The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

A three-parameter model describing the behaviour of a viscoelastic liquid in a tangential annular flow

A three-parameter model describing the shear rate-shear stress relation of viscoelastic liquids and in which each parameter has a physical significance, is applied to a tangential annular flow in order to calculate the velocity profile and the shear rate distribution. Experiments were carried out with a 5000 wppm aqueous solution of polyacrylamide and different types of rheometers. In a shear-rate range of seven decades (5 10^–3 s^–1 < < 1.2 10⁵ s^–1) a good agreement is obtained between apparent viscosities calculated with our model and those measured with three different types of rheometers, i.e. Couette rheometers, a cone-and-plate rheogoniometer and a capillary tube rheometer. a physical quantity defined by:a = {1 – ( / ₀)}/ ₀ (Pa^–1) - C constant of integration (1) - r distancer from the center (m) - r ₁,r ₂ radius of the inner and outer cylinder (m) - v _r local tangential velocity at a distancer from the center (v _r = _r r) (m s^–1) - v ₂ local tangential velocity at a distancer ₂ from the center (m s^–1) - shear rate (s^–1) - local shear rate (s^–1) - ₁ wall shear rate at the inner cylinder (s^–1) - dynamic viscosity (Pa s) - _a apparent viscosity (_a = / ) (Pa s) - _a1 apparent viscosity at the inner cylinder (Pa s) - ₀ zero-shear viscosity (Pa s) - infinite-shear viscosity (Pa s) - shear stress (Pa) - _r local shear stress at a distancer from the center (Pa) - ₀ yield stress (Pa) - ₁, ₂ wall shear-stress at the inner and outer cylinder (Pa) - _r local angular velocity (s^–1) - ₂ angular velocity of the outer cylinder (s^–1)     

Diffusion of moisture in deformable porous media. Anisotropic fibrous materials

This paper presents a study on the deformation of anisotropic fibrous porous media subjected to moistening by water in the liquid phase. The deformation of the medium is studied by applying the concept of effective stress. Given the structure of the medium, the displacement of the solid matrix is not taken into account with respect to the displacement of the liquid phase. The transport equations are derived from the model proposed by Narasimhan. The transport coefficients and the relation between the variation in apparent density and effective stress are obtained by test measurements. A numerical model has been established and applied for studying drip moistening of mineral wool samples capable or incapable of deformation.Nomenclature D mass diffusion coefficient [L²t^–1] - e void fraction - g gravity acceleration [Lt^–2] - J mass transfer density [ML^–2t^–1] - K hydraulic conductivity [Lt^–1] - K _s hydraulic conductivity of the solid phase [Lt^–1] - K ^* hydraulic conductivity of the deformable porous medium [Lt^–1] - P pressure of moistening liquid [ML^–1 t^–2] - S degree of saturation - t time [t] - V speed [Lt^–1] - X horizontal coordinate [L] - Z vertical coordinate measured from the bottom of porous medium [L] - z z-coordinate [L] Greek Letters porosity - ₁ total hydric potential [L] - _g gas density [ML^–3] - ₁ liquid density [ML^–3] - ₀ apparent density [ML^–3] - _s density of the solid phase [ML^–3] - density of the moist porous medium [ML^–3] - external load [ML^–1t^–2] - effective stress [ML^–1t^–2] - bishop's parameter - matrix potential or capillary suction [L] Indices g gas - 1 moistening liquid - p direction perpendicular to fiber planes - s solid matrix - t direction parallel to fiber planes - v pore Exponent * movement of solid particles taken into account     

Anwendung des Übertragungsverfahrens bei stark abklingenden Lösungsfunktionen

Übersicht Bei stark abklingenden Funktionen wird die Übertragungsmatrix U() aufgespalten in die Anteilc U ₁() e^– und U ₂() e. Der zweite Term spielt am Rand = 0 keinc Rolle. Die unbekannten Anfangswerte sind über die Matrix U ₁(0) an die bekannten gebunden und eindeutig bestimmbar.

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Summary For strongly decaying solution functions the transfer matrix U() is splitted into the parts U ₁() e^– and U ₂() e. The second term does not influence at the boundary = 0. The unknown initial values are related by the matrix U ₁(0) to the known values and they can be uniquely determined.

