Glimpses of Flow Development and Degradation During Type B Drag Reduction by Aqueous Solutions of Polyacrylamide B1120

Flow development and degradation during Type B turbulent drag reduction by 0.10 to 10 wppm solutions of a partially-hydrolysed polyacrylamide B1120 of MW \(=\) 18x10⁶ was studied in a smooth pipe of ID \(=\) 4.60 mm and L/D \(=\) 210 at Reynolds numbers from 10000 to 80000 and wall shear stresses Tw from 8 to 600 Pa. B1120 solutions exhibited facets of a Type B ladder, including segments roughly parallel to, but displaced upward from, the P-K line; those that attained asymptotic maximum drag reduction at low Re√ f but departed downwards into the polymeric regime at a higher retro-onset Re√ f; and segments at MDR for all Re√ f. Axial flow enhancement profiles of S\(^{\prime }\) vs L/D reflected a superposition of flow development and polymer degradation effects, the former increasing and the latter diminishing S\(^{\prime }\) with increasing distance downstream. Solutions that induced normalized flow enhancements S\(^{\prime }\)/S\(^{\prime }_{\mathrm {m}} <\) 0.4 developed akin to solvent, with L_e,p/D \(=\) L_e,n/D \(<\) 42.3, while those at maximum drag reduction showed entrance lengths L_e,m/D \(\sim \) 117, roughly 3 times the solvent L_e,n/D. Degradation kinetics were inferred by first detecting a falloff point (Re√f^∧, S\(^{{\prime }\wedge }\)), of maximum observed flow enhancement, for each polymer solution. A plot of S\(^{{\prime }\wedge }\)vs C revealed S\(^{{\prime }\wedge }\)linear in C at low C, with lower bound [S\(^{\prime }\)] \(=\) 5.0 wppm^??1, and S\(^{{\prime }\wedge }\) independent of C at high C, with upper bound S\(^{\prime }_{\mathrm {m}} =\) 15.9. The ratio S\(^{\prime }\)/S\(^{{\prime }\wedge }\) in any pipe section was interpreted to be the undegraded fraction of original polymer therein. Semi-log plots of (S\(^{\prime }\)/S\(^{{\prime }\wedge }\)) at a section vs transit time from pipe entrance thereto revealed first order kinetics, from which apparent degradation rate constants k_deg s^??1 and entrance severities ?ln(S\(^{\prime }\)/S\(^{{\prime }\wedge }\))₀ were extracted. At constant C, k_deg increased linearly with increasing wall shear stress Tw, and at constant Tw, k_deg was independent of C, providing a B1120 degradation modulus (k_deg/Tw) \(=\) (0.012 \(\pm \) 0.001) (Pa s)^??1 for 8 \(<\) Tw Pa \(<\) 600, 0.30 \(<\) C wppm \(<\) 10. Entrance severities were negligible below a threshold Twe \(\sim \) 30 Pa and increased linearly with increasing Tw for Tw \(>\) Twe. The foregoing methods were applied to Type A drag reduction by 0.10 to 10 wppm solutions of a polyethyleneoxide PEO P309, MW \(=\) 11x10⁶, in a smooth pipe of ID \(=\) 7.77 mm and L/D \(=\) 220 at Re from 4000 to 115000. P309 solutions that induced S\(^{\prime }\)/S\(^{\prime }_{\mathrm {m}} <\) 0.4 developed akin to solvent, with L_e,p/D \(=\) L_e,n/D \(<\) 23, while those at MDR had entrance lengths L_e,m/D \(\sim \) 93, roughly 4 times the solvent L_e,n/D. P309 solutions described a Type A fan distorted by polymer degradation. A typical trajectory departed the P-K line at an onset point Re√ f* followed by ascending and descending polymeric regime segments separated by a falloff point Re√f^∧, of maximum flow enhancement; for all P309 solutions, onset Re√ f* = 550 \(\pm \) 100 and falloff Re√f^∧ = 2550 \(\pm \) 250, the interval between them delineating Type A drag reduction unaffected by degradation. A plot of falloff S\(^{{\prime }\wedge }\) vs C for PEO P309 solutions bore a striking resemblance to the analogous S\(^{{\prime }\wedge }\) vs C plot for solutions of PAMH B1120, indicating that the initial Type A drag reduction by P309 after onset at Re√ f* had evolved to Type B drag reduction by falloff at Re√f^∧. Presuming that Type B behaviour persisted past falloff permitted inference of P309 degradation kinetics; k_deg was found to increase linearly with increasing Tw at constant C and was independent of C at constant Tw, providing a P309 degradation modulus (k_deg/Tw) \(=\) (0.011 \(\pm \) 0.002) (Pa s)^??1 for 4 \(<\) Tw Pa \(<\) 400, 0.10 \(<\) C wppm < 5.0. Comparisons between the present degradation kinetics and previous literature showed (k_deg/Tw) data from laboratory pipes of D \(\sim \) 0.01 m to lie on a simple extension of (k_deg/Tw) data from pipelines of D \(\sim \) 0.1 m and 1.0 m, along a power-law relation (k_deg/Tw) \(=\) 10^??5.4.D^??1.6. Intrinsic slips derived from PAMH B1120 and PEO P309-at-falloff experiments were compared with previous examples from Type B drag reduction by polymers with vinylic and glycosidic backbones, showing: (i) For a given polymer, [S\(^{\prime }\)] was independent of Re√ f and pipe ID, implying insensitivity to both micro- and macro-scales of turbulence; and (ii) [S\(^{\prime }\)] increased linearly with increasing polymer chain contour length Lc, the proportionality constant \(\beta =\) 0.053 \(\pm \) 0.036 enabling estimation of flow enhancement S\(^{\prime } =\) C.Lc.β for all Type B drag reduction by polymers.     

