矿渣-粉煤灰基地质聚合物混凝土的冲击力学性能

以矿渣和粉煤灰为原料,以氢氧化钠和液体硅酸钠为激发剂制备出养护28 d后静态抗压强度高达56.4 MPa的矿渣-粉煤灰基地质聚合物混凝土（geopolymer concrete, GC）试件,以普通硅酸盐水泥为原料制备出养护28 d静态抗压强度高达61.6 MPa的普通硅酸盐水泥混凝土（ordinary Portland cement concrete, PC）试件,采用100 mm霍普金森压杆（split Hopkinson pressure bar, SHPB）试验装置分别对GC试件和PC试件进行冲击压缩试验,得到了2种材料在0~100 s-1平均应变率范围内的应力应变曲线。通过分析应力应变曲线,并与PC进行了对比,研究了矿渣-粉煤灰基GC的冲击力学性能。结果表明,GC作为一种新型混凝土类材料,在冲击荷载作用下具有较好的强度、变形性能和韧性;GC是一种率敏感材料,冲击荷载作用下抗压强度、变形性能和韧性随应变率的增大而增强;和PC相比,冲击荷载下GC的抗压强度较小,韧性较低,GC在开始破坏前产生的变形与PC的基本相等,完全破坏时产生的变形较小。     

高流态地质聚合物混凝土的高应变率动态压缩变形特性

以矿渣、粉煤灰为原材料,以NaOH、Na₂CO₃为碱激发剂,制备了强度等级为C30的高流态地质聚合物混凝土（highly-fluidized geopolymer concrete,HFGC）,运用波形整形技术改进了?100mm SHPB实验装置,通过参数控制保证应力均匀和恒应变率加载,对HFGC开展了动态压缩实验,分析了HFGC在冲击压缩荷载下的变形特性。HFGC属于应变率敏感材料和脆性材料,高应变率作用下,HFGC的典型应力应变曲线包括压实挤密阶段、弹性阶段和软化、屈服阶段。在10~100s-1的应变率范围内,HFGC的峰值应变ε_c随应变率的变化表现出明显的冲击韧化效应,ε_c随应变率的升高先增大后减小,满足二次函数关系ε_c＝-1.2×10-6+1.6×10-4+0.001 7,变形特性变化的临界应变率为66.7s-1。HFGC的动态弹性模量均低于其在准静态下的弹性模量。     

新型混凝土桥面铺装材料的冲击力学性能

利用大尺寸Hopkinson压杆对新型混凝土桥面铺装材料钢纤维增强聚合物改性混凝土（steel fiber reinforced and polymer modified concrete,SFRPMC）进行了冲击实验,并且在相同基准配合比下,与普通混凝土、钢纤维混凝土的冲击性能进行了对比。观察了不同打击速度下三种材料的破坏形态,得到了在不同应变率下的应力应变关系,比较了三种材料的应变率敏感性,最后从机理上分析了掺加钢纤维和聚合物对混凝土材料冲击力学性能的影响。结果表明,钢纤维增强聚合物改性混凝土材料具有良好的冲击韧性,是一种理想的混凝土桥面铺装材料。     

钢纤维高强混凝土冲击压缩的试验研究

介绍了利用100 mm SHPB装置获得钢纤维高强混凝土冲击压缩应力-应变曲线的试验研究。同一类试样在静态和动态共4个不同应变率下的试验结果揭示混凝土是应变率敏感材料，其破坏应变、峰值应变和弹性模量表现出显著的应变率强化效应。从静态和动态压缩下混凝土损伤演化的不同形式对这种应变率强化效应进行了详细讨论。从相近应变率下不同钢纤维含量试样的试验结果中，发现冲击压缩下钢纤维对混凝土的增强效应随应变率的增大而减弱。从钢纤维对混凝土静态和动态压缩下损伤演化形式的影响，讨论了钢纤维对混凝土的这种增强效应。     

