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MPCVD金刚石的Raman光谱分析 总被引:3,自引:1,他引:2
用微波等离子体化学气相淀积法(MPCVD)在Si基片上生长了金刚石薄膜,通过对其进行Raman光谱分析,一次表征了金刚石的结构,纯度及应力状况等材料性能,同时并研究了生长过程中微波功率与金刚石性质的关系。研究表明,微波等离子体化学气相溶积法生长的金刚石薄膜,除了金刚石成分的生长外,还会有部分非金刚石成分的生长,金刚石的纯度与微波功率的关系不明显,另外此种方法生长的金刚石薄膜主要表现为张应力。 相似文献
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采用蒙特卡罗方法模拟了电子辅助化学气相淀积(EACVD)金刚石薄膜中的氢分解过程,建立了电子碰撞使氢分解的模型,给出了电子能量分布及氢原子数的空间分布,讨论了电偏压和气压对氢分解的影响。这些结果对EACVD制造金刚石薄膜的研究有重要意义。 相似文献
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本文叙述了电子回旋共振微波等离子体化学气相沉积(ECRPCVD)的工作原理、特点及其应用.ECRPCV D由放电室、淀积室、微波系统、磁场线圈、气路与真空系统组成.处于放电室的等离子体在磁场中做回旋运动,使电子的回旋运动频率与微波频率相同;处于回旋共振条件下的电子有效地吸收微波功率而获得高的能量,从而产生高活性和高密度的等离子体.电离度大于10%,电子密度为1013cm3.ECRPCVD可在低的气体流量、衬底不加热的情况下高速淀积高质量薄膜.以该技术淀积的Si,N4,SiO2薄膜可分别与高温CVD的Si3N4高温热氧化的SiO2相比拟.ECRPCVD淀积a-Si:H淀积速率为通常CVD的20倍,而性能与射频CVD淀积的a-Si:H相当.ECRPCVD 已成功用于淀积多种薄膜。 相似文献
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富勒烯作为过渡层生长金刚石薄膜研究 总被引:1,自引:0,他引:1
采用微波等离子体化学气相淀积法,以C60膜过渡层,在光滑的单晶Si衬底(100)表面的研磨的石英衬底表面等光学衬底上,首次在无衬底负偏压条件下生长出多晶金刚石薄膜,通过扫描电镜观察到生长膜晶粒呈莱花状,生长表面为金刚石(100)界面。 相似文献
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Xin-Lu Lin 《中国物理 B》2022,31(10):108802-108802
Since a hole barrier was formed in back contact due to mismatch of work function, the back contact material for CdTe cell has been a significant research direction. The ZnTe:Cu is an ideal back contact material, which reduces the valence band discontinuity and can be used as the electron back reflection layer to inhibit interface recombination. The conductivity of ZnTe:Cu film is improved by applying RF-coupled DC sputtering and post-deposition heat treatment. The doping efficiency is computed as the ratio of free hole density and copper concentration, which can be correlated with performance for CdTe-based solar cell. The higher doping efficiency means that more copper atoms substitute for Zn sites in ZnTe lattices and less mobilized copper atoms remain which can enter into the CdTe absorber layer. Copper atoms are suspected as dominant element for CdTe-based cell degradation. After optimizing the ZnTe:Cu films, a systematic study is carried out to incorporate ZnTe:Cu film into CdTe solar cell. The EQE spectrum is kept relatively stable over the long wavelength range without decreasing. It is proved that the conduction band barrier of device with ZnTe:Cu/Au contact material has an effect on the EQE response, which works as free electron barrier and reduces the recombination rate of free carrier. According to the dark J—V data or the light J—V data in the linear region, the current indicates that the intercept gives the diode reverse saturation current. The results of ideality factor indicate that the dominant recombination occurs in the space charge region. In addition, the space charge density and depletion width of solar cell can be estimated by C—V profiling. 相似文献
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In this study, we present an effective method of improving the performance of pure sulfide Cu(InGa)S2 (CIGS) solar cells via injection annealing system. The injection annealing system can perform annealing at desired temperatures, and therefore, the CIGS thin film passed over the temperature range in which secondary phases occurs. Via the injection annealing system, secondary phase InSx was effectively removed from the surface of the CIGS thin films at the temperatures over 550°C. This resulted in the formation of good-quality P–N junction CIGS devices, thereby improving significantly the performance of the CIGS solar cell. In addition, the open-circuit-voltage (VOC) and fill factor (FF) of the CIGS devices increased gradually with increasing annealing temperature in the range of 550–640°C. It is speculated that the bulk defects were decreased as the annealing temperature increased. Finally, via injection annealing system, a pure sulfide CIGS solar cell with an efficiency of 12.16% was achieved. 相似文献