Influence of hydrodynamic slip on convective transport in flow past a circular cylinder

The presence of a finite tangential velocity on a hydrodynamically slipping surface is known to reduce vorticity production in bluff body flows substantially while at the same time enhancing its convection downstream and into the wake. Here, we investigate the effect of hydrodynamic slippage on the convective heat transfer (scalar transport) from a heated isothermal circular cylinder placed in a uniform cross-flow of an incompressible fluid through analytical and simulation techniques. At low Reynolds (\({\textit{Re}}\ll 1\)) and high Péclet (\({\textit{Pe}}\gg 1\)) numbers, our theoretical analysis based on Oseen and thermal boundary layer equations allows for an explicit determination of the dependence of the thermal transport on the non-dimensional slip length \(l_s\). In this case, the surface-averaged Nusselt number, Nu transitions gradually between the asymptotic limits of \(Nu \sim {\textit{Pe}}^{1/3}\) and \(Nu \sim {\textit{Pe}}^{1/2}\) for no-slip (\(l_s \rightarrow 0\)) and shear-free (\(l_s \rightarrow \infty \)) boundaries, respectively. Boundary layer analysis also shows that the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) holds for a shear-free cylinder surface in the asymptotic limit of \({\textit{Re}}\gg 1\) so that the corresponding heat transfer rate becomes independent of the fluid viscosity. At finite \({\textit{Re}}\), results from our two-dimensional simulations confirm the scaling \(Nu \sim {\textit{Pe}}^{1/2}\) for a shear-free boundary over the range \(0.1 \le {\textit{Re}}\le 10^3\) and \(0.1\le {\textit{Pr}}\le 10\). A gradual transition from the lower asymptotic limit corresponding to a no-slip surface, to the upper limit for a shear-free boundary, with \(l_s\), is observed in both the maximum slip velocity and the Nu. The local time-averaged Nusselt number \(Nu_{\theta }\) for a shear-free surface exceeds the one for a no-slip surface all along the cylinder boundary except over the downstream portion where unsteady separation and flow reversal lead to an appreciable rise in the local heat transfer rates, especially at high \({\textit{Re}}\) and Pr. At a Reynolds number of \(10^3\), the formation of secondary recirculating eddy pairs results in appearance of additional local maxima in \(Nu_{\theta }\) at locations that are in close proximity to the mean secondary stagnation points. As a consequence, Nu exhibits a non-monotonic variation with \(l_s\) increasing initially from its lowermost value for a no-slip surface and then decreasing before rising gradually toward the upper asymptotic limit for a shear-free cylinder. A non-monotonic dependence of the spanwise-averaged Nu on \(l_s\) is observed in three dimensions as well with the three-dimensional wake instabilities that appear at sufficiently low \(l_s\), strongly influencing the convective thermal transport from the cylinder. The analogy between heat transfer and single-component mass transfer implies that our results can directly be applied to determine the dependency of convective mass transfer of a single solute on hydrodynamic slip length in similar configurations through straightforward replacement of Nu and \({\textit{Pr}}\) with Sherwood and Schmidt numbers, respectively.     

