Single-phase Bi2+x(Ca,Sr) n+1 Cu n O2n+4+δ, n = 0, 1, 2, 3 AND ∞, and some substitutional DERIVATIVES

The preparation, structure and properties of five members of the homologous series Bi_2+x(Ca,Sr) _n+1 Cu _n O_2n+4+δ are discussed, namely for n = 0, 1, 2, 3 and ∞. The two end members are insulating phases with a fixed oxygen stoichiometry but the members n = 1, 2 and 3 are superconducting phases with T_c depending on the calcium to strontium ratio and on oxygen stoichiometry as determined by annealing temperature and oxygen partial pressure. Maximum zero resistance T_c 's obtained are n = 1: 76 K, n = 2: 91 K and n = 3: 106 K. The effects of Pb-substitution in n = 2 and n = 3 are discussed with particular reference to the stabilisation of the latter phase. Rare-earth substitution is shown to raise T_c for n = 2 to at least 101 K without the introduction of the n = 3 phase.     

H+4, H+5和H+7团簇离子的测量和确认

报告了H+4, H+5, H+7等团簇离子的测量结果. 确认可以由H+3与一个或多个H和H2相互作用形成较大的H+4, H+5, H+7等团簇离子.     

Quasiclassical dynamics of light + heavy-heavy atom reactions: the reaction X + F2 → XF + F (X = Mu,H, D,T)

Quasiclassical trajectory calculations have been carried out for the collinear reaction X + F₂(v = 0, 1) → XF + F (X = Mu, H, D, T) using the best extended LEPS surface No II of Jonathan et al.. The behaviour of individual trajectories has been used to find the regions of the potential surface that are important for determining the total reaction probability. The bottleneck close to the saddle point and repulsive wall of the exit valley are found to be the important dynamical regions of the surface. Comparison is made with other quasiclassical calculations for light + heavy-heavy atom reactions and with quantum calculations.     

Θ+-Pentaquark parity from associative baryon production in πd collisions, π ± + d → Θ+ + Σ±

We derive, in model-independent way, the spin structure of the matrix element for the reaction of associative Θ⁺-pentaquark production, π ^± + d → Θ⁺ + Σ^±, in the threshold region and in collinear kinematics. The expressions for the polarization observables in this reaction are found assuming spin 1/2 and different parities for Θ⁺. We have proved that such a reaction can be used for a model-independent determination of the P parity of Θ⁺ only by measuring the Θ⁺ polarization. Other polarization observables, such as the dependence of the Σ^± polarization on the vector and tensor deuteron polarizations, are insensitive to the Θ⁺ parity under the considered kinematical conditions. The linear and quadratic relations between polarization observables in (Θ⁺ is unpolarized) do not depend on the parity of the Θ⁺ pentaquark. The analysis performed for this reaction is also applicable without any modification to the reaction K ⁺ + d → Θ⁺ + p. Using the pole model for the reaction mechanism, we estimated the value of the cross section for the reaction K ⁺ + d → Θ⁺ + p near the threshold. The text was submitted by the authors in English.     

Measurements of π+p,K+p and pp elastic scattering)

The paper presents the results on differential cross sections for elastic scattering of 7⁺-, K⁺-mesons and protons on protons in the 4-momentum transfer squared range 0·08 ¦t¦ 1·0 (GeV/c)² and incident particle momentum of 29 and 43 GeV/c for pions and kaons and 29, 43, 50 and 65 GeV/c for protons. The measurements were taken with the spectrometer Sigma, installed in the positive beam of the IHEP accelerator.Presented by F. A. Yotch at the Symposium on Hadron-Hadron Scattering at High Energies, Liblice, Czechoslovakia, June 16–21, 1975.The authors would like to express their gratitude to A. A.Logunov, Yu. D.Prokoshkin, L. D.Soloviev and V. A.Yarba for their support of this experiment. We are indebted to CERN Administration for giving us a permission to use a part of equipment of the CIBS spectrometer and to W.Kienzle for useful discussions.     

