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1.
O. A. Alekseeva I. A. Verin N. I. Sorokina E. P. Kharitonova V. I. Voronkova 《Crystallography Reports》2011,56(3):435-442
Polycrystalline samples of the composition La2Mo2 − x
Sb
x
O9 − y
, where 0 ≤ x ≤ 0.05, were prepared by solid-phase synthesis. Single crystals of La2Mo1.96Sb0.04O8.17 were obtained by spontaneous crystallization from flux. The structure of the metastable β
ms
phase of this compound was determined at room temperature by X-ray diffraction. It was found that the La, Mo, and O1 atoms
are displaced from the threefold axis on which they are located in the high-temperature β phase. It was shown that molybdenum
atoms in the crystal structure are partially replaced by antimony atoms, which are located on the threefold axis. In antimony-doped
crystals, lanthanum atoms partially return to the site on the threefold axis and the coordination environment of molybdenum
cations becomes more ordered, thus facilitating the stabilization of the cubic phase at room temperature. Calorimetric measurements
(DSC) showed that the introduction of Sb as the dopant into the La2Mo2O9 structure leads to a decrease in the temperature of the α → β phase transition from 570 to 520°C and to the partial suppression
of this transition. The temperature behavior of the conductivity confirms the DSC data. Thus, doping with Sb contributes to
the stabilization of the cubic phase at room temperature. 相似文献
2.
The specific features of synthesis, polymorthism, and electric conductivity of oxide-ion conducting compounds La2 − x
Me
x
Mo2O9 − y
, where Me = Na, K, Rb, or Cs, have been studied. Ceramic samples were obtained by solid-state synthesis in the temperature range of
960–1100°C. The regions where solid solutions exist have been found to depend on the temperature of the sample firing. According
to the calorimetric and electrophysical data, the phase transition from the monoclinic phase (α) to the cubic phase (β) in
samples doped with potassium and rubidium disappears at x = 0.02 and 0.04, respectively. In these cases the only transition from the cubic β
ms
phase to the high-temperature cubic β phase is observed near 450°C. Doping with sodium and cesium does not suppress the α
→ β phase transition. 相似文献
3.
The X-ray powder analysis, calorimetric studies, and conductivity measurements of a series of ceramic La2Mo2−x
V
x
O
y
specimens with different vanadium content are performed with the aim of following the dynamics of phase formation of the
low-temperature α, high-temperature β, and metastable β
ms
phases. At x ≥ 0.06, the cubic phase becomes stable and the monoclinic phase vanishes; therefore, the main α → β transition is suppressed.
According to the data of differential thermal analyses, a weak thermal anomaly is observed in the range 450–470°C at x ≥ 0.06. This anomaly is indicative of the β
ms
→ β transition due to the conversion of the cubic phase with statically disordered oxygen atoms into the cubic phase with
dynamic disorder. The conductivity of the high-temperature β phase obeys the Vogel-Tammann-Fulcher law. 相似文献
4.
Barbara M. Casari Elisabeth Öberg Vratislav Langer 《Journal of chemical crystallography》2007,37(2):135-140
Synthesis and crystal structure of a trichromium(VI) decaoxide compound, α–(NH4)2Cr3O10, is reported. The crystal structure has been determined from three dimensional X-ray data collected at low temperature, 173 K.
The structure is isomorphous with its Rb and Cs trichromate analogues, orthorhombic, space group Pbca, with a = 11.2558(3), b = 9.3193(3), c = 18.9819(5) ? and Z = 8. The title compound is composed of discrete [Cr3O10]2– chains held together by the counter ion charge and a hydrogen bonding network. The different conformations adopted by trichromate
anion within its ammonium, alkali and organic salts are discussed. 相似文献
5.
