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This paper is concerned with a dynamical theory of mixtures, composed of n reactive constituents in relative motion to each other. The theory is developed in terms of the constituent ingredients using a balance of energy and an entropy production inequality for each constituent of the mixture, together with invariance requirements under superposed rigid body motions of the whole mixture. The balance of energy and the entropy production inequality for each of the constituents, which include contributions arising from interactions, combine to yield a single energy equation and a single entropy production inequality in terms of the ingredients of the mixture as a whole; the relations between the thermodynamical variables of the mixture and those of its constituents depend, in general, on the past history of the temperature and the kinematic variables. Full thermodynamical restrictions are deduced, and the theory is applied to the special case of a mixture of two ideal fluids.  相似文献   

3.
Shear stress–displacement model is very important to evaluate the tractive performance of tracked vehicles. A test platform, where track segment shear test and plate load test can be performed in bentonite–water mixture, was built. Through analyzing existing literatures, two shear stress–displacement empirical models were selected to conduct verification tests for seafloor suitability. Test results indicate that the existing models may not be suitable for seafloor soil. To solve this problem, a new empirical model for saturated soft-plastic soil (SSP model) was proposed, and series shearing tests were carried out. Test results indicate that SSP model can describe mechanical behavior of track segment with good approximation in bentonite–water mixture. Through analyzing main external forces applied to test scaled model of seafloor tracked trencher, drawbar pull evaluation functions was deduced with SSP model; and drawbar pull tests were conducted to validate these functions. Test results indicate that drawbar pull evaluation functions was feasible and effective; from another side, this conclusion also proved that SSP model was effective.  相似文献   

4.
A general approach is proposed for defining the macroscopic free energy density function (and its complement, the free enthalpy) of a saturated porous medium submitted to finite deformations under non-isothermal conditions, in the case of compressible fluid and solid constituents. Reference is made to an elementary volume treated as an ‘open system’, moving with the solid skeleton. The proposed free energy depends on the generalised strains (namely an appropriate measure of the strain of the solid skeleton and the variation in fluid mass content) and the absolute temperatures of the solid and fluid phases (which are assumed to differ from each other for the sake of generality). This macroscopic energy proves to be a potential for the generalised stresses (namely the associated measure of the total stress and the free enthalpy of the pore fluid per unit mass) and the entropies of the solid and fluid phases. In contrast with mixture theories, the resulting free energy is not the simple sum of the free energies of the single constituents. Two simplified cases are examined in detail, i.e. the semilinear theory (originally proposed for isothermal conditions and extended here to non-isothermal problems) and the linear theory. The proposed approach paves the way to the consistent non-isothermal-hyperelastic-plastic modelling of saturated porous media with a compressible fluid and solid constituents.  相似文献   

5.
The thermal conductivities of compacted bentonite and a bentonite–sand mixture were measured to investigate the effects of dry density, water content and sand fraction on the thermal conductivity. A single expression has been proposed to describe the thermal conductivity of the compacted bentonite and the bentonite–sand mixture once their primary parameters such as dry density, water content and sand fraction are known.  相似文献   

6.
High speed underwater systems involve many modelling and simulation difficulties related to shocks, expansion waves and evaporation fronts. Modern propulsion systems like underwater missiles also involve extra difficulties related to non-condensable high speed gas flows. Such flows involve many continuous and discontinuous waves or fronts and the difficulty is to model and compute correctly jump conditions across them, particularly in unsteady regime and in multi-dimensions. To this end a new theory has been built that considers the various transformation fronts as ‘diffuse interfaces’. Inside these diffuse interfaces relaxation effects are solved in order to reproduce the correct jump conditions. For example, an interface separating a compressible non-condensable gas and compressible water is solved as a multiphase mixture where stiff mechanical relaxation effects are solved in order to match the jump conditions of equal pressure and equal normal velocities. When an interface separates a metastable liquid and its vapor, the situation becomes more complex as jump conditions involve pressure, velocity, temperature and entropy jumps. However, the same type of multiphase mixture can be considered in the diffuse interface and stiff velocity, pressure, temperature and Gibbs free energy relaxation are used to reproduce the dynamics of such fronts and corresponding jump conditions. A general model, based on multiphase flow theory is thus built. It involves mixture energy and mixture momentum equations together with mass and volume fraction equations for each phase or constituent. For example, in high velocity flows around underwater missiles, three phases (or constituents) have to be considered: liquid, vapor and propulsion gas products. It results in a flow model with 8 partial differential equations. The model is strictly hyperbolic and involves waves speeds that vary under the degree of metastability. When none of the phase is metastable, the non-monotonic sound speed is recovered. When phase transition occurs, the sound speed decreases and phase transition fronts become expansion waves of the equilibrium system. The model is built on the basis of asymptotic analysis of a hyperbolic total non-equilibrium multiphase flow model, in the limit of stiff mechanical relaxation. Closure relations regarding heat and mass transfer are built under the examination of entropy production. The mixture equation of state (EOS) is based on energy conservation and mechanical equilibrium of the mixture. Pure phases EOS are used in the mixture EOS instead of cubic one in order to prevent loss of hyperbolicity in the spinodal zone of the phase diagram. The corresponding model is able to deal with metastable states without using Van der Waals representation.  相似文献   