     

The third-normal stress difference in entangled melts: Quantitative stress-optical measurements in oscillatory shear

Stress-optical measurements are used to quantitatively determine the third-normal stress difference (N ₃ = N ₁ + N ₂) in three entangled polymer melts during small amplitude (<15%) oscillatory shear over a wide dynamic range. The results are presented in terms of the three material functions that describe N ₃ in oscillatory shear: the real and imaginary parts of its complex amplitude ₃ ^* = ₃ - i ₃ , and its displacement ₃ ^d . The results confirm that these functions are related to the dynamic modulus by ² ₃ ^* ()=(1-)[G ^*())– G ^*(2)] and ² ₃ ^d ()=(1- )G() as predicted by many constitutive equations, where = –N ₂/N ₁. The value of (1-) is found to be 0.69±0.07 for poly(ethylene-propylene) and 0.76±0.07 for polyisoprene. This corresponds to –N ₂/N ₁ = 0.31 and 0.24±0.07, close to the prediction of the reptation model when the independent alignment approximation is used, i.e., –N ₂/N ₁ = 2/7 – 0.28.     

A three-parameter model describing the experimental relation between shear stress and shear rate for laminar flow of aqueous polymer solutions

Summary A three-parameter model is introduced to describe the shear rate — shear stress relation for dilute aqueous solutions of polyacrylamide (Separan AP-30) or polyethylenoxide (Polyox WSR-301) in the concentration range 50 wppm – 10,000 wppm. Solutions of both polymers show for a similar rheological behaviour. This behaviour can be described by an equation having three parameters i.e. zero-shear viscosity ₀, infinite-shear viscosity , and yield stress ₀, each depending on the polymer concentration. A good agreement is found between the values calculated with this three-parameter model and the experimental results obtained with a cone-and-plate rheogoniometer and those determined with a capillary-tube rheometer.

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Zusammenfassung Der Zusammenhang zwischen Schubspannung und Schergeschwindigkeit von strukturviskosen Flüssigkeiten wird durch ein Modell mit drei Parametern beschrieben. Mit verdünnten wäßrigen Polyacrylamid-(Separan AP-30) sowie Polyäthylenoxidlösungen (Polyox WSR-301) wird das Modell experimentell geprüft. Beide Polymerlösungen zeigen im untersuchten Schergeschwindigkeitsbereich von ein ähnliches rheologisches Verhalten. Dieses Verhalten kann mit drei konzentrationsabhängigen Größen, nämlich einer Null-Viskosität ₀, einer Grenz-Viskosität und einer Fließgrenze ₀ beschrieben werden. Die Ergebnisse von Experimenten mit einem Kegel-Platte-Rheogoniometer sowie einem Kapillarviskosimeter sind in guter Übereinstimmung mit den Werten, die mit dem Drei-Parameter-Modell berechnet worden sind.

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a Pa^–1 physical quantity defined by:a = {1 – ( / ₀)}/ ₀ - c l concentration (wppm) - D m capillary diameter - L m length of capillary tube - P Pa pressure drop - R m radius of capillary tube - u m s^–1 average velocity - v _r m s^–1 local axial velocity at a distancer from the axis of the tube - shear rate (–dv _r /dr) - local shear rate in capillary flow - s^–1 wall shear rate in capillary flow - Pa s dynamic viscosity - _a Pa s apparent viscosity defined by eq. [2] - ( _a ) Pa s apparent viscosity in capillary tube at a distanceR from the axis - ₀ Pa s zero-shear viscosity defined by eq. [4] - Pa s infinite-shear viscosity defined by eq. [5] - l ratior/R - kg m^– density - Pa shear stress - ₀ Pa yield stress - _r Pa local shear stress in capillary flow - _R Pa wall shear stress in capillary flow _R = (PR/2L) - _v m³ s^–1 volume rate of flow With 8 figures and 1 table     

Free convection from a vertical plate with concentrated and distributed thermal sources

An analysis is developed for the laminar free convection from a vertical plate with uniformly distributed wall heat flux and a concentrated line thermal source embedded at the leading edge. We introduce a parameter=(1 +Q _L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 to describe the relative strength of the two thermal sources; and propose a unified buoyancy parameter=( Ra_L+ Ra_w)^1/5 with=1/(1 +Pr ^–1) to properly scale the dependent and independent variables. The variables are so defined that the resulting nonsimilar boundary-layer equations can describe exactly the buoyancy-induced flow from the dual sources with any relative strength to fluids of any Prandtl number from very small values to infinity. These nonsimilar equations are readily reducible to the self-similar equations of an adiabatic wall plume for=0, and to those of free convection from uniform flux plate for=1. Rigorous finite-difference solutions for fluids of Pr from 0.001 to are obtained over the entire range of from 0 to 1. The effects of both relative source strength and Prandtl number on the velocity profiles, temperature profiles, and the variations of wall temperature, are clearly illustrated.

