LiNbO_3晶体的布里渊散射与弹性常数和压电常数的测定

本文在计算3m晶体的布里渊张量时,不仅考虑弹光效应,且同时计及了局部转动效应和电光效应.经过对实验系统的设计和调整,用90°散射测量了3m晶体LiNbO_3的布里渊谱,得到了LiNbO_3晶体在特超声频率下的所有独立的弹性常数和压电常数,据以计算了慢度曲线.用180°散射测量了LiNbO_3晶体的有关声速,实验结果与计算曲线一致.     

LBO晶体的布里渊散射与弹性和压电系数的测量

简述了应用布里渊散射测量晶体的弹性和压电系数的方法,推导了C_2v点群晶体(100),(010)和(001)晶面内任意波矢方向的布里渊散射张量及声速各向异性方程.根据上述方法及结果,用180°散射测量了LBO晶体不同波矢方向的布里渊散射谱,得到了LBO晶体在特超声频率下所有独立的弹性和压电系数,并依此计算了该晶体的声速各向异性曲线. 关键词：     

布里渊散射研究K_2SnCl_6晶体的弹性常数和声学模软化

本文测量了六卤素金属化合物六氯锡钾室温布里渊散射纵声速和横声速。计算了晶体的弹性常数、折射率、体积压缩系数。并进一步研究了[111]方向声子的纵声速随温度的变化关系,发现当温度从高温降到256K附近,C_(11)+2C_(12)发生突变。利用Pippard关系进行了分析,得出晶体在T=256K附近发生一级相变。这种声学反常行为可以用均匀弹性应变场与软模坐标涨落的非线性耦合来解释。     

氘含量对DKDP晶体横向受激拉曼散射增益系数的影响

本文测量了不同氘含量K(H_1-xD_x)₂PO₄晶体(DKDP晶体)在Z(XX)Y散射配置下的自发拉曼散射光谱, 并详细分析了氘含量对与横向受激拉曼散射(TSRS)增益系数有关的拉曼频移、半峰宽和散射强度的影响. 然后通过与去离子水拉曼散射对比得出了不同氘含量DKDP晶体的TSRS增益系数. 结果表明随着氘含量的增加DKDP晶体的TSRS增益系数先减小至KDP晶体的40.1%, 后增大至68.9%; 本文认为掺氘后拉曼半峰宽的变化是引起TSRS增益系数随氘含量变化的主要原因.     

布里渊散射决定0.67Pb(Mg1/3Nb2/3)Ｏ3－0.33ＰbTiO3单晶的弹性、压电和介电常数

我们报道了用高分辨布里渊散射,确定0.67Pb(Mg1/3Nb2/3)Ｏ３－０．３３ＰbTiO3单晶中的弹性、压电和介电常数.所有的实验数据都是在一块沿［001］方向的极化的单晶样品上获得的。我们实验中得到的这些常数的数值和以往超声共振技术获得的数值相似。我们还研究了压缩模和剪切模在(010)和(001)平面内的方向依赖性。TA1和TA2模式的强度对散射角度有很强列依赖性。在散射角度为45°~65°内, 一个新的峰出现在~18 GHz附近。它可能与晶体中的微观不均匀性或者局域微结构相关。     

布里渊散射决定0.67Pb(Mg_(1/3)Nb_(2/3))O_3-0.33PbTiO_3单晶的弹性、压电和介电常数(英文)

我们报道了用高分辨布里渊散射,确定0.67Pb(Mg1/3Nb2/3)O3-0.33PbTiO3单晶中的弹性、压电和介电常数.所有的实验数据都是在一块沿[001]方向的极化的单晶样品上获得的。我们实验中得到的这些常数的数值和以往超声共振技术获得的数值相似。我们还研究了压缩模和剪切模在(010)和(001)平面内的方向依赖性。TA1和TA2模式的强度对散射角度有很强列依赖性。在散射角度为45°~65°内,一个新的峰出现在~18 GHz附近。它可能与晶体中的微观不均匀性或者局域微结构相关。     

