Qubit Semantics and Quantum Trees

In the qubit semantics the meaning of any sentence α is represented by a quregister: a unit vector of the n–fold tensor product ⊗ⁿ ℂ², where n depends on the number of occurrences of atomic sentences in α (see Cattaneo et al.). The logic characterized by this semantics, called quantum computational logic (QCL), is unsharp, because the noncontradiction principle is violated. We show that QCL does not admit any logical truth. In this framework, any sentence α gives rise to a quantum tree, consisting of a sequence of unitary operators. The quantum tree of α can be regarded as a quantum circuit that transforms the quregister associated to the occurrences of atomic subformulas of α into the quregister associated to α.     

On representations of the groups Sp(n, 1) and Sp(n)

New classes of unitary irreducible representations of Sp(n, 1) which can be useful for applications in physics are obtained. The infinitesimal operators of these representations of Sp(n, 1) and of irreducible representations of Sp(n+1) with highest weights (m, m, m₃,…,m_n+1) and (m₁, m₂, 0,…,0) are expressed in terms of the simple Clebsch–Gordancoefficients for Sp(n). For Sp(3) and Sp(2, 1) they are found in an explicit form.     

HeiddenSL(n) symmetry in conformal field theories

We prove that an irreducible representation of the Virasoro algebra can be extracted from an irreducible representation space of theSL(2, ) current algebra by putting a constraint on the latter using the Becchi-Rouet-Stora-Tyutin formalism. Thus there is aSL(2, ) symmetry in the Virasoro algebra, but it is gauged and hidden. This construction of the Virasoro algebra is the quantum analogue of the Hamiltonian reduction. We then are naturally lead to consider a constrainedSL(2, ) Wess-Zumino-Witten model. This system is also related to quantum field theory of coadjoint orbit of the Virasoro group. Based on this result, we present a canonical derivation of theSL(2, ) current algebra in Polyakov's theory of two-dimensional gravity; it is a manifestation of theSL(2, ) symmetry in conformal field theory hidden by the quantum Hamiltonian reduction. We also discuss the quantum Hamiltonian reduction of theSL(2, ) current algebra and its relation to theW _n -algebra of Zamolodchikov. This makes it possible to define a natural generalization of the geometric action for theW _n -algebra despite its non-Lie-algebraic nature.This paper is dedicated to the memory of Vadik G. Knizhnik     

Realizations of causal manifolds by quantum fields

Quantum mechanical operators and quantum fields are interpreted as realizations of timespace manifolds. Such causal manifolds are parametrized by the classes of the positive unitary operations in all complex operations, i.e., by the homogenous spacesD(n)=GL(C _R ⁿ )/U(n) withn=1 for mechanics andn=2 for relativistic fields. The rankn gives the number of both the discrete and continuous invariants used in the harmonic analysis, i.e., two characteristic masses in the relativistic case. ‘Canonical’ field theories with the familiar divergencies are inappropriate realizations of the real 4-dimensional causal manifoldD(2). Faithful timespace realizations do not lead to divergencies. In general they are reducible, but nondecomposable—in addition to representations with eigenvectors (states, particle), they incorporate principal vectors without a particle (eigenvector) basis as exemplified by the Coulomb field. In theorthogonal andunitary groupsO(N ₊,N ₋), respectively, thepositive orthogonal and unitary ones areO(N) andU(N), respectively.     

Structure and Luminescence Properties of Monomeric and Dimeric Re(I) Complexes with Dicarboxylic Acid-2,2′-Bipyridine Ligands

The luminescence properties of Re(I) complexes incorporating the dcbpy ligand (dcbpy = n,n′-dicarboxylic acid-2,2′-bipyridine; n = 3, 4) were investigated as well as their utility as Pb²⁺ sensors. An unusual binuclear complex of the 3,3′- species was isolated. The emission intensity and lifetime for all complexes were found to be highly temperature-dependent, with quantum yields and lifetimes dramatically greater at 77 K than at room temperature. The monomeric 3,3′-dcbpy Re(I) complex demonstrates nearly 1:1 binding with Pb²⁺. The effect of this lead binding on the emission intensity is great, but the low quantum yields allow only for detection of the metal at the micromolar level. The binding of Pb²⁺ to the 4,4′-dcbpy complex is modeled and the interaction is demonstrated to involve two binding sites.     