C,Al,Cu,Sn,Pb等原子核对高能π+,K+介子及质子的吸收截面

在联合原子核研究所同步稳相加速器上,研究了高能π⁺、K⁺介子和原子核的相互作用。利用角度式气体契连科夫速度选择器,选择出纯度约达99％的K⁺介子束。测量了C,Al,Cu,Sn,Pb等原子核对动量为2.72,3.70,4.75Бэв/с的π⁺介子的吸收截面;C,Al,Cu等原子核对动量为4.75Бэв/с的K⁺介子的吸收截面;C,Sn,Pb等原子核对动量为2.72Бэв/с的质子的吸收截面。利用光学模型,对所得的数据进行了分析。根据π⁺介子数据得到的原子核半径公式,与T.Bowen根据π^-介子的测量数据所得结果不同,而和由低能中子散射工作所得结果(R=1.37A^1/3×10^-13厘米)相符。根据K⁺介子数据得到,高能K⁺介子与核子相互作用全截面的平均值应为σ_KN=16.5毫巴。     

CaS:Ce,Tb中Tb3+到Ce3+的能量传递

本文通过发射光谱、激发光谱和发光的衰减特性,研究了三价稀土离子Ce3+和Tb3+在CaS基质中的相互作用。实验结果表明,在CaS中Tb3+敏化了Ce3+的发光,监测Ce3+的发光(505nm),在激发光谱中出现Tb3+中心特征辐射的激发带。而且在CaS:Ce、Tb中,Ce3+中心的发光衰减变慢,衰减后期的慢成份正是反映了能量施主Tb3+的衰减特性,证明在CaS:Ce、Tb中存在着Tb3+到Ce3+的能量传递。     

基于多体经典轨迹蒙特卡罗方法的H+,Li3+,Be4+,O7+与He原子电荷交换过程

经典轨迹蒙特卡罗(CTMC)方法是研究离子-原子碰撞系统电荷交换过程的常用方法,广泛应用于天体物理以及实验室等离子体环境下重粒子碰撞过程的研究.本文利用四体碰撞模型(4-CTMC)研究了包括两个束缚电子的四体碰撞过程,通过数值求解四体碰撞系统的哈密顿运动方程,计算了高电荷态入射离子(Li³⁺,Be⁴⁺和O⁷⁺)同氦原子在大能量范围的单、双电子电离和俘获截面.H⁺+He碰撞截面的计算中,在50—200 keV/amu的入射能区,4-CTMC的结果几乎重复了实验结果.在高电荷态入射情形下,4-CTMC计算的单电子电离和俘获截面值相较于三体碰撞模型(3-CTMC)在100—500 keV/amu的入射能区内与实验符合更好.尽管4-CTMC和3-CTMC忽略了电子关联,均高估了双电子电离和俘获截面(与实验值相比),但4-CTMC的结果更接近实验.     

LaOBr:Ce,Tb中Ce3+对Tb3+发光的影响

近年来人们对LaOBr:Tb的合成及其发光特性的研究日益增多。LaOBr:Tb不仅是良好的X光增感屏材料,也是较好的阴极射线发光材料。为了进一步提高它的亮度,降低了b的含量(因Tb很贵),寻求LaOBr中Tb3+发光的敏化剂是很重要的。     

Calculation of molecular constants for the X 1Σ g + , A 1Σ u + , B 1Πu, and a 3Σ u + electronic states of 39K2

The molecular constants are calculated for the X ¹Σ _g ⁺ , A ¹Σ _u ⁺ , B ¹Π_u, and a ³Σ _u ⁺ and electronic states of a potassium dimer. The wave functions and vibrational energies necessary for calculating the molecular constants are determined by solving the radial wave equation with the use of potential energy curves constructed by the semiempirical method. The vibrational terms, the rotational constants, and the centrifugal distortion constants calculated from the potential curves are compared with those determined from the experimental data.     