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Freie Konvektion an einer vertikalen Platte mit einer konzentrierten und einer gleichmäßig verteilten Wärmequelle

Zusammenfassung Für die freie Konvektion an einer vertikalen Platte mit einer gleichmäßig verteilten Wandwärmestromdichte und einer in der Vorderkante eingebetteten linienförmigen Wärmequelle wird eine Berechnungsmethode entwickelt. Zur Beschreibung der relativen Stärke der beiden Wärmequellen führen wir einen Parameter=(1 + Q_L/Q_w)^–1=(1 + Ra_L/Ra_w)^–1 ein und schlagen einen vereinheitlichten Auftriebsparameter=( Ra _L+ Ra _w)^1/5 mit=1/(1 +Pr ^–1 für die Skalierung der abhängigen und unabhängigen Variablen vor. Die Variablen werden so definiert, daß mit den sich ergebenden unabhängigen Grenzschichtgleichungen die von den beiden Wärmequellen beliebiger Stärke verursachte Auftriebsströmung von Fluiden beliebiger Prandtl-Zahl genau beschrieben werden kann. Diese unabhängigen Gleichungen können ohne weiteres auf die selbstähnlichen Gleichungen für den Fall einer lokalen Wärmezufuhr an einer sonst adiabatischen Wand für=0 und jenen der freien konvektion an einer Platte mit einheitlichem Wärmestrom für=1 zurückgeführt werden. Für Fluide mit der Prandtl-Zahl zwischen 0,001 und Unendlich werden nach der strengen finite Differenzen-Methode Lösungen im Bereich von zwischen 0 und 1 erhalten. Der jeweilige Einfluß der relativen Quellenstärke und der Prandtl-Zahl auf die Geschwindigkeits- und Temperaturprofile sowie die Veränderung der Wandtemperatur werden deutlich dargestellt.

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Nomenclature C _f friction coefficient - C _p specific heat - f reduced stream function - g gravitational acceleration - k thermal conductivity - L width of the plate - Nu local Nusselt number - Pr Prandtl number - q _w wall heat flux - Q _L heat generated by the line source - Q _w heat released by the uniform-flux wall from 0 tox, q _w Lx - Ra _L local Rayleigh number, g T _L ^* x ³/( ) - Ra _w local Rayleigh number,g T _w ^* w ³/( ) - T fluid temperature - T temperature of ambient fluid - T _L ^* characteristic temperature of the line source,Q _{L/(C p} L) - T _w ^* characteristic temperature of the uniform flux wall, =q _w x/k=Q _w /(C _p L) - u velocity component in then-direction - U₀ dimensionless velocity,u/(/x) Ra _L ^2/5 - U ₁ dimensionless velocity,u/(/x) Ra _w ^2/5 - velocity component in they-direction - x coordinate parallel to the plate - y coordinate normal to the plate - thermal diffusivity - thermal expansion coefficient - pseudo-similarity variable,(y/x) - dimensionless temperature, (T–T )/(T _L ^* +T _w ^* ) - ₀ dimensionless temperature, (Ra_l)^1/5 (T–T )/T _L ^* - ₁ dimensionless temperature, (Ra_w)Ra_w)^1/5 (T–T )/T _w ^* - (Ra _L+Ra_w)^1/5 - kinematic viscosity - (1 +Ra _L/Ra_w)^–1=(1 +T _L ^* /T _w ^* )^–1=(1 + Q_L/Q_w)^–1 - density - Pr/(1 +Pr) - _w wall shear stress - stream function     

Parameter determination for thermodynamical models of the pseudoelastic behaviour of shape memory alloy by resistivity measurements and infrared thermography