Generalizations of Quantum Mechanics Induced by Classical Statistical Field Theory

No Heading We show that the Dirac-von Neumann formalism for quantum mechanics can be obtained as an approximation of classical statistical field theory. This approximation is based on the Taylor expansion (up to terms of the second order) of classical physical variables – maps f : Ω → R, where Ω is the infinite-dimensional Hilbert space. The space of classical statistical states consists of Gaussian measures ρ on Ω having zero mean value and dispersion σ²(ρ) ≈ h. This viewpoint to the conventional quantum formalism gives the possibility to create generalized quantum formalisms based on expansions of classical physical variables in the Taylor series up to terms of nth order and considering statistical states ρ having dispersion σ²(ρ) = hⁿ (for n = 2 we obtain the conventional quantum formalism).     

Localization of Unitary Braid Group Representations

Governed by locality, we explore a connection between unitary braid group representations associated to a unitary R-matrix and to a simple object in a unitary braided fusion category. Unitary R-matrices, namely unitary solutions to the Yang-Baxter equation, afford explicitly local unitary representations of braid groups. Inspired by topological quantum computation, we study whether or not it is possible to reassemble the irreducible summands appearing in the unitary braid group representations from a unitary braided fusion category with possibly different positive multiplicities to get representations that are uniformly equivalent to the ones from a unitary R-matrix. Such an equivalence will be called a localization of the unitary braid group representations. We show that the q = e ^πi/6 specialization of the unitary Jones representation of the braid groups can be localized by a unitary 9 × 9 R-matrix. Actually this Jones representation is the first one in a family of theories (SO(N), 2) for an odd prime N > 1, which are conjectured to be localizable. We formulate several general conjectures and discuss possible connections to physics and computer science.     

On the <Emphasis Type="Italic">SU</Emphasis>(2)×<Emphasis Type="Italic">SU</Emphasis>(2) symmetry in the Hubbard model

We discuss the one-dimensional Hubbard model, on finite sites spin chain, in context of the action of the direct product of two unitary groups SU(2)×SU(2). The symmetry revealed by this group is applicable in the procedure of exact diagonalization of the Hubbard Hamiltonian. This result combined with the translational symmetry, given as the basis of wavelets of the appropriate Fourier transforms, provides, besides the energy, additional conserved quantities, which are presented in the case of a half-filled, four sites spin chain. Since we are dealing with four elementary excitations, two quasiparticles called “spinons”, which carry spin, and two other called “holon” and “antyholon”, which carry charge, the usual spin-SU(2) algebra for spinons and the so called pseudospin-SU(2) algebra for holons and antiholons, provide four additional quantum numbers.     

Adiabatic Times for Markov Chains and Applications

We state and prove a generalized adiabatic theorem for Markov chains and provide examples and applications related to Glauber dynamics of the Ising model over ℤ ^d /nℤ ^d . The theorems derived in this paper describe a type of adiabatic dynamics for l¹(\mathbbRⁿ₊)\ell^{1}(\mathbb{R}^{n}_{+}) norm preserving, time inhomogeneous Markov transformations, while quantum adiabatic theorems deal with ℓ ²(ℂ ⁿ ) norm preserving ones, i.e. gradually changing unitary dynamics in ℂ ⁿ .     

Effects of pseudoscalar-baryon channels in the dynamically generated vector-baryon resonances

We study the interaction of vector mesons with the octet of stable baryons in the framework of the local hidden gauge formalism using a coupled-channels unitary approach, including also the pseudoscalar-baryon channels which couple to the same quantum numbers. We examine the scattering amplitudes and their poles, which can be associated to the known J ^P = 1/2⁻, 3/2⁻ baryon resonances, and determine the role of the pseudoscalar-baryon channels, changing the width and eventually the mass of the resonances generated with only the basis of vector-baryon states.     