K. G. Sanjaya Ranmohotti Wendy L. Queen J. Palmer West Don VanDerveer Shiou-Jyh Hwu 《Journal of chemical crystallography》2009,39(4):303-307
Abstract A new barium chlorovanadate, Ba5(V2O7)2Cl2, was isolated by a high-temperature (850 °C) reaction employing a CsCl/RbCl flux. The structure was determined by single
crystal X-ray diffraction methods. This compound crystallizes in an orthorhombic crystal system, Pmmn (No. 59), with a = 11.558(2) ?, b = 15.164(3) ?, c = 10.023(2) ?, Z = 4 and V = 1756.7(6) ?3. The structure of Ba5(V2O7)2Cl2 was determined by full-matrix, least-squares methods with R
1 = 0.0398, wR
2 = 0.1069 and GOF = 1.048 for all data. This new structure can be described as a composite lattice made up of mixed covalent
and ionic moities. The extended framework is orchestrated by stacked [Ba(V2O7)Cl]3− slabs that are interconnected by Ba2+ cations through Ba–O bonds to the [V2O7] units. The Ba2+ and Cl- ions form BN-type “[BaCl]” sheets with pseudo-hexagonal windows that are centered by [V2O7]4− pyrovanadate units.
Graphical Abstract The structure of a new chlorovanadate, Ba5(V2O7)2Cl2, exhibits an interesting BN-type salt lattice that consists of an extended [BaCl] sheet containing pseudo-hexagonal windows
that are centered by [V2O7] pyrovanadate units.
相似文献
6.
O. A. Alekseeva I. A. Verin N. I. Sorokina A. E. Krasil’nikova V. I. Voronkova 《Crystallography Reports》2010,55(4):583-590
Precision X-ray diffraction studies of La2 − x
Bi
x
Mo2O9 (x = 0.04, 0.06, and 0.18) single crystals are performed. It is found that in the compounds doped with bismuth, analogously
with the structure of the metastable βms phase of pure La2Mo2O9 (LM), the La, Mo1, and O1 atoms deviate from the threefold axis on which they are located in the high-temperature β phase.
It is shown that bismuth atoms substitute for part of lanthanum atoms and occupy a position at the threefold axis in the neighborhood
of the split lanthanum position. The implantation of bismuth atoms in the LM structure results in the return of a part of
the molybdenum atoms to the position at the threefold axis. The occupancy of this position is equal to the occupancy of the
bismuth atomic position. 相似文献
7.
J. E. Drake M. B. Hursthouse M. E. Light R. Kumar R. Ratnani 《Journal of chemical crystallography》2007,37(6):421-427
The molecular structure of trans-dibromodioxodimethylformamide molybdenum(VI), MoO2Br2(OCHNMe2)2 has been determined. Crystal data: Triclinic, P-1, a = 12.3005(2), b = 15.8763(4), c = 21.1653(6) ?, α = 71.992(1)°, β = 88.966(2)°, γ = 89.999(1)°, V = 3930.1(2) ?, Z = 12. Trans-dibromodioxodimethylformamide molybdenum(VI) was obtained by the reaction of sodium molybdate, HBr and dimethylformamide and
was characterized by IR, and 1H NMR spectroscopy and elemental analysis. 相似文献
8.
Abstract The structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4] · 2.5H2O has been determined. The three iron atoms and the μ3-oxo are coplanar. Each carboxylic ligand is bidentate and links two iron atoms in the cluster. The clusters are linked by
intra-trimer hydrogen bonding to form a zigzag motif that forms sheets via hydrogen bonding involving disordered waters of
hydration. The [FeCl4]− anion is intercalated between the hydrogen-bonded sheets. Crystal data: space group P21/n, a = 10.276(2), b = 22.793(5), c = 17.091(3) ?, β = 96.66(3)°, V = 3976(1) ?3, Z = 4, R = 0.0837, wR
2 = 0.1836.
Graphical Abstract The structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4] · 2.5H2O has been determined in which the clusters are linked by intra-trimer hydrogen bonding to form a zigzag motif that forms
sheets via hydrogen bonding involving disordered waters of hydration.
相似文献
9.