氮化铝单晶的布里渊散射几何研究

在对称散射和180°背散射两种散射几何设置下获得了单晶透明氮化铝布里渊散射谱图。分析了谱峰出现的原因及其对应的声波模式,分析了对称散射几何设置下谱图的偏振态。实验观察到对称散射谱图中准纵波峰和背散射谱图中的纯纵模峰,分析了它们出现的原因。文章根据实验谱图求得了样品材料的全部弹性常数信息。     

M型少模光纤中模间受激布里渊散射特性及其温度和应变传感特性

少模光纤的受激布里渊散射对于分布式温度/应变传感具有重要应用价值.本文提出一种纤芯折射率呈M型分布的少模光纤,详细研究了光学模式LP_(01)和LP_(11)模式内及模式间的布里渊增益谱.研究结果表明:LP_(01)-LP_(11)模式对的布里渊增益谱中,其相邻两个布里渊散射峰的频率间隔较宽、增益峰值较大且峰值相差较小.通过优化光纤结构参数,提高了基于LP_(01)-LP_(11)模式对布里渊增益谱的温度和应变传感性能,最小误差分别为0.23℃和5.67μe.该研究对探究少模光纤中模式内及模式间的受激布里渊散射特性具有一定的指导意义,对提升同时温度和应变传感测量的性能具有一定参考价值.     

掺杂和结构对光纤中去极化型声波导布里渊散射频移与散射效率的影响

利用全矢量有限元法研究了单模光纤及光子晶体光纤中掺杂材料及浓度、光纤结构对去极化型声波导布里渊散射频移和散射效率的影响.结果表明增大包层掺氟浓度或纤芯掺锗浓度均会减小光纤布里渊频移,也会增大单模光纤散射效率.光子晶体光纤中整体掺氟浓度不变时,空气孔层数的增加会减小布里渊频移;而纤芯掺锗浓度不变时,随空气孔层数的增加TR2,3模式的布里渊频移增大,而TR2,7模式的布里渊频移减小.     

第二届全国光散射学术会议简讯

第二届全国光散射学术会议于1983年10月12日至16日在苏州大学举行.出席会议的有55个单位的110名代表.会议宣读交流了论文近80篇,其中特邀报告三篇. 报告主要涉及到物理、化学、生物、矿物、谱学、材料、仪器和测试方法等学科.关于导波光的散射、布里渊散射、受激光散射的特邀报告引起了较大兴趣.物理方面的工作主要有:喇曼散射研究固体(主要是铁电体、半导体和非晶态)的晶格振动模和结构相变;高压下晶体的喇曼光谱及压力相变;晶体中的布里渊散射;非线性喇曼散射涉及到相干反斯托克斯喇曼散射,高压氢气、液态空气和光纤中的受激光散射等目前…     

Brillouin and ultrasonic study of the temperature dependence of the elastic constants in NaCN

The temperature dependence of the elastic constants of NaCN has been studied by propagation of ultrasonic waves at 15 MHz and by Brillouin scattering at 3 GHz over the temperature range from 287K to 355K. c₄₄ is observed to soften linearly with temperature as the order-disorder phase transition at 284K is approached from above. The other elastic constants also soften, except for c₁₂ which stiffens. Considerable dispersion is seen in the values of c₄₄ obtained ultrasonically and by Brillouin scattering. Measurements of the temperature dependence of the density are also reported.     

Briullouin scattering in superionic compounds : NdF3 and CaF2 (ReF3)

Abstract

Using Brillouin scattering techniques, the acoustic mode frequencies associated with the set of elastic constants in NdF₃ have been measured as a function of temperature from 300 to 1325 K. Significant deviations from linear behaviour for certain elastic constants were observed above about 1050 K and attributed to a diffuse phase transition into a superionic state. Similar studies on a series of compounds CaF₂ (10 mold% ReF₃) where Re represents La, Nd, Tb and Tm demonstrate a marked reduction in the superionic transition temperature, T_c, compared with pure CaF₂. In the doped crystals significant differences in T_c and the subsequent development of disorder are dismissed in relation to the presence of extrinsic defect clusters.     