Ursell operators in statistical physics of dense systems: the role of high order operators and of exchange cycles

The purpose of this article is to discuss cluster expansions in dense quantum systems, as well as their interconnection with exchange cycles. We show in general how the Ursell operators of order l≥ 3 contribute to an exponential which corresponds to a mean-field energy involving the second operator U₂, instead of the potential itself as usual - in other words, the mean-field correction is expressed in terms of a modification of a local Boltzmann equilibrium. In a first part, we consider classical statistical mechanics and recall the relation between the reducible part of the classical cluster integrals and the mean-field; we introduce an alternative method to obtain the linear density contribution to the mean-field, which is based on the notion of tree-diagrams and provides a preview of the subsequent quantum calculations. We then proceed to study quantum particles with Boltzmann statistics (distinguishable particles) and show that each Ursell operator U_n with n≥ 3 contains a “tree-reducible part”, which groups naturally with U₂ through a linear chain of binary interactions; this part contributes to the associated mean-field experienced by particles in the fluid. The irreducible part, on the other hand, corresponds to the effects associated with three (or more) particles interacting all together at the same time. We then show that the same algebra holds in the case of Fermi or Bose particles, and discuss physically the role of the exchange cycles, combined with interactions. Bose condensed systems are not considered at this stage. The similarities and differences between Boltzmann and quantum statistics are illustrated by this approach, in contrast with field theoretical or Green's functions methods, which do not allow a separate study of the role of quantum statistics and dynamics. Received 18 October 2001     

Potential energy of the K**-He quasimolecule

The potential curves of the nl(²Λ) electronically excited states of the K**-He quasimolecule (n, l, and Λ are the principal quantum number, angular momentum, and its projection on the molecular axis) are calculated. To describe the interaction of the weakly bound electron with the singly charged potassium ion and the ground-state helium atom (with taking into account their long-range electrostatic interactions), the formalism of two-center scattering theory and the finite-range pseudopotential method are used. A comparison with the results of calculations performed by the MRD CI method is carried out. The findings showed that, for small principal quantum numbers n, these methods complement each other, because the first is more reliable for large interatomic distances, R ≥ n, whereas second for small, R < n. The characteristic features of the behavior of the potential curves of the K**-He quasimolecule at large n and l are discussed.     

On the configuration of classical Yang-Mills fields with topological charge <Emphasis Type="Italic">k</Emphasis> = 4

The solutions of the nonlinear matrix equation in the Atiyah-Hitchin-Drifeld-Manin (AHDM) construction that determine the Yang-Mills self-dual fields with topological charge k = 4 for symplectic gauge groups are discussed. In the case of Sp(n), n > 2, it is possible to use a procedure that was proposed earlier for generating solutions with k = 3. It is shown that for SU(2) = Sp(1) the AHDM matrix can be generated by using cubic equation solutions with coefficients that depend on 8k — 3 parameters.     

One-and-a-Half Quantum de Finetti Theorems

When n − k systems of an n-partite permutation-invariant state are traced out, the resulting state can be approximated by a convex combination of tensor product states. This is the quantum de Finetti theorem. In this paper, we show that an upper bound on the trace distance of this approximation is given by , where d is the dimension of the individual system, thereby improving previously known bounds. Our result follows from a more general approximation theorem for representations of the unitary group. Consider a pure state that lies in the irreducible representation of the unitary group U(d), for highest weights μ, ν and μ + ν. Let ξ_μ be the state obtained by tracing out U _ν. Then ξ_μ is close to a convex combination of the coherent states , where and is the highest weight vector in U _μ. For the class of symmetric Werner states, which are invariant under both the permutation and unitary groups, we give a second de Finetti-style theorem (our “half” theorem). It arises from a combinatorial formula for the distance of certain special symmetric Werner states to states of fixed spectrum, making a connection to the recently defined shifted Schur functions [1]. This formula also provides us with useful examples that allow us to conclude that finite quantum de Finetti theorems (unlike their classical counterparts) must depend on the dimension d. The last part of this paper analyses the structure of the set of symmetric Werner states and shows that the product states in this set do not form a polytope in general.     

