Competition between Kondo and RKKY correlations in the presence of strong randomness

We propose that competition between Kondo and magnetic correlations results in a novel universality class for heavy fermion quantum criticality in the presence of strong randomness. Starting from an Anderson lattice model with disorder, we derive an effective local field theory in the dynamical mean-field theory approximation, where randomness is introduced into both hybridization and Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions. Performing the saddle-point analysis in the U(1) slave-boson representation, we reveal its phase diagram which shows a quantum phase transition from a spin liquid state to a local Fermi liquid phase. In contrast with the clean limit case of the Anderson lattice model, the effective hybridization given by holon condensation turns out to vanish, resulting from the zero mean value of the hybridization coupling constant. However, we show that the holon density becomes finite when the variance of the hybridization is sufficiently larger than that of the RKKY coupling, giving rise to the Kondo effect. On the other hand, when the variance of the hybridization becomes smaller than that of the RKKY coupling, the Kondo effect disappears, resulting in a fully symmetric paramagnetic state, adiabatically connected to the spin liquid state of the disordered Heisenberg model. We investigate the quantum critical point beyond the mean-field approximation. Introducing quantum corrections fully self-consistently in the non-crossing approximation, we prove that the local charge susceptibility has exactly the same critical exponent as the local spin susceptibility, suggesting an enhanced symmetry at the local quantum critical point. This leads us to propose novel duality between the Kondo singlet phase and the critical local moment state beyond the Landau-Ginzburg-Wilson paradigm. The Landau-Ginzburg-Wilson forbidden duality serves the mechanism of electron fractionalization in critical impurity dynamics, where such fractionalized excitations are identified with topological excitations.     

Kondo breakdown as a selective Mott transition in the Anderson lattice

We show within the slave-boson technique that the Anderson lattice model exhibits a Kondo breakdown quantum critical point where the hybridization goes to zero at zero temperature. At this fixed point, the f electrons experience as well a selective Mott transition separating a local-moment phase from a Kondo-screened phase. The presence of a multiscale quantum critical point in the Anderson lattice in the absence of magnetism is discussed in the context of heavy fermion compounds. This study is the first evidence for a selective Mott transition in the Anderson lattice.     

Understanding the heavy fermion phenomenology from a microscopic model

We solve the 3D periodic Anderson model using a two impurity cluster dynamical mean field theory. We obtain the temperature versus hybridization phase diagram. Approaching the quantum critical point (QCP) both the Néel and lattice Kondo temperatures decrease and they do not cross at the lowest temperature we reached. While strong ferromagnetic spin fluctuation on the Kondo side is observed, our result suggests the critical static spin susceptibility is local in space at the QCP. We observe in the crossover region a logarithmic temperature dependence in the specific heat coefficient and spin susceptibility.     

Random field effects in field-driven quantum critical points

We investigate the role of disorder for field-driven quantum phase transitions of metallic antiferromagnets. For systems with sufficiently low symmetry, the combination of a uniform external field and non-magnetic impurities leads effectively to a random magnetic field which strongly modifies the behavior close to the critical point. Using perturbative renormalization group, we investigate in which regime of the phase diagram the disorder affects critical properties. In heavy fermion systems where even weak disorder can lead to strong fluctuations of the local Kondo temperature, the random field effects are especially pronounced. We study possible manifestation of random field effects in experiments and discuss in this light neutron scattering results for the field driven quantum phase transition in CeCu_5.8Au_0.2.     

Fermi surface and antiferromagnetism in the Kondo lattice: an asymptotically exact solution in d>1 dimensions

Interest in the heavy fermion metals has motivated us to examine the quantum phases and their Fermi surfaces within the Kondo lattice model. We demonstrate that the model is soluble asymptotically exactly in any dimension d>1, when the Kondo coupling is small compared with the RKKY interaction and in the presence of antiferromagnetic ordering. We show that the Kondo coupling is exactly marginal in the renormalization group sense, establishing the stability of an ordered phase with a small Fermi surface AFS. Our results have implications for the global phase diagram of the heavy fermion metals, suggesting a Lifshitz transition inside the antiferromagnetic region and providing a new perspective for a Kondo-destroying antiferromagnetic quantum critical point.     

Quantum critical end point for the Kondo volume collapse model

The Kondo volume collapse describes valence transitions in f-electron metals and is characterized by a line of first order transitions in the pressure-temperature phase plane terminated at critical end points. We analyze the quantum critical end point, when the lower end point is tuned to T=0, and determine the specific heat, thermal expansion, and compressibility. We find that the inclusion of quantum critical fluctuations leads to a novel bifurcation of the first order phase line. Finally, we show that critical strain fluctuations can cause both, superconductivity and non-Fermi liquid behavior near the critical point.     

