and flat‐on lamellae of a semiflexible polymer, poly(bisphenol‐A‐etheroctane), was investigated by time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) with the aid of principal component analysis (PCA). PCA results empirically indicate that a structurally regular polymer surface was obtained with the formation of the flat‐on lamellae from the amorphous state at a low degree of supercooling. A higher concentration of end group and cilium ion fragments, which are indicative of free chain ends, was observed on the edge‐on lamellar surfaces than on the amorphous and the flat‐on lamellar surfaces. This finding was attributed to the fact that the lateral surface of the edge‐on lamellae contains many growth fronts, leaving behind a large number of uncrystallized chain remnants on the surfaces. Structural disorder was facilitated on both edge‐on and flat‐on lamellar surfaces as the film thickness decreased. Hence, this PCA study offers new insights into the nonequilibrium nature of polymer crystals and the mechanism of polymer crystallization in thin and ultrathin films. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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Alicia L. Gui Guozhen Liu Muthukumar Chockalingam Guillaume Le Saux Erwann Luais Jason B. Harper J. Justin Gooding 《Electroanalysis》2010,22(16):1824-1830
4‐Nitrophenyl layers were grafted on gold and glassy carbon surfaces by electrochemical reductive adsorption of the corresponding diazonium salt. Electrochemical conversion efficiencies of 4‐nitrophenyl moieties to 4‐aminophenyl moieties on gold versus on glassy carbon in a protic medium were investigated using X‐ray photoelectron spectroscopy (XPS). In total contrast to all previous comparative studies showing greater electrochemical reactivity of aryl diazonium salt‐derived layers on gold than on glassy carbon, a much lower rate of conversion to 4‐aminophenyl was observed on gold than on glassy carbon by both cyclic voltammetry (CV) and chronoamperometry (CA) methods. The lower electron transfer rate during conversion observed on gold versus glassy carbon was proposed to be due to a mechanism related to the molecular structure rearrangement of 4‐nitrophenyl during the process on glassy carbon. However, whilst complete conversion of 4‐nitrophenyl to 4‐aminophenyl on gold by chronoamperometry was achieved, on glassy carbon complete reduction could not be achieved under the same conditions. 相似文献
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叙述了化学发光免疫分析的分类及特点,从发光底物、增强剂、过氧化物酶、过氧化物及其他方面,对鲁米诺类化合物化学发光酶免疫分析的进展进行了综述,引用文献34篇。 相似文献
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发现以酒石酸和吡啶二甲酸等羧酸水溶液作淋洗剂时,钠,铵,钾,镁和钙等碱金属及碱土金属离子在ODS反相高效液相色谱柱上有明显的保留,而且相互之间能达到一定程度的分离。单独用分配或疏水作用等反相高效液相色谱的保留机理难以解释其保留行为。为此,作者提出了动态包固定相机理,即认为羧酸根阴离子因其疏水性在ODS固定相有保留,在固定相表面形成具有羧酸基阳离子交换树脂功能的动态包覆固定相。 相似文献
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Biomimetic superhydrophobic UHMWPE/nanosilica films with different sticky behavior on several metals 下载免费PDF全文
Hongling Wang Yunxia Wang Chufeng Sun Yanbin Wang Qiong Su Jianzhang Wang Fengyuan Yan 《Surface and interface analysis : SIA》2017,49(9):850-857
A kind of organic–inorganic composite film with biomimetic superhydrophobic performance was prepared on several metals including steel, aluminum, and copper. The organic matrix was ultrahigh‐molecular‐weight polyethylene (UHMWPE), and the inorganic filler was nanosilica. Scanning electron microscope observation indicated addition of nanosilica greatly changed the topography of the UHMWPE film. Special convexities were formed on the surfaces of the composite films, which made the composite films rougher than that of pure UHMWPE film. The nanosilica randomly scattered on the surface of the convexities and formed hierarchical structure similar to that of some plant leaves with superhydrophobic characteristics. Interestingly, it was found that there were remarkable differences between the sliding angles (SA) of water droplet on the composite films on different metals although the contact angles (CA) of water droplet on these films were quite close. The CA on the composite films on steel was about 157°, and the SA was larger than 90°, which demonstrated obvious superhydrophobic and sticky characteristic. But to the films on aluminum and copper, the CAs on them were larger than 160° and the SAs were between 3° and 4°, which meant excellent superhydrophobic and roll‐off performance. Scanning electron microscope observation indicated that there were some micro‐orifices in the film on steel and these micro‐orifices were connected to some extent. It was believed that these micro‐orifices provided capillary force and restrained sliding of water droplet. A sticky model based on capillary mechanism was proposed. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献