Linear Stability of the Double-Diffusive Convection in a Horizontal Porous Layer with Open Top: Soret and Viscous Dissipation Effects

The linear stability of the double-diffusive convection in a horizontal porous layer is studied considering the upper boundary to be open. A horizontal temperature gradient is applied along the upper boundary. It is assumed that the viscous dissipation and Soret effect are significant in the medium. The governing parameters are horizontal Rayleigh number (\(Ra_\mathrm{H}\)), solutal Rayleigh number (\(Ra_\mathrm{S}\)), Lewis number (Le), Gebhart number (Ge) and Soret parameter (Sr). The Rayleigh number (Ra) corresponding to the applied heat flux at the bottom boundary is considered as the eigenvalue. The influence of the solutal gradient caused due to the thermal diffusion on the double-diffusive instability is investigated by varying the Soret parameter. A horizontal basic flow is induced by the applied horizontal temperature gradient. The stability of this basic flow is analyzed by calculating the critical Rayleigh number (\(Ra_\mathrm{cr}\)) using the Runge–Kutta scheme accompanied by the Shooting method. The longitudinal rolls are more unstable except for some special cases. The Soret parameter has a significant effect on the stability of the flow when the upper boundary is at constant pressure. The critical Rayleigh number is decreasing in the presence of viscous dissipation except for some positive values of the Soret parameter. How a change in Soret parameter is attributing to the convective rolls is presented.     

Existence of $$C^{k}$$-Invariant Foliations for Lorenz-Type Maps

Under conditions similar to those in Shashkov and Shil’nikov (Differ Uravn 30(4):586–595, 732, 1994) we show that a \(C^{k+1}\) Lorenz-type map T has a \(C^{k}\) codimension one foliation which is invariant under the action of T. This allows us to associate T to a \(C^{k}\) one-dimensional transformation.     

Global Attractors of Sixth Order PDEs Describing the Faceting of Growing Surfaces

A spatially two-dimensional sixth order PDE describing the evolution of a growing crystalline surface h(x, y, t) that undergoes faceting is considered with periodic boundary conditions, as well as its reduced one-dimensional version. These equations are expressed in terms of the slopes \(u_1=h_{x}\) and \(u_2=h_y\) to establish the existence of global, connected attractors for both equations. Since unique solutions are guaranteed for initial conditions in \(\dot{H}^2_{per}\), we consider the solution operator \(S(t): \dot{H}^2_{per} \rightarrow \dot{H}^2_{per}\), to gain our results. We prove the necessary continuity, dissipation and compactness properties.     

Passive Boundary Layer Flow Control Using Porous Lamination

The flow over a porous laminated flat plate is investigated from a flow control perspective through experiments and computations. A square array of circular cylinders is used to model the porous lamination. We determine the velocities at the fluid–porous interface by solving the two-dimensional Navier–Stokes and the continuity equations using a staggered flow solver and using LDV in experiments. The control parameters for the porous region are porosity, \(\phi \) and Reynolds number, Re, based on the diameter of the circular cylinders used to model the porous lamination. Computations are conducted for \(0.4< \phi < 0.9\) and \(25< Re < 1000\), and the experiments are conducted for \(\phi = 0.65\) and 0.8 at \(Re \approx 391,\ 497\) and 803. The permeability of the porous lamination is observed to induce a slip velocity at the interface, effectively making it a slip wall. The slip velocity is seen to be increasing functions of \(\phi \) and Re. For higher porosities at higher Re, the slip velocity shows non-uniform and unsteady behavior and a breakdown Reynolds number is defined based on this characteristic. A map demarcating the two regimes of flow is drawn from the computational and experimental data. We observe that the boundary layer over the porous lamination is thinner than the Blasius boundary layer and the shear stress is higher at locations over the porous lamination. We note that the porous lamination helps maintain a favorable pressure gradient at the interface which delays separation. The suitable range of porosities for effective passive separation control is deduced from the results.     

Does Density Ratio Significantly Affect Turbulent Flame Speed?