Singular effects of impurities near the ferromagnetic quantum-critical point

Systematic theoretical results for the effects of a dilute concentration of magnetic impurities on the thermodynamic and transport properties in the region around the quantum critical point of a ferromagnetic transition are obtained. In the quasiclassical regime, the dynamical spin fluctuations enhance the Kondo temperature. This energy scale decreases rapidly in the quantum fluctuation regime, where the properties are those of a line of critical points of the multichannel Kondo problem with the number of channels increasing as the critical point is approached, except at unattainably low temperatures where a single channel wins out.     

Kondo quantum criticality of magnetic adatoms in graphene

We examine the exchange Hamiltonian for magnetic adatoms in graphene with localized inner shell states. On symmetry grounds, we predict the existence of a class of orbitals that lead to a distinct class of quantum critical points in graphene, where the Kondo temperature scales as TK∝|J-Jc|1/3 near the critical coupling Jc, and the local spin is effectively screened by a super-Ohmic bath. For this class, the RKKY interaction decays spatially with a fast power law ～1/R7. Away from half filling, we show that the exchange coupling in graphene can be controlled across the quantum critical region by gating. We propose that the vicinity of the Kondo quantum critical point can be directly accessed with scanning tunneling probes and gating.     

Universal scaling and a novel quantum critical behavior of CeRhSb1-xSnx

We observe and explain a universal scaling rhochi = const for the electrical resistivity rho with the inverse magnetic susceptibility chi(-1) for the Kondo insulator CeRhSb(1-x)Snx. In the regime where the Kondo gap disappears (x > 0.12), the system forms a non-Fermi liquid (NFL), which transforms into a Fermi liquid at higher temperature. The NFL behavior is associated with the presence of a novel quantum critical point (QCP) at the Kondo insulator-correlated metal boundary. The divergent behavior of the resistivity, the susceptibility, and the specific heat has been observed when approaching the QCP from the metallic side and is interpreted as due to the competition between the Kondo and the intersite magnetic correlations.     

Uniaxial stress effect on quasi-one-dimensional Kondo lattice CeCo2Ga8

Quantum critical phenomena in the quasi-one-dimensional limit remain an open issue. We report the uniaxial stress effect on the quasi-one-dimensional Kondo lattice CeCo$_2$Ga$_8$ by electric transport and AC heat capacity measurements. CeCo$_2$Ga$_8$ is speculated to sit in close vicinity but on the quantum-disordered side of a quantum critical point. Upon compressing the ${c}$ axis, parallel to the Ce-Ce chain, the onset of coherent Kondo effect is enhanced. In contrast, the electronic specific heat diverges more rapidly at low temperature when the intra-chain distance is elongated by compressions along ${a}$ or ${b}$ axis. These results suggest that a tensile intra-chain strain ($\varepsilon_c >0$) pushes CeCo$_2$Ga$_8$ closer to the quantum critical point, while a compressive intra-chain strain ($\varepsilon_c<0$) likely causes departure. Our work provides a rare paradigm of manipulation near a quantum critical point in a quasi-1D Kondo lattice by uniaxial stress, and paves the way for further investigations on the unique feature of quantum criticality in the quasi-1D limit.     

Critical Kondo destruction and the violation of the quantum-to-classical mapping of quantum criticality

Antiferromagnetic heavy fermion metals close to their quantum critical points display a richness in their physical properties unanticipated by the traditional approach to quantum criticality, which describes the critical properties solely in terms of fluctuations of the order parameter. This has led to the question as to how the Kondo effect gets destroyed as the system undergoes a phase change. In one approach to the problem, Kondo lattice systems are studied through a self-consistent Bose-Fermi Kondo model within the extended dynamical mean field theory. The quantum phase transition of the Kondo lattice is thus mapped onto that of a sub-Ohmic Bose-Fermi Kondo model. In the present article we address some aspects of the failure of the standard order-parameter functional for the Kondo-destroying quantum critical point of the Bose-Fermi Kondo model.     

Magnetic-field control of quantum critical points of valence transition

We study the mechanism of how critical end points of first-order valence transitions are controlled by a magnetic field. We show that the critical temperature is suppressed to be a quantum critical point (QCP) by a magnetic field, and unexpectedly, the QCP exhibits nonmonotonic field dependence in the ground-state phase diagram, giving rise to the emergence of metamagnetism even in the intermediate valence-crossover regime. The driving force of the field-induced QCP is clarified to be cooperative phenomena of the Zeeman and Kondo effects, which create a distinct energy scale from the Kondo temperature. This mechanism explains the peculiar magnetic response in CeIrIn(5) and the metamagnetic transition in YbXCu(4) for X=In as well as the sharp contrast between X=Ag and Cd.     

Adiabatic pumping in interacting systems

A dc current can be pumped through an interacting system by periodically varying two independent parameters such as the magnetic field and a gate potential. We present a general expression for the adiabatic pumping current in interacting systems, written in terms of instantaneous properties of the system at equilibrium, and find the limits of its applicability. This expression generalizes the scattering approach for noninteracting particles. We apply our formula for a quantum critical system that exhibits the two-channel Kondo effect, where single particle excitations are not well defined. We find that if the quantum critical point is contained in the pumping trajectory, the pumped spin between the channels approaches h, and if it is not contained in the trajectory, the spin approaches zero when the temperature T --> 0. We discuss the non-Fermi liquid features of this system at finite T.     