Two thermodynamical models of pseudoelastic behaviour of shape memory alloys have been formulated. The first corresponds to the ideal reversible case. The second takes into account the hysteresis loop characteristic of this shape memory alloys.Two totally independent techniques are used during a loading-unloading tensile test to determine the whole set of model parameters, namely resistivity and infrared thermography measurements. In the ideal case, there is no difficulty in identifying parameters.Infrared thermography measurements are well adapted for observing the phase transformation thermal effects.Notations 1 austenite 2 martensite - ₍₎ Macroscopic infinitesimal strain tensor of phase - ₍₂₎ ^f Traceless strain tensor associated with the formation of martensite phase - Macroscopic infiniesimal strain tensor - Macroscopic infinitesimal strain tensor deviator - _f Trace - Equivalent strain - ^pe Macroscopic pseudoelastic strain tensor - x Distortion due to parent (austenite =1)product (martensite =2) phase transformation (traceless symmetric second order tensor) - M Total mass of a system - M() Total mass of phase - V Total volume of a system - V() Total volume of phase - z=M(2)/M Weight fraction of martensite - 1-z=M(1)/M Weight fraction of austenite - u ₀ ^* () Specific internal energy of phase (=1,2) - s ₀ ^* () Specific internal entropy of phase - Specific configurational energy - Specific configurational entropy - ₀ ^f (T) Driving force for temperature-induced martensitic transformation at stress free state ( ₀ ^f T) = T ^*–Ts ^*) - Kirchhoff stress tensor - Kirchhoff stress tensor deviator - Equivalent stress - Cauchy stress tensor - Mass density - K Bulk moduli (K ₀=K) - L Elastic moduli tensor (order 4) - E Young modulus - Energetic shear (₀ = ) - Poisson coefficient - M _s ^o (M _F ^o ) Martensite start (finish) temperature at stress free state - A _s ^o (A _F ^o ) Austenite start (finish) temperature at stress free state - C _v Specific heat at constant volume - k Conductivity - Pseudoelastic strain obtained in tensile test after complete phase transformation (AM) (unidimensional test) - ₀ Thermal expansion tensor - r Resistivity - 1MPa 10⁶ N/m ² - ⁽⁾ Specific free energy of phase - _n Specific free energy at non equilibrium (R model) - _n ^eq Specific free energy at equilibrium (R model) - _n ^v Volumic part of ^eq - Specific free energy at non equilibrium (R _L model) - _conf Specific coherency energy (R _L model) - _c Specific free energy at constrained equilibria (R _L model) - _it (T) Coherency term (R _L model)     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Flow of second-order fluids over an enclosed rotating disc

Summary This paper is devoted to a study of the flow of a second-order fluid (flowing with a small mass rate of symmetrical radial outflow m, taken negative for a net radial inflow) over a finite rotating disc enclosed within a coaxial cylinderical casing. The effects of the second-order terms are observed to depend upon two dimensionless parameters ₁ and ₂. Maximum values ₁ and ₂ of the dimensionless radial distances at which there is no recirculation, for the cases of net radial outflow (m>0) and net radial inflow (m<0) respectively, decrease with an increase in the second-order effects [represented by T(=₁+₂)]. The velocities at ₁ and ₂ as well as at some other fixed radii have been calculated for different T and the associated phenomena of no-recirculation/recirculation discussed. The change in flow phenomena due to a reversal of the direction of net radial flow has also been studied. The moment on the rotating disc increases with T.Nomenclature , , z coordinates in a cylindrical polar system - z ₀ distance between rotor and stator (gap length) - =/z ₀, dimensionless radial distance - =z/z ₀, dimensionless axial distance - _s = _s/z₀, dimensionless disc radius - V =(u, v, w), velocity vector - dimensionless velocity components - uniform angular velocity of the rotor - , p fluid density and pressure - P =p/(₂ z ₀₂ ² , dimensionless pressure - ₁, ₂, ₃ kinematic coefficients of Newtonian viscosity, elastico-viscosity and cross-viscosity respectively - ₁, _{2 2}/z ₀ ² , resp. ₃/z ₀ ² , dimensionless parameters representing the ratio of second-order and inertial effects - m = , mass rate of symmetrical radial outflow - l a number associated with induced circulatory flow - Rm =m/(z ₀₁), Reynolds number of radial outflow - R _l =l/(z ₀₁), Reynolds number of induced circulatory flow - Rz =z ₀ ² /₁, Reynolds number based on the gap - ₁, ₂ maximum radii at which there is no recirculation for the cases Rm>0 and Rm<0 respectively - ₁(T), ₂(T) ₁ and ₂ for different T - U _1(T) ⁽⁺⁾ = dimensionless radial velocity, Rm>0 - V _1(T) ⁽⁺⁾ = , dimensionless transverse velocity, Rm>0 - U _2(T) ^(–) = , dimensionless radial velocity, Rm=–Rn<0, m=–n - V _2(T) ^(–) = , dimensionless transverse velocity, Rm<0 - C _m moment coefficient     