Raman and brillouin scattering in a single crystal of K2Hg(CN)4

The temperature dependence of the elastic constants of cubic K₂Hg(CN)₄ has been measured by optical Brillouin spectroscopy in the temperature range from 300-110 K. A decrease of all three elastic constants was found in agreement with the results of ultrasonic measurements. Raman measurements in the temperature range from 300-4 K revealed a splitting of the F_2g modes corresponding to a trigonal distortion of the Hg(CN)₄-tetrahedra in the low temperature phase.     

Anomales elastisches Verhalten von Eis bei tiefen Temperaturen

The temperature dependence of the longitudinal elastic constants of ice single crystals has been measured by an ultrasonic pulse-echo method. With heating, resp. cooling rates less than a critical value, deviations to lower values of the elastic constants have been observed. The time dependence of the anomaly has been studied at fixed temperatures. Limiting values of the elastic constants have been reached after sufficiently long time; the maximum of these values was observed at about 105°K. The findings are interpreted as representing a phase transition within the protonic structure.     

Brillouin Scattering Study on the single crystals ofl-arginine phosphate (LAP)

This is the first report representing Brillouin Scattering Studies on single crystals of monoclinic LAP, which is a new organic material very useful for secondary harmonic generation. The crystal elastic constants were evaluated from the measured data. The curves of the reciprocal velocity and the acoustic velocity as a function of temperature are given here.     

钨青铜型结构铁电体的低温扩散相转变

对六种钨青铜结构的铌酸盐铁电晶体进行了从15 K 到室温范围的介电特性及热电特性的研究. 分析其介电特性和热电特性与极化电场的关系, 用x 射线粉末衍射进行佐证. 证实在50 一70 K 的范围内, SBN , PBN , KNSBN 三类铁电钨青铜铌酸盐晶体均存在着一个新的相变. 相变是由点群4mm铁电相到点群mm2 铁电相的转变. 铁电自发极化方向由四方晶胞的c轴方向转变到正交晶胞的b 轴方向.介电特性的高频及低频测量表明该相变具有扩散(或称弥散)型特征. 比热的实验结果证明相变是属于高于一阶相变的高阶相变. 对相变前后的晶胞结构提出了一个模型解释. 关键词：     

Protein dynamics in Brillouin light scattering: Termal denaturation of hen egg white lysozyme

Thermal denaturation of hen egg white lysozyme has been investigated by Brillouin light scattering in the temperature range from 297 to 350 K. Anomalies in the temperature dependences of velocity and damping of hypersound and also in the behavior of the intensity of Brillouin components for the lysozyme solution at thermal denaturation have been revealed. These anomalies are attributable to phase transformations of the protein in the high-temperature region. It has been shown that Brillouin light scattering is a suitable tool for studying the structural evolution of proteins.     

First-principles investigation of the phonon spectrum of β-GaS

This paper presents the results of the first-principles density functional theory calculation of the phonon spectrum of the ??-GaS semiconductor with a layered structure. The elastic constants and velocities of sound along and across the layers of the ??-GaS semiconductor have been determined. Investigation of the equilibrium structure and the phonon spectrum of the (0001) surface of the ??-GaS crystals has demonstrated that the bulk and surface structural and dynamical properties of these crystals differ only slightly. The calculated frequencies and symmetries of phonon modes at the center of the Brillouin zone of the semiconductor are in satisfactory agreement with the experimental data obtained from the Raman and infrared spectra.     

First-principles study of the phonon spectrum of ɛ-GaSe

The phonon spectrum and phonon density of states of ?-GaSe layered semiconductor have been studied from the first principles in the linear-response approximation. The elastic constants and acoustic velocities along and across layers have been determined. The study of the equilibrium structure and phonon spectrum of the (0001) surface of ?-GaSe has demonstrated that the volume and surface structural dynamic properties of these crystals differ insignificantly. The calculated frequencies and symmetries of the phonon modes in the center of the Brillouin zone are in good agreement with the experimental data obtained from the Raman scattering and infrared spectra.