Wireless retrospective gating: Application to cine cardiac imaging

A new “wireless” method of cardiac imaging is introduced, which, unlike ECG triggering, allows imaging the heart at end-diastole, and greatly reduces smearing artifacts in the phase-encoding direction. It is an improvement over ECG-driven retrospective gating, in that patients with poor ECGs can be imaged. This method extends the applicability of cardiac imaging, and since it requires no physiological monitoring hardware, can be implemented easily on any MR imager. The images produced by this method are superior to those from ECG triggering, especially when viewed in a “cine” loop. The technique described herein is, furthermore, extendable to any area where periodic or quasi-periodic motion is a problem.     

On the low-frequency limit of the Schönfeld pulse 1/f law

On the basis of propositions of the common fluctuation theory, peculiarities of small fluctuations in real physical systems with limited sizes are analyzed. It is established that small fluctuations should necessarily be divided into two types of fluctuations: “small” and “very small”. It is shown that the damping process of “small” fluctuations has relaxation character, while the damping process of “very small” fluctuations is of random character, i.e., it represents a random rectangular signal. The probability density of “very small” fluctuations is shown to be Gaussian. The agreement of the obtained results with experimental data acquired from semiconductor-based devices is analyzed. A relation between the generation–recombination noise and phonon number fluctuations in semiconductors is studied. On the basis of this consideration it is shown that the Schönfeld pulse spectrum preserves its well-known 1/f form only in the range of intermediate frequencies; at lower frequencies the spectrum gets saturated. An expression for the low-frequency limit of Schönfeld pulse 1/f law is obtained.     

Acoustic Analyses of Developmental Changes and Emotional Expression in the Preverbal Vocalizations of Infants

The nonverbal vocal utterances of seven normally hearing infants were studied within their first year of life with respect to age- and emotion-related changes. Supported by a multiparametric acoustic analysis it was possible to distinguish one inspiratory and eleven expiratory call types. Most of the call types appeared within the first two months; some emerged in the majority of infants not until the 5th (“laugh”) or 7th month (“babble”). Age-related changes in acoustic structure were found in only 4 call types (“discomfort cry,” “short discomfort cry,” “wail,” “moan”). The acoustic changes were characterized mainly by an increase in harmonic-to-noise ratio and homogeneity of the call, a decrease in frequency range and a downward shift of acoustic energy from higher to lower frequencies. Emotion-related differences were found in the acoustic structure of single call types as well as in the frequency of occurrence of different call types. A change from positive to negative emotional state was accompanied by an increase in call duration, frequency range, and peak frequency (frequency with the highest amplitude within the power spectrum). Negative emotions, in addition, were characterized by a significantly higher rate of “crying,” “hic” and “ingressive vocalizations” than positive emotions, while positive emotions showed a significantly higher rate of “babble,” “laugh,” and “raspberry.”     

A beamline for time resolved photoelectron microscopy on magnetic materials at the Swiss light source

We describe the “Surface/Interface: Microscopy” beamline currently under construction at the Paul Scherrer Institut. This beamline will use a photoemission electron microscope to study the electronic and magnetic structure of materials. Its photon energy range will be 94–2000 eV.

To allow time resolved measurements with millisecond resolution we use a new scheme allowing to switch the photon helicity optically without perturbing the electron orbit. Two identical elliptical insertion devices are placed behind each other in the same straight section. They can produce light with opposing helicities. These two sources are separated horizontally by introducing a small static parallel offset in the electron orbit. Switching between the two rays of opposite helicities is done mechanically at the horizontal focus behind the monochromator. The two sources are brought to overlap on the sample by slightly defocussing the refocussing mirror.

A commercial microscope (Δx20 nm resolution) is adapted to the synchrotron by various upgrades. These include a software combining microscope and beamline control, a computer controlled mechanical alignment system, a separate sample preparation chamber, and sample cooling using liquid nitrogen. The beamline will be available for user operation in 2002.     

Alternative procedure for LR 115 chemical etching and alpha tracks counting

An improved procedure for etching and analysis of alpha tracks induced in LR-115 detectors is proposed with the advantages of simplicity and its relatively low cost. A new type of detector holder was designed to etch and rinse efficiently up to 100 detectors. We develop a simple and reliable methodology with a semiautomatic track count using a Nikon digital camera coupled to a PC and employing software “SCION” freely available on the Internet. Track images are binarized prior the application of software “SCION” so that original track shapes are not distorted, space resolution is improved and track counting has low dependence on focus and illumination level. High discrimination for tracks is achieved when marks and rips perturb the detector surface. An image generator of nuclear tracks is included to study the effect of track overlapping effect on counting.     

The Casimir-like size effects in ideal gases

The wave character of atoms can produce Casimir-like size effects in gases confined in a narrow box. Thus the pressure tensor is not isotropic anymore and size difference becomes a driving force for isothermal diffusion by a permeable wall. Such size effects give rise to “thermosize effects” similar to thermoelectric effects.     

Methane activation over Ag-exchanged ZSM-5 zeolites: A theoretical study

Methane activation catalyzed over Ag-exchanged ZSM-5 zeolites was investigated by using the density functional theory (DFT) with a cluster model. Two different pathways were taken into account in this work: the “alkyl” and the “carbenium” pathways. The activation barriers obtained are 34.09 and 66.63 kcal/mol for the “alkyl” and the “carbenium” pathway, respectively. The calculated results show that the activation barrier of the “alkyl” pathway is smaller than that of “carbenium” pathway. Consequently, the “alkyl” pathway is the preferential reaction pathway. A new mechanism of methane conversion in the presence of ethene was proposed. In the catalytic cycle, the initial step of methane activation proceeds with the “alkyl” pathway and the Ag⁺ cation acts as an acceptor of the methyl group, then ethene reacts with the Ag⁺CH₃⁻ group to form propene. In addition, it is found that the Ag⁺ cations play an important role in the methane activation, compared with the reaction of methane activation over H-ZSM-5.     

Completeness of “good” Bethe ansatz solutions of a quantum-group-invariant Heisenberg model

The sl_q(2) quantum-group-invariant Heisenberg model with open boundary conditions is investigated by means of the Bethe ansatz. As is well known, quantum groups for q equal to a root of unity possess a finite number of “good” representations with non-zero q-dimension and “bad” ones with vanishing q-dimension. Correspondingly, the state space of an invariant Heisenberg chain decomposes into “good” and “bad” states. A “good” state may be described by a path of only “good” representations. It is shown that the “good” states are given by all “good” Bethe ansatz solutions with roots restricted to the first periodicity strip, i.e. only positive-parity strings (in the language of Takahashi) are allowed. Applying Bethe's string-counting technique completeness of the “good” Bethe states is proven, i.e. the same number of states is found as the number of all restricted paths on the sl_q(2) Bratteli diagram. It is the first time that a “completeness” proof for an anisotropic quantum-invariant reduced Heisenberg model is performed.     

Vulnerability in one-dimensional excitable media

Potentially life-threatening cardiac arrhythmias can be iniated with stimuli timed to occur during the “vulnerable window (VW)”. We defined VW as the time interval between the “conditioning” and “test” stimuli following in sequence, during which the test stimulus response propagates in only one direction. We show that the VW is a generic feature of excitable media and describe the relationship between the properties of an excitable medium and the VW. We present asymptotic results that reveal the sensitivity of the VW to both the propagation velocity of the conditioning wavefront and the recovery process parameters. We also have identified a critical length of medium that must be excited in order to reveal vulnerability. Analytical results are in agreement with numerical studies.