荧光粉表面吸附汞的检测

在荧光灯的燃点过程中，荧光粉表面沉积吸附的汞对光衰有重要的影响。本文提出用冷原子吸收方法（CVAAS）直接检测荧光粉表面吸附汞量的变化，利用室温下原子汞对254nm共振线的吸收，且其吸收与汞原子蒸气浓度成正比进行汞量测试，测得方法的标准曲线回归方程为Y＝0.4455X 0.2000，试样的加标回收率为92.3-99.8%，满足荧光粉含汞量测定的要求。对燃点不同时间后的铝酸盐蓝色荧光粉（BAM）进行测定，结果表明：荧光粉表面沉积吸附的汞量随点灯时间的延长而增加，与灯的光衰增大趋向一致，汞的吸附沉积确实是造成荧光灯光衰的主要原因之一。检测结果还表明，将未作表面包膜处理的BAM粉与经过表面包覆纳米Al2O3膜层处理的BAM粉作对照，前者的含汞量比后者的含汞量明显要高。可见：对荧光粉进行表面包膜处理，能够保护粉体、减少汞的沉积吸附，从而降低点灯过程中的光衰。     

BaMgAl10 O17 ： Eu^2＋的 MgF2表面包覆表面包覆

采用溶胶-凝胶法对蓝色荧光粉BaMgAl10 O17 ： Eu^2＋（BAM）进行表面包膜处理，获得了表面均匀包覆MgF2膜层的BAM荧光粉。并用SEM、XRD和IR手段对其表面形貌、晶格结构性能进行了表征；用EDS对BAM粉体的表面元素进行了定性分析；用荧光光谱测试对荧光粉的发光性能进行了研究。结果表明，在BAM粉体表面均匀包覆MgF2层后，BAM的品格结构，发光性能没有改变，初始亮度较未包覆的荧光粉有所降低，经过相同条件的热处理后，包覆MgF2荧光粉的亮度热衰减程度明显低于未包覆的荧光粉，且色坐标偏移现象不明显。     

BaMgAl_(10)O_(17)∶Eu~(2 )的MgF_2表面包覆(英文)

采用溶胶-凝胶法对蓝色荧光粉BaMgAl10O17∶Eu2 (BAM)进行表面包膜处理,获得了表面均匀包覆MgF2膜层的BAM荧光粉。并用SEM、XRD和IR手段对其表面形貌、晶格结构性能进行了表征;用EDS对BAM粉体的表面元素进行了定性分析;用荧光光谱测试对荧光粉的发光性能进行了研究。结果表明,在BAM粉体表面均匀包覆MgF2层后,BAM的晶格结构,发光性能没有改变,初始亮度较未包覆的荧光粉有所降低,经过相同条件的热处理后,包覆MgF2荧光粉的亮度热衰减程度明显低于未包覆的荧光粉,且色坐标偏移现象不明显。     

BaMgAl10O17:Eu2+的MgF2表面包覆

采用溶胶-凝胶法对蓝色荧光粉BaMgAl10O17:Eu2 (BAM)进行表面包膜处理,获得了表面均匀包覆MgF2膜层的BAM荧光粉.并用SEM、XRD和IR手段对其表面形貌、晶格结构性能进行了表征;用EDS对BAM粉体的表面元素进行了定性分析;用荧光光谱测试对荧光粉的发光性能进行了研究.结果表明,在BAM粉体表面均匀包覆MgF2层后,BAM的晶格结构,发光性能没有改变,初始亮度较未包覆的荧光粉有所降低,经过相同条件的热处理后,包覆MgF2荧光粉的亮度热衰减程度明显低于未包覆的荧光粉,且色坐标偏移现象不明显.     

BaSi_2O_5∶Pb荧光粉表面性能的改善

BaSi2O5∶Pb(BSP)荧光粉现主要应用于晒黑灯,也常用于其他一些特殊用途的荧光灯,如捕蝇、光催化等。相比其他灯用荧光粉来说,这种荧光粉有一明显缺点,即光衰较大。目前解决这个问题的办法主要通过化学气相沉积法在BSP粉表面包覆Al2O3膜,提出了一种基于液相的表面处理方法,且在较高pH值下进行,该方法通过将荧光粉加入Ba2 离子溶液,使得溶液中Ba2 离子在粉表面富集,再经过滤、灼烧等后处理,得到处理后的BSP粉。以SEM,XPS等方法对其表面形貌和组分进行测试,并以未处理的BSP粉作对照进行发光性能测试,结果表明:阳离子溶液处理后荧光粉在发光性能上有了明显改善,光通维持率明显提高。     