In order to experimentally study whether or not the density ratio σ substantially affects flame displacement speed at low and moderate turbulent intensities, two stoichiometric methane/oxygen/nitrogen mixtures characterized by the same laminar flame speed S _L = 0.36 m/s, but substantially different σ were designed using (i) preheating from T _u = 298 to 423 K in order to increase S _L , but to decrease σ, and (ii) dilution with nitrogen in order to further decrease σ and to reduce S _L back to the initial value. As a result, the density ratio was reduced from 7.52 to 4.95. In both reference and preheated/diluted cases, direct images of statistically spherical laminar and turbulent flames that expanded after spark ignition in the center of a large 3D cruciform burner were recorded and processed in order to evaluate the mean flame radius \(\bar {R}_{f}\left (t \right )\) and flame displacement speed \(S_{t}=\sigma ^{-1}{d\bar {R}_{f}} \left / \right . {dt}\) with respect to unburned gas. The use of two counter-rotating fans and perforated plates for near-isotropic turbulence generation allowed us to vary the rms turbulent velocity \(u^{\prime }\) by changing the fan frequency. In this study, \(u^{\prime }\) was varied from 0.14 to 1.39 m/s. For each set of initial conditions (two different mixture compositions, two different temperatures T _u , and six different \(u^{\prime })\), five (respectively, three) statistically equivalent runs were performed in turbulent (respectively, laminar) environment. The obtained experimental data do not show any significant effect of the density ratio on S _t . Moreover, the flame displacement speeds measured at u′/S _L = 0.4 are close to the laminar flame speeds in all investigated cases. These results imply, in particular, a minor effect of the density ratio on flame displacement speed in spark ignition engines and support simulations of the engine combustion using models that (i) do not allow for effects of the density ratio on S _t and (ii) have been validated against experimental data obtained under the room conditions, i.e. at higher σ.     

Damköhler-Shelkin Paradox in the Theory of Turbulent Flame Propagation,and a Concept of the Premixed Flame at the Intermediate Asymptotic Stage

We formulated a paradox in the theory of turbulent premixed flame in the flamelet regime: discrepancy between the Damköhler (1940) and Shelkin (1943) estimate of the turbulence flame speed \(U_{t} \sim {u}^{\prime }\) in the case of strong turbulence (\({u}^{\prime }>>S_{L} \)) and numerous experiments that show a strong dependence of U_t on the speed of the instantaneous flame S_L. We name this discrepancy the Damköhler-Shelkin paradox. The first aim of the research is to validate and clarify this estimate, which is based on intuitive considerations, as the paradox must be a statement that seems contradictory to observations but is actually true. We analysed the turbulent flame in the context of the original hyperbolic combustion equation that directly describes the leading edge of the flame, which is a locus of the Zel’dovich “leading points” controlling the speed of the turbulent flame. Analysis of the corresponding characteristic equations results in the expression for speed on the steady-state turbulent flame \(U_{t} ={u}^{\prime }\sqrt {1+(S_{L} /{u}^{\prime })^{2}} \), which is the case when \({u}^{\prime }>>S_{L} \) becomes \(U_{t} \cong {u}^{\prime }\). This result confirms and improves the Damköhler-Shelkin estimate \(U_{t} \sim {u}^{\prime }\). The second aim is to resolve the Damköhler-Shelkin paradox. We explain the discrepancy with observations by the fact that turbulent flames are transient due to insufficient residence time in the real burners to reach statistical equilibrium of wrinkle structures of the random flame surface. We consider the transient flame in the intermediate asymptotic stage when the small-scales wrinkles are in statistical equilibrium, while at the same time the large-scale wrinkles are far from equilibrium. The expressions for the flame speed and width, which we deduce using the dimensional analysis and general properties of the ransom surface, \(U_{t} \sim ({u}^{\prime }S_{L})^{1/2}\) and \(\delta _{t} \sim ({u}^{\prime }Lt)^{1/2}\), show that this transient flame is in fact a turbulent mixing layer travelling with constant speed U_t depending on S_L, the intermediate steady propagation (ISP) flame. Qualitative estimations of the times required for the small-scale and large-scale wrinkles to reach statistical equilibrium show that the turbulent Bunsen- and V-flames correspond to the intermediated asymptotic stage, and the turbulent flames with a complete equilibrium structure of the wrinkled flamelet surface are not attainable under laboratory conditions. We present the results of numerical simulations of the impingent flames, which count in favour of the belief that these flames are also transient.     

