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1.
孔超  徐征  赵谡玲  张福俊  黄金英  闫光  厉军明 《物理学报》2008,57(12):7891-7895
用Si3N4作为电子加速层制备了固态阴极射线发光器件,其中发光层为聚[2-甲氧基-5-(2-乙基-己氧基)-1,4-苯撑乙烯撑](MEH-PPV).在交流电压的驱动下,实现了MEH-PPV的固态阴极射线发光.与SiO2做电子加速层的器件进行了对比研究,两种器件在交流电场的驱动下都得到了波峰位于417nm的短波长发光峰,它来自有机物中电子从最低未占分子轨道到最高占据分子轨道的直接复合发光,这进一步证明了固态阴极射线理论的正确性.在交流高场下比 关键词: 固态阴极射线发光 3N4')" href="#">Si3N4 电子加速层 电致发光  相似文献   

2.
利用ZnO纳米棒阵列场发射电极,以SiO2做为电子加速层制备了固态阴极射线器件,发光层为聚[2-甲氧基-5-(2-乙基-己氧基)-1,4-苯撑乙烯撑](MEH-PPV),在交流驱动下得到了MEH-PPV的固态阴极射线发光,探测到了长波峰和短波峰的发射,并和无电子加速层的器件做了比较,证明混合激发模式下的器件在长波长的发光亮度更大. 关键词: 固态阴极射线 ZnO纳米棒阵列 电子加速 电致发光  相似文献   

3.
在固态阴极射线发光中,过热电子碰撞激发有机材料而发光,因此加速层对电子的加速能力是影响器件发光亮度的关键因素之一.分别以SiO2和ZnO作为加速层.制备出两种固态阴极射线发光器件A:ITO/MEH-PPV/SiO2/Al和B:ITO/MEH-PPV/ZnO/Al.通过理论计算比较了电子从电极注入到加速层的隧穿电流密度以及SiO2层与ZnO层的电场强度,计算结果表明:在相同驱动电压下,SiO2作为电子加速层时隧穿电流的密度要大于ZnO层的隧穿电流的密度,并且SiO2层的电场强度比ZnO层的电场强度大.实验结果表明:SiO2作为加速层的器件的发光强度高于以ZnO为电子加速层器件的发光强度.  相似文献   

4.
固态阴极射线器件的加速层,是提高固态阴极射线性能的重要部分,它能够加大电子能量,倍增电子数量.其中增加注入电子从而提高过热电子的数量,是提高固态阴极射线器件性能的关键.为此,文章尝试将加速层复合,兼顾加速与电子注入性能.首先将SiO2,ZnS和ZnO分别与有机聚合物MEH-PPV组合,确定较适合的复合加速层的组合:SiO2/ZnS和ZnO)/SiO2.然后将这两种复合加速层的性能对比,发现SiO2/ZnS的性能更优越,因为电子注入性能ZnS和ZnO相当,而电子加速倍增性能ZnS明显优于ZnO,其中SiO2为主要的加速层,而ZnS起到降低注入势垒变成阶梯势垒的作用.最后又将复合加速层结构的固态阴极射线器件和传统的SiO2夹层固态阴极射线器件对比,发现这种复合加速层结构,尤其在高场下,可提高固态阴极射线的初电子源和过热电子的数目,从而提高其发光效率具有促进作用.  相似文献   

5.
固态阴极射线发光(SSCL)是发光学中一种新的激发方式,引发出一些发光学中的重要问题,但是固态阴极射线发光的性质还不是十分清楚,需要进一步研究.文章用SiO2作为电子加速层,有机材料MEH-PPV为发光层,在正弦交流电压驱动下实现了固态阴极射线发光,得到410和580 nm两个发光峰.通过研究这两个发光峰的性质,证实它们分别符合能带理论和分子理论.改变驱动电压的频率时,长波峰的发光强度随频率的增加而增加,而短波峰的发光强度随频率的增加而减小,这是由于这两个发光峰对应的上能级寿命不同引起的.  相似文献   

6.
O482.312006053829驱动电压频率对固态阴极射线发光影响的研究=Influenceof frequency on solid state cathodoluminescence[刊,中]/刘德昂(北京交通大学光电子技术研究所,发光与光信息技术教育部重点实验室.北京(100044)),徐征…//光谱学与光谱分析.—2006,26(6).—987-990用Si O2作为电子加速层,有机材料MEH-PPV为发光层,在正弦交流电压驱动下实现了固态阴极射线发光,得到410和580nm两个发光峰。通过研究这两个发光峰的性质,证实它们分别符合能带理论和分子理论。改变驱动电压的频率时,长波峰的发光强度随频率的增加而增加,而短波峰的…  相似文献   