Critical heat fluxes in boiling of liquid nitrogen underheated to saturation point in forced-flow conditions

This paper gives the results of experimental determinations of the critical heat fluxes in the boiling of Liquid nitrogen in forced-flow conditions in the mass velocity range 2 · 10³-40 · 10³ kg/m² · sec, pressure range 29 · 10⁴–245 · 10⁴ N/m², and at underheatings corresponding to the onset of normal boiling crises.Notation q₀ critical heat flux - r heat of vaporization - i enthalpy of flow corresponding to saturation point - i enthalpy of flow corresponding to liquid temperature - surface tension - density of liquid - density of saturated vapor - C _f friction factor - W_g mass velocity - Fr_* Froude number - g acceleration due to gravity     

Supersonic air flow past a sphere with account for vibrational relaxation

A numerical solution is obtained for the problem of air flow past a sphere under conditions when nonequilibrium excitation of the vibrational degrees of freedom of the molecular components takes place in the shock layer. The problem is solved using the method of [1]. In calculating the relaxation rates account was taken of two processes: 1) transition of the molecular translational energy into vibrational energy during collision; 2) exchange of vibrational energy between the air components. Expressions for the relaxation rates were computed in [2]. The solution indicates that in the state far from equilibrium a relaxation layer is formed near the sphere surface. A comparison is made of the calculated values of the shock standoff with the experimental data of [3].Notation uV_max, vV_max velocity components normal and tangential to the sphere surface - V_max maximal velocity - P V _max ² pressure - density - TT temperature - e_viRT vibrational energy of the i-th component per mole (i=–O₂, N₂) - =rb–1 shock wave shape - a _f the frozen speed of sound - HRT/m gas total enthalpy     

The wedge subjected to tractions: a paradox resolved

The classical two-dimensional solution provided by Lévy for the stress distribution in an elastic wedge, loaded by a uniform pressure on one face, becomes infinite when the opening angle 2 of the wedge satisfies the equation tan 2 = 2. Such pathological behavior prompted the investigation in this paper of the stresses and displacements that are induced by tractions of O(r ^–) as r0. The key point is to choose an Airy stress function which generates stresses capable of accommodating unrestricted loading. Fortunately conditions can be derived which pre-determine the form of the necessary Airy stress function. The results show that inhomogeneous boundary conditions can induce stresses of O(r ^–), O(r ^– ln r), or O(r ^– ln² r) as r0, depending on which conditions are satisfied. The stress function used by Williams is sufficient only if the induced stress and displacement behavior is of the power type. The wedge loaded by uniform antisymmetric shear tractions is shown in this paper to exhibit stresses of O(ln r) as r0 for the half-plane or crack geometry. At the critical opening angle 2, uniform antisymmetric normal and symmetric shear tractions also induce the above type of stress singularity. No anticipating such stresses, Lévy used an insufficiently general Airy stress function that led to the observed pathological behavior at 2.     

Thermal stability of composite superconducting tape under the effect of a two-dimensional dual-phase-lag heat conduction model

Thermal stability of composite superconducting tape subjected to a thermal disturbance is numerically investigated under the effect of a two-dimensional dual-phase-lag heat conduction model. It is found that the dual-phase-lag model predicts a wider stable region as compared to the predictions of the parabolic and the hyperbolic heat conduction models. The effects of different design, geometrical and operating conditions on superconducting tape thermal stability were also studied.a conductor width, (m) - A conductor cross sectional area of, (m²) - As conductor aspect ratio, (a/b) - b conductor thickness, (m) - Bi Biot number - B dimensionless disturbance Intensity - C heat capacity, (J m^–3 K^–1) - D disturbance energy density, (W m^–3) - f volume fraction of the stabilizer in the conductor - g(T) steady capacity of the Ohmic heat source, (W m^–3) - g_max Ohmic heat generation with the whole current in the stabilizer, (W m^–3) - G_max dimensionless maximum Joule heating - h convective heat transfer coefficient, (W m^–2 K^–1) - J current density, (A m^–2) - k thermal conductivity of conductor, (W m^–1 K^–1) - q conduction heat flux vector, (W m^–2) - Q dimensionless Joule heating - R relaxation times ratio (_T/2_q) - t rime, (s) - T temperature, (K) - T_c critical temperature, (K) - T_c1 current sharing temperature, (K) - T_i initial temperature, (K) - T_o ambient temperature, (K) - x, y co-ordinate defined in Fig. 1, (m) - thermal diffusivity (m² s^–1) - dimensionless time - _i dimensionless duration time - dimensionless y-variable - _o superconductor dimensionless thickness - dimensionless temperature - _c1 dimensionless current sharing temperature - 1 dimensionless maximum temperature - dimensionless disturbance energy - numerical tolerance - x width of conductor subjected to heat disturbances, (m) - y thickness of conductor subjected to heat disturbances, (m) - dimensionless x-variable - _o superconductor dimensionless width - stabilizer electrical resistivity, () - _q relaxation time of heat flux, (s) - _T relaxation time of temperature gradient, (s) - i initial - sc current sharing - max maximum - o ambient     

