Semianalytical Solution for \text{ CO}_{2} Plume Shape and Pressure Evolution During \text{ CO}_{2} Injection in Deep Saline Formations

The injection of supercritical carbon dioxide ( $\text{ CO}_{2})$ in deep saline aquifers leads to the formation of a $\text{ CO}_{2}$ rich phase plume that tends to float over the resident brine. As pressure builds up, $\text{ CO}_{2}$ density will increase because of its high compressibility. Current analytical solutions do not account for $\text{ CO}_{2}$ compressibility and consider a volumetric injection rate that is uniformly distributed along the whole thickness of the aquifer, which is unrealistic. Furthermore, the slope of the $\text{ CO}_{2}$ pressure with respect to the logarithm of distance obtained from these solutions differs from that of numerical solutions. We develop a semianalytical solution for the $\text{ CO}_{2}$ plume geometry and fluid pressure evolution, accounting for $\text{ CO}_{2}$ compressibility and buoyancy effects in the injection well, so $\text{ CO}_{2}$ is not uniformly injected along the aquifer thickness. We formulate the problem in terms of a $\text{ CO}_{2}$ potential that facilitates solution in horizontal layers, with which we discretize the aquifer. Capillary pressure is considered at the interface between the $\text{ CO}_{2}$ rich phase and the aqueous phase. When a prescribed $\text{ CO}_{2}$ mass flow rate is injected, $\text{ CO}_{2}$ advances initially through the top portion of the aquifer. As $\text{ CO}_{2}$ is being injected, the $\text{ CO}_{2}$ plume advances not only laterally, but also vertically downwards. However, the $\text{ CO}_{2}$ plume does not necessarily occupy the whole thickness of the aquifer. We found that even in the cases in which the $\text{ CO}_{2}$ plume reaches the bottom of the aquifer, most of the injected $\text{ CO}_{2}$ enters the aquifer through the layers at the top. Both $\text{ CO}_{2}$ plume position and fluid pressure compare well with numerical simulations. This solution permits quick evaluations of the $\text{ CO}_{2}$ plume position and fluid pressure distribution when injecting supercritical $\text{ CO}_{2}$ in a deep saline aquifer.     

Mixed Convection Boundary-Layer Flow Over a Vertical Surface Embedded in a Porous Material Subject to a Convective Boundary Condition

The mixed convection boundary-layer flow on one face of a semi-infinite vertical surface embedded in a fluid-saturated porous medium is considered when the other face is taken to be in contact with a hot or cooled fluid maintaining that surface at a constant temperature $T_\mathrm{{f}}$ . The governing system of partial differential equations is transformed into a system of ordinary differential equations through an appropriate similarity transformation. These equations are solved numerically in terms of a dimensionless mixed convection parameter $\epsilon $ and a surface heat transfer parameter $\gamma $ . The results indicate that dual solutions exist for opposing flow, $\epsilon <0$ , with the dependence of the critical values $\epsilon _\mathrm{{c}}$ on $\gamma $ being determined, whereas for the assisting flow $\epsilon >0$ , the solution is unique. Limiting asymptotic forms for both $\gamma $ small and large and $\epsilon $ large are also discussed.     

Global Compensated Compactness Theorem for General Differential Operators of First Order

Let A ₁(x, D) and A ₂(x, D) be differential operators of the first order acting on l-vector functions ${u= (u_1, \ldots, u_l)}$ in a bounded domain ${\Omega \subset \mathbb{R}^{n}}$ with the smooth boundary ${\partial\Omega}$ . We assume that the H ¹-norm ${\|u\|_{H^{1}(\Omega)}}$ is equivalent to ${\sum_{i=1}^2\|A_iu\|_{L^2(\Omega)} + \|B_1u\|_{H^{\frac{1}{2}}(\partial\Omega)}}$ and ${\sum_{i=1}^2\|A_iu\|_{L^2(\Omega)} + \|B_2u\|_{H^{\frac{1}{2}}(\partial\Omega)}}$ , where B _i  = B _i (x, ν) is the trace operator onto ${\partial\Omega}$ associated with A _i (x, D) for i = 1, 2 which is determined by the Stokes integral formula (ν: unit outer normal to ${\partial\Omega}$ ). Furthermore, we impose on A ₁ and A ₂ a cancellation property such as ${A_1A_2^{\prime}=0}$ and ${A_2A_1^{\prime}=0}$ , where ${A^{\prime}_i}$ is the formal adjoint differential operator of A _i (i = 1, 2). Suppose that ${\{u_m\}_{m=1}^{\infty}}$ and ${\{v_m\}_{m=1}^{\infty}}$ converge to u and v weakly in ${L^2(\Omega)}$ , respectively. Assume also that ${\{A_{1}u_m\}_{m=1}^{\infty}}$ and ${\{A_{2}v_{m}\}_{m=1}^{\infty}}$ are bounded in ${L^{2}(\Omega)}$ . If either ${\{B_{1}u_m\}_{m=1}^{\infty}}$ or ${\{B_{2}v_m\}_{m=1}^{\infty}}$ is bounded in ${H^{\frac{1}{2}}(\partial\Omega)}$ , then it holds that ${\int_{\Omega}u_m\cdot v_m \,{\rm d}x \to \int_{\Omega}u\cdot v \,{\rm d}x}$ . We also discuss a corresponding result on compact Riemannian manifolds with boundary.     

