Study of the reaction238U (α, α′f) atE α=480 MeV

The excitation function of the fission probability P _E E _x) for²³⁸U has been measured in the reaction²³⁸U(α, α′ f) at 480 MeV bombarding energy. The reaction mechanism of this reaction is discussed for excitation energies belowB _nf , the threshold for second chance fission, and aboveB _nf up toE _x =37 MeV. In comparing with results from fission induced by photons and by particle transfer reactions the (α, α′f) reaction gives too low values for the fission probabilityP _f at excitation energies well aboveB _nE . The role of the quasi-elastic knock-out process in this reaction is discussed.     

Vacancy formation energies from positron trapping measurements

The threshold temperatureT _t at which thermally generated vacancies produce measurable positron trapping is a linear function of the energy of self-diffusionQ. SinceQ is also linearly related to the vacancy formation energyE _1v ^f , a measurement ofT _t leads directly to a determination of the latter. It is possible to make a precise determination ofE _1v ^f without approaching the melting point—a major advantage in dealing with refractories or with metals having a high vapour pressure in the solid state.     

Surface energies of metals in both liquid and solid states

Although during the last years one has seen a number of systematic studies of the surface energies of metals, the aim and the scientific meaning of this research is to establish a simple and a straightforward theoretical model to calculate accurately the mechanical and the thermodynamic properties of metal surfaces due to their important application in materials processes and in the understanding of a wide range of surface phenomena. Through extensive theoretical calculations of the surface tension of most of the liquid metals, we found that the fraction of broken bonds in liquid metals (f) is constant which is equal to 0.287. Using our estimated f value, the surface tension (γ_m), surface energy (γ_SV), surface excess entropy (−dγ/dT), surface excess enthalpy (H_s), coefficient of thermal expansion (α_m and α_b), sound velocity (c_m) and its temperature coefficient (−dc/dT) have been calculated for more than sixty metals. The results of the calculated quantities agree well with available experimental data.     

The probability of prompt and delayed fission of muonic237Np

Fission fragments from the reaction²³⁷Np(μ ^?,γ,f) have been measured in coincidence with muonic X-rays. The efficiency of the fission fragment detector is determined from (μ ^?,γ,f)-data of the same experiment. The total fission probability perμ-stopP _t has been measured as well as the fission probabilities P_f of the non-radiative muonic (3d→1s)- and (2p→1s)-transitions; the latter has been divided into two parts leading to different mean excitation energiesE:P _t =(54±17)%,P _f (3d→1s)=(41±21)%,P _f (2p→1s,E=6.218 MeV)=(61±19)%, andP _f (2p→1s,E=6.525 MeV)=(57±18)%. The influence of the muon on the fission barrier is discussed. The fission probability after muon capture is compared with a calculated value using a distribution of nuclear excitation energies following muon capture and the fission probability as measured in a²³⁸U(³He,αf)-reaction.     

Hypernuclear binding energies in the α-particle model

The binding energies B_Λ for the hypernuclei with baryon number A = 4N + 1 up to_Λ²⁵Mg have been calculated by the variational method in the framework of Brink's α-particle model. The central ΛN potential is adjusted to the binding energy of_Λ⁵He. Due to their strong dependence on the nuclear density, the B_Λ energies are very sensitive to the choice of the effective nuclear interaction and have reasonable values for large A with the potential B1 of Brink and Boeker. The comparison with the B_Λ values obtained in the limiting shell model and the consideration of two different Λ-particle wave functions both indicate that the effect of nuclear clustering on B_Λ is significant only for_Λ⁹Be and_Λ¹³C. The nuclear distortion due to the Λ-particle binding is also evaluated in this calculation.     

Coupled electron-phonon system in two dimensions and its implications for inversion layers

The first order electron-phonon vertex in two dimensions is calculated in the regime (q_o/qvf)?1 and (q_o/qvf)?1 where, q_o and q are the phonon frequency and wave vector, and v_f is the electron Fermi velocity. In the former case, the vertex correction is found to be λ. (Ωph/E_f)^{$\text{1}\text{2}$} and in the latter case it is λ, where λ is the dimensionless electron-phonon coupling, Ωph a characteristic phonon energy and E_f the Fermi energy. It is shown that for the relevant range of carrier density and phonon branches in the inversion layer, the term (Ωph/E_f)^{$\text{1}\text{2}$} is of order unity, possibly implying significant higher order effects.     

