水岩化学作用对黑色页岩的化学损伤及力学劣化试验研究

为模拟黑色页岩化学风化中酸性水-页岩化学作用过程,本文对其进行氧化条件下的不同pH值H2SO4溶液的非平衡流动态腐蚀性试验,获得了黑色页岩化学腐蚀前后矿物变化、相对质量损失、次生孔隙率、纵波波速变化及微观结构特征的变化。通过单轴压缩试验,获得黑色页岩在不同浸泡时段的变形和强度特性规律,探讨了酸性水对黑色页岩化学作用的化学损伤和力学劣化的腐蚀效应及机制。研究表明,页岩试件在化学腐蚀后,易溶性矿物成分减小,黏土矿物增加,同时矿物胶结变得松散,矿物边缘变得模糊;页岩试件的相对质量损失与次生孔隙率随pH值减小和浸泡时间的增长而增大,而纵波波速则减小;其力学特性有从脆性破坏向延性破坏转化的趋势,单轴抗压强度和弹性模量有随pH值减小和浸泡时间的增长而减小的趋势。基于次生孔隙率,构建化学损伤变量来描述试件化学-力学损伤演化过程。分析酸性水-页岩化学作用的机理主要为:溶解作用、氧化作用、水解作用及离子交换吸附作用。     

Microstructural modeling of asphalt concrete using a coupled moisture–mechanical constitutive relationship

The coupled effect of moisture diffusion and mechanical loading on the microstructure of asphalt concrete is studied. The traditional Continuum Damage Mechanics (CDM) framework is modified to model detrimental effects of moisture and mechanical loading. Adhesive/cohesive moisture-induced damage constitutive relationships are proposed to describe the time-dependent degradation of material properties due to moisture. X-ray two-dimensional (2D) computed tomography-imaging technique is used to construct finite element (FE) microstructural representation of a typical dense-graded asphalt concrete. After being calibrated against pull-off experiments, the proposed moisture-induced damage constitutive relationship, which is coupled to thermo-viscoelastic–viscoplastic–viscodamage mechanisms, is used to simulate the microstructure of asphalt concrete. Simulation results demonstrate that the generated 2D FE microstructural representation along with the coupled moisture–mechanical constitutive relationship can be effectively used to model the overall thermo-hygro-mechanical response of asphalt concrete.     

含热冲击预损伤的陶瓷基复合材料损伤本构模型

陶瓷基复合材料结构在服役过程中不可避免地经受热冲击(较高的热应力梯度)而产生热机械损伤, 因此, 建立含循环热冲击预损伤材料的损伤本构模型, 以描述材料在热机械载荷作用下的力学行为, 对材料结构损伤容限设计与结构完整性评估非常重要. 本文首先对经历了循环热冲击的材料进行单调拉伸损伤实验, 发现对于含循环热冲击预损伤的材料, 其弹性模量的下降与所施加的应变直接相关. 然后在连续介质损伤力学的框架下, 基于平面应力假设, 建立了含循环热冲击预损伤材料的损伤演化模型, 该模型所涉及的参数可通过一个偏轴(45$^\circ$)以及两个正轴(平行于两个主方向)的单调拉伸试验获得. 最后, 采用经典塑性理论对由基体损伤引起的非弹性应变进行了描述. 本文所提出的应变损伤宏观模型可以描述陶瓷基复合材料在热机械载荷作用下的损伤演化, 同时弥补了含预损伤的陶瓷基复合材料在机械载荷下损伤本构模型在理论及实验研究方面的不足.      

A thermodynamics based damage mechanics constitutive model for low cycle fatigue analysis of microelectronics solder joints incorporating size effects

Below certain length scales and in the presence of a non-uniform plastic strain field the mechanical behavior of many metals and its alloys is substantially different from that in bulk specimens. In particular, an increase in resistance with decreasing size has been observed in Pb/Sn eutectic solder alloys which are extensively used in microelectronics packaging interconnects. Due to the high homologous temperature, the Pb/Sn solder exhibits creep–fatigue interaction and significant time, temperature, stress and rate dependent material characteristics. The simultaneous consideration of all the above mentioned factors makes constitutive modeling an extremely difficult task. In this paper, a viscoplastic constitutive model unified with a thermodynamics based damage evolution model is embedded into a couple stress framework in order to simulate low cycle fatigue response coupled to size effects. The model is implemented into commercial finite element code ABAQUS. The microbending experiment on thin nickel foils is used to validate the model. Analyses are performed on a thin layer solder joint in bending under cyclic loading conditions.     

