Dynamic viscosity and material relaxation time during shock loading

The dynamic viscosity and characteristic relaxation time at various scale-structural levels of deformation of a shock-loaded medium are determined using concepts of multilevel solid-state mechanics. The notion of the quasi-time fractal dimension is introduced and used to calculate the indicated characteristics. Computational-experimental data for the viscosity and relaxation time are given for three materials:M2 copper, AMg6 aluminum base alloy and Armco iron.     

Mathematical modeling of mechanical properties of metals and alloys at large strains

We discuss problems in mathematical modeling of the mechanical behavior of metals and alloys at large strains. Attention is mainly paid to the analysis of the stress-strain state of specimens and structural fragments made of highly plastic materials with the effect of stability loss under tensile stresses taken into account. We discuss the methods for determining the true property diagram at strains exceeding the ultimate uniform strain. We process experimental data and determine the true property diagrams for AMg6, AMg6M, and 1201 aluminum alloys and BrKh08 alloy. To calculate the load-carrying capacity of structural members, one often uses the conventional ultimate strength σ _b accepted in regulations as a material characteristic. But it follows from the method for experimentally determining this characteristic that it depends on the properties of the specimen viewed as a structure. As a result, a formal use of fracture criteria recommended in regulations leads to a discrepancy between design and experimental values of fracture loads. Nowadays, the finite element method is widely used in practical strength analysis. This method permits one to study the elastoplastic strained state of geometrically complicated structures in detail, take into account physical nonlinearity at large strains, determine damage boundaries, and improve experimental methodology. The wide capabilities of this method allow one to use test results more completely.     

Stability of thin plates with cracks under biaxial tension

Conclusions A method has been developed for analyzing the stability of thin plates with cracks under biaxial tension which is based on measuring the local buckling of the plate in the crack region with pneumatic instruments and describing the results in the system of plate coordinates.It has been demonstrated that the critical stress corresponding to local loss of stability depends strongly on the magnitude of the force acting along the crack. Values of the bending factor have been determined experimentally for plates of the grade AMg6M aluminum alloy. Unlike in the case of no load along the crack, in the case of biaxial loading the value of this bending factor does depend on the geometrical parameters of the plate.An empirical expression has been derived for the bending factor which, for this particular material, yields values close to experimental ones.Institute of Mechanics, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Prikladnaya Mekhanika, Vol. 18, No. 10, pp. 80–85, October, 1982.     

Simple linear viscoelastic models of dilute solutions of polymer molecules and emulsion droplets

The complex viscosity of microemulsions shows relaxation processes of which the largest relaxation time is about 10^–5 s or less. This time can be attributed to relaxation of stresses in the surface of emulsion droplets pertaining to interfacial tension. Superimposed on a spherical droplet surface shape fluctuations can occur due to thermal energies. Our aim is to show the influence of thermal shape fluctuations on the complex viscosity of emulsions. The method used in the derivation has also been applied to inflexible rods to demonstrate its feasibility by showing the formal rheological equivalence of in length thermally fluctuating rods and Rouse's simple model of polymers. The emulsion results have been applied to a dilution series of a non-ionic microemulsion.     

Uniaxial deformation and relaxation of polymer blends: relationship between flow and morphology development

Uniaxial elongational flow followed by stress relaxation of a dilute mixture of polystyrene/polymethylmethacrylate) PS/PMMA with PS (5 wt%) as a dispersed phase was investigated. The behavior of the blend was found to be dominated by the PMMA matrix during elongation and by the interface during the relaxation at long time. Such a behavior was related to drop deformation and shape recovery during the relaxation process as was confirmed by morphological analyses on samples quenched within the rheometer just after elongation and at various times during the relaxation process. The morphology and the rheological material functions variation were compared to the Yu model (Yu W, Bousmina M, Grmela M, Palierne JF, Zhou C (2002) Quantitative relationship between rheology and morphology in emulsions. J Rheol 46(6):1381–1399).     