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在太阳能电池效率的评价中,电池材料、掺杂浓度、扩散长度等都是比较重要的参数,合理地改变相关参数可以优化太阳能电池的性能,提高电池效率。此外,在太阳能电池表面镀一层具有减反作用的光学薄膜(简称减反膜)也是提高电池效率的重要手段。以提高电池效率为目标,对单晶硅太阳能电池的掺杂浓度和扩散长度等微观参数进行计算优化,分析了掺杂浓度和扩散长度变化对电池效率的影响。并在此基础上分析了不同类型的减反膜对于电池效率的影响,给出了最佳减反膜材料及其膜系厚度,并且结合镀膜后电池量子效率的变化验证了其准确性。结果表明,在优化电池掺杂浓度和扩散长度的基础上,选择合适的减反膜,电池效率最高可达20.35%,相比于优化前提高了8.25%。 相似文献
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Meng Yuan Ning Zhou Dongsheng Li Deren Yang 《Applied Physics A: Materials Science & Processing》2014,117(2):573-577
Broadband light absorption enhancement in crystalline silicon thin-film solar cells by rear-located 400 nm lumpy silver particles has been studied, based on the theoretical simulations of 3D finite-difference time-domain method. By simulations, we have investigated the light scattering properties of 400 nm lumpy Ag particles and put it to silicon thin-film solar cells. In addition, the varying rear-located Ag particles coverage and two surface situations of silicon films, which could influence on the light absorption of solar devices, have also been comprehensively considered. The results have shown that rear-located 400 nm lumpy Ag particles would enhance the absorption in silicon films in a broadband range. And it has been proved that 20 % coverage density of rear-located Ag particles is optimal for improving the light absorption of smooth silicon thin-film solar devices. When we create rough surface on one or both sides of silicon films, the absorbed light would further increase, and the theoretical maximum enhancement is 15.1 % compared with the smooth silicon thin-film solar cell without Ag particles. 相似文献
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Nanoimprint texturing of transparent flexible substrates for improved light management in thin‐film solar cells 下载免费PDF全文
Karen Wilken Ulrich W. Paetzold Matthias Meier Nicole Prager Matthias Fahland Friedhelm Finger Vladimir Smirnov 《固体物理学:研究快报》2015,9(4):215-219
We present a nanoimprint based approach to achieve efficient light management for solar cells on low temperature transparent polymer films. These films are particularly low‐priced, though sensitive to temperature, and therefore limiting the range of deposition temperatures of subsequent solar cell layers. By using nanoimprint technology, we successfully replicated optimized light trapping textures of etched high temperature ZnO:Al on a low temperature PET film without deterioration of optical properties of the substrate. The imprint‐textured PET substrates show excellent light scattering properties and lead to significantly improved incoupling and trapping of light in the solar cell, resulting in a current density of 12.9 mA/cm2, similar to that on a glass substrate. An overall efficiency of 6.9% was achieved for a flexible thin‐film silicon solar cell on low cost PET substrate. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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Crystalline Si thin-film solar cells: a review 总被引:3,自引:0,他引:3
R.B. Bergmann 《Applied Physics A: Materials Science & Processing》1999,69(2):187-194
The present review summarizes the results of research efforts in the field of crystalline silicon thin-film solar cells on
foreign substrates. The large number of competing approaches can be broadly classified according to the grain size of the
crystalline Si films and the doping of the crystalline absorber. Currently, solar cells based on microcrystalline Si films
on glass with an intrinsic or moderately doped absorber film achieve efficiencies around 10%, whereas thin-film cells fabricated
from large-grained polycrystalline Si on high-temperature-resistant substrates have efficiencies in the range of 15%. The
paper discusses the limitations of various approaches and describes recent developments in the area of thin, monocrystalline
Si films that may open the way towards 20% efficient thin-film Si solar cells.
