共查询到19条相似文献,搜索用时 234 毫秒
1.
采用溶胶凝胶和表面接枝的方法, 合成了一种新型核壳结构的电流变液材料, 其组成为Li0:1(TixNi1-x)0:9O/聚苯乙烯(x=0.02,0.05).通过透射电镜、X射线衍射和红外光谱分析方法研究了该材料的形貌和结构, 并利用宽频阻抗测量仪、静态电流变测量仪研究了该材料的介电性质和电流变性能, 进而讨论了其结构与电流变性能之间的关系.研究发现,随着Ti含量增加,Li0:1(TixNi1-x)0:9O的介电常数减小,电流变效应减弱,且聚苯乙烯包裹后,介电常数进一步下降,但电流变效应有明显增强.结果表明,利用核、壳两部分各自具有的不同电学和力学性质组合制备得到的核壳结构电流变材料,可具有很高的介电常数,合适的介电损耗以及较小的漏电流密度,其电流变性能可得到明显的提高. 相似文献
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研究了纳米二氧化钛包覆高岭土和钇掺杂钛酸钡两种电流变液的微波反射行为.实验发现,在垂直于微波传播方向电场作用下,两种电流变液微波反射系数均随电场强度的增大而增大;钇掺杂钛酸钡电流变液微波反射系数变化幅度比二氧化钛包覆高岭土电流变液宽,并且电场调节的能力随浓度的增加有减弱的趋势.对钇掺杂钛酸钡电流变液存在一个临界浓度,低于这个浓度,电场的调控能力随电场强度的增加而增大,高于这个浓度,电场的调控能力随电场的增加先增大后减小.另外,二氧化钛包覆高岭土电流变液反射回波相位随电场强度的增大出现最大值后逐渐减小趋于平
关键词:
电流变液
微波反射
相位 相似文献
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理论计算表明,介质包覆导体颗粒用作电流变液的分散相,可以获得高剪切应力的电流变液.采用溶胶-凝胶技术在尺度为5—10μm的石墨颗粒表面成功地包覆了TiO2,获得了金红石相TiO2包覆石墨的复合颗粒.配制成复合颗粒/硅油电流变液,其剪切应力与纯TiO2/硅油电流变液相比,可提高一个数量级.当电场强度为1.7kV/mm时,复合颗粒/硅油电流变液的剪切应力可达1.25kPa,电流密度小于10μA/cm2.
关键词:
电流变液
包覆
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石墨 相似文献
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具有核/壳结构的磁性复合纳米材料是十分重要的功能材料,其综合物性受材料微结构的影响,而这很大程度上又取决于复合体系的可控合成.本文综述了近二十年来有关核/壳磁性复合纳米材料的制备、表征及性能研究方面的进展,讨论的体系主要有:铁氧体基永磁/软磁(反铁磁)复合纳米材料、非磁性体包覆磁性核而成的复合纳米材料、用磁性颗粒催化合成的碳基复合纳米材料、基于交换偏置效应而设计的复合纳米材料、核-壳同轴结构的一维复合纳米材料和核/壳/壳三元结构的磁性复合纳米材料等.构建复合体系的组分包括M型永磁铁氧体、3d过渡金属(及其合金、氧化物、碳化物)、多铁化合物、非磁性体(比如绝缘体、半导体、有机分子)和碳材料等,着重分析了复合纳米材料的热稳定性、光致发光性能、光电催化能力、电化学特性、微波吸收性能、磁电阻效应、永磁体性能、高频软磁特性、交换偏置效应及其相关现象.最后,对核/壳结构磁性复合纳米材料的未来发展趋势进行了展望,并在基础研究和改性应用方面提出了一些建议. 相似文献
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本文用复合粒子表象理论对31Si核进行研究计算, 求出了31Si核的能谱和波函数. 能谱与壳模型能谱完全一致, 波函数与壳模型波函数严格等价, 因而有力地支持了复合粒子表象理论. 相似文献
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用推广的裂变扩散模型研究了裂变前壳效应对粒子发射的影响.双幻核208Pb和132Sn被用作例子来展示这个壳效应.计算结果表明壳效应对这两个复合系统断前发射的粒子有影响.对中子,壳的影响非常明显.我们发现壳对中子发射的影响随着裂变系统激发能的增加而逐渐变弱. 相似文献
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制备了二氧化钛前驱体粉体, 它具有优良的巨电流变效应, 但不含一水草酸钙的成分. 通过X射线衍射谱、扫描电子显微镜、电感耦合等离子体光谱仪和热失重-质谱联用仪等一系列实验手段, 对二氧化钛前驱体粉体进行了表征, 发现它是非晶形态的纳米粉体, 其主要成分为TiOC2O4·2H2O和TiO(OH)2. 由二氧化钛前驱体配置的电流变液具有与钛酸钙前驱体电流变液类似的温度特征, 即 当处理温度超过160℃后, 电流变液的屈服强度会逐渐降低, 至200℃后, 巨电流变效应完全消失. 通过对比分析发现, 伴随上述巨电流变效应消失过程的化学反应是TiOC2O4·2H2O 在加热过程中失去了结晶水. 这些特征在所有钛酸盐系列的电流变液中均可观察到, 因此我们推断TiOC2O4·2H2O是钛酸盐系列巨电流变液中的关键物质.
