Relationship between the diffusion rate constant and rate constant of triplet-triplet annihilation for porphyrins in liquid solutions

Institute of Molecular and Atomic Physics, Academy of Sciences of Belarus, 70. F. Skorina Ave., Minsk, 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 63, No. 4, pp. 613–621, July–August, 1996.     

Determination of quasi-elastic coefficients of intermolecular interaction in associates of fatty acids and their perfluorine derivatives

Kuzbass State Technical University, 28 Vesennyaya Str., Kemerovo, 650026, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 6, pp. 58–61, November–December, 1995.     

Interchromophore interactions and energy transfer in covalently bound porphyrin-chlorine heterodimer

Energetis of interchromophore interactions in a covalently bound prophyrin-chlorine heterodimer (Por-O-Chl) is investigated at temperatures from 77 to 293 K in solvents with differing polarity (toluene, tetrahydrofurane, and diethyl ether: petroleum ester: isopropanole=5∶5∶2 mixture). We substantiate the conclusion that the strong quenching of fluoresence and phosphorescence of the porphyrin fragments in both stable isomers of the Por-O-Chl heterodimer is induced not by the photoinduced charge transfer but rather by efficient processes of singlet-singlet (probability F^SS=1.3·10¹¹ to 6.8°10¹⁰ sec⁻¹) and triplet-triplet (probability F^TT≥10⁸ sec⁻¹) radiationless electronic excitation transfer. It is shown that the S−S transfer takes place without quantum losses from the thermodynamically equilibrated S₁ state of the donor, and its dynamics and main regularities at temperatures from 77 to 293 K are described by the inductive resonance theory without any additional asssumptions. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 1, pp. 75–82, January–February, 1998.     

Picosecond dynamics of intramolecular charge transfer in benzophenone amino derivatives

Institute of Molecular and Atomic Physics, Academy of Sciences of Belarus, 70 F. Skaryna Ave, Minsk 220072, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 3, pp. 49–55, May–June, 1995.