Abstract
A novel quaternary borate, Na2.18K0.82SrB5O10, has been prepared by high-temperature solution reaction below 800 °C. Single-crystal XRD analyses showed that it crystallizes in the triclinic P[`1] P\bar{1} group with a = 7.3900(15) ?, b = 7.6490(15) ?, c = 9.773(2) ?, α = 79.31(2)°, β = 70.85(2)°, γ = 62.09(1)°, Z = 2. The basic structural unit in Na2.18K0.82SrB5O10 is a double ring [B5O10]5− composed of one BO4 tetrahedron and four BO3 triangles. The [B5O10]5− groups are arranged around crystallographic centers of symmetry to form [B10O20]10− columns that are held together by Na+, K+/Na+, and Sr2+ cations via electrostatic interactions. The IR spectrum further confirmed the presence of both BO3 and BO4 groups. UV–vis diffuse reflectance spectrum showed a band gap of about 3.80 eV. Solid-state fluorescence spectrum exhibited the maximum emission peak at around 337.6 nm. 相似文献10.
Abstract
The reaction of tetra-n-butylammonium-octachloridodirhenate(III), (Bu4N)2[Re2Cl8], with molten 2-oxobutanoic acid Et(CO)CO2H at 75 °C afforded pale-green tetra-n-butylammonium-hexachlorido-(2-oxobutanoato)-dirhenate(III), (Bu4N)[Re2(O2C(CO)Et)Cl6]. Slow evaporation of a solution in CHCl3 yielded shiny, mint-green crystals of the dirhenate complex. The X-ray crystal structure determination (monoclinic, P21/n, a = 11.6557(3) ?, b = 20.5382(5) ?, c = 13.9281(3) ?, β = 112.508(1)°, Z = 4) revealed the presence of [Re2(O2C(CO)Et)Cl6]− anions and tetra-n-butylammonium cations. The central [Re2]6+ core with a Re≣Re quadruple bond of 2.2263(3) ? length is μ2-bridged by one 2-oxobutanoato ligand and additionally coordinated by six chlorido ligands. Each dirhenate unit is linked via two Re···Cl contacts to dimeric, centrosymmetric entities of the constitution {[Re2(O2C(CO)Et)Cl6]2}2−. In the crystal, these dimers of dinuclear complexes are separated from each other by the bulky tetra-n-butylammonium cations. 相似文献11.
The influence of structural defect ordering on ionic conductivity (σ) in the cubic (fluorite) modification of BiO0.5F2.0 oxyfluoride has been investigated. Upon cooling, the disordered fluorite BiO0.5F2.0 phase undergoes a reversible transition to an ordered form. This transition manifests itself as a jump in the temperature
dependence σ(T) near 583 ± 6 K. The ordering of structural defects deteriorates the characteristics of ion transport in BiO0.5F2.0. At 500 K, the σ value for the ordered phase is 1 × 10−4 S/cm, whereas an extrapolation to this temperature for the disordered phase gives σ = 4 × 10−4 S/cm. 相似文献
12.
Nadia Belfguira Siwar Walha Abdelhamid Ben Salah Frédéric Hatert André Mathieu Fransolet Ahlem Kabadou 《Journal of chemical crystallography》2010,40(12):1125-1128
Abstract
Single crystals of iron and manganese phosphate Fe6.36Mn0.64(PO3(OH))4(PO4)2 was synthesized by hydrothermal method. The compound crystallizes in the Fe7(PO4)6 structure type and is isotypic with the solid solution \textM7 - \textx \textM\textx¢ ( \textHPO4 )4 ( \textPO4 )2 {\text{M}}_{{7 - {\text{x}}}} {\text{M}}_{\text{x}}^{\prime} \left( {{\text{HPO}}_{4} } \right)_{4} \left( {{\text{PO}}_{4} } \right)_{2} where M is Fe, Co, Mg, Mn. The compound is triclinic, P-1, a = 6.571(5), b = 7.993(3), c = 9.547(2) Ǻ, α = 103.97(1)°, β = 109.29(2)°, γ = 101.57(3)°. The structure is based on a three-dimensional framework of distorted edge-sharing MO6 and MO5 polyhedra, forming infinite chains, which are interlinked by corner-sharing with PO4 tetrahedra. The formula unit is centrosymmetric, with all atoms in general positions except for one Fe atom, which has site symmetry −1. 相似文献13.
