The third-normal stress difference in entangled melts: Quantitative stress-optical measurements in oscillatory shear

Stress-optical measurements are used to quantitatively determine the third-normal stress difference (N ₃ = N ₁ + N ₂) in three entangled polymer melts during small amplitude (<15%) oscillatory shear over a wide dynamic range. The results are presented in terms of the three material functions that describe N ₃ in oscillatory shear: the real and imaginary parts of its complex amplitude ₃ ^* = ₃ - i ₃ , and its displacement ₃ ^d . The results confirm that these functions are related to the dynamic modulus by ² ₃ ^* ()=(1-)[G ^*())– G ^*(2)] and ² ₃ ^d ()=(1- )G() as predicted by many constitutive equations, where = –N ₂/N ₁. The value of (1-) is found to be 0.69±0.07 for poly(ethylene-propylene) and 0.76±0.07 for polyisoprene. This corresponds to –N ₂/N ₁ = 0.31 and 0.24±0.07, close to the prediction of the reptation model when the independent alignment approximation is used, i.e., –N ₂/N ₁ = 2/7 – 0.28.     

Flow over a body with development of a steady separation zone as re → ∞

This paper discusses formulation of the total problem of flow of an incompressible liquid over a body, with formation of a closed stationary separation zone as Re . The scheme used is based on the method of matched asymptotic expansions [1]. Following [1], it is postulated that the separated zone is developed (i.e., it is not infinitely fragmented and does not vanish as Re ), and the flow inside it has a definite degree of regularity with respect to Re. With these hypotheses we can use the Prandtl-Batchelor theorem [2], which states that, in the limit as Re , a region of circulating flow becomes vortex flow of an inviscid liquid with constant vorticity . Therefore, a basis for constructing matched asymptotic expansions is the vortex-potential problem (the problem of determining a stream function , satisfying the equation = 0 in the region of translational motion and the equation = in a certain region, unknowna priori, of circulating motion). In the general case the solution of the vortex-potential problem depends on two parameters: the total pressure p_o and the vorticity in the separated zone. These parameters appear in the condition for matching the solutions of the first and second boundary-layer approximations (at the boundary of the separated zone for the end Re values) with the corresponding solutions for the inviscid flow. It is shown in the present paper that the conditions for matching the cyclic boundary layer with the external translational flow are the same additional relations which allow us to close the total problem. Thus, in using the method of matched asymptotic expansions to solve the problem of flow over a body with closed stationary separation zones one must simultaneously consider no less than two approximations.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 28–37, March–April, 1978.The authors thank G. Yu. Stepanov for discussion of the paper and valuable comments.     

New trends in the analysis of masonry structures

The modern theory of masonry structures has been set up on the hypothesis of no-tension behaviour, with the aim of offering a reference model, independent of materials and building techniques employed. This hypothesis gives rise to inequalities which have to be satisfied by the stress tensor components and, as a dual aspect, to the kinematic behaviour characteristics of media which can be classified as lying between solids and fluids: the structure of the masonry material consists of particles reacting elastically only when in contact. An examination of the plane-stress problem leads us to define, within the prescribed domain under admissible loads, three different subdomains with null, regular, or non-regular principal stress tensors, respectively. As the boundaries of such subdomains are not known a priori, the problem can be classified as a free boundary value problem. The analysis concerns mainly the subdomains where the stress tensor is non-regular; and a non-regularity condition det =0 is added to the equilibrium equations. This condition makes the stress problem isostatic and leads to a violation of Saint-Venant's compliance conditions on strains. Hence there is a need to introduce a strain tensor, not related to the stress tensor, which can be decomposed into an extensional component and a shearing component; we prove that such strains, of the class ^c, are similar to those of the theory of plastic flow. From the point of view of computational analysis the anelastic strains are considered as given distortions; they are computed by means of the Haar-Kármán principle, modified for computational purposes by an idea of Prager and Hodge.

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Sommario La moderna teoria delle strutture murarie, fondata sulla rigorosa non reagenza a trazione del materiale, ha lo scopo di fornire un modello di riferimento indipendente sia dalle caratteristiche del materiale sia dalle techniche costruttive impiegate. L'ipotesi di non reagenza a trazione si traduce in disuguaglianze che le componenti del tensore di stress devono verificare; dualmente il comportamento caratteristico cinematico può esser classificato di confine, come del resto la stessa statica, tra solidi e fluidi: la struttura ipotizzata del materiale muratura consiste di particelle che reagiscono solo se sono in contatto. L'esame del problema piano porta a definire all'interno del dominio di definizione tre differenti tipi di sub-regioni in cui lo stress è nullo, canonico, o singolare. Poiché le frontiere di queste sub-regioni non sono note a priori il problema può anche essere classificato di frontiera libera. L'analisi concerne fondamentalmente la sub-regione in cui il tensore è non regolare, perché deve verificare anche la condizione det =0. Ciò rende isostatico il problema e conduce anche alla violazione della condizione di integrabilità delle deformazioni. Questo passaggio può essere superato introducendo un tensore di deformazioni a tensioni nulle che si può decomporre in una componente estensionale ed in una componente di scorrimento; si dimostra che queste deformazioni sono equivalenti a quelle che intervengono nella Teoria del flusso plastico. Dal punto di vista computazionale le deformazioni anelastiche sono considerate come distorsioni impresse determinate attraverso il principio di Haar-Kármán modificato, per le techniche computazionali, su idee di Prager e Hodge.