Topological Pressure of Generic Points for Amenable Group Actions

Let (X, G) be a G-action topological dynamical system (t.d.s. for short), where G is a countably infinite discrete amenable group. In this paper, we study the topological pressure of the sets of generic points. We show that when the system satisfies the almost specification property, for any G-invariant measure \(\mu \) and any continuous map \(\varphi \),

$$\begin{aligned} P\left( X_{\mu },\varphi ,\{F_n\}\right) = h_{\mu }(X)+\int \varphi d\mu , \end{aligned}$$

where \(\{F_n\}\) is a Følner sequence, \(X_{\mu }\) is the set of generic points of \(\mu \) with respect to (w.r.t. for short) \(\{F_n\}\), \(P(X_{\mu },\varphi ,\{F_n\})\) is the topological pressure of \(X_{\mu }\) for \(\varphi \) w.r.t. \(\{F_n\}\) and \(h_{\mu }(X)\) is the measure-theoretic entropy.

     

A Simple Method for the Determination of Adsorption Kinetic Parameters Using Recycle Fixed-Bed Adsorber

This study focuses on the development of a novel analysis technique for determining the intraparticle diffusivity \((D_{\mathrm{S}})\) and fluid film mass transfer coefficient \((k_\mathrm{F})\) from a concentration history curve of a recycle fixed-bed reactor without using the linear driving force approximation and empirical equations for the estimation of \(k_\mathrm{F}\). The recycle fixed-bed method requires lesser amounts of working fluid for experiment purposes, which is an advantage over the usual fixed-bed method. Based on the characterization results of the concentration history curves, simulated by rigorous numerical calculations, a novel analysis technique was established. The \(D_{\mathrm{S}}\) value can be determined from the experimentally obtained time at which the concentration of the curve is minimal \((t_{C\mathrm{min}})\). The \(k_\mathrm{F}\) value can be determined from the \(D_{\mathrm{S}}\) value and Biot number (Bi), which can be estimated from the experimental ratio of the maximum concentration to the minimum concentration \((c_{\max }/c_{\min })\). The \(D_{\mathrm{S}}\) and \(k_\mathrm{F}\) values of phenol adsorption on an activated carbon material were determined experimentally using the proposed analysis method. This method enables the determination of reliable adsorption kinetic parameters through a simple and economical experiment. However, appropriate experimental data must be acquired under regulated experimental conditions, especially in the case of fluctuation of the concentration history curve.     

A Reaction–Diffusion–Advection Equation with Mixed and Free Boundary Conditions

We investigate a reaction–diffusion–advection equation of the form \(u_t-u_{xx}+\beta u_x=f(u)\) \((t>0,\,0<x<h(t))\) with mixed boundary condition at \(x=0\) and Stefan free boundary condition at \(x=h(t)\). Such a model may be applied to describe the dynamical process of a new or invasive species adopting a combination of random movement and advection upward or downward along the resource gradient, with the free boundary representing the expanding front. The goal of this paper is to understand the effect of advection environment and no flux across the left boundary on the dynamics of this species. For the case \(|\beta |<c_0\), we first derive the spreading–vanishing dichotomy and sharp threshold for spreading and vanishing, and then provide a much sharper estimate for the spreading speed of h(t) and the uniform convergence of u(t, x) when spreading happens. For the case \(|\beta |\ge c_0\), some results concerning virtual spreading, vanishing and virtual vanishing are obtained. Here \(c_0\) is the minimal speed of traveling waves of the differential equation.     

Monte Carlo Assessment of the Impact of Oscillatory and Pulsating Boundary Conditions on the Flow Through Porous Media

The linear stability analysis of vertical throughflow of power law fluid for double-diffusive convection with Soret effect in a porous channel is investigated in this study. The upper and lower boundaries are assumed to be permeable, isothermal and isosolutal. The linear stability of vertical through flow is influenced by the interactions among the non-Newtonian Rayleigh number (Ra), Buoyancy ratio (N), Lewis number (Le), Péclet number (Pe), Soret parameter (Sr) and power law index (n). The results indicate that the Soret parameter has a significant influence on convective instability of power law fluid. It has also been noticed that buoyancy ratio has a dual effect on the instability of fluid flow. Further, it is noticed that the basic temperature and concentration profiles have singularities at \(Pe = 0\) and \(Le = 1\), the convective instability is looked into for the limiting case of \(Pe\rightarrow 0\) and \(Le \rightarrow 1\). For the case of pure thermal convection with no vertical throughflow, the present numerical results coincide with the solution of standard Horton–Rogers–Lapwood problem. The present results for critical Rayleigh number obtained using bvp4c and two-term Galerkin approximation are compared with those available in the literature and are tabulated.     