DFT studies on the interaction of PtxRuyMz (M = Fe,Ni, Cu,Mo, Sn,x + y + z = 4, x ≥ 1, y ≥ 1) alloy clusters with O2

The reaction mechanism of O₂ dissociation on Pt_xRu_yM_z (M = Fe, Ni, Cu, Mo, Sn, x + y + z = 4, x ≥ 1, y ≥ 1) alloy catalysts have been investigated with density functional theory calculations in this work. For bare alloy clusters, bimetallic clusters are more stable than the ternary alloy clusters. The geometries of the Pt_xRu_yM_z–O₂ system, O–O bond stretching frequency and electronic-structure details have been investigated. The energies of O₂ adsorption on PtRu clusters are slightly higher than those on Pt_xRu_yM_z clusters, and the more charge transfer to O₂ from the metal cluster, the higher O₂ the adsorption energy obtains. The reaction barriers show that the catalytic performance of trimetallic clusters are better than those of bimetallic clusters, and Pt₂RuM clusters exhibit superior catalytic activity for O₂ dissociation. The different performance of these alloy clusters for O₂ dissociation is scrutinised with aid of molecular orbital and natural bond orbital population analysis.     

纳米YAG∶Ce3+, Mn+(Mn+=Ca2+, Gd3+)荧光粉的结构与发光性能

当前商用白光LED器件中YAG∶Ce3+荧光粉的单一黄光发射,导致其缺乏红光限制了器件的应用和发展,在YAG∶Ce3+中掺杂其他离子是解决该问题的有效途径之一。采用溶胶凝胶法制备了系列单掺Ce3+,Ca2+和Gd3+的YAG纳米荧光粉。研究了离子掺杂量对荧光粉的物相、结构、形貌、粒度、发光性能及量子效率的影响,分析了发光机理。结果表明：制备的纳米荧光粉粒径为100～200 nm。Ce3+和Gd3+掺杂时均得到YAG纯相,但晶体结构膨胀,晶面衍射峰向小角度方向移动。样品结晶度随Ce3+和Ca2+(<0.025 mol)掺杂量增大变化不明显,随Gd3+则呈现逐步降低趋势。三种离子掺杂量增大时,Ce3+的晶格能上升,5d能级晶体场劈裂加剧;Gd系列荧光粉激发和发射光谱随掺杂量的增大发生红移,Ce和Ca系列则因掺杂量小表现不明显。荧光粉发光强度随Ce3+掺杂量上升先增大后减小,最佳掺杂量为0.06 mol;随Gd3+掺杂量增加逐步降低;随Ca2+掺杂量增大则急剧下降,0.03 mol掺杂量时荧光强度几乎为零,YAG晶体结构破坏,生成YAM和YAP相。研究的开展,将对后续纳米YAG荧光粉及其相关功能材料的进一步开发使用提供一定的理论依据和实践参考。     

μ+SR study of two-dimensional antiferromagnets,delafossite-type compounds

⁺SR experiments were performed on delafossite-type compounds, CuCrO₂, AgCrO₂, CuFeO₂, which are model compounds of triangular lattice antiferromagnets. The initial asymmetries are much smaller than the expected value, implying muonium formation. The time spectra are composed of slow andfast relaxation components. We attributed the components to signals from ⁺ stopped at the center of O^2– ions andmuonium far from nuclear dipole moments, respectively. The asymmetries decrease belowT _N but no precession spectra were observed. Relaxation rates of slow andfast relaxation components show maxima atT _N.     

Upconversion Luminescence of Eu3 + in NaYbF4∶ Tm3 + , Eu3 +Nanocrystals Induced by 980 nm Excitation

利用水热法制备得到NaYbF4∶0.01％Tm3+,20％ Eu3+上转换材料,利用X射线衍射分析、扫描电子显微镜及光谱测试技术分别对其进行了结构、形貌以及光谱性质的表征.在980 nm近红外激光激发下,得到了Eu3+的可见到紫外范围的上转换荧光发射.分析表明:共掺杂NaYbF4纳米材料中Tm3+到Eu3+离子的能量传递对布居Eu3+离子的激发态能级,获得Eu3+的上转换发光起着至关重要的作用.另外,在实验中首次获得了Eu3+对应于3P0→7Fj(j=0,1,2)能级跃迁的上转换光发射.     

