The ferromagnetic to antiferromagnetic transition in La1−x Y x Mn2Si2(57Fe) compounds

A set of La_1–xY_xMn₂Si₂(⁵⁷Fe) samples withx=0, 0.1, 0.15, 0.2, 0.25, 0.3, 0.5 and 1.0 have been prepared with the tetragonal ThCr₂Si₂ structure.⁵⁷Fe Mössbauer spectra have been collected at 4.2 K for all samples. The spectra can be well fitted by two sextets, the predominant one (90% of the spectral area) being associated with⁵⁷Fe atoms in the Mn 4d site, with the remainder located in the Si 4e site. The analysis shows that there are distinct changes in the hyperfine interaction parameters for samples above and below the critical concentrationx _c 0.15, at which a transition from ferromagnetism to antiferromagnetism occurs. This transition is a result of a change in the exchange interactions linked with changes in the interatomic distances, due to the smaller atomic volume of Y compared to that of La.On leave from Applied Acoustics Institute, Shaanxi Teachers University, Xian, PR China.     

Effect of hydrogen on the hyperfine magnetic field in crystalline Zr-Fe alloys

This paper deals with room temperature⁵⁷Fe Mössbauer studies performed on crystalline Zr_1–y Fe _y and Zr_1–y Fe _y H _x (0.05y0.5) alloys. For hydrogenated alloys, the transition from parato ferromagnetic behaviour is observed aty = 0.25, i.e. a considerably lower concentration of iron compared to uncharged alloys. It seems to be not only attributable to ZrFe₂ formation. Apart from ZrFe₂, a relatively intensive and quite different than the ZrFe₂ contribution to theP(B) distribution has been observed for hydrogen charged alloys with only 25 at.% Fe. It is linked to the origin of the additional magnetic component due to hydrogen absorption in which Fe has less than 6 Fe nearest neighbours.     

Electronic Structure of Nanostructured Nickel Oxide Using Ni 2p XPS Analysis

We examine the electronic structure of nanostructured nickel oxide with an average particle size of 4–5nm using Ni 2p X-ray photoelectron spectrum. The most striking features of the spectrum are the Ni 2p main line broadening and an increase in the relative intensity of the 1.5eV satellite. We explain the observations as due to an enhancement in the non-local screening process on the basis of Ni₇O₃₆ cluster model by taking into account the large surface area to volume ratio and high Ni²⁺ vacancy concentration in nanostructured nickel oxide. The important contribution of an enhanced Ni 3d–O 2p hybridization and the origin of shake-up peaks above the 7eV satellite is also discussed. The study underlines the importance of factors such as the actual local environment of the core hole site, defect density and distribution, possible structural transitions, etc. in determining the Ni 2p core level X-ray photoelectron spectrum of nanostructured nickel oxide and shows that the actual synthesis routes and the thermal history greatly influence the electronic structure of nanostructured nickel oxide.     

The magnetic moment of103Ru

The nuclear magnetic moment of¹⁰³Ru has been determined using the technique of low-temperature nuclear orientation on¹⁰³Ru as a dilute impurity in Fe. The Fe lattice was cooled to 1.7 mK using a PrNi₅ enhanced nuclear demagnetisation stage precooled with a³He–⁴He dilution refrigerator. The¹⁰³RuFe system was observed to have a long nuclear spin-lattice relaxation time, but analysis of the relaxation indicates that the¹⁰³Ru nuclei are close to thermal equilibrium with the Fe lattice at times>200 min after demagnetising. From the near thermal equilibrium anisotropy of the 497 keV -ray in¹⁰³Rh we have deduced the nuclear magnetic moment as |(¹⁰³Ru)|=0.18(2)_N. This value is almost independent of the choice of spinI=3/2 or 5/2 for the nucleus, but is only consistent with systematics ifI(¹⁰³Ru)=3/2 and <0. UsingI=3/2 we obtain the E2/M1 mixing ratio of the 497 keV -ray as =–0.42(4). The sign of the anisotropy of the 610 keV -ray from the 650 keV level in¹⁰³Rh is only consistent with an allowed -decay to the state ifI(650 keV,¹⁰³Rh)=5/2. The E2/M1 mixing ratio of the 610 keV -ray is then =+0.15(3) or +60( _–40 ⁺ ), <–80. From the initial rise in -ray anisotropy following demagnetisation we determine the Korringa constant for¹⁰³RuFe to beC=5.7(5) K·s.     

Electric field gradient at100Rh in HCP zirconium and gadolinium

The measurement of QI frequencies at¹⁰⁰Rh in Zr and Gd reveal that the electronic contribution to the EFG is quite large. The value of ¦K¦ is 8 for¹⁰⁰RhZr whereas it is 45 for¹⁰⁰RhGd. The temperature variation of¹⁰⁰RhZr neither follows T^1.5 nor has a linear T dependence.     