FEM solution to natural convection flow of a micropolar nanofluid in the presence of a magnetic field

The two-dimensional, laminar, unsteady natural convection flow in a square enclosure filled with aluminum oxide (\(\hbox {Al}_{2} \hbox {O}_{3}\))–water nanofluid under the influence of a magnetic field, is considered numerically. The nanofluid is considered as Newtonian and incompressible, the nanoparticles and water are assumed to be in thermal equilibrium. The mathematical modelling results in a coupled nonlinear system of partial differential equations. The equations are solved using finite element method (FEM) in space, whereas, the implicit backward difference scheme is used in time direction. The results are obtained for Rayleigh (Ra), Hartmann (Ha) numbers, and nanoparticles volume fractions (\(\phi\)), in the ranges of \(10^3 \le Ra \le 10^7\), \(0\le Ha \le 500\) and \(0 \le \phi \le 0.2\), respectively. The streamlines and microrotation contours are observed to show similar behaviors with altering magnitudes. For low Ra values, when \(Ha=0\), symmetric vortices near the walls and a central vortex in opposite direction are observed in vorticity. As Ra increases, the central vortex splits into two due to the circulation in the effect of the buoyant flow. Boundary layer formation is observed when Ha increases for almost all Rayleigh numbers in both streamlines and vorticity. The isotherms have horizontal profiles for high Ra values owing to convective dominance over conduction. As Ha is increased, the convection effect is reduced, and isotherms tend to have vertical profiles. This study presents the first FEM application for solving highly nonlinear PDEs defining micropolar nanofluid flow especially for large values of Rayleigh and Hartmann numbers.     

The Effect of Grain Size Distribution on Nonlinear Flow Behavior in Sandy Porous Media

The current study provides new experimental data on nonlinear flow behavior in various uniformly graded granular materials (20 samples) ranging from medium sands (\(d_{50 }>0.39\) mm) to gravel (\(d_{50}=6.3\) mm). Generally, theoretical equations relate the Forchheimer parameters a and b to the porosity, as well as the characteristic pore length, which is assumed to be the median grain size \((d_{50})\) of the porous medium. However, numerical and experimental studies show that flow resistance in porous media is largely determined by the geometry of the pore structure. In this study, the effect of the grain size distribution was analyzed using subangular-subrounded sands and approximately equal compaction grades. We have used a reference dataset of 11 uniformly graded filter sands. Mixtures of filter sands were used to obtain a slightly more well-graded composite sand (increased \(C_{u}\) values by a factor of 1.19 up to 2.32) with respect to its associated reference sand at equal median grain size \((d_{50})\) and porosity. For all composite sands, the observed flow resistance was higher than in the corresponding reference sand at equal \(d_{50}\), resulting in increased a coefficients by factors up to 1.68, as well as increased b coefficients by factors up to 1.44. A modified Ergun relationship with Ergun constants of 139.1 for A and 2.2 for B, as well as the use of \(d_{m}-\sigma \) as characteristic pore length predicted the coefficients a and b accurately.     

Smooth positon solutions of the focusing modified Korteweg–de Vries equation

The n-fold Darboux transformation \(T_{n}\) of the focusing real modified Korteweg–de Vries (mKdV) equation is expressed in terms of the determinant representation. Using this representation, the n-soliton solutions of the mKdV equation are also expressed by determinants whose elements consist of the eigenvalues \(\lambda _{j}\) and the corresponding eigenfunctions of the associated Lax equation. The nonsingular n-positon solutions of the focusing mKdV equation are obtained in the special limit \(\lambda _{j}\rightarrow \lambda _{1}\), from the corresponding n-soliton solutions and by using the associated higher-order Taylor expansion. Furthermore, the decomposition method of the n-positon solution into n single-soliton solutions, the trajectories, and the corresponding “phase shifts” of the multi-positons are also investigated.     