Fission barriers and other characteristics of nuclei from the uranium region

Fission barriers in nuclei belonging to the uranium region and their other characteristics are calculated on the basis of the FaNDF⁰ energy density functional. In particular, the neutron-separation energies S _n and S _2n, the proton-separation energies S _p, and the beta-transition energiesQ _β are calculated for uranium, neptunium, and plutonium isotopes. In addition, the deformation energies and parameters of these nuclei are presented along with their radii. A comparison with the predictions of the Skyrme–Hartree–Fock method implemented with several versions of the Skyrme energy density functionals is performed. The role of the octupole deformation β ₃ is studied for the ²³⁸U nucleus. It is shown that this deformation does not have any significant effect on the first-barrier height B ⁽¹⁾ _f or ground-state properties. At the same time, the second-barrier height B(2) f decreases by a factor of about two upon taking into account β ₃. A phase transition at A ~ 260 is found for the three isotopic chains being considered: this point is a bifurcation point at which B ⁽¹⁾ _f (A) forks into two curves. Of these, the curve B ⁽²⁾ _f (A) splits from it, prolonging the former curve for B ⁽¹⁾ _f (A) almost continuously, whereas the curve for B ⁽¹⁾ _f (A) itself goes down sharply.     

The microwave spectrum of IF5 in excited vibrational states: Accidental degeneracy and avoided crossing of the kl = 3 and kl = −1 levels in the state v9(E) = 1

Measurements of the microwave spectrum of the C_4v molecule IF₅ in the excited vibrational states v₉(E) = 1 and v₅(B₁) = 1 are reported for the transitions J12 ← 11 and J13 ← 12 (65–72 GHz). The considerable spectral perturbations produced by an accidental degeneracy and avoided crossing of the ψ^? (kl = 3) and ψ^? (kl = ?1) levels of the v₉(E) = 1 state have been measured and analyzed. A spectroscopic determination of the axial rotation constant C₉ is reported and its implications for the molecular structure of IF₅ discussed.     

Prompt mass distributions in fission

A previously developed structure-sensitive statistical model, incorporating the nuclear structure and deformation effects, has been utilised to study the prompt mass distributions in fision and other related characteristics. The principle of detailed balance has been applied to calculate the yield probabilities. The fusion barriers and the penetrabilities of the fragments were estimated from a nuclear plus Coulomb interaction potential. The prompt fragment mass yields were then obtained as a product of three quantities: the product level densities of the conjugates at their most probable excitation energies, the barrier penetrabilities and the isobaric charge yields. The calculations are free from any arbitrary parameters. Comparison with experimental data for²²⁶Ra(p, f) atE _p =11.1MeV,²³²Th(n, f) atE _n =1.0 MeV,²³⁵U(n, f) and²³⁹Pu(n, f) at thermal neutron energies and for the spontaneous fission of²⁵²Cf shows fairly good agreement.     

Relationship between charge transfer energies of Yb and Sm and crystal environmental factor

Relationship between charge transfer energies E_CT of Yb³⁺ and Sm³⁺ and environmental factors h_e in various crystals was investigated using a dielectric chemical bond method. Both results show that they have an exponential relation E_CT=A+B exp(−kh_e), but the exponential factors are different, which indicates that the interaction between the rare earth ions and environment is connected with the kind of rare earth ion. This result provides a method of determining charge transfer energies of Yb³⁺ and Sm³⁺ from a crystal structure.     