Application of holographic interferometry to predict long-time torsional relaxation

The objective of the work described in this paper was to develop techniques to predict long-term relaxation in torsional springs based on short-time data. The torsional springs examined in this study were torsion bars fabricated from 300M steel (280–300-ksi tensile strength). A holographic technique was utilized to perform very precise measurements of relaxation in torsion bars. The technique utilizes real-time holographic interferometry and was capable of resolving relaxation (torque losses) as small as. 01 in.-lb for a bar initially torqued to 825 in.-lb. The holographically determined torque-logs data were used to develop a model to estimate the relaxation behavior of the torsion bars. The model determined to best fit the data is described by: ΔT=0.32(t+50)^0.4?qt ^?1 wheret = time in hours ΔT = total change in torque (in.-lb) The model was developed to fit the holographic data from 0 to 5000 h. Excellent agreement between the torque-loss rate predicted by the model and that actually measured holographically at 10,000 h was obtained. This further indicates that long-time relaxation behavior of the torsion bars can be accurately predicted from short-time tests. Using the model, it is now a simple matter to holographically measure and evaluate the relaxation of other lots of torsion bars to predict their long-time relaxation behavior. The measurement period can be as short as 100 h to show the comparison with baseline data. The long-time prediction can be compared with the acceptable engineering-energy requirements to determine suitability for service.     

Testing Aluminum Alloy from Quasi-static to Dynamic Strain-rates with a Modified Split Hopkinson Bar Method

An aluminum alloy¹ was tested at quasi-static to dynamic strain-rates (from 10⁻¹ to 5 10³ s⁻¹), using a single measuring device, a modified Split Hopkinson Bar. A wave separation technique [Bussac et al., J Mech Phys Solids 50:321–350, 2002] based on the maximum likelihood method was applied to process the strain and velocity measurements recorded at various points on each bar. With this method, it is possible to compute the stress, strain, displacement and velocity at any point on the bar. Since the measurement time is unlimited, the maximum strain measured in a given specimen no longer decreases with the strain-rate, as occurs with the classical Split Hopkinson Bar method. ¹The authors wish to thank the automobile manufacturer who provided samples of the alloy used in this study. For reasons of commercial and industrial confidentiality, we were not informed about the composition of this alloy.     

A linear viscoelastic model for solid polyethylene

Stress relaxation tests have been carried out on a blue, pipe grade PE 80 medium density polyethylene (BP Chemicals), to provide thermo-viscoelastic rheology for use in calculating thermal stresses in pipe production. Stresses up to 4 MPa were used, with strains up to about 2%, in tests at temperatures from 23° to 90°C. Within this range a linear viscoelastic model was applicable, provided the initial ramp strain rate was less than 7×10^–5 s^–1. The stress relaxation data was fitted directly by a model incorporating an elastic response to volumetric strains, and a generalised linear solid model, consisting of two Maxwell elements and a purely elastic element in parallel, for deviatoric strains. Arrhenius type temperature dependence of relaxation times and shear moduli is found, and within experimental accuracy the temperature dependence of all these model parameters is the same. As a consequence, and provided that the duration of the strain ramp is sufficiently short relative to relaxation times, the model leads to time-temperature superposition of the relaxation moduli, using the same shift factor on both the response magnitude and time axes.     

Steady and transient shear flows of polystyrene solutions I: Concentration and molecular weight dependence of non-dimensional viscometric functions

Start up from rest and relaxation from steady shear flow experiments have been performed on monodisperse polystyrene solutions with molecular weight ranging from 1.3 × 10⁵ to 1.6 × 10⁶ and concentration c ranging from 5% to 40%. A method of reduced variables based on the use of a characteristic time τ_w is proposed. τ_w is defined as the product of zero shear viscosity with the steady state elastic compliance.Reduced steady and transient viscometric functions so obtained depend on the ratio M/M_e (where M_e is the entanglement molecular weight). Limiting forms are obtained when M/M_e ? 18. In steady flow, a simple correlation is found between shear and normal stresses.In stress relaxation experiments, independent of shear rate, the long-time behaviour can be characterised by a single relaxation time τ₁, which is identical for shear and normal stresses. τ₁ can be simply related to the zero shear rate viscosity and the limiting elastic compliance.     

Nonlinear rheology for threadlike micelles of tetraethylammonium perfluorooctyl sulfonate

Nonlinear rheological features were investigated for an aqueous solution of tetraethylammonium perfluorooctyl sulfonate (C₈F₁₇SO₃ ^–N⁺(C₂H₅)₄; abbreviated as FOSTEA). In the solution (c=0.045 mol/l; 28.3 g/l), spherical micelles of FOSTEA were connected with each other to form threads of pearl-necklace shape. These threads were further organized into a transient network to exhibit linear relaxation characteristic of living polymers, single-mode terminal relaxation widely separated from faster relaxation processes. Nonlinear relaxation experiments against large step-strains γ(≤8) revealed that the terminal relaxation mode had a γ-insensitive relaxation time but its relaxation intensity exhibited significant damping (much stronger than that for entangled polymers). In contrast, the relaxation time and intensity for the fast relaxation modes first increased and then decreased with increasing γ. Under shear flow, the FOSTEA threads exhibited strong thinning of the viscosity. These nonlinear features of the FOSTEA threads were compared with those of other threadlike micelles, analyzed on the basis of an empirically introduced constitutive equation, and discussed in relation to strain/low-induced scission of the living threads. Received: 20 February 1998 Accepted: 30 July 1998     