Synchronization transitions induced by partial time delay in a excitatory–inhibitory coupled neuronal network

Information transmission delays are an inherent factor of neuronal systems as a consequence of the finite propagation speeds and time lapses occurring by both dendritic and synaptic processes. In real neuronal systems, some delay between two neurons is too small and can be ignored, which results in partial time delay. In this paper, we focus on investigating influences of partial time delay on synchronization transitions in a excitatory–inhibitory (E–I) coupled neuronal networks. Here, we suppose time delay between two neurons equals to \(\tau \) with probability \(p_{\mathrm{delay}}\) and investigate effect of partial time delay on synchronization transitions of the neuronal networks by controlling \(\tau \) and \(p_{\mathrm{delay}}\) under three cases. In these three cases, excitatory synapses are always considered to delayed with probability \(p_{\mathrm{delay}}\), while inhibitory synapses are considered to be without delays (case I), delayed with probability \(p_{\mathrm{delay}}\) (case II), and always delayed (case III), respectively. It is revealed that, in the first two cases, partial time delay has little influences on synchronization of the neuronal network for small \(p_{\mathrm{delay}}\), while it could induce synchronization transitions at \(\tau \) around integer multiples of the period of individual neuron T when \(p_{\mathrm{delay}}\) is large enough, while in the case III, partial time delay could induce synchronization transitions at \(\tau \) being around odd integer multiples of T / 2 for small \(p_{\mathrm{delay}}\) and at \(\tau \) being around integer multiples of T for large \(p_{\mathrm{delay}}\). Most interesting observation is that partial time delay could induce frequent synchronization transitions at \(\tau \) being around integer multiples of T / 2 for intermediate \(p_{\mathrm{delay}}\). Moreover, effect of rewiring probability on synchronization transitions induced by partial time delay has been discussed. It is found that synchronization transitions induced by partial time delay are robust to rewiring probability for large \(p_{\mathrm{delay}}\) under the three cases.     

Insight into Heterogeneity Effects in Methane Hydrate Dissociation via Pore-Scale Modeling

A large number (1253) of high-quality streaming potential coefficient (\(C_\mathrm{sp})\) measurements have been carried out on Berea, Boise, Fontainebleau, and Lochaline sandstones (the latter two including both detrital and authigenic overgrowth forms), as a function of pore fluid salinity (\(C_\mathrm{f})\) and rock microstructure. All samples were saturated with fully equilibrated aqueous solutions of NaCl (10\(^{-5}\) and 4.5 mol/dm\(^{3})\) upon which accurate measurements of their electrical conductivity and pH were taken. These \(C_\mathrm{sp}\) measurements represent about a fivefold increase in streaming potential data available in the literature, are consistent with the pre-existing 266 measurements, and have lower experimental uncertainties. The \(C_\mathrm{sp}\) measurements follow a pH-sensitive power law behaviour with respect to \(C_\mathrm{f}\) at medium salinities (\(C_\mathrm{sp} =-\,1.44\times 10^{-9} C_\mathrm{f}^{-\,1.127} \), units: V/Pa and mol/dm\(^{3})\) and show the effect of rock microstructure on the low salinity \(C_\mathrm{sp}\) clearly, producing a smaller decrease in \(C_\mathrm{sp}\) per decade reduction in \(C_\mathrm{f}\) for samples with (i) lower porosity, (ii) larger cementation exponents, (iii) smaller grain sizes (and hence pore and pore throat sizes), and (iv) larger surface conduction. The \(C_\mathrm{sp}\) measurements include 313 made at \(C_\mathrm{f} > 1\) mol/dm\(^{3}\), which confirm the limiting high salinity \(C_\mathrm{sp}\) behaviour noted by Vinogradov et al., which has been ascribed to the attainment of maximum charge density in the electrical double layer occurring when the Debye length approximates to the size of the hydrated metal ion. The zeta potential (\(\zeta \)) was calculated from each \(C_\mathrm{sp}\) measurement. It was found that \(\zeta \) is highly sensitive to pH but not sensitive to rock microstructure. It exhibits a pH-dependent logarithmic behaviour with respect to \(C_\mathrm{f}\) at low to medium salinities (\(\zeta =0.01133 \log _{10} \left( {C_\mathrm{f} } \right) +0.003505\), units: V and mol/dm\(^{3})\) and a limiting zeta potential (zeta potential offset) at high salinities of \({\zeta }_\mathrm{o} = -\,17.36\pm 5.11\) mV in the pH range 6–8, which is also pH dependent. The sensitivity of both \(C_\mathrm{sp}\) and \(\zeta \) to pH and of \(C_\mathrm{sp}\) to rock microstructure indicates that \(C_\mathrm{sp}\) and \(\zeta \) measurements can only be interpreted together with accurate and equilibrated measurements of pore fluid conductivity and pH and supporting microstructural and surface conduction measurements for each sample.     