The contribution of internal degrees of freedom to the non-Newtonian rheology of model polymer fluids

We report non-equilibrium molecular dynamics simulations of rigid and non-rigid dumbbell fluids to determine the contribution of internal degrees of freedom to strain-rate-dependent shear viscosity. The model adopted for non-rigid molecules is a modification of the finitely extensible nonlinear elastic (FENE) dumbbell commonly used in kinetic theories of polymer solutions. We consider model polymer melts — that is, fluids composed of rigid dumbbells and of FENE dumbbells. We report the steady-state stress tensor and the transient stress response to an applied Couerte strain field for several strain rates. We find that the rheological properties of the rigid and FENE dumbbells are qualitatively and quantitatively similar. (The only exception to this is the zero strain rate shear viscosity.) Except at high strain rates, the average conformation of the FENE dumbbells in a Couette strain field is found to be very similar to that of FENE dumbbells in the absence of strain. The theological properties of the two dumbbell fluids are compared to those of a corresponding fluid of spheres which is shown to be the most non-Newtonian of the three fluids considered.Symbol Definition b dimensionless time constant relating vibration to other forms of motion - F force on center of mass of dumbbell - F _i force on bead i of dumbbell - F force between center of masses of dumbbells and - F _ij force between beads i and j - h vector connecting bead to center of mass of dumbbell - H dimensionless spring constant for dumbbells, in units of / ² - I moment of inertia of dumbbell - J general current induced by applied field - k _B Boltzmann's constant - L angular momentum - m mass of bead, (= m/2) - M mass of dumbbell, g - N number of dumbbells in simulation cell - P translational momentum of center of mass of dumbbell - P pressure tensor - P _xy xy component of pressure tensor - Q separation of beads in dumbbell - Q _eq equilibrium extension of FENE dumbbell and fixed extension of rigid dumbbell - Q ₀ maximum extension of dumbbell - r _ij vector connecting beads i and j - r position vector of center of mass dumbbell - R vector connecting centers of mass of two dumbbells - t time - t ^* dimensionless time, in units of m/ - T ^* dimensionless temperature, in units of /k - u potential energy - u velocity vector of flow field - u _x x component of velocity vector - V volume of simulation cell - X general applied field - strain rate, s^–1 - ^* dimensionless shear rate, in units of /m ² - general transport property - Lennard-Jones potential well depth - friction factor for Gaussian thermostat - shear viscosity, g/cms - ^* dimensionless shear viscosity, in units of m/ ² - ^* dimensionless number density, in units of ^–3 - Lennard-Jones separation of minimum energy - relaxation time of a fluid - angular velocity of dumbbell - orientation angle of dumbbell      

Material functions generated by the complex viscosity

Based on the complex viscosity model various steady-state and transient material functions have been completed. The model is investigated in terms of a corotational frame reference. Also, BKZ-type integral constitutive equations have been studied. Some relations between material functions have been derived. C ^–1 Finger tensor - F[], (F ^–1[]) Fourier (inverse) transform - rate of deformation tensor in corotating frame - h(I, II) Wagner's damping function - J (x) Bessel function - m parameter inh (I, II) - m(s) memory function - m _k, n_k integers (powers in complex viscosity model) - P principal value of the integral - parameter in the complex viscosity model - rate of deformation tensor - shear rates - [], [] incomplete gamma function - (a) gamma function - steady-shear viscosity - ^* complex viscosity - , real and imaginary parts of ^* - ₀ zero shear viscosity - ⁺, ₁ ⁺ stress growth functions - ^–, ₁ ^- stress relaxation functions - (s) relaxation modulus - ₁(s) primary normal-stress coefficient - ø(a, b; z) degenerate hypergeometric function - ₁, ₂ time constants (parameters of ^*) - frequency - extra stress tensor     

On nonlinear problems of mixed type: A qualitative theory using infinite-dimensional center manifolds