     

Existence theorem for a minimum problem with free discontinuity set

We study the variational problem Where is an open set in ⁿ ,n2gL ^q () L (), 1q<+, O<, <+ andH _n–1 is the (n–1)-dimensional Hausdorff Measure.     

Unsteady Viscous Flows about Bodies: Vorticity Release and Forces

The force (drag and lift) exerted on a body moving in a viscous fluid is expressed via the free and bound vorticity moments, and the role of vortex shedding is discussed. The formulation encompasses classical, inviscid flows, and leads to efficient computational methods. Numerical results for a few prototype flows are presented.     

On internal variable models of phase transitions

Some models of phase equilibria as local minima of a Lagrangian functional are shown to allow configurations where macroscopic strain is generally discontinuous, but internal variables (and derivatives) vary smoothly across the phases. The stability properties of regularizations of such equilibria are also investigated.     

Existence and Uniqueness of Time-Periodic Physically Reasonable Navier-Stokes Flow Past a Body

Let be a three-dimensional exterior domain of class C^2,, 0<<1. Assume that a Navier-Stokes liquid is moving in under the action of a body force F that is time-periodic of period T, and that the velocity of the liquid is zero at spatial infinity. In this paper we show that, if F satisfies suitable conditions, and its norm, in appropriate function spaces, is sufficiently small, there is at least one time-periodic strong solution. Furthermore, the velocity field v of such a solution decays to zero for large |x| as |x|^–1 and its spatial gradient decays as |x|^–2, both uniformly in time. In addition, the pressure p decays like |x|^–2 and its gradient like |x|^–3, for almost all t[0,T]. In the special case where F is time-independent, these solutions are also time-independent and coincide with Finns physically reasonable solutions [4]. Moreover, we show that our time-periodic solutions are unique in a very large class, namely, the class of time-periodic weak solutions satisfying the energy inequality and with corresponding pressure fields verifying mild summability conditions in ×[0,T].     

A New Optimal Growth Constant for the Hele–Shaw Instability

We study the immiscible displacement of the oil from a homogeneous porous medium by using a less viscous fluid (water). We use the Hele–Shaw model, then a sharp interface exists between the fluids. The fingering phenomenon appears, first studied by Saffman and Taylor (1958). Gorell and Homsy (1983) consider an intermediate region (I. R.) between water and oil, containing a polymer mixture. The unknown viscosity in I. R. is a parameter which can improve the stability of the I. R.–oil interface. A numerical optimal viscosity profile in I. R. is given. Carasso and Paa (1998) obtain an explicit formula for an optimal viscosity profile in I. R. An upper estimation of the growth constant is given. In this paper, a very slow viscosity profile in I. R. is defined and an optimal formula for the growth constant is obtained, less than the previous estimation of Carasso and Paa. Moreover, this formula is similar with the Saffman–Taylor result, only the water viscosity is replaced by the limit value of viscosity in I. R. on the interface with the oil. We explain the apparent contradiction between the previous results of Gorell and Homsy (1983) and Paa and Polisevski (1992).     

Asymptotic analysis of equilibrium states for rotating turbulent flows

The equilibrium states of homogeneous turbulence simultaneously subjected to a mean velocity gradient and a rotation are examined by using asymptotic analysis. The present work is concerned with the asymptotic behavior of quantities such as the turbulent kinetic energy and its dissipation rate associated with the fixed point (/kS)=0, whereS is the shear rate. The classical form of the model transport equation for (Hanjalic and Launder, 1972) is used. The present analysis shows that, asymptotically, the turbulent kinetic energy (a) undergoes a power-law decay with time for (P/)<1, (b) is independent of time for (P/)=1, (c) undergoes a power-law growth with time for 1<(P/)<(C ₂–1), and (d) is represented by an exponential law versus time for (P/)=(C ₂–1)/(C ₁–1) and (/kS)>0 whereP is the production rate. For the commonly used second-order models the equilibrium solutions forP/,II, andIII (whereII andIII are respectively the second and third invariants of the anisotropy tensor) depend on the rotation number when (P/kS)=(/kS)=0. The variation of (P/kS) andII versusR given by the second-order model of Yakhot and Orzag are compared with results of Rapid Distortion Theory corrected for decay (Townsend, 1970).     

Uniqueness and the maximum principle for quasilinear elliptic equations with quadratic growth conditions

In this paper, we show that the maximum principle holds for quasilinear elliptic equations with quadratic growth under general structure conditions.Two typical particular cases of our results are the following. On one hand, we prove that the equation (1) {ie77-01} where {ie77-02} and {ie77-03} satisfies the maximum principle for solutions in H ¹()L(), i.e., that two solutions u ₁, u ₂H¹() L() of (1) such that u ₁u₂ on , satisfy u ₁u₂ in . This implies in particular the uniqueness of the solution of (1) in H ₀ ¹ ()L().On the other hand, we prove that the equation (2) {ie77-04} where fH^–1() and g(u)>0, g(0)=0, satisfies the maximum principle for solutions uH¹() such that g(u)¦Du|{²L¹(). Again this implies the uniqueness of the solution of (2) in the class uH ₀ ¹ () with g(u)¦Du|{²L¹().In both cases, the method of proof consists in making a certain change of function u=(v) in equation (1) or (2), and in proving that the transformed equation, which is of the form (3) {ie77-05}satisfies a certain structure condition, which using ((v₁ -v ₂)⁺)ⁿ for some n>0 as a test function, allows us to prove the maximum principle.