转动传能量子干涉效应:干涉角影响因素的研究

碰撞转动传能中存在量子干涉效应已经在静态池实验中被观测到,并且积分角也能被测量.利用分子束实验可得到转动传能更准确的信息,进而得到影响干涉角的的具体因素.文中利用一阶含时波恩近似和L-J相互作用势,建立了原子—双原子分子碰撞系统转动传能的量子干涉模型,描述了观察和测量微分干涉角的方法,得到了微分干涉角与碰撞半径和碰撞速度间的关系,同时也得到了积分干涉角和实验温度的关系.此理论模型对于理解和进行分子束实验是非常重要的.     

原子-双原子分子体系碰撞诱导中的量子干涉效应

碰撞转动传能中存在量子干涉效应已经在静态池实验中被观测到,并且积分角也能被测量.但静态池掩盖了大量的实验信息,利用分子束实验可得到转动传能更准确的信息,进而得到影响干涉角的的具体因素.文中运用含时微扰的一级波恩近似理论和各向异性相互作用势,建立了原子-双原子分子(混合态)体系碰撞诱导转动能量传递中的量子干涉效应的理论模型,描述了观察和测量微分干涉角的方法,得到了微分干涉角与碰撞半径和碰撞速度间的关系,同时也得到了实验温度对微分干涉角的影响.此理论模型对于理解和进行分子束实验是非常重要的.     

原子-双原子分子体系碰撞诱导中的量子干涉效应（第十五届全国原子与分子物理学术会议会议论文）

碰撞转动传能中存在量子干涉效应已经在静态池实验中被观测到,并且积分角也能被测量。但静态池掩盖了大量的实验信息,利用分子束实验可得到转动传能更准确的信息,进而得到影响干涉角的的具体因素。文中运用含时微扰的一级波恩近似理论和各向异性相互作用势,建立了原子-双原子分子（混合态）体系碰撞诱导转动能量传递中的量子干涉效应的理论模型,描述了观察和测量微分干涉角的方法,得到了微分干涉角与碰撞半径和碰撞速度间的关系,同时也得到了实验温度对微分干涉角的影响。此理论模型对于理解和进行分子束实验是非常重要的.     

NaH– He碰撞系统转动传能量子干涉效应的研究

为了进一步理解原子双原子系统碰撞转动传能中的量子干涉效应,本文对NaH —He碰撞系统进行了理论计算。本文利用一阶含时波恩近似和L-J相互作用势,建立了原子-双原子分子碰撞系统转动传能的量子干涉模型,通过本文理论可得出影响碰撞系统积分干涉角的因素,同时也得到了积分干涉角和转动量子数间的关系。此理论模型对于理解和进行分子束实验是非常重要的。     

NaH (b3Π～A1∑+)-He碰撞系统转动传能量子干涉效应的研究

为了进一步理解原子双原子系统碰撞转动传能中的量子干涉效应,本文对NaH(b3Π～A1∑+)-He碰撞系统进行了理论计算.本文利用一阶含时波恩近似和L-J相互作用势,建立了原子-双原子分子碰撞系统转动传能的量子干涉模型.通过本文理论可得出影响碰撞系统积分干涉角的因素,同时也得到了积分干涉角和转动量子数间的关系.此理论模型对于理解和进行分子束实验是非常重要的.     

量子干涉效应中干涉角和散射角的研究

利用波恩近似理论对双原子激发态转动传能进行了剖析,更深入的研究了原子分子碰撞过程中量子干涉效应相关信息.利用各项异性相互作用势和直线轨迹近似建立了新的量子干涉模型,讨论了原子与双原子分子碰撞时散射角和微分干涉角的关系,得到了干涉角和各向异性参数及转动量子数的关系.     

碰撞转动传能的量子干涉效应中微分干涉角的研究

转动传能的量子干涉效应在静态池实验中发现,并且已测得积分干涉角.为了得到更多关于传能的准确信息,应利用分子束进行实验.本文基于一阶含时波恩近似,模拟了利用分子束实验进行量子干涉效应研究的理论模型.此模型采用了Lennard-Jones相互作用势和直线轨道近似.通过本文建立的模型,研究了影响干涉效应的微分干涉角的因素,并且得到了徽分干涉角和碰撞速度、碰撞参数及碰撞体的关系.此理论模型对于指导分子束实验具有重要的意义.     