We consider the equation a(y)u_xx+div_y(b(y)_yu)+c(y)u=g(y, u) in the cylinder (–l,l)×, being elliptic where b(y)>0 and hyperbolic where b(y)<0. We construct self-adjoint realizations in L₂() of the operatorAu= (1/a) div_y(b_yu)+(c/a) in the case ofb changing sign. This leads to the abstract problem u_xx+Au=g(u), whereA has a spectrum extending to + as well as to –. For l= it is shown that all sufficiently small solutions lie on an infinite-dimensional center manifold and behave like those of a hyperbolic problem. Anx-independent cross-sectional integral E=E(u, u_x) is derived showing that all solutions on the center manifold remain bounded forx ±. For finitel, all small solutionsu are close to a solution on the center manifold such that u(x)-(x) Ce ^-(1-|x|) for allx, whereC and are independent ofu. Hence, the solutions are dominated by hyperbolic properties, except close to the terminal ends {±1}×, where boundary layers of elliptic type appear.     

Recording and evaluation methods of PIV investigations on a helicopter rotor model

Three-component particle image velocimetry measurements at moderate speeds and observation distances can now be accomplished on a routine basis. This article discusses the experiment performed on a 4 m-diameter model rotor in the 6-m×8-m open test section of the Large Low Speed Facility of the German–Dutch Wind Tunnels. More than half a terabyte of raw data were recorded at various positions on the advancing and retreating sides of the rotor in order to obtain detailed measurements of the trailing vortex in the frame of an international project. This paper addresses measuring techniques and possible sources of errors and presents a limited number of cases for the purpose of illustrating the solutions to numerous technical challenges relating to the acquisition and analysis of vortical flows.List of symbols C _T thrust coefficient (T/² R ⁴) - M magnification - r _c radius of vortex core (mm) - R rotor radius (m) - T thrust (N) - u,v,w velocity components in x, y and z coordinates (m/s) - (u,v,w)_wt velocity components in wind tunnel coordinates (m/s) - U _max maximum in-plane velocity component (m/s) - W _max maximum out-of-plane velocity component (m/s) - x,y,z particle image velocimetry (PIV) frame coordinates (m) - (x,y,z)_wt wind tunnel coordinates (m) - t time delay (s) - Z light sheet thickness (mm) - Z light sheet thickness (mm) - rotor rotation frequency (rad/s) - rotor azimuth angle during recording (deg) vortex age - rotor shaft angle (deg) - _x displacement measurement error - advance ratio (V/R) - air density (kg/m³) - circulation (m²/s) - _z vorticity (s^–1) Abbreviations AFDD Aeroflightdynamics Directorate - BVI blade–vortex interaction - DLR Deutches zentrum für Luft- und Raumfahrt - DNW German–Dutch Wind tunnel - HART HHC aeroacoustic rotor test - LLF large low speed facility - NASA National Aeronautics and Space Administration - ONERA Office National dEtudes e de Recherches Aerospatiales - RANS Reynolds-averaged Navier–Stokes - SPR stereo pattern recognition - 3C-PIV three-component particle image velocimetry     

Nicht-isotherme Rieselfilmströmung einer hochviskosen Flüssigkeit mit stark temperaturabhÄngiger ViskositÄt

Zusammenfassung Es werden Geschwindigkeitsverteilungen und Filmdickenabnahmen von nichtisothermen NEWTONschen und nicht-NEWTONschen (Potenzansatz) Rieselfilmen mit temperaturanhÄngiger ViskositÄt berechnet, wobei die Temperaturverteilung im Film als linear vorausgesetzt wird. An dicken Rieselfilmen mit Re=10^–4... 10^–2 sind Geschwindigkeitsprofile, Filmdicken und OberflÄchentemperaturen gemessen und daraus die thermische EinlauflÄnge bestimmt worden. Ausgehend von der Penetrationstheorie für eine endlich dicke Platte kann man für diese EinlauflÄnge eine Approximationsformel erhalten, die für Strömungen mit Re < 1000 verwendet werden kann.

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Non-isothermal filmflow of a highly viscous liquid, the viscosity strongly depending on temperature

Velocity distributions and film thicknesses of nonisothermal NEWTONIAN and non-NEWTONIAN (power-law) falling films are computed assuming that the temperature across the film varies linearly. Experimental studies on thick falling films of Re=10^–4...10^–2 had been carried out to measure velocities, film thickness and surface temperature and to calculate the thermal entrance length. One can get for this entrance length a approximation formula which is valid for flows with RePr <1000 by applying the results for the thermal penetration into a material finite plate.