Well-Posedness and Singular Limit of a Semilinear Hyperbolic Relaxation System with a Two-Scale Discontinuous Relaxation Rate

Nonlinear hyperbolic systems with relaxations may encounter different scales of relaxation time, which is a prototype multiscale phenomenon that arises in many applications. In such a problem the relaxation time is of O(1) in part of the domain and very small in the remaining domain in which the solution can be approximated by the zero relaxation limit which can be solved numerically much more efficiently. For the Jin–Xin relaxation system in such a two-scale setting, we establish its wellposedness and singular limit as the (smaller) relaxation time goes to zero. The limit is a multiscale coupling problem which couples the original Jin–Xin system on the domain when the relaxation time is O(1) with its relaxation limit in the other domain through interface conditions which can be derived by matched interface layer analysis.As a result, we also establish the well-posedness and regularity (such as boundedness in sup norm with bounded total variation and L ¹-contraction) of the coupling problem, thus providing a rigorous mathematical foundation, in the general nonlinear setting, to the multiscale domain decomposition method for this two-scale problem originally proposed in Jin et al. in Math. Comp. 82, 749–779, 2013.     

Simulation of the linear rheological behavior of silica-filled,star-shaped SBR compounds

The rheological behavior of star-shaped SSBR/silica 60 phr compounds with different filler surface areas was experimentally studied and simulated using constitutive modeling. Rheological behavior was characterized in small amplitude oscillatory shear (SAOS) and stress relaxation after a small step shear. Unfilled SBR and SBR filled with four different silica grades with BET surface areas of 55, 135, 160, and 195 m²/g were used. A clear trend in rheological behavior was observed with surface area. A frequency sweep in the SAOS regime indicated an increase in dynamic properties with surface area. Additionally, linear stress relaxation tests at a strain level of 0.05 showed an increase in relaxation modulus with surface area and the presence of a plateau in the relaxation modulus at large times in compounds containing silica with high surface areas. The Leonov and Simhambhatla-Leonov models, modified to incorporate multimode particle network relaxation, were successfully used to simulate the frequency dependence of the storage modulus and the time evolution of the linear relaxation modulus for all samples. However, simulations of the frequency dependence of the loss modulus showed poor results in comparison with experimental data for the filled compounds.     

铜基非晶合金热效应和剪切模量变化起源

剪切模量在非晶合金黏性流动、扩散及结构弛豫等行为中起着重要作用. 宏观剪切弹性决定非晶合金热流变化.探索非晶合金在结构弛豫和玻璃转变过程中宏观力学性能与热流的关联有助于理解其力学行为起源. 本研究基于自间隙理论对Cu$_{49}$Hf$_{42}$Al$_{9}$非晶合金热流、剪切模量及黏度进行研究,建立剪切模量与热流之间的关联. 通过测量剪切模量精确测定自间隙缺陷浓度演化规律.从能量角度出发,通过激活能图谱探索自间隙缺陷浓度对非晶合金热力学性能的影响. 借助于动态力学分析仪研究非晶合金从室温到过冷液相区的动态弛豫行为,探索物理时效引起的结构弛豫以及内耗演化规律. 研究结果表明,自间隙理论可准确描述非晶合金的弛豫动力学、剪切软化及结构弛豫诱导的力学行为. 结合热流数据可以很好描述铸态和弛豫态非晶合金剪切模量随温度演化过程,激活能图谱直观表述了单位激活能可激活的自间隙缺陷浓度. 自间隙缺陷在结构弛豫中湮灭,表现为玻璃体系结构向更稳定状态迁移.在玻璃化转变过程中,缺陷浓度显著升高伴随热吸收,表现为原子大规模协同运动和剪切软化. 物理时效诱导非晶合金内耗和原子移动性降低. 过冷液相区内原子移动性高至消除了结构弛豫影响.      