Regularity and Asymptotic Behavior of Nonlinear Stefan Problems

We study the following nonlinear Stefan problem $$\left\{\begin{aligned}\!\!&u_t\,-\,d\Delta u = g(u) & &\quad{\rm for}\,x\,\in\,\Omega(t), t > 0, \\ & u = 0 \, {\rm and} u_t = \mu|\nabla_{x} u|^{2} &&\quad {\rm for}\,x\,\in\,\Gamma(t), t > 0, \\ &u(0, x) = u_{0}(x) &&\quad {\rm for}\,x\,\in\,\Omega_0,\end{aligned} \right.$$ where ${\Omega(t) \subset \mathbb{R}^{n}}$ ( ${n \geqq 2}$ ) is bounded by the free boundary ${\Gamma(t)}$ , with ${\Omega(0) = \Omega_0}$ , μ and d are given positive constants. The initial function u ₀ is positive in ${\Omega_0}$ and vanishes on ${\partial \Omega_0}$ . The class of nonlinear functions g(u) includes the standard monostable, bistable and combustion type nonlinearities. We show that the free boundary ${\Gamma(t)}$ is smooth outside the closed convex hull of ${\Omega_0}$ , and as ${t \to \infty}$ , either ${\Omega(t)}$ expands to the entire ${\mathbb{R}^n}$ , or it stays bounded. Moreover, in the former case, ${\Gamma(t)}$ converges to the unit sphere when normalized, and in the latter case, ${u \to 0}$ uniformly. When ${g(u) = au - bu^2}$ , we further prove that in the case ${\Omega(t)}$ expands to ${{\mathbb R}^n}$ , ${u \to a/b}$ as ${t \to \infty}$ , and the spreading speed of the free boundary converges to a positive constant; moreover, there exists ${\mu^* \geqq 0}$ such that ${\Omega(t)}$ expands to ${{\mathbb{R}}^n}$ exactly when ${\mu > \mu^*}$ .     

Spatiotemporal complexity of a three-species ratio-dependent food chain model

In this paper, we investigate the complex dynamics of a ratio-dependent spatially extended food chain model. Through a detailed analytical study of the reaction–diffusion model, we obtain some conditions for global stability. On the basis of bifurcation analysis, we present the evolutionary process of pattern formation near the coexistence equilibrium point $(N^*,P^*,Z^*)$ via numerical simulation. And the sequence cold spots $\rightarrow $ stripe–spots mixtures $\rightarrow $ stripes $\rightarrow $ hot stripe–spots mixtures $\rightarrow $ hot spots $\rightarrow $ chaotic wave patterns controlled by parameters $a_1$ or $c_1$ in the model are presented. These results indicate that the reaction–diffusion model is an appropriate tool for investigating fundamental mechanism of complex spatiotemporal dynamics.     

Simultaneous measurement of fluctuating velocity and pressure in the near wake of a circular cylinder

Simultaneous measurement of fluctuating velocity and pressure by a static-pressure probe and a hot-wire probe was performed in the near wake of a circular cylinder, in order to strengthen reliability of the measurement technique. Effect of geometry of the static-pressure probe was systematically investigated, and validity of the measurement results was addressed by quantitative comparison with reference data by a large-eddy simulation. Interference between the probes was found to mainly depend on the diameter of the pressure probe and only weakly on the length. A certain time lag between the velocity and pressure signals was detected in the experiment, and the measurement results of velocity–pressure correlation $\overline{up}$ and $\overline{vp}$ obtained with the correction of the time lag were in good agreement with the computational results. It was also found that the measurement of $\overline{vp}$ is extremely sensitive to a small time lag between the velocity and pressure signals, while that of $\overline{up}$ is not.     