A coupled temperature and strain rate dependent yield function for dynamic deformations of bcc metals

A coupled temperature and strain rate microstructure physically based yield function is proposed in this work. It is incorporated along with the Clausius–Duhem inequality and an appropriate free energy definition in a general thermodynamic framework for deriving a three-dimensional kinematical model for thermo-viscoplastic deformations of body centered cubic (bcc) metals. The evolution equations are expressed in terms of the material time derivatives of the elastic strain, accumulated plastic strain (isotropic hardening), and the back stress conjugate tensor (kinematic hardening). The viscoplastic multipliers are obtained using both the Consistency and Perzyna viscoplasticity models. The athermal yield function is employed instead of the static yield function in the case of the Perzyna viscoplasticity model. It is found that the static strain rate value, at which the material shows rate-independent behavior, varies with the material deformation temperature. Computational aspects of the proposed model are addressed through the finite element implementation with an implicit stress integration algorithm. Finite element simulations are performed by implementing the proposed viscoplasticity constitutive models in the commercial finite element program ABAQUS/Explicit [ABAQUS, 2003. User Manual, Version 6.3. Habbitt, Karlsson and Sorensen Inc., Providence, RI] via the user material subroutine coded as VUMAT. Numerical implementation for a simple compression problem meshed with one element is used to validate the proposed model implementation with applications to tantalum, niobium, and vanadium at low and high strain rates and temperatures. The analysis of a tensile shear banding is also investigated to show the effectiveness and the performance of the proposed framework in describing the strain localizations at high velocity impact. Results show mesh independency as a result of the viscoplastic regularization used in the proposed formulation.     

混凝土化学-力学耦合作用的非局部损伤模型

提出了混凝土化学损伤和力学损伤的耦合模型.用损伤变量表示的本构关系模拟混凝土力学性能.分析了化学侵蚀下混凝土损伤发展过程.研究表明,应力软化造成混凝土局部损伤是结构失效的根源.局部化学损伤出现的时候,平衡微分方程不能满足.为了解决这个问题,采用了非局部损伤模型.试验和有限元计算结果表明,混凝土化学-力学耦合作用的非局部损伤模型能够较好地描述受化学侵蚀与荷载共同作用的损伤状态.     

Investigation of shear damage considering the evolution of anisotropy

The damage that occurs in shear deformations in view of anisotropy evolution is investigated. It is widely believed in the mechanics research community that damage (or porosity) does not evolve (increase) in shear deformations since the hydrostatic stress in shear is zero. This paper proves that the above statement can be false in large deformations of simple shear. The simulation using the proposed anisotropic ductile fracture model (macro-scale) in this study indicates that hydrostatic stress becomes nonzero and (thus) porosity evolves (increases or decreases) in the simple shear deformation of anisotropic (orthotropic) materials. The simple shear simulation using a crystal plasticity based damage model (meso-scale) shows the same physics as manifested in the above macro-scale model that porosity evolves due to the grain-to-grain interaction, i.e., due to the evolution of anisotropy. Through a series of simple shear simulations, this study investigates the effect of the evolution of anisotropy, i.e., the rotation of the orthotropic axes onto the damage (porosity) evolution. The effect of the evolutions of void orientation and void shape onto the damage (porosity) evolution is investigated as well. It is found out that the interaction among porosity, the matrix anisotropy and void orientation/shape plays a crucial role in the ductile damage of porous materials.     

Anisotropic damage–plasticity model for concrete

A material model for concrete is proposed here within the framework of a thermodynamically consistent elasto-plasticity–damage theory. Two anisotropic damage tensors and two damage criteria are adopted to describe the distinctive degradation of the mechanical properties of concrete under tensile and compressive loadings. The total stress tensor is decomposed into tensile and compressive components in order to accommodate the need for the above mentioned damage tensors. The plasticity yield criterion presented in this work accounts for the spectral decomposition of the stress tensor and allows multiple hardening rules to be used. This plastic yield criterion is used simultaneously with the damage criteria to simulate the physical behavior of concrete. Non-associative flow rule for the plastic strains is used to account for the dilatancy of concrete as a frictional material. The thermodynamic Helmholtz free energy concept is used to consistently derive dissipation potentials for damage and plasticity and to allow evolution laws for different hardening parameters. The evolution of the two damage tensors is accounted for through the use of fracture-energy-based continuum damage mechanics. An expression is derived for the damage–elasto-plastic tangent operator. The theoretical framework of the model is described here while the implementation of this model will be discussed in a subsequent paper.     