Annamária Krajníková Róbert Gyepes Katarína Győryová 《Journal of chemical crystallography》2010,40(8):650-655
Abstract
The syntheses and structural characterizations of two novel 2-bromobenzoatozinc(II) complexes—[Zn(2-BrC6H4COO)2] n (I) and [Zn(2-BrC6H4COO)2(mnad)]2 (II), where mnad is N-methylnicotinamide are reported. Compound (I) crystallized with a monoclinic lattice (space group P21/c) and is polymeric in solid state. Its cell parameters are: a = 7.37220(10) Å, b = 19.9639(3) Å, c = 30.2756(5) Å, β = 94.7510(7)°, V = 4440.59(12) Å3, Z = 4. The coordination environments of all zinc atoms are distorted tetrahedra built from four carboxylate oxygen atoms coming from four 2-bromobenzoato ligands. Compound (II) crystallized with a monoclinic lattice (space group P21/c) with a = 11.7488(2) Å, b = 20.3683(3) Å, c = 9.30130(10) Å, β = 100.3941(11)°, V = 2189.30(5) Å3, Z = 2. This dimeric molecule features a paddle-wheel [Zn2O8] cage in solid state; the coordination environment of the central atom is square pyramidal consisting of four carboxylate oxygen atoms and the pyridine N atom of the mnad ligand. 相似文献14.
Assia Djeghri Fadila Balegroune Achoura Guehria-Laidoudi Thierry Roisnel 《Journal of chemical crystallography》2007,37(2):97-101
The title compound [Cu2(OOC-(CH2)6-COO)2] was synthesized and its crystal structure has been determined by single crystal X-ray diffraction methods. The complex crystallizes
in the triclinic space group P-1 with a=5.1077(5) ?, b=8.362(2) ?, c=11.378(2) ?, α=93.773(6)°, β=97.587(9)°, γ=90.493(’9)°
and D
cal=1.629 mg/m3 for Z=1.
The structure is polymeric and consists of discrete anhydrous centrosymmetric binuclear units [Cu2(OOC-(CH2)6-COO)2]. The two copper(II) centres bridged by the suberate groups in a syn-syn conformation, are in pentacoordinated distorted
square-pyramidal coordination environment, with an intramolecular Cu–Cu distance of 2.5793(10) ?. Each binuclear unit, related
to the next through μoxo bridges with a Cuμoxo–Cuμoxo separation of 3.2326(10)?, defines infinite chains of one-edge sharing CuO5 square pyramid. 相似文献
15.
T. I. Mel’nikova G. M. Kuz’micheva V. B. Rybakov N. B. Bolotina A. B. Dubovskii 《Crystallography Reports》2011,56(2):227-232
X-ray diffraction studies of sillenite Bi24V2O40 single crystals grown by the hydrothermal method are performed for a separate crystal and powdered crystals. It is found
that the composition of the two specimens is described by the (Bi24 − x
▭
x
)[Bi
y
3+V1−y
5+]2 O40 general formula with completely populated oxygen sites but differs in the content of vacancies at the bismuth site (this
was established for the first time) and the Bi: V ratio at the tetrahedral site. The structural models of all the vanadium-containing
sillenites reported in the literature are considered, and the possibility that Bi atoms are located at the centers of BiO4 tetrahedra is established. 相似文献
16.
Chengzhi Xie Baofeng Zhang Xiaoqing Wang Ruji Wang Guangqiu Shen Dezhong Shen 《Journal of chemical crystallography》2007,37(1):25-29
A novel cobalt complex [Co(2,5-PDC)2(H2O)2Co(H2O)4]·4H2O (2,5-PDCH2 = 2,5-pyridinedicarboxylic acid) was synthesized and its crystal structure has been determined by X-ray diffraction. The
crystallographic data are: triclinic P−1, a = 7.112(2) ?, b = 8.939(3) ?, c = 9.719(3) ?, α = 91.153(5)°, β = 101.136(5)°, γ = 108.001(4)°, V = 574.4(3) ?3, Z = 1. The compound [Co(2,5-PDC)2(H2O)2Co(H2O)4]·4H2O exhibits a novel one-dimensional network constructed from the interconnection of Co(2,5-PDC)2(H2O)2 and Co(H2O)4, in which two kinds of six-coordinated Co(II) atoms have both octahedral coordination environments. Each 2,5-PDC anion connects
two different coordinated cobalt ions alternately in an one-dimensional chain. The zigzag 1D alternating chains are linked
by extensive hydrogen bonds to form a three-dimensional (3D) supramolecular structure, in which uncoordinated solvate molecules
act as space filling particles.