Quantum Gates and Quantum Algorithms with Clifford Algebra Technique

We use the Clifford algebra technique (J. Math. Phys. 43:5782, 2002; J. Math. Phys. 44:4817, 2003), that is nilpotents and projectors which are binomials of the Clifford algebra objects γ ^a with the property {γ ^a ,γ ^b }₊=2η ^ab , for representing quantum gates and quantum algorithms needed in quantum computers in a simple and an elegant way. We identify n-qubits with the spinor representations of the group SO(1,3) for a system of n spinors. Representations are expressed in terms of products of projectors and nilpotents; we pay attention also on the nonrelativistic limit. An algorithm for extracting a particular information out of a general superposition of 2 ⁿ qubit states is presented. It reproduces for a particular choice of the initial state the Grover’s algorithm (Proc. 28th Annual ACM Symp. Theory Comput. 212, 1996).     

Influence of the medium on the electromagnetic radiation spectrum of highly excited atoms and molecules

The influence of neutral species in the E- and D-layers of the Earth’s upper atmosphere on the spectrum of the spontaneous emission (absorption) of Rydberg atoms and molecules for transitions that occur without changing the principal quantum number (Δn = 0) is examined. Along with the process of l-mixing, the splitting of orbitally degenerate states due to interaction with perturbing neutral species of the medium is taken into account. The possible types of radiative transitions between them are analyzed. It is demonstrated that, for principal quantum numbers of n = 10–30, decimeter-band radiation corresponds to transitions between the levels of split states, whereas meter-band radiation, to transitions between their individual components. It is established that, for these values of n, the ratios of the intensities of the decimeter and meter bands for Δn = 0 transitions to the intensity of IR radiation (Δn = 1) are 10⁻⁴ and 10⁻⁶, respectively. The issue of satellite signal phase shift because of multiple Raman scattering in the D-layer of the atmosphere is discussed.     

Realization of the Spectrum Generating Algebra for the Generalized Kratzer Potentials

The dynamical symmetries of the Kratzer-type molecular potentials (generalized Kratzer molecular potentials) are studied by using the factorization method. The creation and annihilation (ladder) operators for the radial eigenfunctions satisfying quantum dynamical algebra SU(1,1) are established. Factorization method is a very simple method of calculating the matrix elements from these ladder operators. The matrix elements of different functions of r, r\fracddrr\frac{d}{dr}, their sum Γ₁ and difference Γ₂ are evaluated in a closed form. The exact bound state energy eigenvalues E _n,ℓ and matrix elements of r, r\fracddrr\frac{d}{dr}, their sum Γ₁ and difference Γ₂ are calculated for various values of n and ℓ quantum numbers for CO and NO diatomic molecules for the two potentials. The results obtained are in very good agreement with those obtained by other methods.     

Interference in Phase Space of Squeezed States for the Time-Dependent Hamiltonian System

We showed that the idea of Schleich and Wheeler (1987, Nature 326, 574) for the semiclassical approach of the interference in phase space of harmonic oscillator squeezed states can be extended to that of general time-dependent Hamiltonian system. The quantum phase properties of squeezed states for the general time-dependent Hamiltonian system are investigated by using the quantum distribution function. The weighted overlaps A _n and phases θ _n for the system are evaluated in the semiclassical limit.     

The hopf algebra of vector fields on complex quantum groups

We derive the equivalence of the complex quantum enveloping algebra and the algebra of complex quantum vector fields for the Lie algebra types A _n , B _n , C _n , and D _n by factorizing the vector fields uniquely into a triangular and a unitary part and identifying them with the corresponding elements of the algebra of regular functionals.Humboldt Fellow.     

Isospin dependence of electric-transition probabilities <Emphasis Type="Italic">B</Emphasis>(E2) in the unitary scheme

In a physical basis of the unitary scheme, analytic formulas for the probabilities B(E2κL → κ′L′) and their isospin factors for the (λ0) and (λ2) representations of the SU(3) group were obtained for even-even nuclei. It was shown that the isospin correction must be taken into account at low L and in the case of off-diagonal transitions in κ. The results obtained in the unitary scheme are compared with the results of other models and with experimental data. At high L, the transition probabilities B(E2κL → κ′L′) are markedly smaller in the unitary scheme than in the rotational model, while, for L ≪ λ, these probabilities in the unitary scheme and in the rotational model are close.