A multi-axial constitutive model for metal matrix composites

Metal matrix composites (MMCs) generally do not follow the classical plasticity theory, even though the matrix metals do deform plastically. A tension-compression yield asymmetry is typically observed in MMCs. For particulate-reinforced MMCs, this non-classical response is mainly due to the variation of damage evolution with loading modes. In this paper, a viscoplastic multi-axial constitutive model for plastic deformation of MMCs is constructed using the Mises-Schleicher yield criterion. The subsequent plastic flow is characterized by an associated and decomposed flow rule considering effects from both deviatoric and hydrostatic stresses. This model is capable of describing the multi-axial yield and flow behavior of MMCs by using simulated or measured asymmetric tensile and compressive stress-strain responses as input. As an example, the influence of damage evolution in terms of interfacial debonding in MMCs (obtained from FEM simulations) is incorporated through the different tensile and compressive stress-strain behaviors. Applying this model to predict the torsion and the pressure-dependant tensile responses of some commonly used MMCs provides good agreement with experimental data.     

A thermodynamics based damage mechanics model for particulate composites

A micro-mechanical damage model is proposed to predict the overall viscoplastic behavior and damage evolution in a particle filled polymer matrix composite. Particulate composite consists of polymer matrix, particle fillers, and an interfacial transition interphase around the filler particles. Yet the composite is treated as a two distinct phase material, namely the matrix and the equivalent particle-interface assembly. The CTE mismatch between the matrix and the filler particles is introduced into the model. A damage evolution function based on irreversible thermodynamics is also introduced into the constitutive model to describe the degradation of the composite. The efficient general return-mapping algorithm is exploited to implement the proposed unified damage coupled viscoplastic model into finite element formulation. Furthermore, the model predictions for uniaxial loading conditions are compared with the experimental data.     

A phase field model incorporating strain gradient viscoplasticity: Application to rafting in Ni-base superalloys

The first formulation of a phase field model accounting for size-dependent viscoplasticity is developed to study materials in which microstructure evolution and viscoplastic behavior are strongly coupled. Plasticity is introduced using a continuum strain gradient formalism which captures the size effect of the viscoplastic behavior. First, the influence of this size effect on the mechanical behavior of the material is discussed in static microstructures. Then, the dynamic coupling between microstructure evolution and viscoplastic activity is addressed and illustrated by the rafting of the microstructure observed in Ni-base superalloys under creep conditions. It is found that the plastic size effect has only a moderate impact on the shape of the rafts but is crucial to reproduce the macroscopic mechanical behavior of that particular material.     

A thermodynamic consistent damage and healing model for self healing materials

Thermodynamics of the damage and the healing processes for viscoplastic materials is discussed in detail and constitutive equations for coupled inelastic-damage-healing processes are proposed in a thermodynamic consistent framework. Small deformation state is utilized and the kinematic and the isotropic hardening effects for the damage and healing processes are introduced into the governing equations. Two new yield surfaces for the damage and healing processes are proposed that take into account the isotropic hardening effect. The computational aspect for solving the coupled elasto-plastic-damage-healing problem is investigated, and the mechanical behavior of the proposed polymeric based self healing system is obtained. Uniaxial compression tests are implemented on a shape memory polymer based self healing system and the damage and the healing are captured by measurement of the changes in the modulus of elasticity. It is concluded that the proposed constitutive equations can model the damage and healing effectively and the mechanical behavior of a shape memory polymer based self healing system can be precisely modeled using this formulation.     

A study on the damage evaluation of weld heat affected zone

From the micro- and macroscopic points of view, the damage evolution of weld-simulated heat affected zone (HAZ) is studied. In the framework of continuum damage mechanics (CDM), the ductile and low cycle fatigue (LCF) damage evolution laws of HAZ have been examined. Two alternative laws of damage are proposed in this paper, which may meet the need for describing damage evolution of ductile rupture and LCF fracture, respectively.     