Semiclassical and quasiclassical calculation of reaction probabilities for collinear X + F2→XF + F (X = Mu,H, D,T)

Semiclassical calculations of reaction probabilities have been carried out for the collinear H + F₂ (n = 0, 1) reaction using the best extended LEPS surface No. II of Jonathan et al. Both real and complex valued classical trajectories have been included in the calculations for an energy range where the quasiclassical total reaction probability is unity. Comparison with quantum results shows the semiclassical reaction probabilities are accurate to about ± 0·05 provided only two real or complex stationary phase points make an important contribution to the S matrix element, so that the uniform Airy or integer Bessel approximations are valid. Real semiclassical calculations are also reported for the collinear Mu, D, T + F₂ (n = 0) reactions. For the D and T reactions, the semiclassical reaction probabilities are estimated to be accurate to ± 0·05, except close to the reaction threshold, but for the Mu reaction the estimated errors are much larger. In addition, quasiclassical calculations for the reaction probabilities have been carried out using half integer boxing and smooth sampling methods to quantize the product distributions. For the H + F₂ reaction, there are usually systematic deviations from the quantum reaction probabilities and the same is expected to be true for the Mu, D and T reactions.     

On the reactions p + p↦p + Λ + K+ and p + p↦p + Σ0 + K+ near thresholds

The cross-sections for the reactions of the strange production p + p ↦ p + Λ + K⁺ and p + p ↦ p + Σ⁰ + K⁺ near thresholds of the final states pΛK⁺ and pΣ⁰K⁺ are calculated in the effective Lagrangian approach. Our approach is based on the dominant contribution of the one-pion exchange and strong interaction of the colliding protons in the initial state. The theoretical values of the cross-sections agree reasonably well with the experimental data. The polarization properties of the Λ- and Σ⁰-hyperons are discussed.     

Large scale simulations of two-species annihilation,A+B→0, with drift

We present results of computer simulations of the diffusion-limited reaction process A+B→0, on the line, under extreme drift conditions, for lattices of up to 2²⁷ sites, and where the process proceeds to completion (no particles left). These enormous simulations are made possible by the renormalized reaction-cell method (RRC). Our results allow us to resolve an existing controversy about the rate of growth of domain sizes, and about corrections to scaling of the concentration decay.     

μ + SR studies of UM2Al3, M=Ni,Pd

Positive-muon spin rotation ( ⁺ SR) measurements have been carried out in the new heavy-fermion superconductors UM₂Al₃, M=Ni and Pd. In UNi₂Al₃ the observed ⁺ frequencies in zero applied field indicate commensurate antiferromagnetic (AF) ordering of U moments 0.1 _B /U atom. These moments coexist with superconductivity and have the highest values observed in an AF heavy-fermion superconductor. The absence of well-defined frequencies in zero-field ⁺ SR in the AF state of UPd₂Al₃ suggests symmetric ⁺ stopping sites. In this system ⁺ SR linewidths belowT _c yield a preliminary value of 8000 Å for the London penetration depth.     

Cr3+:GGG(Ca,Mg,Zr)和Nd3+,Cr3+:GGG(Ca,Mg,Zr)激光晶体的光谱特性

本文分析了Cr3+:GGG(Ca,Mg,Zr)的荧光谱和吸收谱,测算到Cr3+离子在4T2g-2Eg的能级间距为ΔE≈70cm-1,晶场强度Dq/B=2.50.说明由于GGGa(Ca,Mg,Zr)晶格扩大减弱了晶场,可望实现Cr3+:GGG(Ca,Mg,Zr)室温下的调谐及Nd3+:Cr3+:GGG(Ca,Mg,Zr)中Cr3+→Nd3+能量的转移.最后从理论上阐明了Cr3+在晶体GGG(Ca,Mg,Zr)中的能级结构.