A New Insight into the Convective Boundary Condition

The steady mixed convection boundary layer flows over a vertical surface adjacent to a Darcy porous medium and subject respectively to (i) a prescribed constant wall temperature, (ii) a prescribed variable heat flux, $q_\mathrm{w} =q_0 x^{-1/2}$ q w = q 0 x ? 1 / 2 , and (iii) a convective boundary condition are compared to each other in this article. It is shown that, in the characteristic plane spanned by the dimensionless flow velocity at the wall ${f}^{\prime }(0)\equiv \lambda $ f ′ ( 0 ) ≡ λ and the dimensionless wall shear stress $f^{\prime \prime }(0)\equiv S$ f ′ ′ ( 0 ) ≡ S , every solution $(\lambda , S)$ ( λ , S ) of one of these three flow problems at the same time is also a solution of the other two ones. There also turns out that with respect to the governing mixed convection and surface heat transfer parameters $\varepsilon $ ε and $\gamma $ γ , every solution $(\lambda , S)$ ( λ , S ) of the flow problem (iii) is infinitely degenerate. Specifically, to the very same flow solution $(\lambda , S)$ ( λ , S ) there corresponds a whole continuous set of values of $\varepsilon $ ε and $\gamma $ γ which satisfy the equation $S=-\gamma (1+\varepsilon -\lambda )$ S = ? γ ( 1 + ε ? λ ) . For the temperature solutions, however, the infinite degeneracy of the velocity solutions becomes lifted. These and further outstanding features of the convective problem (iii) are discussed in the article in some detail.     

A Comment on the Flow and Heat Transfer Past a Permeable Stretching/Shrinking Surface in a Porous Medium: Brinkman Model

An analytical solution is presented for the boundary-layer flow and heat transfer over a permeable stretching/shrinking surface embedded in a porous medium using the Brinkman model. The problem is seen to be characterized by the Prandtl number $Pr$ , a mass flux parameter $s$ , with $s>0$ for suction, $s=0$ for an impermeable surface, and $s<0$ for blowing, a viscosity ratio parameter $M$ , the porous medium parameter $\Lambda $ and a wall velocity parameter $\lambda $ . The analytical solution identifies critical values which agree with those previously determined numerically (Bachok et al. Proceedings of the fifth International Conference on Applications of Porous Media, 2013) and shows that these critical values, and the consequent dual solutions, can arise only when there is suction through the wall, $s>0$ .     

Experimental Characterization of Porosity Structure and Transport Property Changes in Limestone Undergoing Different Dissolution Regimes

Limestone dissolution by $\hbox {CO}_2$ -rich brine induces critical changes of the pore network geometrical parameters such as the pore size distribution, the connectivity, and the tortuosity which govern the macroscopic transport properties (permeability and dispersivity) that are required to parameterize the models, simulating the injection and the fate of $\hbox {CO}_2$ . A set of four reactive core-flood experiments reproducing underground conditions ( $T = 100\,^{\circ }\hbox {C}$ and $P = 12$ MPa) has been conducted for different $\hbox {CO}_2$ partial pressures $(0.034 < P_{\mathrm{CO}_2}< 3.4\; \hbox {MPa})$ in order to study the different dissolution regimes. X-ray microtomographic images have been used to characterize the changes in the structural properties from pore scale to Darcy scale, while time-resolved pressure loss and chemical fluxes enabled the determination of the sample-scale change in porosity and permeability. The results show the growth of localized dissolution features associated with high permeability increase for the highest $P_{\mathrm{CO}_2}$ , whereas dissolution tends to be more homogeneously distributed for lower values of $P_{\mathrm{CO}_2}$ . For the latter, the higher the $P_{\mathrm{CO}_2}$ , the more the dissolution patterns display ramified structures and permeability increase. For the lowest value of $P_{\mathrm{CO}_2}$ , the preferential dissolution of the calcite cement associated with the low dissolution kinetics triggers the transport that may locally accumulate and form a microporous material that alters permeability and produces an anti-correlated porosity–permeability relationship. The combined analysis of the pore network geometry and the macroscopic measurements shows that $P_{\mathrm{CO}_2}$ regulates the tortuosity change during dissolution. Conversely, the increase of the exponent value of the observed power law permeability–porosity trend while $P_{\mathrm{CO}_2}$ increases, which appears to be strongly linked to the increase of the effective hydraulic diameter, depends on the initial rock structure.     