BaSi2O5：Pb荧光粉表面性能的改善

BaSi₂O₅:Pb(BSP)荧光粉现主要应用于晒黑灯,也常用于其他一些特殊用途的荧光灯,如捕蝇、光催化等。相比其他灯用荧光粉来说,这种荧光粉有一明显缺点,即光衰较大。目前解决这个问题的办法主要通过化学气相沉积法在BSP粉表面包覆Al₂O₃膜,提出了一种基于液相的表面处理方法,且在较高pH值下进行,该方法通过将荧光粉加入Ba²⁺离子溶液,使得溶液中Ba²⁺离子在粉表面富集,再经过滤、灼烧等后处理,得到处理后的BSP粉。以SEM,XPS等方法对其表面形貌和组分进行测试,并以未处理的BSP粉作对照进行发光性能测试,结果表明:阳离子溶液处理后荧光粉在发光性能上有了明显改善,光通维持率明显提高。     

溶胶-凝胶法制备MgF2包覆BaMgAl10O17:Eu荧光粉及其发光特性

用溶胶-凝胶法在等离子显示屏(PDP)用蓝色荧光粉BaMgAl10O17：Eu(BAM)的表面上成功地包覆了MgF2膜,并研究了其发光与热衰减特性。XPS和SEM结果表明BAM荧光粉颗粒表面上形成了MgF2包覆膜。对包覆样品和未包覆样品的发光特性研究表明：在254nm激发下,最佳包覆量为0．2％(质量比),其在600℃热处理30min后包覆样品的发光强度比未包覆样品的发光强度约高12％。在147nm激发下,最佳包覆量为0．5％,其在600℃热处理30min后的发光强度比未包覆样品的发光强度高15％。这表明对BAM荧光粉进行表面包覆MgF2可以有效地稳定荧光粉的发光性能。这一结果不仅对提高PDP性能有重要意义,而且对开发无汞荧光灯用荧光粉等也具有指导意义。     

Y(PV)O_4:Eu~(3+)荧光粉表面包覆Y(OH)_3的性能

采用化学共沉淀法对Y(PV)O4∶Eu3+荧光粉进行表面包膜处理,获得了表面均匀包覆Y(OH)3膜层的Y(PV)O4∶Eu3+荧光粉。用SEM、XRD等手段对其表面形貌、晶格结构性能进行了表征。结果表明:在Y(PV)O4∶Eu3+粉体表面均匀包覆Y(OH)3膜层后,Y(PV)O4∶Eu3+的晶格结构、发光性能没有改变,亮度较未包覆的荧光粉有较大提高,且没有发生色坐标偏移现象。     

CaS:Eu,Sm荧光粉表面二氧化硅包覆对其光激励发光特性的影响(英文)

改进了CaS∶Eu,Sm荧光粉在实时剂量计系统中的稳定性和实用性。以不同体积的正硅酸乙酯作为前驱体,采用溶胶凝胶法对CaS∶Eu,Sm荧光粉进行表面包覆。分别使用荧光分光光度计和酸度计对荧光粉的发光特性和防水特性进行表征。实验结果显示当质量分数为5%时,包覆层能明显提高荧光粉的稳定性且不影响荧光粉的发光强度。从材料的光激励发光和剂量响应测试实验中可以得出材料的退火特性以及相应的辐射剂量值。以CaS∶Eu,Sm荧光粉为基础的辐射剂量测试系统显示在0.1～300 Gy范围内具有良好的线性关系。结果显示表面包覆层明显抑制光激励发光特性,而且随着辐射剂量的增加,这种影响愈来愈显著。最后,我们提出了以光激励发光技术为基础的辐射剂量在线测试改进系统。     

LED芯片与YAG荧光粉的相互热作用

大功率白光LED作为新一代照明光源的优势越来越明显,但其光衰机制综合了YAG荧光粉、LED芯片以及封装散热多重因素,衰减机理复杂。为研究LED芯片与荧光胶的相互热影响,基于蓝光LED器件基板温度可控实现蓝光LED器件温度稳定,并通过外部加热(以此作为LED热量作用于荧光胶)的方式控制荧光胶、荧光粉、硅胶的温度。重点研究了温度从27℃升高到220℃对三者光衰、主波长特性的影响。对荧光胶与LED芯片的近距离相互热影响进行了测试,结果表明荧光粉涂覆量会引起光功率的降低,而且随着光功率的降低,LED芯片结温呈现指数升高。实验证明荧光胶层与LED芯片是一个相互影响的复合热源模型。     

Theoretical analysis and simulation of conjugate heights for dual-conjugate AO system in lidar

A multi-conjugate adaptive optics （MCAO） can offer a possibility of widening field of view （FOV） characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle＇s expressions of two deformable mirrors （DMs） MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance.     

Quick single-photon detector with many avalanche photo diodes working on the time division

Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use.     