Spectral Studies of Vanadyl-Doped Cadmium–Strontium Borosilicate Glass System

Glasses with composition CdO–(20-x) SrO–B₂O₃–SiO₂–x V₂O₅ (CdSBSi) (x = 0.5, 1, 1.5, 2, 2.5 mol%) were prepared by melt quenching technique. The amorphous nature of prepared glasses is confirmed by X-ray diffraction. Optical absorption spectra, electron paramagnetic resonance (EPR) and Fourier transform infrared (FTIR) measurements were also carried out for the prepared glass samples. The optical band gap energy (E _opt) and Urbach energy (?E) were calculated from their ultraviolet edges. The theoretical values of optical basicity (Λ _th) of glasses have been evaluated. The optical absorption spectrum exhibits two band characteristic of VO²⁺ ions in tetragonally distorted octahedral site symmetry. The two bands have been assigned to the transitions ²B₂ → ²B₁ and ²B₂ → ²E in the decreasing order of energy. The spin–Hamiltonian parameters (g and A), bonding parameters (β*² and $ \varepsilon_{\pi }^{*2} $ ), Fermi contact interaction parameter (K) have been evaluated from the EPR spectra. The VO²⁺ site symmetry is ascribed to a tetragonally (C_4v) distorted octahedron. FTIR spectra of these glasses were analyzed in order to identify the contribution of each component to the local structure. The physical properties of these glasses were also evaluated.     

硅中三空位V3-的超精细相互作用的理论计算

利用Koster-Slater的格林函数方法,计算了硅中三空位V₃^-的电子态能级和波函数.结果表明,V₃^-在禁带中有五条能级:E_(A2)=0.417eV,E_(B1)=0.492eV,E_(B2¹)=0.512ev, E_(A1)=0.532eV,E_(B2²)=0.608eV.根据算得的超精细相互作用常数同实验值的比较,定出V₃^-处于B₁态.V₃^-的B₁态点据第1壳层的几率为60.2％,但主要集中在三空位所确定的平面内的二个原子上. 关键词：     

Systematic study of the product((E(2_2~+)/E(2_1~+)) * B(E2)↑) through the asymmetric rotor model

A systematic study of the product((E(2_2~+)/E(2_1~+))*B(E2)↑) is carried out in the major shell space Z=50-82,N=82-126 within the framework of the asymmetric rotor model where the asymmetry parameter γ0reflects change in the nuclear structure.A systematic study of the product((E(2+)/E(2+))*B(E2)↑) with neutron number N is also discussed.The product((E(2_2~+)/E(2_1~+))*B(E2)↑) provides a direct correlation with the asymmetry parameter γ0.The effect of subshells is visible in Ba-Gd nuclei with N 82,but not in Hf-Pt nuclei with N 104.We study,for the first time,the dependency of the product((E(2_2~+)/E(2_1~+))*B(E2)↑) on the asymmetry parameterγ0.     

A kinetic study of the thermal decomposition process of potassium metabisulfite: Estimation of distributed reactivity model

The thermal decomposition kinetics of potassium metabisulfite was studied by thermogravimetric (TG) and differential thermogravimetric (DTG) techniques using non-isothermal experiments. The apparent activation energy (E_a) is determined using the differential (Friedman) isoconversional method. The results of the Friedman's isoconversional analysis of the TG data suggests that the investigated decomposition process follows a single-step reaction and the observed apparent activation energy was determined as 122.4±2.1 kJ mol⁻¹. A kinetic rate equation was derived for the decomposition process of potassium metabisulfite with contracting area model, f(α)=2(1−α)^1/2, which is established using the Malek's kinetic procedure. The value of pre-exponential factor (A) is also evaluated and was found to be A=1.37×10¹² min⁻¹. By applying the Miura's procedure the distributed reactivity model (DRM) for investigated decomposition process was established. From the dependence α versus E_a, the experimental distribution curve of apparent activation energies, f(E_a), was estimated. By applying the non-linear least-squares analysis, it was found that the Gaussian distribution model (with distribution parameters E₀=121.3 kJ mol⁻¹ and σ=1.5 kJ mol⁻¹) represents the best reactivity model for describing the investigated process. Using the Miura's method, the A values were estimated at five different heating rates and the average A values are plotted against E_a. The linear relationship between the A and E_a values was established (compensation effect). Also, it was concluded that the E_a values calculated by the Friedman's method and estimated distribution curve, f(E_a), are correct even in the case when the investigated decomposition process occurs through the single-step reaction mechanism.     