玄武岩纤维高延性水泥基复合材料的动态力学性能

利用玄武岩纤维和水泥基材料，通过一定配比融合制成了在静态拉伸试验中呈现多缝开裂、应变硬化、极限拉伸应变0.5%以上的玄武岩纤维高延性水泥基复合材料(basalt fiber engineered cementitious composites, BF-ECCs)。用分离式霍普金森压杆(split Hopkinson pressure bar, SHPB)装置对不同玄武岩纤维掺量的水泥基复合材料进行动态压缩和动态劈裂试验。结果表明:(1)在压、拉两种应力状态下,玄武岩纤维对水泥基复合材料的静态强度、动态强度均有增强，且高应变率下玄武岩纤维对抗压强度动态增幅较小，对劈裂强度动态增幅较大；(2) BF-ECC的抗压强度和劈裂强度均随应变率升高而显著提高，两者均可以采用动态增强因子(dynamic increase factor, DIF)反映动态强度的增幅，但劈裂强度的应变率敏感性强于抗压强度；(3)依据试验得到的普通水泥混凝土速率敏感性的CEB-FIP方程(2010)不适用于BF-ECCs。     

干燥和饱和混凝土动态力学特性及其机理

采用分离式Hopkinson杆装置,对混凝土进行干燥和饱和状态下的SHPB实验,并与准静态实验进行对比。结果表明:干燥和饱和混凝土均具有明显的应变率效应,中等应变率条件下的应力应变曲线上升段比准静态的曲线陡;饱和混凝土动态强度提高的幅度接近干燥混凝土的2倍,具有更强的应变率敏感性;存在一个应变率临界值,仅当应变率大于临界值时,饱和混凝土的动态强度才大于干燥混凝土的的动态强度;基于实验结果,给出了不同饱和度混凝土强度与应变率的关系。     

ABAQUS混凝土损伤塑性模型中损伤因子的率相关性及实现方法

ABAQUS程序中最常用的混凝土损伤塑性（concrete damage plasticity, CDP）模型无法实现损伤因子与应变率相关。为了准确描述混凝土材料在高应变率下的损伤特性,基于CDP模型定义了新的应变率场变量,编制了VUSDFLD用户子程序,开发了能够考虑损伤因子率相关性的改进的CDP（modified CDP,MCDP）模型。MCDP模型采用能量法求解混凝土拉压损伤因子,主求解程序能够随着应变率场变量的变化而自动更新不同应变率对应的损伤参数,计算得到的混凝土单轴静态加载结果与CDP模型吻合较好。MCDP模型对高应变率下动态压缩性能的模拟结果表明:混凝土材料在不同应变率下的拉压损伤对其动态力学性能有显著影响,编制的VUSDFLD子程序和MCDP模型能够有效地解决损伤应变率相关的模拟难题,可以准确地模拟爆炸荷载作用下钢筋混凝土梁的动态响应,为预测爆炸冲击等强动载作用下混凝土结构的响应和破坏提供了更可靠的技术途径。     

基于S准则发展的混凝土动态多轴强度准则

通过对经典强度理论或准则的强度参数分析,将强度参数转化为由混凝土的单轴压缩和单轴拉伸强度表示,结合S准则给出的混凝土单轴强度的率效应规律,得出了强度参数受应变率影响的率效应函数,进而将常用的静态多轴强度准则摩尔-库伦强度理论、松岗-中井强度理论、德鲁克-普拉格强度理论、拉得-邓肯强度准则和胡克-布朗强度准则发展为动态多轴强度准则.利用混凝土动态单轴压缩和动态单轴拉伸试验结果统计分析给出的S准则率效应参数,分析了5种强度准则中强度参数随应变率的变化规律以及取值范围.基于混凝土单轴压缩和单轴拉伸强度,分别给出了5种强度准则在子午面、偏平面和平面应力条件下的强度曲线与主应力空间中的强度曲面,对比分析了5种强度准则间的异同,以及每种强度准则随应变率的变化规律.利用混凝土材料的动态双轴和动态真三轴强度试验结果,分析评价了5种动态多轴强度准则,并且阐述了各动态多轴强度准则的应变率适用范围.德鲁克-普拉格强度理论与试验结果相差甚远,不适于描述混凝土材料的强度规律.动态双轴加载时,在拉压区各强度准则差别不大,都可较好地描述试验规律;在压压区各强度准则差别较大,松岗-中井强度理论与试验结果吻合最好.在动态真三轴比例加载时,摩尔-库伦强度理论和胡克-布朗强度准则无法考虑中主应力的影响;松岗-中井强度理论和拉得-邓肯强度准则都可较好地描述试验规律.      