7.
曲崇  徐征  滕枫  钱磊  于文革  权善玉  徐叙瑢 《物理学报》2004,53(12):4387-4391
在分层优化基础上,用MEH-PPV和SiO2复合制成夹层结构器件,在交流电压的三个区域下 ,表现出不同的发光.在电压较低时得到了红色发光,电压较高时得到了蓝色发光,电压的中间区域为两种发光的叠加.这两种发光都是源于SiO2中加速电子直接碰撞激发有机发光层而引起的固态阴极射线发光.通过对器件光学特性的研究,分析了光谱变化的范围及规律.  相似文献   

8.
一种新型平板彩色显示器件的制备和光谱分析   总被引:1,自引:1,他引:0  
以MEH-PPV(聚[2-甲氧基-5-(2'-乙基己氧基-对苯乙烯)])和Alq3作为发光层,成功制备出ITO/SiO2/MEH-PPV/SiO2/Al结构和ITO/SiO2/Alq3/SiO2/Al结构的固态阴极射线器件.通过分析SSCL光谱,认为这些高速电子激发有机材料后形成Frenkel激子.当器件两个电极之间加的电压比较低时,有机薄膜层的场强也比较低,这些激子被解离的概率很小,从而产生的是激子发光的长波发射;当器件两个电极之间加的电压比较高时,有机薄膜层的场强很高,在有机层形成的激子大部分被解离,解离后的电子直接跃迁至LUMO(lowest unoccupancied molecular orbit),这些电子弛豫后从LUMO能级到HOMO(highest occupancied molecular orbit)能级直接辐射跃迁,接着重新复合发光,从而产生短波发射.制作的固态阴极射线器件可以实现全色发光,提高发光效率和加强蓝光发射.作者可以预期所研制出的这种SSCL器件必将引发平板显示领域一场新的革命性变革.  相似文献   

9.
董谦  赵谡玲  徐征  张福俊  李远  宋丹丹  徐叙瑢 《物理学报》2008,57(12):7896-7899
采用有机磷光材料三-(2-苯基吡啶)-铱(Ir(PPY)3)与无机材料SiO2复合制成夹层结构器件,用交流电压驱动获得了Ir(PPY)3主峰位于517nm的发光和主峰位于435nm的蓝色发光.通过分析器件的光谱特性,发现这两个发光峰都是源于SiO2中加速电子直接碰撞激发有机层引起的固态阴极射线发光.继实现多种有机聚合物材料和有机小分子材料八羟基喹啉铝(Alq3)的固体阴极射线发光之后,又证实了有机 关键词: 夹层结构器件 有机磷光材料 固态阴极射线发光  相似文献   

10.
SiO2厚度对类阴极射线发光中电子加速的影响   总被引:1,自引:1,他引:0  
研究了有机 /无机复合结构ITO/SiO2 /MEH PPV/SiO2 /Al器件的类阴极射线发光性质 ,电子经过SiO2层加速后 ,激发MEH PPV层发光。发光除了MEH PPV激子发光峰外 ,还有一个带间复合的能量更高的短波发光峰。通过 2个发光峰随SiO2 层的厚度的变化规律 ,研究了SiO2 对电子的加速能力。  相似文献   

11.
We report calculated values of isotope fractionation factors between chlorine, bromine and sulphide hydrated anions and respective gaseous compounds: hydrogen chloride, hydrogen bromide, molecular chlorine and bromine and hydrogen sulphide. For the calculation of the reduced partition function ratios (β-factors) of hydrated Cl(-), Br(-) and S(2-) anions, we used a model of a cluster composed of the considered ion surrounded by two shells of H(2)O molecules. Only the electrostatic interaction between ion and water molecules treated as electric dipoles was taken into account. The β-factors for the gaseous compounds (HCl, Cl(2), HBr, Br(2) and H(2)S) were calculated from vibrational frequencies reported by Urey and Greiff [Isotopic Exchange Equilibria, J. Am. Chem. Soc. 57, 321 (1935)] and Schauble et al. [Theoretical Estimates Equilibrium Chlorine-Isotope Fractionation, Geochim. Cosmochim. Acta 67, 3267 (2003)]. Low-temperature isotope fractionation between chlorine-hydrated anion and hydrogen chloride attains 1.55-1.68‰ (this work), which is in good agreement with experimental data (1.4-1.8‰) [Z.D. Sharp, J.D. Barnes, T.P. Fischer and M. Halick, An Experimental Determination of Chlorine Isotope Fractionation in Acid Systems and Applications to Volcanic Fumaroles, Geochim. Cosmochim. Acta 74, 264 (2010)]. The predicted isotope fractionations for hydrated bromine and HBr, Br(2) gases are very small, 1000?ln α, do not exceed 0.8‰; thus, the expected variations of bromine isotope composition in aqua-gas systems will require enhanced precision for their detection. In contrast, the sulphur isotope fractionation between H(2)S( gas ) and S(2-) attains 6.0‰ at room temperature and drops nearly linearly to 3.1‰ at 350°C.  相似文献   