关键词:
电流变液
钛酸盐
极性分子 相似文献
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Surface modification of M-Ba-ferrite powders by polyaniline: Towards improving microwave electromagnetic response 总被引:1,自引:0,他引:1
A composite of polyaniline (PANI)-coated M-type hexagonal barium ferrite (M-Ba-ferrite) powder was prepared by an in situ polymerization of an aniline monomer in the presence of M-Ba-ferrite particles. The obtained composite was characterized by Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The structure and microwave response properties were investigated. The continuous coverage of polyaniline has been produced on the platelet M-Ba-ferrite particle surface, and a core–shell structure has been formed. The results show that the coverage of polyaniline has a great influence on microwave response of M-Ba-ferrite particles. A polyaniline thin layer formed on the surface of a barium ferrite particle changes the character of frequency dispersion of microwave absorption. The results indicate the existence of an interaction at the interface of polyaniline macromolecule and barium ferrite particle, which influences the physical and chemical properties of the composite. The interaction and interfacial polarization are seen as important factors contributing to the influence on microwave response of the PANI-coated ferrite composite powders. 相似文献
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Myakin S. V. Bubis N. A. Kuznetsov L. M. Zhukov M. V. Shmykov A. Yu. 《Physics of the Solid State》2022,64(3):157-160
Physics of the Solid State - A number of composites based on oligomeric diisocyanate with different content of submicrometer particles of ferroelectric filler barium titanate (BaTiO3) are... 相似文献
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《Current Applied Physics》2007,7(4):352-355
A conducting polyaniline (PANI) was synthesized via an oxidative dispersion polymerization technique, using poly(vinyl alcohol) (PVA) as a polymeric stabilizer, in the presence of multi-walled carbon nanotubes (MWNT) purified in acidic solution, and dispersion stability of the MWNT in an aqueous solution of PVA was studied for different PVA concentrations. Their morphology was confirmed by a scanning electron microscope. Its electrorheological (ER) characteristics were also investigated by dispersing the PANI/MWNT composite particles in an insulating silicone oil. Its ER properties were examined using a rotational rheometer under varying applied DC electric field strengths, in which the ER fluid is generally composed of a suspension of conducting particles dispersed in an insulating fluid, which shows a rapid and reversible change in shear viscosity with an applied electric field. Synthesized PANI/MWNT composite particles are observed to enhance interparticular interactions, since the degree of polarization of PANI/MWNT composite particle increases with applied electric field strengths. The shear stresses of the PANI/MWNT nanocomposite based ER fluid increase with the electric field strength for a broad range of shear rates. 相似文献
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Cheng Hai Hong 《Journal of Macromolecular Science: Physics》2013,52(4):683-692
We synthesized phosphoric acid (PA) doped polyaniline (PANI) particles (PANI‐PA) and investigated their electrorheological (ER) and dielectric characteristics when they were dispersed in silicone oil. Flow curves of the PANI‐PA based ER fluid under several applied electric field strengths were analyzed using a shear stress model. We also examined ER characteristics based on the relaxation time obtained from the dielectric spectrum. 相似文献