Model of quantum criticality in He3 bilayers adsorbed on graphite

Recent experiments on He3 bilayers adsorbed on graphite have shown striking quantum critical properties at the point where the first layer localizes. We model this system with the Anderson lattice plus interlayer Coulomb repulsion in two dimensions. Assuming that quantum critical fluctuations come from a vanishing of the effective hybridization, we can reproduce several features of the system, including the apparent occurrence of two quantum critical points, the variation of the effective mass and coherence temperature with coverage.     

Magnetic quantum phase transition in an anisotropic kondo lattice

The quantum phase transition between paramagnetic and antiferromagnetic phases of the Kondo lattice model with Ising anisotropy in the intersite exchange is studied within extended dynamical mean-field theory. Nonperturbative numerical solutions at zero temperature point to a continuous transition for both two- and three-dimensional magnetism. In the former case, the transition is associated with critical local physics, characterized by a vanishing Kondo scale and by an anomalous exponent in the dynamics close in value to that measured in heavy-fermion CeCu5.9Au0.1.     

CeAu2In4: A candidate of quasi-one-dimensional antiferromagnetic Kondo lattice

Needle-like single crystals of CeAu₂In₄ have been grown from In flux and characterized as a new candidate of quasi-one-dimensional Kondo lattice compound by crystallographic, magnetic, transport, and specific-heat measurements down to very low temperatures. We observe an antiferromagnetic transition at T_N ≈ 0.9 K, a highly non-mean-field profile of the corresponding peak in specific heat, and a large Sommerfeld coefficient γ =369 mJ·mol^-1·K^-2. The Kondo temperature T_K is estimated to be 1.1 K, being low and comparable to T_N. While Fermi liquid behavior is observed deep into the magnetically ordered phase, the Kadowaki-Woods ratio is much reduced relative to the expected value for Ce compounds with Kramers doublet ground state. Markedly, this feature shares striking similarities to that of the prototypical quasi-one-dimensional compounds YbNi₄P₂ and CeRh₆Ge₄ with tunable ferromagnetic quantum critical point. Given the shortest Ce-Ce distance along the needle direction, CeAu₂In₄ appears to be an interesting model system for exploring antiferromagnetic quantum critical behaviors in a quasi-one-dimensional Kondo lattice with enhanced quantum fluctuations.     

The Kondo necklace model with planar anisotropy

We study the one-dimensional anisotropic Kondo necklace model at zero temperature through White's density matrix renormalization group technique. The ground state energy and the spin gap were calculated as a function of the exchange parameter for two anisotropy values. We found a finite critical point separating a Kondo singlet from an antiferromagnetic phase. The transition is highly congruent with a Kosterlitz–Thouless form. We observed that the critical point increases with the anisotropy.     

Junction of three off-critical quantum Ising chains and two-channel Kondo effect in a superconductor

We show that a junction of three off-critical quantum Ising chains can be regarded as a quantum spin chain realization of the two-channel spin-1/2 overscreened Kondo effect with two superconducting leads. We prove that, as long as the Kondo temperature is larger than the superconducting gap, the equivalent Kondo model flows towards the two channel Kondo fixed point. We argue that our system provides the first controlled realization of two channel Kondo effect with superconducting leads. Besides its theoretical interest, this result is of importance for potential applications to a number of contexts, including the analysis of the quantum entanglement properties of a Kondo system.     

Universal scaling in nonequilibrium transport through a single channel Kondo dot

Scaling laws and universality play an important role in our understanding of critical phenomena and the Kondo effect. We present measurements of nonequilibrium transport through a single-channel Kondo quantum dot at low temperature and bias. We find that the low-energy Kondo conductance is consistent with universality between temperature and bias and is characterized by a quadratic scaling exponent, as expected for the spin-1/2 Kondo effect. We show that the nonequilibrium Kondo transport measurements are well described by a universal scaling function with two scaling parameters.     

Scaling and enhanced symmetry at the quantum critical point of the sub-ohmic Bose-Fermi Kondo model

We consider the finite-temperature scaling properties of a Kondo-destroying quantum critical point in the Ising-anisotropic Bose-Fermi Kondo model (BFKM). A cluster-updating Monte Carlo approach is used, in order to reliably access a wide temperature range. The scaling function for the two-point spin correlator is found to have the form dictated by a boundary conformal field theory, even though the underlying Hamiltonian lacks conformal invariance. Similar conclusions are reached for all multipoint correlators of the spin-isotropic BFKM in a dynamical large-N limit. Our results suggest that the quantum critical local properties of the sub-Ohmic BFKM are those of an underlying boundary conformal field theory.