Aripiprazole salts. III. Bis(aripiprazolium) oxalate–oxalic acid (1/1)

The asymmetric unit of the title salt [systematic name: bis(4‐(2,3‐dichlorophenyl)‐1‐{4‐[(2‐oxo‐1,2,3,4‐tetrahydroquinolin‐7‐yl)oxy]butyl}piperazin‐1‐ium) oxalate–oxalic acid (1/1)], 2C₂₃H₂₈Cl₂N₃O₂⁺·C₂O₄²⁻·C₂H₂O₄, consists of one protonated aripiprazole unit (HArip⁺), half an oxalate dianion and half an oxalic acid molecule, the latter two lying on inversion centres. The conformation of the HArip⁺ cation differs from that in other reported salts and resembles more the conformation of neutral Arip units in reported polymorphs and solvates. The intermolecular interaction linking HArip⁺ cations is also similar to those in reported Arip compounds crystallizing in the space group P, with head‐to‐head N—H...O hydrogen bonds generating centrosymmetric dimers, which are further organized into planar ribbons parallel to (01). The oxalate anions and oxalic acid molecules form hydrogen‐bonded chains running along [010], which `pierce' the planar ribbons, interacting with them through a number of stronger N—H...O and weaker C—H...O hydrogen bonds, forming a three‐dimensional network.     

Low-temperature magnetic behavior of perovskite compounds PbFe(1/2)Ta(1/2)O3 and PbFe(1/2)Nb(1/2)O3

The isostructural perovskite compounds PbFe(1/2)Ta(1/2)O3 and PbFe(1/2)Nb(1/2)O3 have been known for long time, and they are part of the important class of materials called multiferroic, where ferroelasticity, ferroelectricity, and ferromagnetism coexist. In the literature regarding PbFe(1/2)Ta(1/2)O3 and PbFe(1/2)Nb(1/2)O3, an "anomaly" of their low-temperature magnetic behavior has not always been reported. Moreover, both the origin of this behavior, and the cause for which it was not always observed, were never completely explained. In this paper, the magnetic behavior of the two compounds at low temperature has been extensively studied and explained as the occurring of a spin-glasslike transition.     

The crystal structures of α,ω-diaminoalkanecadmium(II) tetracyanonickelate(II)-aromatic molecule inclusion compounds. IV. (1,6-Diaminohexane)cadmium(II) tetracyanonickelate(II)-m-toluidine(1/1),-p-toluidine(1/1), and-2,4-xylidine(1/1) clathrates,and the coordination complex bis(p-toluidine) (1,6-diaminohexane)cadmium(II) tetracyanonickelate(II)

The crystal structures of the four title compounds have been analyzed by single crystal X-ray diffraction methods at room temperature. Three with a general formula Cd[NH₂(CH₂)₆NH₂]Ni(CN)₄·G (G=m-toluidine,Im;p-toluidine,Ip; and 2,4-xylidine,Ix) are the inclusion compounds of the respective aromatic molecules in the three-dimensional metal complex host (1,6-diaminohexane)cadmium(II) tetracyanonickelate(II). The remaining one is a coordination complex ofp-toluidine, bis(p-toluidine) (1,6-diaminohexane)cadmium(II) tetracyanonick-elate(II),II, Im, Ix, andII crystallize under similar experimental conditions;Ip is obtained using thep-toluidinemesitylene mixture at higher dilution than that used forII. Im crystallizes in the tri linic space group \(P\bar 1\) , witha=9.725(2),b=7.598(1),c=7.177(1) Å, α=90.44(1), β=98.80(1), γ=95.70(1)^o, andZ=1 (the final conventionalR=0.037 for 3526 reflections);Ip: monoclinic,P2/m,a=9.540(2),b=7.611(1),c=7.120(1) Å, β=100.95(1)^o, andZ=1 (R=0.027 for 1700 reflections);Ix: monoclinic,P2/m,a=9.628(2),b=7.613(1),c=7.122(1) Å, β=100.01(1)^o, andZ=1 (R=0.049 for 2704 reflections);II: monoclinic,P2₁/n,a=12.107(3),b=10.117(2),c=12.471(3) Å, β=113.67(2)^o, andZ=2 (R=0.037 for 2616 reflections). The structures ofIm, Ip andIx are similar to that of theo-toluidine inclusion compound of the same metal complex host. InII atrans pair of thep-toluidine molecules to the cadmium atom in the two-dimensional network formed by thecatena-μ-linkages of ?Cd?NH₂(CH₂)₆NH₂?Cd? and ?NC?Ni?CN?Cd?NC?Ni?CN?intersecting at each Cd atom; two cyanide groups of the tetracyanonickelate(II) moiety have free N-ends.     

Verticine ethanol hydrate (2/1/1)

The two symmetry‐independent mol­ecules of the title compound, cevane‐3β,6α,20‐triol ethanol hydrate (2/1/1), 2C₂₇H₄₅NO₃·C₂H₆O·H₂O, have the same stereochemical assignments. The six‐membered rings A, B, E and F are in the chair conformation, while ring D is in a boat conformation. The ring fusions are A/Btrans, B/Ctrans, C/Dcis, D/Etrans and E/Ftrans. The verticine mol­ecules are bridged by water and ethanol mol­ecules via hydrogen bonds to form two‐dimensional layers, and the crystal structure is built up by stacking of these layers.     

Alkaloids ofUngernia severtzovii (RG1) B. Fed.

Summary 1.Ungernia severtzovii has yielded lycorine, hippeastrine, 1-narwedine, d-narwedine, dl-narwedine, ungerwine, unsevine, galanthamine, tazettine, pancratine, and ungminorine; 1-narwedine and unsevine have been obtained from the plant for the first time.2. Unsevine has the structure of 9, 10-methylenedioxy-5-methoxy-12-hydroxy-N-methylbenzopyranoindole with a double bond between C_3a and C₄.3. Interconversions of unsevine, ungerine, and hippeastrine have been effected.Khimiya Prirodnykh Soedinenii, Vol. 1, No. 5, pp. 322–328, 1965