量子干涉效应中干涉角和散射角的研究

利用波恩近似理论对双原子激发态转动传能进行了剖析,更深入的研究了原子分子碰撞过程中量子干涉效应相关信息．利用各项异性相互作用势和直线轨迹近似建立了新的量子干涉模型,讨论了原子与分子碰撞时散射角和微分干涉角的关系,得到了干涉角和各向异性参数及转动量子数的关系．     

碰撞转动传能的量子干涉效应中微分干涉角的研究

转动传能的量子干涉效应在静态池实验中发现,并且已测得积分干涉角．为了得到更多关于穿能的准确信息,应利用分之束进行实验．本文基于一阶含时波恩近似,模拟了利用分子束实验进行量子干涉效应研究的理论模型．此模型采用了Lennard-Jones 相互作用势和直线轨道近似．通过本文建立的模型,研究了影响干涉效应的微分干涉角的因素,并且得到了微分干涉角和碰撞速度、碰撞参数及碰撞伴间的关系．此理论模型对于对于指导分子束实验具有重要的意义．     

转动传能中的量子干涉--干涉角和转动量子数的关系

沙国河等人在CO(A1∏(v=0)~e3∑-(v=1))体系与He,Ne和Ar碰撞诱导转动传能中首次观测到了量子干涉效应,并测量了干涉度。从理论上进一步研究原子-双原子分子体系碰撞诱导转动传能中量子干涉效应与转动量子数以及能量间隔的关系是十分必要的。我们考虑长程相互作用势,应用一级玻恩近似和直线轨迹近似,分别计算了CO(A1∏(v=0)~e3∑-(v=1))体系和He,Ne,Ar碰撞诱导转动传能中不同转动量子数以及不同能量间隔下的干涉角,得到了干涉角随转动量子数和能量间隔的变化趋势。这些结果对设计、分析这种类型的实验有一定的指导意义。     

Collisional quantum interference on rotational energy transfer： physical interpretation of the differential interference angle

Collisional quantum interference （CQI） on the intramolecular rotational energy transfer is observed in an experiment with a static cell, and the integral interference angles are measured. To obtain more accurate information, an experiment with a molecular beam is carried out, and thereby the relationship between the differential interference angle and the scattering angle is obtained. Based on the first-Born approximation of time-dependent perturbation theory, the theoretical model of CQI is developed in an atom-diatom system in the condition of the molecular beam, with the long-range interaction potential taken into account. The method of measuring correctly the differential interference angle is presented. The tendencies of the differential interference angle changing with the impact parameter and rel- ative velocity are discussed. The theoretical model presented here is important for understanding or performing the experiment in the molecular beam.     

Relationship Between Differential Interference Angle and Parameter of Experiment in Molecular Beam

Collisional quantum interference (CQI) was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise information, the experiment in the molecular beam should be taken, from which the relationship between the differential interference angle and the scattering angle can be obtained. In this paper, the theoretical model of CQI is described in an atom-diatom system in the condition of the molecular beam, based on the first-Born approximation of time-dependent perturbation theory, taking into accounts the long-range interaction potential. The method of observing and measuring correctly the differential interference angle is presented. The changing tendency of the differential interference angle with the impact parameter and relative velocity is discussed. The changing tendencies of the differential interference angle with the parameter of experiment in the molecular beam, including the impact parameter and the velocity are discussed. This theoretical model is important to understand or perform the experiment in the molecular beam.     

Relationship Between Differential Interference Angle and Parameter of Experiment in Molecular Beam

Collisional quantum interference （CQI） was observed in the intramolecular rotational energy transfer in the experiment of the static cell, and the integral interference angles were measured. To observe more precise information, the experiment in the molecular beam should be taken,from which the relationship between the differential interference angle and the scattering angle can be obtained. In this paper, the theoretical model of CQI is described in an atom-diatom system in the condition of the molecular beam, based on the first-Born approximation of time-dependent perturbation theory, taking into accounts the long-range interaction potential. The method of observing and measuring correctly the differential interference angle is presented. The changing tendency of the differential interference angle with the impact parameter and relative velocity is discussed. The changing tendencies of the differential interference angle with the parameter of experiment in the molecular beam, including the impact parameter and the velocity are discussed. This theoretical model is important to understand or perform the experiment in the molecular beam.     

