Intracavity Frequency Doubling of a New Low－threshold High－efficiency Crystal Nd：Sr_5（VO_4）_3F

ＩｎｔｒａｃａｖｉｔｙＦｒｅｑｕｅｎｃｙＤｏｕｂｌｉｎｇｏｆａＮｅｗＬｏｗ－ｔｈｒｅｓｈｏｌｄＨｉｇｈ－ｅｆｆｉｃｉｅｎｃｙＣｒｙｓｔａｌＮｄ：Ｓｒ＿５（ＶＯ＿４）＿３ＦＺＨＡＯＳｈｅｎｇｚｈｉ；ＷＡＮＧＱｉｎｇｐｕ；ＺＨＡＮＧＸｉｎｇｙｕ；ＷＡＮＧ...     

Study of the Frog-legs Phase Conjugator in BaTiO_3

Ｓｔｕｄｙ　ｏｆ　ｔｈｅ　Ｆｒｏｇ－ｌｅｇｓ　Ｐｈａｓｅ　Ｃｏｎｊｕｇａｔｏｒ　ｉｎ　ＢａＴｉＯ_３ＳｔｕｄｙｏｆｔｈｅＦｒｏｇ－ｌｅｇｓＰｈａｓｅＣｏｎｊｕｇａｔｏｒｉｎＢａＴｉＯ_３￥ＷＡＮＧＬｉｊｕｎ；ＷＡＮＧＪｉａｙｏｕ；ＧＵＯＳｉｊｉ（Ｄｅｐ...     

Laser Diode－end－pumped Laser Performance of Nd－doped Sr＿5（PO＿4）＿3F at 1059 and 1328 nm

ＬａｓｅｒＤｉｏｄｅ－ｅｎｄ－ｐｕｍｐｅｄＬａｓｅｒＰｅｒｆｏｒｍａｎｃｅｏｆＮｄ－ｄｏｐｅｄＳｒ＿５（ＰＯ＿４）＿３Ｆａｔ１０５９ａｎｄ１３２８ｎｍ￥ＳＵＮＬｉａｎｋｅ；ＺＨＡＮＧＳｈａｏｊｕｎ；ＣＨＥＮＧＲｕｐｉｎｇ；ＬＩＵＸｕｎｍｉｎ（Ｉｎｓｔ...     

Wavelength-Flattened 1×3 Single-Mode Fibre-Optical Splitters

Ｗａｖｅｌｅｎｇｔｈ－Ｆｌａｔｔｅｎｅｄ１×３Ｓｉｎｇｌｅ－ＭｏｄｅＦｉｂｒｅ－ＯｐｔｉｃａｌＳｐｌｉｔｔｅｒｓ￥ＨＵＡＮＧＹｏｎｇ；ＺＥＮＧＱｉｎｇｊｉ（ＰｈｏｔｏｎｉｃＴｅｃｈｎｏｌｏｇｙＬａｂｏｒａｔｏｒｙ，ＩｎｓｔｉｔｕｔｅｏｆＯｐｔｉｃａｌ...     

原子吸收法测定人精子中锌和铜含量的研究

本文采用石墨炉原子吸收法，以ＮＨ４ＮＯ３和Ｍｇ（ＮＯ３）２混合剂作基体改进剂，测定了人精子中微量元素铜和锌。基方法的特征质量分别为１０．００ｐｇＣｕ／０．００４４Ａ．Ｓ．，９．８０ＰｇＺ／０．００４Ａ．Ｓ；平均加收率为９７．４２％，锌为１０１．９１％，铜和锌的精密度分别是４．１％和４．０３％。     

970nmLD激发Tm^3＋,Yb^3＋掺杂的MFT玻璃材料上转换发光的研究

设计并制备了一种Ｔｍ＾３＋、Ｙｂ＾３＋共掺杂的多氟化物调整碲酸盐（ＭＦＴ）玻璃材料,其组份为５０ＴｅＯ２－１４．ＰｂＦ２－１０ＡｌＦ３－１０ＢａＦ２－１０ＮａＦ－０．１Ｔｍ２Ｏ３－５Ｙｂ２Ｏ３。测量了该玻璃系统的Ｒａｍａｎ散射光谱,在９７０ｎｍＬＤ激发下裸眼可以观察到很强的蓝色我,光谱测量证实这个蓝色发射（４７６ｎｍ）来源于＾１Ｇ４→＾３Ｈ６的跃迁,同时,还有两个较弱的红色发射源于＾１Ｇ４→＾３Ｈ     

Fe-CAS-NH4F-OP体系高灵敏度分光光度法测定二氧化硅中微量铁

在ＨＡｃ－ＮＨ４Ａｃ缓冲介质中,当有ＮＨ４Ｆ和乳化剂ＯＰ存在时,Ｆｅ与ＣＡＳ形成络合比为１：３的有色络合物,其最大吸收波长位于６５４．０ｎｍ,表观摩尔吸光系数为１．１８×１０＾５Ｌ·ｍｏｌ＾－１·ｃｍ＾－１,１－２０μｇ Ｆｅ／５０ｍＬ线性关系良好。该法用于二氧化硅中铁的测定,结果令人满意。     