Received: 1 March 1999 / Accepted: 28 March 1999 / Published online: 24 June 1999 相似文献
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Hongliang Wang Fernando Lusquiños Y. Lawrence Yao 《Applied Physics A: Materials Science & Processing》2012,107(2):307-320
Hydrogenated amorphous silicon (a-Si:H) thin films have been considered for use in solar cell applications because of their
significantly reduced cost compared to crystalline bulk silicon. However, their overall efficiency and stability are lower
than that of their bulk crystalline counterpart. Limited work has been performed on simultaneously solving the efficiency
and stability issues of a-Si:H. Previous work has shown that surface texturing and crystallization on a-Si:H thin film can
be achieved through a single-step laser processing, which can potentially alleviate the disadvantages of a-Si:H in solar cell
applications. In this study, hydrogenated and dehydrogenated amorphous silicon thin films deposited on glass substrates were
irradiated by KrF excimer laser pulses and the effect of hydrogen on surface morphologies and microstructures is discussed.
Sharp spikes are focused only on hydrogenated films, and the large-grained and fine-grained regions caused by two crystallization
processes are also induced by presence of hydrogen. Enhanced light absorptance is observed due to light trapping based on
surface geometry changes of a-Si:H films, while the formation of a mixture of nanocrystalline silicon and original amorphous
silicon after crystallization suggests that the overall material stability can potentially improve. The relationship between
crystallinity, fluence and number of pulses is also investigated. Furthermore, a step-by-step crystallization process is introduced
to prevent the hydrogen from diffusing out in order to reduce the defect density, and the relationship between residue hydrogen
concentration, fluence and step width is discussed. Finally, the combined effects show that the single-step process of surface
texturing and step-by-step crystallization induced by excimer laser processing are promising for a-Si:H thin-film solar cell
applications. 相似文献
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The present paper reports the preparation of a solar cell which has a cross-sectional scheme: ITO/CdS/PbS, containing a commercially transparent conductive ITO; chemically deposited n-type CdS (340 nm) and absorbed layer of p-type PbS (1400 nm). The structural and optical properties of the constituent films are presented. X-ray diffraction showed that all of the thin films are polycrystalline. Using scanning electron microscopy, the present study revealed that the films have uniform surface morphology over the substrate. The solar cell was characterized by determining the open circuit voltage, short-circuit current density, and J–V under 40 mW/cm2 solar radiation. The efficiency of the solar cells was 1.35%, which is much higher (0.041, 0.5 and 0.1–0.4%) and slightly smaller (1.65%) than some solar cells reported in the literature. 相似文献
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A giant photovoltaic effect was revealed in silicon-type photoelectronic converters (solar cells) coated with specific antireflecting
films developed by our research group. More specifically, it was found that the ratio of photoconversion efficiency for a
solar cell with such an antireflective film on its surface to the efficiency for a solar cell without the film equals a second
power of relation of photoelectromotive force of a converter with the film to the photoelectromotive force of a converter
without the film. The film comprises an antireflecting coating that is high-efficient in the wavelength range of 450 to 1000
nm and that is synthesized on the basis of novel nanomaterials that provide the quasi-zero average complex refractive index
of nanocomposite film. 相似文献
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CdTe/CdS heterojunction solar cell structure has been fabricated using simple, easy and low-cost methods. To fabricate this structure, CdS and CdTe thin films are deposited onto FTO-coated conducting glass substrates by chemical bath deposition (CBD) and electrodeposition method, respectively. The optimized growth conditions are chosen for both CdS and CdTe films by investigating the optical, structural and morphological properties of both the as-deposited and annealed films. Optical measurement showed that CdS films have higher transmittance and lower absorbance, and CdTe films have lower transmittance and higher absorbance in the near infrared region. The band gap of CdS films is estimated to lie in the range 2.29–2.41 eV and that of CdTe films is in the range 1.53–1.55 eV. X-ray diffraction (XRD) study reveals that CdS and CdTe films are polycrystalline with preferential orientation of (1 1 1) plane. Scanning electron microscopy (SEM) study reveals that both films are smooth, void-free and uniformly distributed over the surface of the substrate. Fabricated CdTe/CdS structure showed the anticipated rectifying behaviour, and the rectifying behaviour is observed to improve due to CdCl2 treatment. 相似文献