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1.
Twenty-seven new FIR, far-infrared, laser lines from the isotopomers of methanol: 12CD3OH, 12CH3OD, and 12CH2DOH, were obtained by optically pumping the molecules with an efficient cw CO2 laser. The CO2 laser provided pumping from regular, sequence, and hot-band CO2 laser transitions. The 2 m long far-infrared cavity was a metal-dielectric waveguide closed by two, flat end mirrors. Several short-wavelength (below 100 m) lines were observed. The frequencies of 28 laser lines observed in this cavity (including new lines and already known lines) were measured with a fractional uncertainty limited by the fractional resetability of the far-infrared laser cavity, of 2 parts in 107.  相似文献   

2.
Twenty-seven new far-infrared laser lines from the isotopomers of methanol: 12CD3OH, 12CH3OD, and 12CH2DOH, were obtained by optically-pumping the molecules with an efficient cw CO2 laser. The CO2 laser provided pumping from regular, sequence, and hot-band CO2 laser transitions. The 2-m long far-infrared cavity was a metal-dielectric waveguide closed by two, flat end mirrors. Several short-wavelength (below 100 m) lines were observed. The frequencies of 28 laser lines observed in this cavity (including new lines and already known lines) were measured with a fractional uncertainty limited by the fractional resetability of the far-infrared laser cavity, of 2 parts in 107.  相似文献   

3.
We obtained twelve new far infrared laser transitions by optically pumping the CH2DOH, CH3I, CD3I and Trioxymethylene molecules with a CW CO2 laser having a tunability range of 280 MHz. We measured the wavelength, polarization, relative intensity and pump offset relative to the CO2 center frequency for all the new lines.  相似文献   

4.
We use a 13CO2 laser as optical pumping source to search for new THz laser lines generated from 13CH3OH. Nineteen new THz laser lines (also identified as far-infrared, FIR) ranging from 42.3 μm (7.1 THz) to 717.7 μm (0.42 THz) are reported. They are characterized in wavelength, offset, relative polarization, relative intensity, and optimum working pressure. We have assigned eight laser lines to specific rotational energy levels in the excited state associated with the C-O stretching mode.  相似文献   

5.
We report here the discovery of 13 new far-infrared laser lines from12CH2F2 and seven new lines from13CH2F2. Most of the new lines were pumped by high-J lines of the 9R branch of a cw-CO2 laser. Wavelengths range from 97.6 to 616.18 μm. Frequency, pump offset, relative polarization, and relative intensity were measured for most of the new lines.  相似文献   

6.
The methanol isotopic species CH3OD has also proved to be an efficient and powerful medium to generate radiation in the far infrared (FIR) region. After the critical review of 1994, six papers have been published dealing with new FIR laser lines from this molecule. As a consequence of the use of wide tunability waveguide CO2 lasers as well as a new pulsed CO2 laser operating at hot and sequential bands, as of optical pumping sources, the total number of the FIR laser lines increased from 122 in 1994 to 227 today. In this communication we present an updated and complete catalogue of FIR laser lines generated from CH3OD. Information on wavelength, offset, relative polarization, intensity, and optimum operation pressure is generally available.  相似文献   

7.
We have measured the output powers and relative polarizations of 66 cw FIR laser lines from CH2DOH (including 50 not previously reported), which were optically pumped by a CO2 laser. The frequencies of 43 of these lines were measured relative to stabilized CO2 lasers.  相似文献   

8.
We have investigated CHD2OH methanol as source of far-infrared (FIR) laser radiation using the optical pumping technique. Our new waveguide pulsed CO2 laser, with peak powers as high as some kW, has allowed us to observe 12 new lines. Each of them is characterized in wavelength, relative polarization, intensity, optimum operating pressure and pump offset from the center of the exciting CO2 line.  相似文献   

9.
Reported far-infrared laser lines for five different transition systems of CH3NH2 optically pumped by a CO2 laser have been identified spectroscopically through a high-resolution Fourier transform infrared study of the C-N stretching band together with CO2-laser/microwave-sideband broad-scan and Lamb-dip measurements. From the infrared analysis plus previous far-infrared (FIR) results for the ground vibrational state, quantum numbers have been assigned for seven methylamine FIR laser transitions and their C-N stretching pump absorptions coincident with the CO2 laser lines. The assignments are confirmed through the use of closed frequency combination loops that also provide improved FIR laser frequencies to spectroscopic accuracy.  相似文献   

10.
8 new large offset FIR laser lines of CH2F2 have been discovered by pumping with a high tunability waveguide CW CO2 laser. Optoacoustic measurements of CH2F2 have also been performed and the pump offsets of the new and of previously known lines have been measured and checked. Some assignments are proposed and a few assignments found in literature are checked  相似文献   

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