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以醋酸钡和钛酸四丁酯为原料,采用溶胶-凝胶法合成了纳米BaTiO3粉体;运用差示/热重、X射线衍射及透射电镜对前驱体凝胶和产物进行了表征,并根据XRD结果,研究了纳米BaTiO3的晶格常数、晶格畸变度和晶粒尺寸随焙烧温度及时间的变化。结果表明,焙烧温度与时间对纳米BaTiO3晶格常数的影响不明显;随焙烧温度或时间的延长,纳米BaTiO3的晶格畸变度减小,晶粒尺寸增大,但晶格畸变度和晶粒尺寸更敏感于焙烧温度. 基于扩散控制机理的传统模型探讨了焙烧过程纳米BaTiO3晶粒生长动力学,得出其晶粒生长指数为7,晶粒生长活化能为75.49 kJ/mol. 将基于扩散与反应共同控制机理的新型等温模型应用于本研究中,结果表明,新型等温模型更能真实地反映纳米BaTiO3焙烧过程中的晶粒生长行为,说明纳米BaTiO3晶粒生长过程同时受溶质扩散和表面反应控制,其藕合晶粒生长活化能为27.23 kJ/mol. 相似文献
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Nanocrystalline BaTiO3 particles modified with polarizable ligands were synthesized through hydrolysis of modified metal–organics below 100°C. BaTiO3 precursor was synthesized from barium metal, titanium isopropoxide and polarizable ligands in a mixture of ethanol and 2-ethoxyethanol.
The modified Ba–Ti complex alkoxide was hydrolyzed yielding BaTiO3 particles modified with organics. The crystallinty of nanometer-sized particles was dependent upon the hydrolysis conditions,
and increased with increasing water amount and time. The nanocrystalline particles were identified to be BaTiO3 by X-ray diffraction (XRD) and electron diffraction. A fluid consisting of modified BaTiO3 particles and silicone oil revealed a typical electrorheological (ER) behavior on applying DC field. The ER behavior was
found to depend upon the kind of ligand. 4-Fluorobenzyloxy modifier revealed the highest yield stress in the ER measurement
among 4-substitued benzyloxy ligands examined. 相似文献
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The production method of the elastic composite containing ferrous particles and titanium barium particles dispersed in the porous silicone matrix is described in this article. Since it contains ferrous and titanium barium particles, this composite shows magnetorheological and also electrorheological properties. The electrostriction of composite samples in the electric field with maximal intensity 1.5×106 V/m was investigated. The magnetostriction in the magnetic field with maximal induction 1 T was also investigated. It was found that samples elongate with increased electric field intensity, and the magnetic field induction was detected. By increasing the samples’ elongation with increase of ferrous particles, titanium barium particles and pores number were also detected. In the investigated division of the electric and magnetic field the elongation changed in a linear way. The maximal elongation achieved was 1.59%. 相似文献
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Preparation and Characterization of Nano-structured Ceramic Powders Synthesized by Emulsion Combustion Method 总被引:7,自引:0,他引:7
Takatori Kazumasa Tani Takao Watanabe Naoyoshi Kamiya Nobuo 《Journal of nanoparticle research》1999,1(2):197-204
The emulsion combustion method (ECM), a novel powder production process, was originally developed to synthesize nano-structured metal-oxide powders. Metal ions in the aqueous droplets were rapidly oxidized by the combustion of the surrounding flammable liquid. The ECM achieved a small reaction field and a short reaction period to fabricate the submicron-sized hollow ceramic particles with extremely thin wall and chemically homogeneous ceramic powder. Alumina, zirconia, zirconia–ceria solid solutions and barium titanate were synthesized by the ECM process. Alumina and zirconia powders were characterized to be metastable in crystalline phase and hollow structure. The wall thickness of alumina was about 10nm. The zirconia–ceria powders were found to be single-phase solid solutions for a wide composition range. These powders were characterized as equiaxed-shape, submicron-sized chemically homogeneous materials. The powder formation mechanism was investigated through the synthesis of barium titanate powder with different metal sources. 相似文献