Characterization of PolyA and PolyC mismatches by Raman spectroscopy

A.C mismatches are studied by Raman spectral characterization of PolyA, PolyC, and their equimolar complex in solution of 0.14 mol/L Na ,pH7.0.Experimental results show that A·C mismatches occur to be A/B (mainly A) conformers, and unlike Watson-Crick base pairing, this kind of mismatches is stabilized by only one hydrogen bond involving cytosine N4H2 and adenine N7.The formation of A·C complex makes the base stacking interactions much stronger, and conformation of the backbone more ordered, which leads to obvious Raman hypochromic effect with some shifts in corresponding bands.     

Improvement of four-wave mixing-based wavelength conversion efficiency in dispersion shifted fiber by 40-GHz clock pumping

40-GHz clock modulated signal as a pump to improve the efficiency of four-wave mixing (FWM)-based wavelength conversion in a 26.5-km dispersion shifted fiber (DSF) is investigated. The experimental results demonstrate that the conjugated FWM component has higher intensity with the clock pumping than that with the continuous-wave (CW) light pumping. The improvement of FWM-based wavelength conversion efficiency is negligible when the pump power is less than Brillouin threshold. But when the pump power is greater than Brillouin threshold, the improvement becomes significant and increases with the increment of pump power. The improvement can increase up to 9 dB if pump power reaches 17 dBm.     

Speech enhancement by array crosstalk resistant ANC and spectrum subtraction

Microphone array-based speech enhancement has great importance for speech communications and speech recognition. To reduce the aperture of the microphone array and to increase the effect of the speech enhancement will greatly broaden the application areas of the microphone array. An array crosstalk resistant adaptive noise cancellation method is therefore presented. And then an improved spectral subtraction algorithm is further cascaded to obtain better enhancement results. Theoretic analysis and experiments indicate that the proposed scheme needs only a very small microphone array while it simultaneously achieves a higher SNR improvement. Besides, the proposed scheme can be used in many noisy environments and is easy for real-time implementation.     

Multi-pulse operation of a Kerr-lens mode-locked femtosecond laser

Our experimental results show that the presence of a proper amount of negative group velocity dispersion is essential to multi-pulse operation of a Kerr-lens mode-locked femtosecond laser. We demonstrate that the pulse separations and the number of pulses contained within a cavity round trip are strongly dependent on the initial perturbations. The results allow us to get a better understanding on the influences of the convoluted self-phase modulation and intra-cavity dispersions on the stable multi-pulse oscillation in a Kerr-lens mode-locked femtosecond laser.     

Propagation of Helmholtz-Gauss beams in weak turbulent atmosphere

Based on the Rytov approximation of light propagation in weak turbulent atmosphere,the closed-form expressions of field and average irradiance of each one of the four fundamental families of Helmholtz-Gauss (HzG)beams:cosine-Gauss beams,stationary Mathieu-Gauss beams,stationary parabolic-Gauss beams,and Bessel-Gauss beams,which are propagating in weak turbulent atmosphere,are obtained.The results show that the field and average irradiance can be written as the product of four factors:complex amplitude depending on the z-coordinate only,a Ganssian beam.a factor of complex phase perturbation induced by atmospheric turbulence,and a complex scaled version of the transverse shape of the non-diffracting beam.The effect of weak atmospheric turbulence on irradiance distribution of the HzG beam can be ignored.     

An effective method for reducing speckle noise in digital holography

An effective method for reducing the speckle noise in digital holography is proposed in this paper.Different from the methods based on classical filtering technique,it utilizes the multiple holograms which are generated by rotating the illuminating light continuously.The intensity images reconstructed by a series of holograms generated by rotating the illuminating light possess different speckle patterns.Hence by properly averaging the reconstructed intensity fields,the speckle noises can be reduced greatly.Experimental results show that the proposed method is simple and effective to reduce speckle noise in digital holography.     

Influence of purity of HfO2 on reflectance of ultraviolet multilayer

The impurities in two kinds of HfO2 materials and in their corresponding single layer thin films were determined through glow discharge mass spectrum technology and secondary ion mass spectrometry(SIMS) equipment respectively.It was found that ZrO2 was the main impurity in the two kinds of HfO2 either in the original HfO2 materials or in the electron beam deposited films.In addition,the difference of Zr content in the two kinds of HfO2 single laver films was much laxger than that of the other impurities such as Ti and Fe.which showed that it was just ZrO2 that made the difference between the optical performance of the film products including the two kinds of HfO2.With these two kinds of HfO2 and the same kind of SiO2.we deposited HfO2/SiO2 multilayer reflective coatings at the wavelength of 266 nm.Experimental results showed that the reflectances of these two mirrors were about 99.85% and 99.15% respectively,which agreed well with the designed results what were based on the optical constants obtained from the corresponding single layer thin films.