高强混凝土动态压缩试验分析

准确测量混凝土动态压缩性能及其应变率强化效应一直是冲击动力学研究领域的重点和难点之一。针对混凝土大口径SHPB实验，分析探讨了其中几个主要问题:应力均匀性问题、恒应变率问题和端面接触问题。研究表明:对于此次试验中混凝土试件而言，应力均匀性假设限制试验最大应变率小于166 s?1；杆和试件端面接触不平和接触不良使得测算出的杨氏模量和屈服强度明显小于实际值；在此基础上，给出了五步测试法和预应力法；利用复合整形技术实现了近似恒应变率加载。利用以上所发展和改进的技术得到了C110混凝土动静态应力应变曲线，结果显示，在试验范围内混凝土杨氏模量并没有应变率效应，其单轴压缩屈服强度与应变率对数呈线性正比关系，其唯象应变率强化因子为0.10。理论分析表明，大口径SHPB试验所得混凝土应变率效应是一种唯象效应，对于混凝土类压力敏感屈服材料而言，应该根据其屈服面方程对其进行校正，从而得到其本构方程中材料的应变率强化因子，分别利用Tresca屈服准则和K&C本构中屈服面方程对其进行校正，得到C110材料的真实应变率强化因子分别为0.015和0.038。     

基于3D细观模型的混凝土动态压缩行为分析

通过建立混凝土的3D细观模型,在细观尺度上分析动态压缩荷载作用下混凝土材料内部裂缝的产生和发展、损伤演化和动态强度及其影响因素。首先,基于传统的“生成-投放”法生成粒径、形状和空间分布均随机的凸多面体粗骨料模型,并通过骨料沉降和粒径缩放实现粗骨料的大体积率（达50%）和可调控;使用四面体网格划分骨料和砂浆表征其真实物理形状;使用界面粘结接触表征界面过渡区（ITZ）提升计算效率。进一步通过对比不同粗骨料粒径混凝土的分离式霍普金森压杆（SHPB）试验数据与模拟结果,如杆上应变时程、试件动态应力-应变曲线和试件损伤破坏模式,验证了建立的混凝土3D细观有限元模型、参数确定方法和数值仿真方法的准确性。最后,分析了30～100 s-1应变率范围内骨料粒径（4～8、10～14和22～26 mm）、体积率（20%、30%和40%）和类型（石灰岩、花岗岩和玄武岩）对混凝土动态压缩强度的影响。结果表明：粗骨料粒径增大,混凝土动态压缩强度先增大后减小;粗骨料体积率越高,混凝土动态压缩强度越大;混凝土动态压缩强度随粗骨料强度的增加而提高。     

不同晶型CL-20热分解反应机理计算分析

基于反应力场,采用NPT、NVT系综和Berendsen方法,对ε-、β-和γ-CL-20超晶胞在不同温度下的热分解反应过程进行分子动力学计算。结果表明:3种晶型CL-20的初始分解路径均是五元环和六元环中的N-NO₂键断裂生成·NO₂自由基,生成的主产物包括N₂、H₂O、CO、CO₂、NO₂、NO₃、HNO₂、HNO₃、N₂O₅、N₂O₂和NO等。相同晶型的CL-20发生热分解生成的主产物的反应速率常数随温度的升高而增大。     