Ultra-high energy neutrino-nucleon and neutrino-electron cross-sections in the standard model,in supersymmetric and superstring models

The neutrino-nucleon cross-section is calculated for energies up to 10¹⁵ GeV in the framework of the standard model assuming that the nucleon structure functionF ₂(x, Q ²) goes like ln²(a/x) asx→0. The cross-sections forv _μ e ^?(v _e e ^?)-interactions rise linearly with energy up toE _ν～10⁷ GeV and amount at this energy to ～10% of the neutrino-nucleon cross-section. The νN-cross-sections with production of supersymmetric particles in the framework of a supersymmetric model with minimal particle content are estimated. Photino-nucleon and photino-electron interactions are considered for masses of the squarks and sleptons in the range of 80–300 GeV. In superstring inspired unified models an estimation is made of the νN-interaction with an exchange of light leptoquarks.     

On directly measuring relative Fermi energies of noble metals and their alloys

We present the first evidence of direct measurement of relative Fermi energies in alloys and between pure metals. From applying the “atomic” concept of core hole final state screening, the Auger energy shift of noble metal A equals E_F^A?E_F(x). High resolution Auger shifts in P_1?x^tCu_x,Au_xCu_1?x and Au_xAg_1?x demonstrate experimental verification of this simple relation. We find E_F^CuE_F^Au ? ? 0.2 eV, and E_F^Pt ? E_F^Cu and E_F^Ag ? E_F^Au.     

Analysis of the ν6 band of 12CH3D at 8.6 μm

The ν₆(E) fundamental vibration-rotation band of monodeuteromethane (¹²CH₃D) has been recorded in the spectral range 1033–1270 cm^?1 with a resolution of approximately 0.04 cm^?1. Of the 669 transitions with J′ ≤ 17 identified, 633 have been retained for the determination of the rotational levels in the upper state v₆ = 1. The Coriolis interaction between the v₆ = 1(E) and v₃ = 1 (A₁) vibrational states of ¹²CH₃D results in large A₁A₂ splittings of levels with v₆ = 1 and |K ? l₆| = 0 or 3; the mixing in K and l₆ also gives rise to some ten forbidden transitions observed in the spectra. These effects have been very well explained within the formulation based on the contact transformation method. Values of 15 molecular structure constants of the v₆ = 1 state have been determined from a least-squares analysis of the 633 retained transitions. These constants can be used to estimate values of the upper-state energies up to fourth order, and through them the spectral positions of the 633 retained transitions are reproduced with an overall standard deviation of 0.013 cm^?1, which is within experimental uncertainties.     

The16O(α, γ)20Ne direct capture reaction at low energies

The¹⁶O(α, γ)²⁰Ne direct capture cross section has been calculated in a microscopically founded cluster model which reproduces simultaneously both the correct binding energies and the deformations of the²⁰Ne bound states. Theα+¹⁶O scattering states are derived from a microscopically derived local potential. The astrophysicalS-factor is found to increase linearly with energy in the energy rangeE _cm≈0.4–2 MeV and might therefore be determinable experimentally.     

Investigation of 38Ar levels by 37Cl+p reactions: (I). Yield curves,excitation energies and branching ratios

Yield measurements have been performed on the reactions ³⁷Cl(p, p₀)³⁷Cl, ³⁷Cl(p, α₀)³⁴S (E_p = 1.17–1.70 MeV) and ³⁷Cl(p, n₀)³⁷Ar, ³⁷Cl(p.γ)³⁸Ar (E_p = 0.64–2.92 MeV); detailed investigations are restricted to resonances below E_p = 1.79 MeV. Resonance energies, strengths and (some) widths are reported for 12, 26 and 247 resonances in the reactions (p, p₀), (p, n₀) and (p, γ), respectively.Simultaneous (p, α₀) and (p, γ) yield measurements over selected E_p intervals in the E_p = 0.88–1.64 MeV range established the existence of 42 resonances decaying by both γ and α₀ emission. Analysis of the γ-ray spectra of 100 ³⁷Cl(p, γ)³⁸Ar resonances leads to precision excitation energies (ΔE_x = 0.1–2 keV) of 57 bound states (E_x < 8 MeV) and branching ratios of the resonances and of 50 bound states.