Anion dependence of the valence state detrapping behavior for a fused hydrocarbon bridged binuclear mixed valence iron compound and its di-oxygen sensitivity

Monocationic forms of the symmetric and asymmetric indacene bridged species [(Cp^*Fe)₂(-s-indacene)],I, and [(Cp^*Fe)₂(-as-indacene)],II, are fully detrapped and trapped, respectively, over the entire range from 1.5 K to ambient temperature as their BF ₄ ^– salts. In contrast to [II ⁺][BF ₄ ^– ], the TCNE^.– salt [II ⁺][TCNE^.–] exhibits a transition from fully trapped to a largely detrapped valence state behaviour over the increasing temperature range 100 to 300 K. Mössbauer spectra ofI suggest that while it is relatively insensitive to oxygen as a neat solid, it is strongly oxidized by O₂ in dry hexane solution. Similar studies ofII indicate essential insensitivity to O₂, both as a solid and in hexane solution.     

Infrared phonon spectra of 3d-metal doped YBa2(Cu1-x M x )3O7-δ

Infrared (IR) absorption spectra of doped YBa₂(Cu_1–x M _x )₃O_7–, with M representing Co, Fe, Ni, and Zn were observed as a function of concentrationx. TheB _1u IR mode at 580 cm^–1 was observed for all samples which were in the orthorhombic phase, which includes all the Ni and Zn doped samples and the lower concentrations (x<2.5%) for Fe and Co samples. The tetragonal phase of Co and Fe systems (x%>2.5%) shows three new IR modes at 655 cm^–1, 340 cm^–1, and 175 cm^–1. The frequency of the B_1u mode at 580 cm^–1 remains unchanged for all the Ni and Zn concentrations. In contrast, this mode shows a strong monotonic frequency softening with increase in Co substitution, while in the Fe-system it shows a comparable monotonic mode softening for 3%x%0%, and then remains unchanged for 12%x%3%. These observations indicate that Fe and Co substitute on the Cu(1) sites, whereas Ni and Zn most likely substitute on Cu(2) sites. We attribute the difference in the mode softening for Co and Fe to different Cu(1) local environments for these two elements. Indication for a chain-plane charge transfer based on our results is also discussed.     

Internal conversion study on the contact charge density of57Fe impurity atoms in Au metal

Three different internal conversion spectra were measured on the 14.4 keV transition of⁵⁷Fe in Au metals. Adaptability of our method for analysing the line intensity, i.e. the deconvolution-reconvolution method with the constant tail fraction rule was tested experimentally. The obtained 4s electron densities, 4_s(o), of Fe impurity atoms in Au agreed on four samples within the error. The weighted mean value of 4_s(o) of Fe in Au is 4.98±0.68a ₀ ^–3 . It is concluded that the method of analysis is reasonable in this type of experiment.     

A Mössbauer study of rapidly quenchedCuFe alloys — Antiferromagnetic γ-Fe

A series ofCuFe alloys containing 5, 10 and 16 at% Fe has been prepared using standard ribbon spinning techniques. It is found that samples containing significant fractions ( 5%) of Fe in the form of r-Fe can be obtained readily on quenching from the (r + liquid) phase, applied field spectra (0–5.2 T) on antiferromagnetic r-Fe at 4. 2 K indicate that the anisotropy energy is small and that spins tilt from the minimum energy configuration (spin axes perpendicular to B_appl) for B_appl 2.5T.     

A high flux,liquid-helium cooled source of metastable rare gas atoms

We have developed a novel, high flux source of metastable rare gas atoms (helium, neon and argon) that uses liquid helium cooling to reduce the initial atomic velocity. Fluxes exceeding 10¹⁴ atoms/ster/s with He and Ne were obtained. With average velocities of 600 m/s for He and 300 m/s for Ne and Ar, this source will enable simpler, more compact beam lines for loading magneto-optical traps. PACS 34.80.Dp; 39.10.+j; 39.25.+k     

Attenuation of powerful ruby laser pulses in the atmosphere by resonant absorption of water vapor

The attenuation of a ruby laser pulse at the wavelength = 6943.8å is calculated under conditions of spectroscopic saturation for a parallel beam and a diverging beam with divergence angle = 10^–5 rad. It is shown that deviation from the Bouguer law may reach 45% at a path length = 2 km for an initial power level of I₀ = 0.5I_s for the parallel beam, and 20% for I₀ = 0.25I_s for the divergent beam (I_s, saturation power).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 7–12, February, 1978.     