Observation and identification of X－ray（0．3－30Bnm) multiple－order diffraction spectra

ＯｂｓｅｒｖａｔｉｏｎａｎｄｉｄｅｎｔｉｆｉｃａｔｉｏｎｏｆＸ－ｒａｙ（０．３－３０ｎｍ）ｍｕｌｔｉｐｌｅ－ｏｒｄｅｒｄｉｆｆｒａｃｔｉｏｎｓｐｅｃｔｒａＦＥＮＧＸ．Ｐ；ＨＯＵＸ．Ｂ；ＺＨＡＮＧＺ．Ｑ；ＸＵＺ．Ｚ．（ＳｈａｎｇｈａｉＩｎｓｔｉｔｕｔｅ...     

在Ar和Xe低温基体中Fe（CO）3与CO扩散控制反应研究

本文用２８０ｎｍ脉冲激光光解被Ａｒ和Ｘｅ基体隔离的Ｆｅ（ＣＯ）５以产生配位不饱和的Ｆｅ（ＣＯ）３。用傅里衰变换红外光谱仪实时监察光解停止后Ｆｅ（ＣＯ）３和ＣＤ的复合，并以Ｓｍｏｌｕｃｈｏｗｓｋｉ扩散控制反应动力学理论模型求得Ｆｅ（ＣＯ）３与ＣＯ的反应半径为４．０×１０＾－１０ｍ，ＣＯ在１０Ｋ的Ａｒ和Ｘｅ基体中的扩散系数分别为２．２×１０＾－２３ｍ＾２／ｓ和４．５×±∩＾－２３ｍ＾２／ｓ。     

3-methyl-4-metroxy-4'-nitrostilbene (MMONS) Crystal Growth and Studies of It

３－ｍｅｔｈｙｌ－４－ｍｅｔｒｏｘｙ－４＇－ｎｉｔｒｏｓｔｉｌｂｅｎｅ（ＭＭＯＮＳ）ＣｒｙｓｔａｌＧｒｏｗｔｈａｎｄＳｔｕｄｉｅｓｏｆＩｔｓＳｅｃｏｎｄＮｏｎｌｉｎｅａｒＯｐｔｉｃａｌＰｒｏｐｅｒｔｉｅｓ￥ＣＡＯＹａｎｇ；ＺＨＵＺｈｉｄｏｎｇ；ＨＵＡ...     

Effects of acid anions,major metallic elements,and chlorides on Li detection by DFWM in graphite furnace

In trace Li analysis with degenerate four-wave mixing （DFWM） method, acid anions and major metallic elements are dominant interferences in Li-eontaining samples. To better use DFWM technique to analyze trace Li in actual samples, we study their effects on Li DFWM signal intensity. It is found that K, Cs, and Ni can enhance the Li DFWM signal, SO4^2, PO^34-, Cl-, and Ca can cause significant suppression, and NO3-, Mg, Ba, Sr, and Na almost have no effects. Finally, we use HaBOa to eliminate the depressive effects of chlorides on Li DFWM signal. The result is also of reference in other trace elements analysis with DFWM.     

Two-Stage Evaporation of Silver Samples in a Graphite Atomizer

A study has been made of the process of separation of silver from the excess in a sample of alkali-earth chlorides and sulfates by two-stage evaporation from the wall of a graphite atomizer and by fractional condensation on its integrated platform. It has been shown that after the condensation on the platform at room temperature the influence of the salts on the signal of atomic absorption is two times higher than that in ordinary one-stage evaporation. The reason for this is the formation of a cloud of condensed salt particles preventing the silver atoms from depositing on the platform. The atoms are deposited on these particles and are removed from the atomizer together with them before the stage of measurement of an analytical signal.     

ICP—AES中四十种常见元素光谱干扰的研究及校正

本文用Leeman Plasma-Spec等离子光谱仪对常见四十种元素的光谱进行了探讨,测定了其光谱干扰系数,并对干扰系数校正法进行了研究。     

Separation of Silver from Chloride and Sulfate Matrices by Fractional Condensation in a Two-Step Graphite Atomizer

The influence of the excess of sodium chloride and potassium sulfate in a sample on the signal of atomic absorption of silver in a two-step graphite atomizer comprising a cup-evaporator and a tube-atomizer heated independently has been investigated. It is shown that the preliminary fractional condensation of the element to be determined in the tube-atomizer can be used to decrease the interferences from the matrix. The undesirable gas-phase condensation of the matrix vapor is eliminated by heating the tube to a temperature close to the temperature of desorption of silver from its surface (700–800°C). The attained level of the influence of the matrix on the signal of atomic absorption is approximately equal to the level of the interferences from the matrix in a graphite atomizer with transverse heating and is higher than that in an atomizer with longitudinal heating.     