A Novel Relative Permeability Model Based on Mixture Theory Approach Accounting for Solid–Fluid and Fluid–Fluid Interactions

A novel model is presented for estimating steady-state co- and counter-current relative permeabilities analytically derived from macroscopic momentum equations originating from mixture theory accounting for fluid–fluid (momentum transfer) and solid–fluid interactions (friction). The full model is developed in two stages: first as a general model based on a two-fluid Stokes formulation and second with further specification of solid–fluid and fluid–fluid interaction terms referred to as \(R_{{i}}\) (i =  water, oil) and R, respectively, for developing analytical expressions for generalized relative permeability functions. The analytical expressions give a direct link between experimental observable quantities (end point and shape of the relative permeability curves) versus water saturation and model input variables (fluid viscosities, solid–fluid/fluid–fluid interactions strength and water and oil saturation exponents). The general two-phase model is obeying Onsager’s reciprocal law stating that the cross-mobility terms \(\lambda _\mathrm{wo}\) and \(\lambda _\mathrm{ow}\) are equal (requires the fluid–fluid interaction term R to be symmetrical with respect to momentum transfer). The fully developed model is further tested by comparing its predictions with experimental data for co- and counter-current relative permeabilities. Experimental data indicate that counter-current relative permeabilities are significantly lower than corresponding co-current curves which is captured well by the proposed model. Fluid–fluid interaction will impact the shape of the relative permeabilities. In particular, the model shows that an inflection point can occur on the relative permeability curve when the fluid–fluid interaction coefficient \(I>0\) which is not captured by standard Corey formulation. Further, the model predicts that fluid–fluid interaction can affect the relative permeability end points. The model is also accounting for the observed experimental behavior that the water-to-oil relative permeability ratio \(\hat{{k}}_{\mathrm{rw}} /\hat{{\mathrm{k}}}_{\mathrm{ro}} \) is decreasing for increasing oil-to-water viscosity ratio. Hence, the fully developed model looks like a promising tool for analyzing, understanding and interpretation of relative permeability data in terms of the physical processes involved through the solid–fluid interaction terms \(R_{{i}}\) and the fluid–fluid interaction term R.     

Bonded contact and general crack problems in generalized materials and their relationships

The term of generalized material is introduced here as the material, whose state is described by the second order homogeneous differential equations with constant coefficients. The generalized point sources are described by homogeneous expressions, containing the first order derivatives with constant coefficients. The Green’s function for a half-space, made of generalized material, subjected to the action of generalized point sources, is derived in the form of a single integral over a circle. Some of the components of the surface Green’s function are presented in finite form, no computation of any integral is needed. The bonded contact problem is described as mixed–mixed boundary value problem for a half-space, with normal and tangential displacements prescribed inside domain S and vanishing tractions outside this domain on the plane \(x_{3}=0\). A set of governing integral equations for bonded contact problem was derived, with some of the kernels defined in finite form. The general crack problem is defined as that of a flat crack of arbitrary shape S in the plane \(x_{3}=0\), with normal tractions \(\sigma _{33}\) applied symmetrically to the crack faces and tangential tractions \(\sigma _{31}\) and \(\sigma _{23}\) applied anti-symmetrically to the crack faces. A set of 3 governing integral equations is derived, with some of the kernels presented in the finite form. The relationship between the integrands in Fourier transform of the kernels of the sets of the integral equations of both problems is established: they are related in such a way, as if they were the coefficients in the schematic sets of algebraic equations. This relationship can also be presented as a general relationship between matrices of arbitrary rank n, with their components being determinants of certain matrices of rank q, with \(q\ge n\).