The hyperfine magnetic field of172Yb in Fe and Ni

Time-differential perturbed angular correlation measurements have been performed on the 91–1095 keV -ray cascade emitted by¹⁷²Yb nuclei in the capture decay of¹⁷²Lu, using implanted sources of¹⁷²Lu in Fe and Ni. From these measurements hyperfine field valuesB(YbFe)=–1253±83 kG andB(YbNi)=–143±12 kG follow at room temperature. From the modulation amplitude of the spectra it follows that only about 20% of the ytterbium nuclei participate in the precession.     

Spectroscopic trace-gas sensor with rapidly scanned wavelengths of a pulsed quantum cascade laser for in situ NO monitoring of industrial exhaust systems

Development of a pulsed quantum cascade laser (QCL)-based spectroscopic trace-gas sensor for sub-part-per-million detection of nitric oxide (NO) and capable of monitoring other molecular species such as CO₂, H₂O, and NH₃ in industrial combustion exhaust systems is reported. Rapid frequency modulation is applied to the QCL to minimize the influence of fluctuating non-selective absorption. A novel method utilizes only a few laser pulses within a single wavelength scan to probe an absorption spectrum at precisely selected optical frequencies. A high-temperature gas cell was used for laboratory evaluation of the NO sensor performance. A noise-equivalent sensitivity (1) of 100 ppb × m/ at room temperature and 200 ppb × m/ at 630 K was achieved by measuring the NO R(6.5) absorption doublet at 1900.075 cm^–1.     

Study of hexagonal R-type BaFe4Sn2O11 by57Fe and119Sn Mössbauer spectroscopy

Mössbauer data have been obtained from both the⁵⁷Fe and¹¹⁹Sn isotopes for BaFe₄Sn₂O₁₁. Variable temperature studies show that magnetic ordering occurs at 77K and is probably complete at 4K. Average hyperfine fields of 504kG and 45kG were observed at the iron and tin nuclei respectively.     

Local spin correlations in partially frustrated amorphous Fe-Mn

Mössbauer measurements in a-(Fe_0.765Mn_0.235)₇₈Sn₂Si₆B₁₄ have been performed with⁵⁷Fe and¹¹⁹Sn. Both hyperfine fields show a kink near 70 K, indicating a freezing of the transverse spins. The ratio of the two hyperfine fields contains information about the correlation of the transverse spins. The ratioB _hf(Sn)/B _hf(Fe) stays constant aboveT _xy and rises belowT _xy . This indicates an alignment of the transverse spins on a local scale, as was also found inAuFe and a-FeZr.     

Probing depth of the low energy cascade electrons from a transition metal

A surface probing depth of only 2 layers for low energy cascade electrons excited with a 3.2 keV primary electron beam is clearly demonstrated by model experiments with non-magnetic overlayers of Ta on magnetic substrates of Fe/Ni₈₀Fe₂₀. This result establishes a short probing depth of low energy electrons in transition metals generalizing the previously observed short magnetic probing depth for spin-polarized electrons in ferromagnets. The short probing depth sheds new light on a number of spectroscopic observations on ferromagnetic transition metals, and has important implications concerning surface magnetic properties and scattering processes of hot electrons in transition metals.     

Influence of linear elastic stresses on dynamic magnetostriction of cold-rolled transformer steel

The anisotropy of dynamic magnetostriction is investigated without external stresses, in extension, and in compression. Results are obtained expressing the (B) dependence for constant elastic stresses and also — () for certain induction values. Oscillograph traces are taken of the (H) and B(H) hysteresis loops with the specimens under investigation in extension and compression.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 110–115, May, 1977.     

Hydrogen-like recombination X-ray lasers using ps pulse drivers

We propose a scheme for producing high gain recombination X-ray lasers on hydrogen-like Balmer transitions by irradiating fibre targets with a 2 ps Chirped Pulse Amplification CPA beam of a Nd-glass laser facility. Very high gain coefficients for H-like C, N, O, F, Na Balmer transitions are predicted. The optimum electron density and temperature for maximum gain operation scale approximately asN _e 4 × 10¹³ Z ⁷ cm^–3 and T_e 7 × 10^–3 Z ⁴ eV, respectively, at the time when maximum lasing gain appears. Significant improvement in gain performance of recombination X-ray lasers is predicted by using CPA ps pulse drivers.     

On the interface stiffness of the random field ising model

Recent results of Grinstein, Ma, Villain and Binder on interface roughening incontinuum andlattice random field Ising models are related by introducing an effective interface stiffness function {ei247-1}. Ford3 dimensions the continuum theory is shown to be valid for non-zero random field strengthh for all temperatures and on a length scaleL>l _d (h,T) _d (h,T). Ford=2 and smallT a smeared spin-glass transition occurs at ₂(h,T)h. It is argued, that for 3<d<5 interface roughening occurs only forh larger than a critical field strengthh _R (T).