梁-颗粒模型在混凝土侵彻问题中的应用

用二维梁-颗粒模型BPM2D（beam-particle model in two dimensions）模拟了混凝土侵彻问题。在模型中用3种类型梁单元形成混凝土数值试样。每种类型梁单元的力学性质均按韦伯分布随机赋值来模拟混凝土细观结构的非均匀性。利用此模型对在钢弹侵彻下混凝土圆板的破坏过程进行了数值模拟。通过将计算结果与实验数据及LS-DYNA程序模拟结果比较,表明梁-颗粒模型可有效地应用于计算和模拟材料从连续介质向非连续介质转变的动态破坏问题。     

铝合金 2A12韧性断裂机制的实验研究

用轴对称圆棒静拉伸实验研究了铝合金2A12韧性断裂的特点,并探讨了临界空穴扩张比参数-VGC在实验材料上的适用性。实验测试了实验材料的拉伸特性参数及VGC参数。实验证实实验材料在不同应力状态下会发生断裂形式的转变,光滑试样表现为剪切破坏,而缺口试样为拉伸破坏,VGC参数对材料的断裂形式较为敏感。用SEM观测了试样断口显示缺口试样为空穴聚合型断裂机制。VGC参数只适用于以拉伸型断裂为主的缺口试样,对以剪切断裂为主的光滑拉伸试样不适用。     

先张预应力CFL加固RC梁预应力损失的实验研究

由于预应力碳纤维增强复合材料(CFRP)加固钢筋混凝土(RC)结构技术能够充分发挥其优异的力学性能而备受关注。本文以预应力碳纤维薄板(CFL)加固RC桥梁结构为研究对象,研制了采用先张法对CFL施加预应力的实验装置,提出了先张预应力CFL加固RC梁的实验方法及其预应力损失的监测方法,并在3个预应力水平下对RC梁实施了预应力CFL加固,测试和分析了CFL的预应力损失演化规律。研究结果表明,本文提出的先张预应力CFL加固RC梁以及预应力损失测试的方法是可行和有效的。     

On the motion of flying plate under explosive attack

The one-dimensional problem of the motion of a rigid flying plate under explosive attack has an analytic solution only when the polytropic index of detonation products equals to three. In general, a numerical analysis is required. In this paper, however, by utilizing the weak shock behavior of the reflection shock in the explosive products, and applying the small parameter purterbation method, an analytic, first-order approximate solution is obtained for the problem of flying plate driven by various high explosives with polytropic indices other than but nearly equal to three. Final velocities of flying plate obtained agree very well with numerical results by computers. Thus an analytic formula with two parameters of high explosive (i.e. detonation velocity and polytropic index) for estimation of the velocity of flying plate is established.     

FAILURE MODE AND CONSTITUTIVE MODEL OF PLAIN HIGH-STRENGTH HIGH-PERFORMANCE CONCRETE UNDER BIAXIAL COMPRESSION AFTER EXPOSURE TO HIGH TEMPERATURES

An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.     

STUDY ON COUPLING MODEL OF SEEPAGE-FIELD AND STRESS-FIELD FOR ROLLED CONTROL CONCRETE DAM

IntroductionRCCDisbuiltwithconcreterolledandcompactedlayeruponlayer.Therefore,thereisonehorizontalconstructioninterfacebetweentwoconterminouslayers.Iftheconterminouslayersarenotcementedclosely ,theconstructioninterfaceswillbecomeweakpartsofRCCDthatinfluencethestrengthandstabilityofRCCD .Ontheotherhand ,theanti_seepageabilityofconstructioninterfacesisthedeterminantofanti_seepagecharacteristicsofthewholeRCCD .Whenadamisconstructedandfilledbywater,seepage_fieldcomesintobeinginthedambody ,w…     

Visual Investigation of Improvement in Extra-Heavy Oil Recovery by Borate-Assisted $$\hbox {CO}_{2}$$-Foam Injection