7.
A method is presented for accurate calculation of equation of state (EOS) for warm dense matter. The method extends an approach presented recently, based on the adjustment of the correlation energy to impose consistency between two pressure representations: the volume derivative of the free energy and the relativistic virial theorem. In this work we show that the free energy of any neutral system obeys a fundamental differential equation, which bypasses the correlation specifics and serves as a basis to enhance EOS approximations. Specifically, we start with LDA calculations and improve the results significantly using this equation with a boundary condition at the zero pressure point. The method retains the emphasis on thermal excitations, but connects to the appropriate results at low temperatures. It effectively compensates for simplifications, including the use of a spherical model to account for global solid structure effects. EOS and opacities are calculated on the same footing for low to high Z elements and in large domains of density and temperature without recourse to parametric fitting procedures. Excellent agreement is obtained with experiments. Finally the method is applied successfully to calculate EOS and opacities for mixtures. Results for C–H mixture are compared with other calculations.  相似文献   

8.
A new finite element method is developed to simulate time‐dependent viscoelastic shear‐thinning flows characterized by the generalized Oldroyd‐B model. The focus of the algorithm is improved stability through a free‐energy dissipative scheme by using low‐order piecewise‐constant finite element approximations for stress. The algorithm is further modified by incorporating a pressure‐projection method, a DG‐upwinding scheme, a symmetric interior penalty DG method to solve the elliptic pressure‐update equation and a geometric multigrid preconditioner. The improved stability and cost to accuracy is compared when using higher order discontinuous bilinear approximation, where in addition, we consider the influence of a slope limiter for these elements. The algorithm is applied to the 2D start‐up‐driven cavity problem, and the stability of the free energy is illustrated and compared between element choices. An application of the model to modelling blood in small arterioles and channels is considered by simulating pulsatile blood flow through a stenotic arteriole. The individual influences of viscoelasticity and shear‐thinning within the generalized Oldroyd‐B model are investigated by comparing results to the Newtonian, generalized Newtonian and Oldroyd‐B models. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

9.
Boundary conditions come from Nature. Therefore these conditions exist at natural boundaries. Often, owing to limitations in computing power and means, large domains are truncated and confined between artificial synthetic boundaries. Then the required boundary conditions there cannot be provided naturally and there is a need to fabricate them by intuition, experience, asymptotic behaviour and numerical experimentation. In this work several kinds of outflow boundary conditions, including essential, natural and free boundar conditions, are evaluated for two flow and heat transfer model problems. A new outflow boundary condition, called hereafter the free boundary condition, is introduced and tested. This free boundary condition is equivalent to extending the validity of the weak form of the governing equations to the synthetic outflow instead of replacing them there with unknown essential or natural boundary conditions. In the limit of zero Reynolds number the free boundary condition minimizes the energy functional among all possible choices of outflow boundary conditions. A review of results from applications of the same boundary conditions to several other flow situations is also presented and discussed.  相似文献   

10.
A mixture theory is developed for multi-component micropolar porous media with a combination of the hybrid mixture theory and the micropolar continuum theory. The system is modeled as multi-component micropolar elastic solids saturated with multi- component micropolar viscous fluids. Balance equations are given through the mixture theory. Constitutive equations are developed based on the second law of thermodynamics and constitutive assumptions. Taking account of compressibility of solid phases, the volume fraction of fluid as an independent state variable is introduced in the free energy function, and the dynamic compatibility condition is obtained to restrict the change of pressure difference on the solid-fluid interface. The constructed constitutive equations are used to close the field equations. The linear field equations are obtained using a linearization procedure, and the micropolar thermo-hydro-mechanical component transport model is established. This model can be applied to practical problems, such as contaminant, drug, and pesticide transport. When the proposed model is supposed to be porous media, and both fluid and solid are single-component, it will almost agree with Eringen's model.  相似文献   

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