The differential interference angle in collisional quantum interference on rotational energy transfer

Collisional quantum interference （CQI） in the intramolecular rotational energy transfer was observed in experiment by Sha and co-workers. The interference angle, which measuring the degree of the coherence, were measured in the experiment of the static cell. Based on the first Born approximation of time dependent perturbation theory, taking into accounts the anisotropic Lennard-Jones interaction potentials, this paper describes the theoretical model of CQI in intramolecular rotational energy transfer in an atom-diatom collision system. In the model, the differential interference angle for the experiment of the molecular beam is calculated, the changing tendencies of the differential interference angle with the impact parameter and collision partners are obtained. This theoretical model is important for understanding or performing this kind of experiments.     

The differential interference angle of ^2∏[Case（a）] diatom on rotational energy transfer in NO（X^2∏） collision with He,Ne and Ar system

To study theoretically the relationship between the differential interference angle and the scattering angle in collisional quantum interference （CQI）, we have investigated the differential interference angle of the atom-diatomic [case（a）] molecule system in detail. For the 2∏ electronic state in Hund＇s case （a）, the degree of the differential interference is also discussed. The differential interference angles of NO（X^2∏） are calculated quantitatively for the rotational energy transfer in Hund＇s case （a） induced by collision with He, Ne and Ar atoms. The method to calculate the differential interference angle is presented. Several factors that affect the differential interference angle are investigated. Finally the variation of the differential interference angle with the impact parameter and relative velocity is discussed.     

Na2(A1∑u+,v=8～b3Ⅱ0u,v=14)-Na体系转动传能的碰撞量子干涉效应

沙国河及其工作组于1995年发表了CO A1Π(v=0)～e3∑-(v=1)与He1,Ne及其它碰撞伴的碰撞过程中转动传能的碰撞量子干涉现象,并得到了积分干涉角,陈等从理论和实验上发现了Na2(A1∑u ,v=8～b3Π0u,v=14)体系与Na(3s)碰撞的碰撞量子干涉现象,孙等计算了其积分干涉角,但是对微分干涉角没有过多的计算.本文作为对原子-双原子体系碰撞诱导转动传能的进一步理论研究,在含时一级波恩近似的基础上考虑各向异性相互作用势和长程相互作用势,计算了单叁混合态的Na2(A1∑u ,v=8-bΠ0u,v=14)体系与Na碰撞的微分干涉角,并得到了微分干涉角与碰撞参数的关系,此理论模型对理解和进行分子束实验是非常重要的.     

基于激光自混合干涉的物体旋转中心确定方法

在被测物体上设置一低反射率反射镜,激光器输出的激光束入射到反射镜上,激光束经反射镜反射反馈回激光器内.入射光线若偏离被测物体的旋转中心,当被测物体旋转时,将引起激光器的输出功率随角度变化的自混合干涉信号.当入射光线通过被侧物体的旋转中心时,被测物体的角度变化将不会导致回馈光的光程变化,被侧物体旋转时也就观测不到自混合干...     

Interference Angle on Quantum Rotational Energy Transfer in Na+Na2 (A1 Σ+u,v=8∽ b3 Π0u,v=14) Molecular Collision System

In order to study the collisional quantum interference (CQI) on rotational energy transfer in atom-diatom system, we have studied the relation of the integral interference angle and differential interference angle in Na+Na₂ (A¹Σ^+_u, v=8∽b³Π_0u, v=14) collision system. In this paper, based on the first-Born approximation of time-dependent perturbation theory and takinginto accounts the anisotropic effect of Lennard-Jones interaction potentials,we present a theoretical model of collisional quantum interference inintramolecular rotational energy transfer, and a relationship betweendifferential and integral interference angles.