Unsteady flow with separation behind a shock wave diffracting over curved walls

The unsteady separation of the compressible flow field behind a diffracting shock wave was investigated along convex curved walls, using shock tube experimentation at large length and time scales, complemented by numerical computation. Tests were conducted at incident shock Mach numbers of $M_{\hbox {s}} =$ 1.5 and 1.6 over a 100 mm radius wall over a dimensionless time range up to $\tau \le $ 6.45. The development of the near wall flow at $M_{\hbox {s}} =$ 1.5 has been described in detail and is very similar to that observed for slightly lower $\tau $ ’s at $M_{\hbox {s}} =$ 1.6. Computations were performed at wall radii of 100 and 200 mm and for incident shock Mach numbers from 1.5 up to and including Mach 2.0. Comparing dimensionless times for different size walls shows that for a given value of $\tau $ the flow field is very similar for the various wall radii published to date and tested in this study. Previously published results that were examined alongside the results from this study had typical values of $1.6 < \tau < 3.2$ . At the later times presented here, flow features were observed that previously had only been observed at higher Mach numbers. The larger length scales allowed for a degree of Reynolds number independence in the results published here. The effect of turbulence on the numerical and experimental results could not be adequately examined due to limitations of the flow imaging system used and a number of questions remain unanswered.     

Predominant Gas Transport in Microporous Hydrotalcite–Silica Membrane

The prepared microporous hydrotalcite (HT)–silica membrane was found to exhibit the molecular sieving characteristic of pristine silica material and high $\mathrm{CO}_{2}$ adsorption capacity of HT. The combined properties made enhanced $\mathrm{CO}_{2}$ permeability and separability from $\mathrm{CH}_{4}$ possible. The gas transport in the membrane was predominantly surface adsorption. The porous membrane overcame the Knudsen limitation and yielded the highest separation selectivity of 120 at 40 % $\mathrm{CO}_{2}$ feed concentration, $30\,^{\circ }\mathrm{C}$ operating temperature, and 100 kPa pressure difference.     

Drainage of Capillary-Trapped Oil by an Immiscible Gas: Impact of Transient and Steady-State Water Displacement on Three-Phase Oil Permeability

In a previous paper (Dehghanpour et al., Phys Rev E 83:065302, 2011a), we showed that relative permeability of mobilized oil, $k_\mathrm{ro}$ , measured during tertiary gravity drainage, is significantly higher than that of the same oil saturation in other tests where oil is initially a continuous phase. We also showed that tertiary $k_\mathrm{ro}$ strongly correlates to both water saturation, $S_\mathrm{w}$ , water flux (water relative permeability), $k_\mathrm{rw}$ , and the change in water saturation with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . To develop a model and understanding of the enhanced oil transport, identifying which of these parameters ( $S_\mathrm{w},\,k_{\mathrm{rw}}$ , or $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ ) plays the controlling role is necessary, but in the previous experiments these could not be deconvolved. To answer the remaining question, we conduct specific three-phase displacement experiments in which $k_{\mathrm{rw}}$ is controlled by applying a fixed water influx, and $S_\mathrm{w}$ develops naturally. We obtain $k_{\mathrm{ro}}$ by using the saturation data measured in time and space. The results suggest that steady-state water influx, in contrast to transient water displacement, does not enhance $k_{\mathrm{ro}}$ . Instead, reducing water influx rate results in excess oil flow. Furthermore, according to our pore scale hydraulic conductivity calculations, viscous coupling and fluid positioning do not sufficiently explain the observed correlation between $k_{\mathrm{ro}}$ and $S_{\mathrm{w}}$ . We conclude that tertiary $k_{\mathrm{ro}}$ is controlled by the oil mobilization rate, which in turn is linked to the rate of water saturation decrease with time, $\mathrm{d}S_\mathrm{w}/\mathrm{d}t$ . Finally, we develop a simple model which relates tertiary $k_{\mathrm{ro}}$ to transient two-phase gas/water relative permeability.     

Dynamical Parallelepipeds in Minimal Systems

For a topological dynamical system $(X,T)$ ( X , T ) and $d\in \mathbb N $ d ∈ N , the associated dynamical parallelepiped $\mathbf{Q}^{[d]}$ Q [ d ] was defined by Host–Kra–Maass. For a minimal distal system it was shown by them that the relation $\sim _{d-1}$ ～ d ? 1 defined on $\mathbf{Q}^{[d-1]}$ Q [ d ? 1 ] is an equivalence relation; the closing parallelepiped property holds, and for each $x\in X$ x ∈ X the collection of points in $\mathbf{Q}^{[d]}$ Q [ d ] with first coordinate $x$ x is a minimal subset under the face transformations. We give examples showing that the results do not extend to general minimal systems.     