Supplementary data CCDC-264249 contains the supplementary crystallographic data for this paper. Copies of this information may be obtained free
of charge from the Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: t44–1223–336033; e-mail: deposit@ccdc.cam.ac.uk
or ) or also available from the author Xiaoqing Wang. 相似文献
17.
S. A. Sveleba I. M. Katerinchuk O. V. Semotyuk I. M. Kunyo I. V. Karpa E. I. Phitsych Yu. I. Pankivskyi 《Crystallography Reports》2010,55(2):253-257
The optical birefringence, optical indicatrix rotation, and residual intensity have been experimentally investigated in the
parent and incommensurate phases of [N(CH3)4]2ZnCl4 crystals doped with Ni2+. The temperature dependences obtained are nonlinear in a wide temperature range (T
i
− 360 K). It is shown that the nature of this nonlinearity is related to the presence of local spatial regions of the correlated
motion of tetrahedral groups. It is established that the deformation of tetrahedral groups increases the temperature range
of existence of these regions. 相似文献
18.
A. I. Beskrovnyi S. G. Vasilovskii A. V. Belushkin L. S. Smirnov A. M. Balagurov M. L. Martinez Sarrion L. Mestres M. Herriaz 《Crystallography Reports》2003,48(3):396-400
A new compound of composition Bi2.53Li0.29Nb2O9 was synthesized in the course of the search for new materials with high ionic conductivity. Its crystal structure was determined from the neutron diffraction data. The new compound Bi2.53Li0.29Nb2O9 is crystallized in the orthorhombic system, sp. gr. Cmc21, and unit-cell parameters a = 24.849(1) Å, b = 5.4536(3) Å, and c = 5.4619(2) Å at T = 290 K (a = 24.843(2) Å, b = 5.4456(5) Å, and c = 5.4546(5) Å at T = 10 K). Within the temperature range 10–870 K, no structural phase transitions were revealed. The atomic coordinates and the thermal factors in the isotropic approximation were refined by the Rietveld method at 290 and 10 K. The data obtained were analyzed based on the calculated local balance of bond strengths. 相似文献
19.
A. U. Sheleg E. M. Zub A. Ya. Yachkovskii S. N. Mustafaeva E. M. Kerimova 《Crystallography Reports》2012,57(2):283-285
The crystallographic and dynamic characteristics of TlInSe2 and TlGaTe2 crystals have been studied by X-ray diffraction in the temperature range of 85–320 K. The temperature dependences of the
unit-cell parameters a of TlInSe2 and TlGaTe2 crystals, as well as their coefficients of thermal expansion along the [100] direction, are determined. The concentration
dependences of the unit-cell parameters a and c for (TlInSe2)1 − x
(TlGaTe2)
x
crystals are measured. Anomalies are found in the temperature dependences of the unit-cell parameters a and, correspondingly, the coefficient of thermal expansion, indicating the existence of phase transitions in TlInSe2 and TlGaTe2 crystals. 相似文献
20.
Dennis W. Bennett Tasneem A. Siddiquee Daniel T. Haworth Sergey V. Lindeman 《Journal of chemical crystallography》2007,37(3):207-212
The crystal and molecular structure of Sc(CH3COCHCOCF3)3 has been determined by X-ray diffraction. The compound crystallizes as pure mer-isomer in the orthorhombic space group Pbca with lattice parameters a=15.166(8) ?, b=13.560(7) ?, c=19.327(10) ?, α=β=γ=90°, V=3974(4) ?3, Z=8. The complex at 100 K is partially disordered in the crystal structure in an approximate 5:1 ratio with 83% fluorine population
at C-11 and 17% at C-15. NMR data is compared to that previously reported. 相似文献