微珠析相微萃取-石墨炉原子吸收法测定岩石样品中痕量铬

采用二苯碳酰二肼为络合剂,正戊醇为萃取剂,乙醇为助溶剂,建立了微珠析相微萃取-石墨炉原子吸收法测定地质样品中痕量Cr的分析方法。实验详细探讨了微珠析相微萃取的析相条件、石墨炉原子吸收工作参数及共存离子的干扰,优化了体系萃取条件。实验结果表明:微珠析相微萃取既起到了分离富集的作用,在石墨炉升温程序中又起到了基体改进剂的作用;当萃取剂用量为0.2~1.5 mL时,使之与水完全互溶所需助溶剂体积约为水相体积的0.2~0.5倍;方法线性范围为0~10μg.L-1,检出限为0.057μg.L-1,相对标准偏差(RSD)为3.3%(c=2.5μg.L-1,n=11);当萃取剂用量为1.5 mL、水相体积15 mL时,与直接溶液进样相比其灵敏度可提高10倍。所建立的方法用于地质标准参考物质AGV-2和G-2中Cr的测定,测定值与参考值具有较好的一致性。     

双硫腙浊点萃取-石墨炉原子吸收光谱法测定环境水样中痕量铅的研究

基于表面活性剂的浊点现象,建立了以双硫腙为螯合剂、Triton X-114为表面活性剂的浊点萃取-石墨炉原子吸收光谱法测定痕量铅的新方法.研究了溶液pH值、试剂浓度、平衡温度和加热时间等实验条件对浊点萃取及测定灵敏度的影响.以4 000 r·min-1离心15 min使分相,分相后的溶液在冰水浴中冷却至接近0℃,然后反转离心管弃去水相,用0.1 mol·L-1HNO3-甲醇溶液定容至0.5 mL,溶液以磷酸二氢铵及硝酸镁为基体改进剂由石墨炉原子吸收分光光度法进行测定.在pH 8.0和0.05%Triton X-114及20μmol·L-1双硫腙存在下,富集10 mL样品溶液,铅的检出限为0.089μg·L,富集倍率为19.1,所得工作曲线回归方程为A=0.0261c(μg·L-1) 0.010 6,线性范围0.1～30μg·L-1,相关系数r为0.998.方法用于环境水样中测定痕量铅的测定,获得满意结果.     

萃取分离-石墨炉原子吸收光谱法测定铁镍基高温合金中砷、铅、锡、锑、铋

基于砷、铅、锡、锑、铋与碘离子形成络合物,用MIBK萃取使其与基体分离,用石墨炉原子吸收光谱法测定了铁镍基高温合金中这五种元素.文章主要对萃取条件及萃取后剩余基体对待测元素的影响进行了研究,同时采用掩蔽的方法消除了合金中钨、铌、钽的干扰.在所选定的实验条件下,测得砷、铅、锡、锑、铋的回收率范围为93%～99%;相对标准偏差范围为8.8%～12%.     

一种测量磁光阱中冷原子密度和温度的新方法

报道了对磁光阱中冷铯原子吸收谱的实验观察,由于冷原子的多普勒增宽远小于激光发态超精细分裂,实验观察到三个孤立的吸收峰（Cs,6S1/2,F=4→6P3／2,F＝3,4,5,）其吸收系数比为3：7：12,这与相应跃迁振子强度一致。利用吸收信号测量了冷原子云的密度.结果与荧光探测法在10％的精度内符合;用吸收信号测量了冷原子的温度,测量结果与用荧光飞行时间法和释放捕捉法的结果吻合。     

氢化物—石墨炉原位富集原子吸收光谱法测定痕量锑

本文对标示问题进行了研究，自行设计了氢化物发生器，采用以石墨炉两端输入氢化物方式，载气流向用活塞控制，大幅度减少原子化阶段石墨炉内氢气分压，提高了锑的灵敏度，对氢化锑的石墨炉表面分解沉积和原子化机理进行了讨论，方法有于矿泉水和自来水痕量锑的测定，结果令人满意，锑的特征浓度为３０ｐｇ／０．００４４Ａ。     

新型离子液体预富集-石墨炉原子吸收法测定透析液中超痕量铅

设计合成了新型室温离子液体—1-丁基-3-三甲基硅烷咪唑六氟磷酸,并用于透析液中超痕量铅的预富集。从双硫腙作为螯合剂使透析液(1000mL或更大体积)中存在的铅(Ⅱ)形成中性的铅-双硫腙配合物,摒弃传统的有机萃取剂—四氯化碳,代以1-丁基-3-三甲基硅烷咪唑六氟磷酸为绿色萃取剂来萃取铅配合物。收集含有配合物的下层离子液体相,加入硝酸分解铅配合物从而使铅(Ⅱ)进入水相,其水溶液中的铅含量直接用石墨炉原子吸收法测定。实验表明此富集体系明显优于传统有机溶剂四氯化碳和经典离子液体1-丁基-3-甲基咪唑六氟磷酸萃取体,铅的一次萃取率和富集倍数分别在99%和200以上。预富集结合石墨炉原子吸收法应用于透析液中超痕量铅的测定,结果令人满意。