Non-uniqueness of solutions in asymptotically self-similar shock reflections

The present study addresses the self-similar problem of unsteady shock reflection on an inclined wedge. The start-up conditions are studied by modifying the wedge corner and allowing for a finite radius of curvature. It is found that the type of shock reflection observed far from the corner, namely regular or Mach reflection, depends intimately on the start-up condition, as the flow “remembers” how it was started. Substantial differences were found. For example, the type of shock reflection for an incident shock Mach number $M=6.6$ and an isentropic exponent $\gamma =1.2$ changes from regular to Mach reflection between $44^\circ $ and $45^\circ $ when a straight wedge tip is used, while the transition for an initially curved wedge occurs between $57^\circ $ and $58^\circ $ .     

Generalized Resolvent Estimates of the Stokes Equations with First Order Boundary Condition in a General Domain

In this paper, we prove unique existence of solutions to the generalized resolvent problem of the Stokes operator with first order boundary condition in a general domain ${\Omega}$ of the N-dimensional Eulidean space ${\mathbb{R}^N, N \geq 2}$ . This type of problem arises in the mathematical study of the flow of a viscous incompressible one-phase fluid with free surface. Moreover, we prove uniform estimates of solutions with respect to resolvent parameter ${\lambda}$ varying in a sector ${\Sigma_{\sigma, \lambda_0} = \{\lambda \in \mathbb{C} \mid |\arg \lambda| < \pi-\sigma, \enskip |\lambda| \geq \lambda_0\}}$ , where ${0 < \sigma < \pi/2}$ and ${\lambda_0 \geq 1}$ . The essential assumption of this paper is the existence of a unique solution to a suitable weak Dirichlet problem, namely it is assumed the unique existence of solution ${p \in \hat{W}^1_{q, \Gamma}(\Omega)}$ to the variational problem: ${(\nabla p, \nabla \varphi) = (f, \nabla \varphi)}$ for any ${\varphi \in \hat W^1_{q', \Gamma}(\Omega)}$ . Here, ${1 < q < \infty, q' = q/(q-1), \hat W^1_{q, \Gamma}(\Omega)}$ is the closure of ${W^1_{q, \Gamma}(\Omega) = \{ p \in W^1_q(\Omega) \mid p|_\Gamma = 0\}}$ by the semi-norm ${\|\nabla \cdot \|_{L_q(\Omega)}}$ , and ${\Gamma}$ is the boundary of ${\Omega}$ . In fact, we show that the unique solvability of such a Dirichlet problem is necessary for the unique existence of a solution to the resolvent problem with uniform estimate with respect to resolvent parameter varying in ${(\lambda_0, \infty)}$ . Our assumption is satisfied for any ${q \in (1, \infty)}$ by the following domains: whole space, half space, layer, bounded domains, exterior domains, perturbed half space, perturbed layer, but for a general domain, we do not know any result about the unique existence of solutions to the weak Dirichlet problem except for q =  2.     

A Fast Algorithm for Invasion Percolation

We present a computationally fast Invasion Percolation (IP) algorithm. IP is a numerical approach for generating realistic fluid distributions for quasi-static (i.e., slow) immiscible fluid invasion in porous media. The algorithm proposed here uses a binary-tree data structure to identify the site (pore) connected to the invasion cluster that is the next to be invaded. Gravity is included. Trapping is not explicitly treated in the numerical examples but can be added, for example, using a Hoshen–Kopelman algorithm. Computation time to percolation for a 3D system having $N$ total sites and $M$ invaded sites at percolation goes as $O(M \log M)$ for the proposed binary-tree algorithm and as $O(M N)$ for a standard implementation of IP that searches through all of the uninvaded sites at each step. The relation between $M$ and $N$ is $M = N^{D/E}$ , where $D$ is the fractal dimension of an infinite cluster and $E$ is Euclidean space dimension. In numerical practice, on finite-sized cubic lattices with invasion structures influenced by the injection boundary and boundary conditions lateral to the flow direction, we observe the scaling $M = N^{0.852}$ in 3D (valid through the second decimal place) instead of $M= N^{0.843}$ based on the infinite cluster fractal dimension $D=2.53$ .     