12.

An unusual and unexpected synthesis of 3-(2-(arylamino)thiazol-4-yl)-2H-chromen-2-ones has been observed by the reaction of ethyl 2-(chloromethyl)-2-hydroxy-2H-chromene-3-carboxylate with various arylthioureas in ethanol under mild reaction conditions with excellent yields. The ambiguity in the structure of the obtained products has been solved by recording its single-crystal X-ray analysis. This protocol has been found to be a novel approach for the preparation of title compounds via benzopyran ring opening. A systematic plausible mechanism has been proposed for the formation of the product. Also, an efficient one-pot three-component method has been demonstrated for the formation of title compounds starting from salicylaldehyde.

  相似文献   

13.
The reaction of 2/4-pyridine carboxaldehyes with 2-tetralone analogs in the presence of catalytic amounts of Pd/C and trimethylsilyl chloride in DMF resulted in the formation of 1-(pyridin-2/4-ylmethyl)-2-naphthols in moderate to good yields as opposed to the expected 1-(pyridin-2/4-ylmethylene)-2-tetralones. 3-Pyridine carboxaldehyde, however, formed 1-(pyridin-3-ylmethylene)-2-tetralones with 2-tetralone analogs under similar conditions. When representative reactions were repeated in the presence of anhydrous HCl gas in acetic acid, including one with 3-pyridine carboxaldehyde, 1-(pyridinylmethyl)-2-naphthols were the only products obtained with significantly improved yields. A possible mechanism explaining these results is discussed.  相似文献   

14.
采用色谱法从蒲儿根花部位中分离得到2-甲基-6-(2-甲苯基)-2-庚烯,该化合物第一次以单体的形式得到,通过测定氢-氢相关谱(1H-1H COSY)、DEPT谱、异核单量子相关谱(HSQC)及异核多键相关谱(HMBC)等二维谱确定了该化合物的结构,并对该化合物的1H NMR和13C NMR谱进行了归属.  相似文献   

15.
16.
2-(2-喹啉偶氮)-5-二甲氨基苯胺光度法测定铜   总被引:1,自引:0,他引:1  
在pH=4.0的磷酸盐缓冲介质中,CTMAB存在下,2-(2-喹啉偶氮)-5-二甲氨基苯胺(QADMAA)与铜反应生成2:1稳定络合物,络合物λmax=580nm,ε=1.14×105L·mol-1·cm-1.铜含量在0.01-0.6μg/mL内符合比耳定律,方法用于环境样品中铜的测定,结果令人满意.  相似文献   

17.
Mössbauer studies have been made on low-spin octahedral complexes of iron(II) and iron(III) formed with two terdentate ligands, viz., 1-(2-pyridylazo)-2-naphthol and 1-(2-pyridylazo)-2-phenanthrol. The data are suggestive of π-back bonding in the two iron(II) complexes.  相似文献   

18.
19.
Density functional theory (DFT) calculations have been carried out for the compound 4-[2-(tert-butylamino)-1-hydroxyethyl]-2-hydroxymethyl) phenol (4BAHEHMP) by using the B3LYP method at the 6-311++G (d,p) basis set level. The electric dipole moment (μ) and the first hyperpolarizability (α) values of the investigated molecule were computed. Total and partial density of state (TDOS and PDOS) and also overlap population density of state (COOP or OPDOS) diagrams analysis were presented. HOMO and LUMO energies confirm that charge transfer occurs within the molecule. In addition Molecular Electrostatic Potential (MEP), Natural Bond Orbital analysis (NBO) and Non- Linear Optical (NLO) properties are studied.  相似文献   

20.
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