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Bezeichnungen B dimensionsloser Temperaturkoeffizient - ¯B [K] Temperaturkoeffizient (ln)/(1/T) - c_p [J/kgK] spezif. WÄrme bei konst. Druck - Fo FOURIER-Zahl - g [m/s²] Erdbeschleunigung - H dimensionslose Filmdicke - h [m] Filmdicke - m [Pas^2–n] ViskositÄtskoeffizient im Potenzansatz von OSTWALD-DE WAELE - Nu NUSSELT-Zahl - n Flüssigkeitsexponent im Potenzansatz von OSTWALD-DE WAELE - Pr PRANDTL-Zahl (Gl.3.5) - q [W/m²] WÄrmestromdichte - Re REYNOLDS-Zahl (Gl.3.4) - T [K] Temperatur - t [s] Zeit - U dimensionslose Geschwindigkeit (X-Komponente) - u [m/s] Geschwindigkeitskomponente in x-Richtung - X dimensionslose Koordinate (X=x/h₀) - x [m] LÄnge, Koordinate - Y dimensionslose Koordinate (Y=y/h₀) - y [m] Höhe, Koordinate - [W/m²K] WÄrmeübergangskoeffizient - Plattenneigungswinkel gegen Horizontale - [s^–1] Schergeschwindigkeit - dimensionslose Temperatur (Gl.3.3) - [m²/s] TemperaturleitfÄhigkeit (Gl.3.3) - [W/mK] WÄrmeleitfÄhigkeit - [Pas] ViskositÄt - [kg/m³] spezif. Dichte - [Pa] Schubspannung Indizes a scheinbar (apparent) - 0 bei x=0, auch: isotherm - P auf die Penetrationszeit bezogen - s an der OberflÄche - T bei linearer Temperaturdifferenz T - w an der Wand - 99 auf =0,99 bezogen - gemittelt, Mittelwert - thermisch ausgebildet, bei x - proportional - ¯t ungefÄhr - kleiner oder gleich ungefÄhr     

A distributed electrical analog for transient diffusion-techniques of model fabrication and calibration

Simulation of transient two-dimensional diffusion by means of a distributed electrical analog is discussed. After present techniques of analog model construction and calibration are reviewed, an improved calibration technique is presented and a convenient method of analog fabrication, not previously reported, is described. The proposed new method allows complete access to any point on the analog model during a test. Frequency response and step response measurements indicate that an adequate simulation is provided by this particular type of analog model.

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Zusammenfassung Die Simulierung eines nichtstationären, zweidimensionalen Diffusionsvorganges mittels eines kontinuierlichen, elektro-thermischen Analogapparates wird besprochen. Eine Übersicht der gegenwärtigen Methoden für die Konstruktion und Kalibrierung von elektro-thermischen Analogmodellen wird gegeben. Ein verbessertes Verfahren für die Kalibrierung und eine handliche Fertigungsmethode von Analogmodellen, die noch nicht in der Literatur beschrieben wurden, werden dargestellt. Das vorgeschlagene neue Verfahren gestattet vollständigen Zugang zu jedem Punkt im Analogmodell während des Experiments. Meßbeobachtungen des periodischen Frequenzverhaltens und des nichtstationären Verhaltens zeigen, daß dieses spezielle Analogmodell eine ausreichende Simulierung des Diffusionsvorganges gestattet.

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Nomenclature A ₀ Potential amplitude atx=0 (see Fig. 5) - A _x Potential amplitude at locationx (see Fig. 5) - A _L Potential amplitude atx=L (see Fig. 5) - C Capacitance per unit area - j Frequency - L Characteristic length - R Resistance per square - t Time - x Coordinate - X Dimensionless distance,x/L - y Coordinate - Y Dimensionless distance,y/L - Diffusivity - _x Phase angle at locationx (see Fig. 5) - _L Phase angle atx=L (see Fig. 5) - _d Thickness of dielectric sheet - _r Thickness of resistance sheet - Dielectric constant - Resistivity - Dimensionless time,t/L ² - Potential - ₁ Reference potential - ₂ Reference potential - Dimensionless potential, ( – ₁)/( ₂ – ₁) - Angular frequency, 2f - Dimensionless frequency,L ²/ The investigation was performed while the first author was Visiting Associate Professor at Purdue University during 1967/68.