Hadamard Variational Formula for the Green’s Function of the Boundary Value Problem on the Stokes Equations

For every ${\varepsilon > 0}$ , we consider the Green’s matrix ${G_{\varepsilon}(x, y)}$ of the Stokes equations describing the motion of incompressible fluids in a bounded domain ${\Omega_{\varepsilon} \subset \mathbb{R}^d}$ , which is a family of perturbation of domains from ${\Omega\equiv \Omega_0}$ with the smooth boundary ${\partial\Omega}$ . Assuming the volume preserving property, that is, ${\mbox{vol.}\Omega_{\varepsilon} = \mbox{vol.}\Omega}$ for all ${\varepsilon > 0}$ , we give an explicit representation formula for ${\delta G(x, y) \equiv \lim_{\varepsilon\to +0}\varepsilon^{-1}(G_{\varepsilon}(x, y) - G_0(x, y))}$ in terms of the boundary integral on ${\partial \Omega}$ of ${G_0(x, y)}$ . Our result may be regarded as a classical Hadamard variational formula for the Green’s functions of the elliptic boundary value problems.     

Bounded and Unbounded Motions in Asymmetric Oscillators at Resonance

We consider the boundedness and unboundedness of solutions for the asymmetric oscillator $$\begin{aligned} x''+ax^+-bx^-+g(x)=p(t), \end{aligned}$$ where $x^+=\max \{x,0\},x^-=\max \{-x,0\}, a$ and $b$ are two positive constants, $ p(t)$ is a $2\pi $ -periodic smooth function and $g(x)$ satisfies $\lim _{|x|\rightarrow +\infty }x^{-1}g(x)=0$ . We establish some sharp sufficient conditions concerning the boundedness of all the solutions and the existence of unbounded solutions. It turns out that the boundedness of all the solutions and the existence of unbounded solutions have a close relation to the interaction of some well-defined functions $\Phi _p(\theta )$ and $\Lambda (h)$ . Some explicit conditions are given for the boundedness of all the solutions and the existence of unbounded solutions. Unlike many existing results in the literature where the function $g(x)$ is required to be a bounded function with asymptotic limits, here we allow $g(x)$ be unbounded or oscillatory without asymptotic limits.     

Microfluidic extensional rheometry using a hyperbolic contraction geometry

Microfluidic devices are ideally suited for the study of complex fluids undergoing large deformation rates in the absence of inertial complications. In particular, a microfluidic contraction geometry can be utilized to characterize the material response of complex fluids in an extensionally-dominated flow, but the mixed nature of the flow kinematics makes quantitative measurements of material functions such as the true extensional viscosity challenging. In this paper, we introduce the ‘extensional viscometer-rheometer-on-a-chip’ (EVROC), which is a hyperbolically-shaped contraction-expansion geometry fabricated using microfluidic technology for characterizing the importance of viscoelastic effects in an extensionally-dominated flow at large extension rates ( $\lambda \dot \varepsilon _a \gg 1$ , where $\lambda $ is the characteristic relaxation time, or for many industrial processes $\dot \varepsilon _a \gg 1$ s $^{-1}$ ). We combine measurements of the flow kinematics, the mechanical pressure drop across the contraction and spatially-resolved flow-induced birefringence to study a number of model rheological fluids, as well as several representative liquid consumer products, in order to assess the utility of EVROC as an extensional viscosity indexer.     

Elongational rheology of NIPAM-based hydrogels

Hydrogels of different composition based on the copolymerization of N-isopropyl acrylamide and surfmers of different chemical structure were tested in elongation using Hencky/real definitions for stress, strain, and strain rate, offering a more scientific insight into the effect of deformation on the properties. In a range between $\dot {\varepsilon }=10$ and 0.01 s $^{-1}$ , the material properties are independent of strain rate and show a very clear strain hardening with a “brittle” sudden fracture. The addition of surfmer increases the strain at break $\varepsilon _{\mathrm {H}}^{\max }$ and at the same time leads to a failure of hyperelastic models. The samples can be stretched up to Hencky strains $\varepsilon _{\mathrm {H}}^{\max }$ between 0.6 and 2.5, depending on the molecular structure, yielding linear Young’s moduli E $_{0}$ between 2,700 and 39,000 Pa. The strain-rate independence indicates an ideal rubberlike behavior and fracture in a brittle-like fashion. The resulting stress at break $\sigma _{\textrm max}$ can be correlated with $\varepsilon _{\mathrm {H}}^{\max } $ and $E_{0}$ as well as with the solid molar mass between the cross-linking points $M_{\mathrm {c}}^{\textrm {solids}} $ , derived from $E_{0}$ .