The significant reduction in heavy oil viscosity when mixed with \(\hbox {CO}_{2}\) is well documented. However, for \(\hbox {CO}_{2}\) injection to be an efficient method for improving heavy oil recovery, other mechanisms are required to improve the mobility ratio between the \(\hbox {CO}_{2}\) front and the resident heavy oil. In situ generation of \(\hbox {CO}_{2}\)-foam can improve \(\hbox {CO}_{2}\) injection performance by (a) increasing the effective viscosity of \(\hbox {CO}_{2}\) in the reservoir and (b) increasing the contact area between the heavy oil and injected \(\hbox {CO}_{2}\) and hence improving \(\hbox {CO}_{2}\) dissolution rate. However, in situ generation of stable \(\hbox {CO}_{2}\)-foam capable of travelling from the injection well to the production well is hard to achieve. We have previously published the results of a series of foam stability experiments using alkali and in the presence of heavy crude oil (Farzaneh and Sohrabi 2015). The results showed that stability of \(\hbox {CO}_{2}\)-foam decreased by addition of NaOH, while it increased by addition of \(\hbox {Na}_{2}\hbox {CO}_{3}\). However, the highest increase in \(\hbox {CO}_{2}\)-foam stability was achieved by adding borate to the surfactant solution. Borate is a mild alkaline with an excellent pH buffering ability. The previous study was performed in a foam column in the absence of a porous medium. In this paper, we present the results of a new series of experiments carried out in a high-pressure glass micromodel to visually investigate the performance of borate–surfactant \(\hbox {CO}_{2}\)-foam injection in an extra-heavy crude oil in a transparent porous medium. In the first part of the paper, the pore-scale interactions of \(\hbox {CO}_{2}\)-foam and extra-heavy oil and the mechanisms of oil displacement and hence oil recovery are presented through image analysis of micromodel images. The results show that very high oil recovery was achieved by co-injection of the borate–surfactant solution with \(\hbox {CO}_{2}\), due to in-situ formation of stable foam. Dissolution of \(\hbox {CO}_{2}\) in heavy oil resulted in significant reduction in its viscosity. \(\hbox {CO}_{2}\)-foam significantly increased the contact area between the oil and \(\hbox {CO}_{2}\) significantly and thus the efficiency of the process. The synergy effect between the borate and surfactant resulted in (1) alteration of the wettability of the porous medium towards water wet and (2) significant reduction of the oil–water IFT. As a result, a bank of oil-in-water (O/W) emulsion was formed in the porous medium and moved ahead of the \(\hbox {CO}_{2}\)-foam front. The in-situ generated O/W emulsion has a much lower viscosity than the original oil and plays a major role in the observed additional oil recovery in the range of performed experiments. Borate also made \(\hbox {CO}_{2}\)-foam more stable by changing the system to non-spreading oil and reducing coalescence of the foam bubbles. The results of these visual experiments suggest that borate can be a useful additive for improving heavy oil recovery in the range of the performed tests, by increasing \(\hbox {CO}_{2}\)-foam stability and producing O/W emulsions.     

Detection and quantification of industrial polyethylene branching topologies via Fourier-transform rheology,NMR and simulation using the Pom-pom model

The significance of sparse long-chain branching in polyolefines towards mechanical properties is well-known. Topology is a very important structural property of polyethylene, as is molecular weight distribution. The method of Fourier-transform rheology (FTR) and melt state nuclear magnetic resonance (NMR) is applied for the detection and quantification of branching topology (number of branches per molecule), for industrial polyethylenes of various molecular weight and molecular weight distributions. FT rheology consists of studying the development of higher harmonics contribution of the stress response to a large amplitude oscillatory shear deformation. In particular, when applying large-amplitude oscillatory shear (LAOS), one observes the development of mechanical higher harmonic contributions at 3ω ₁, 5ω ₁,..., in the shear stress response. We correlate the relative intensity, I _3/1, and phase Φ ₃ of these harmonics with structural properties of industrial polyethylene, i.e. polymer topology and molecular weight distribution. Experiments are complemented by numerical simulations, using a multimode differential Pom-pom constitutive model (DCPP formulation), by fitting to the experimental linear and nonlinear viscoelastic behaviours. Simulation results in the nonlinear regime are correlated with molecular properties of the “pom-pom” macromolecular architecture. Qualitative agreement is found between predicted and experimental FT rheology results.