准脆性材料的弹塑性各向异性损伤耦合本构模型研究

针对准脆性材料的非线性特征：强度软化和刚度退化、单边效应、侧限强化和拉压软化、不可恢复变形、剪胀及非弹性体胀,在热动力学框架内,建立了准脆性材料的弹塑性与各向异性损伤耦合的本构关系。对准脆性材料的变形机理和损伤诱发的各向异性进行了诠释,并给出了损伤构形和有效构形中各物理量之间的关系。在有效应力空间内,建立了塑性屈服准则、拉压不同的塑性随动强化法则和各向同性强化法则。在损伤构形中,采用应变能释放率,建立了拉压损伤准则、拉压不同的损伤随动强化法则和各向同性强化法则。基于塑性屈服准则和损伤准则,构建了塑性势泛函和损伤势泛函,并由正交性法则,给出了塑性和损伤强化效应内变量的演化规律,同时,联立塑性屈服面和损伤加载面,给出了塑性流动和损伤演化内变量的演化法则。将损伤力学和塑性力学结合起来,建立了应变驱动的应力-应变增量本构关系,给出了本构数值积分的要点。以单轴加载-卸载往复试验识别和校准了本构材料常数,并对单轴单调试验、单轴加载-卸载往复试验、二轴受压、二轴拉压试验和三轴受压试验进行了预测,并与试验结果作了比较,结果表明,所建本构模型对准脆性材料的非线性材料性能有良好的预测能力。     

Modelling cell wall growth using a fibre-reinforced hyperelastic–viscoplastic constitutive law

A fibre-reinforced hyperelastic–viscoplastic model using a finite strain Finite Element (FE) analysis is presented to study the expansive growth of cell walls. Based on the connections between biological concepts and plasticity theory, e.g. wall-loosening and plastic yield, wall-stiffening and plastic hardening, the modelling of cell wall growth is established within a framework of anisotropic viscoplasticity aiming to represent the corresponding biology-controlled behaviour of a cell wall. In order to model in vivo growth, special attention is paid to the differences between a living cell and an isolated wall. The proposed hyperelastic–viscoplastic theory provides a unique framework to clarify the interplay between cellulose microfibrils and cell wall matrix and how this interplay regulates sustainable growth in a particular direction while maintaining the mechanical strength of the cell walls by new material deposition. Moreover, the effect of temperature is taken into account. A numerical scheme is suggested and FE case studies are presented and compared with experimental data.     

Damage of ductile materials deforming under multiple plastic or viscoplastic mechanisms

This work presents a model to represent ductile failure (i.e. failure controlled by nucleation, growth and coalescence) of materials whose irreversible deformation is controlled by several plastic or viscoplastic deformation mechanisms. In addition work hardening may result from both isotropic and kinematic hardening. Damage is represented by a single variable representing void volume fraction. The model uses an additive decomposition of the plastic strain rate tensor. The model is developed based on the definition of damage dependant effective scalar stresses. The model is first developed within the generalized standard material framework and expressions for Helmholtz free energy, yield potential and dissipation potential are proposed. In absence of void nucleation, the evolution of the void volume fraction is governed by mass conservation and damage does not need to be represented by state variables. The model is extended to account for void nucleation. It is implemented in a finite element software to perform structural computations. The model is applied to three case studies: (i) failure by void growth and coalescence by internal necking (pipeline steel) where plastic flow is either governed by the Gurson–Tvergaard–Needleman model or the Thomason model, (ii) creep failure (Grade 91 creep resistant steel) where viscoplastic flow is controlled by dislocation creep or diffusional creep and (iii) ductile rupture after pre-compression (aluminum alloy) where kinematic hardening plays an important role.     

混凝土黏塑性动力损伤本构关系

从静力弹塑性损伤本构关系的基本框架出发, 综合考虑塑性应变与损伤 演化的率敏感性, 建立了能够较为全面地描述混凝土在动力加载条件下非线性性能的混凝土 黏塑性动力损伤本构模型. 为了考虑塑性应变的率敏感性, 基于Perzyna理论推导了有效应 力空间黏塑性力学基本公式, 采用改进的Perzyna型动力演化方程, 将损伤静力演化方程推 广到动力加载情形. 基于并联弹簧模型, 从概率论的角度推导给出了一维损伤静力演化方程, 并基于能量等效应变的基本概念将其推广到多维损伤演化. 利用数值模拟, 计算得到了 混凝土在不同应变率下的应力应变全曲线, 同时得到了一维动力提高因子和二维动力强度包 络图, 数值结果与试验结果的对比表明了该模型的有效性.