Effect of stress biaxiality on the high-strain fatigue behavior of an aluminum-copper alloy

Although there is now a considerable volume of high-strain (<10⁵ cycles) fatigue data for uniaxial tension-compression and simple-bending conditions, relatively little information is available regarding the effects of stress and strain biaxiality. A method which has been used to study the effects of biaxiality on longlife fatigue strength is to subject thin-walled tubes to repeated internal pressure and an end load which is in phase with, and a linear function of, the pressure. The object of the present research was to use this method to study the influence of stress biaxiality on the high-strain fatigue behavior of a high strength, aluminum-4% copper alloy at room temperature. From a continuum-mechanics point of view, this material is completely elastic after the first few load cycles. Cylinder results for hoop to axial stress ratios of 2:1, 1:1, 1:2 and 2: ?1 suggest that fatigue failure of this material in the life range 10³ to 10⁵ cycles is primarily dependent on the maximum range of tensile stress. This conclusion and a study of fracture surfaces led to the use of linear-elastic fracture mechanics to interpret the fatigue and brittle fracture behavior of these cylinders.     

ORIGIN OF HEAT EFFECTS AND SHEAR MODULUS CHANGES OF A Cu-BASED AMORPHOUS ALLOY 1)

剪切模量在非晶合金黏性流动、扩散及结构弛豫等行为中起着重要作用. 宏观剪切弹性决定非晶合金热流变化.探索非晶合金在结构弛豫和玻璃转变过程中宏观力学性能与热流的关联有助于理解其力学行为起源. 本研究基于自间隙理论对Cu$_{49}$Hf$_{42}$Al$_{9}$非晶合金热流、剪切模量及黏度进行研究,建立剪切模量与热流之间的关联. 通过测量剪切模量精确测定自间隙缺陷浓度演化规律.从能量角度出发,通过激活能图谱探索自间隙缺陷浓度对非晶合金热力学性能的影响. 借助于动态力学分析仪研究非晶合金从室温到过冷液相区的动态弛豫行为,探索物理时效引起的结构弛豫以及内耗演化规律. 研究结果表明,自间隙理论可准确描述非晶合金的弛豫动力学、剪切软化及结构弛豫诱导的力学行为. 结合热流数据可以很好描述铸态和弛豫态非晶合金剪切模量随温度演化过程,激活能图谱直观表述了单位激活能可激活的自间隙缺陷浓度. 自间隙缺陷在结构弛豫中湮灭,表现为玻璃体系结构向更稳定状态迁移.在玻璃化转变过程中,缺陷浓度显著升高伴随热吸收,表现为原子大规模协同运动和剪切软化. 物理时效诱导非晶合金内耗和原子移动性降低. 过冷液相区内原子移动性高至消除了结构弛豫影响.     

Method for identification of the filled polymer material relaxation kernel in millisecond time range

The filled polymer materials exhibit viscoelastic properties in a wide time range including the millisecond range (∼10⁻²–10 ms) characteristic of different shock loadings of structures made of these materials. We propose a method for the identification of the filled polymer material relaxation kernel in the millisecond time range; this method is based on a shock loading test of a cylindrical sample made of this material. In this test, the disk indenter acceleration is measured by using a piezotransducer. The test scheme does not impose any rigid constraints on the sample dimensions. In particular, it is possible to use samples of typical dimensions of the order of 10 cm, for which the conditions that the sample material is representative of the structure material are necessarily satisfied. The relaxation kernel parameters are identified by numerical minimization of the theoretically predicted indenter velocity deviation from the velocity-time dependence obtained by integrating the acceleration transducer readings. The minimization problem is solved by using a genetic algorithm. The problem of theoretical prediction of the indenter velocity is solved numerically by using a reduced computational scheme whose parameters are chosen from the minimum condition for the deviation from the prediction obtained in the framework of the detailed computational scheme. The use of the reduced computational scheme permits decreasing the computational costs by 3–4 orders of magnitude compared with the detailed computational scheme, which is a necessary condition for the practical applicability of the genetic algorithm in identification problems. We present examples of relaxation kernel identification in the range of 0.1–10ms from the results of the test where the disk indenter raised to the height of 1m falls on the sample end surface.     

Shock polarization of solutions of strong electrolytes

It is shown that the main cause of shock emf in shock compression of a metal-electrolyte-metal system is shock polarization of the electrolyte solution. The emf is linearly dependent on ion mass and is an additive function of the ion composition of the electrolyte solution. The relaxation time for the nonequilibrium processes produced by shock polarization of the metal-electrolyte boundary does not exceed 5·10^?7 sec for single-time compression.