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1.
对Fe735Cu1Nb3Si135B9等非晶合金进行了退火和激波诱导两种方式的晶化实验以及XRD和DSC分析.着重对合金的晶化速率和晶化度等特性展开了研究和讨论.进一步证实了激波纳米晶化是一种包含着新机理的寓意丰富的晶化现象.也再次验证了作者曾经提出过的“激波流化相变”模型的合理性. 关键词: 非晶合金 激波 纳米晶化  相似文献   

2.
对Fe73.5Cu1Nb3Si13.5B9等非晶合金进行了退火和激波诱导两种方式的晶化实验以及XRD和DSC分析.着重对合金的晶化速率和晶化度等特性展开了研究和讨论.进一步证实了激波纳米晶化是一种包含着新机理的寓意丰富的晶化现象.也再次验证了作者曾经提出过的"激波流化相变"模型的合理性.  相似文献   

3.
Fe73.5Cu1Nb3B9Si13.5非晶态合金的激波纳米晶化研究   总被引:3,自引:0,他引:3       下载免费PDF全文
周效锋  刘应开  刘佐权  李德修 《物理学报》1999,48(11):2098-2103
实验表明,非晶态合金在激波影响下会转变为纳米晶.最近的实验进一步发现,Fe73.5Cu1Nb3B9Si13.5非晶态合金中的Cu,Nb在激波晶化中的细化作用被抑制,且样品在这种转变之后作进一步的退火处理,其晶粒度变大而晶格常数变小.在激波晶化机理分析中提出了“激波流体晶化”构想. 关键词:  相似文献   

4.
FeCuNbBSi等多中Fe基非晶态合金激波晶化的DSC研究   总被引:1,自引:0,他引:1  
应用升温、等温和重复加热的DSC技术,对几种非晶合金的激波晶化和退化晶化作了对比研究,结果表明,尽管激波晶化时间极短,仅为退火晶化时间为10^-6--10^-8,但晶化度却极高,接近100%。激波晶化形成多种成分和结构的结晶相,形式上很像扩散性相变,然而其相变速率却是退火转变的千万倍,而且生成相十分稳定,这一现象用传统的固态扩散相变理论很难解释,激波晶化是一种新的晶化形式,是一种新的纳米合成技术。  相似文献   

5.
 应用升温、等温和重复加热的DSC技术,对几种非晶合金的激波晶化和退火晶化作了对比研究。结果表明,尽管激波晶化时间极短,仅为退火晶化时间的10-6~10-8,但晶化度却极高,接近100%。激波晶化形成多种成分和结构的结晶相,形式上很像扩散性相变,然而其相变速率却是退火转变的千万倍,而且生成相十分稳定,这一现象用传统的固态扩散相变理论很难解释。激波晶化是一种新的晶化形式,是一种新的纳米合成技术。  相似文献   

6.
非晶合金Fe73.5Cu1Nb3Si13.5B9的激波晶化及其特征   总被引:3,自引:0,他引:3       下载免费PDF全文
 研究了非晶合金Fe73.5Cu1Nb3Si13.5B9(FINEMET)的激波晶化。与退火晶化比较,激波晶化具有一系列鲜明特征,这些特征是固态下扩散性相变理论难以解释的,有深刻的物理内涵。  相似文献   

7.
 研究了Fe78B13Si9、(Fe0.99Mo0.01)78B13Si9非晶合金的激波晶化行为。激波是由氢-氧爆炸产生的。实验结果表明:激波能使非晶合金在微秒时间内晶化,晶化主相为α-Fe基固溶体,次晶化相为Fe3Si,且观察到α-Fe基因溶体晶格常数变小。用DTA分析进一步证实:激波晶化是比较完全的,晶化相相当稳定。  相似文献   

8.
林怀俊  朱云峰  刘雅娜  李李泉  朱敏 《物理学报》2017,66(17):176105-176105
非晶态合金在力学性能、耐磨耐蚀性、磁性等方面比传统晶态合金具有显著优势,是一类有优良应用前景的新型结构与功能材料.非晶态合金与氢相互作用可以产生很多有趣的物理化学现象和应用.本文从物理基础和材料应用两个方面评述非晶态合金和氢相互作用的研究进展,在物理基础研究方面,从氢在非晶态合金中的存在状态出发,讨论氢在非晶态合金中的溶解、分布、占位和扩散等相关物理问题,进而分析氢对非晶态合金的热稳定性、磁性、内耗、氢脆等的影响.在材料应用研究方面,对非晶态储氢合金、非晶态合金氢功能膜、吸氢改善非晶态合金的塑性和玻璃形成能力、氢致非晶化、利用非晶态合金制备纳米储氢材料等方面的研究进展进行评述.最后总结并展望有关非晶态合金与氢相互作用的研究和应用.  相似文献   

9.
何开元  周飞 《物理》1993,22(9):535-541
从非晶态合金的晶化出发,介绍了最近发展起来的新型优质软磁材料──纳米晶软磁合金.其中包含:(1)非晶态合金的晶化概念以及微晶析出对非晶态合金磁性的影响;(2)纳米晶软磁材料的发现及其具有的优良的综合磁性能;(3)分析了该合金优良磁性能的来源,介绍了目前理论上的解释.最后展望了该合金的发展趋势.  相似文献   

10.
吴东昌  黄林军  梁工英 《物理学报》2008,57(3):1813-1817
通过对Buschow提出的预测二元非晶态合金晶化温度的“最小空位”模型进行扩展,并进一步结合Miedema理论得到了一种预测三元非晶态合金晶化温度和晶化驱动力的理论方法.利用该方法计算了(Mg70.6Ni29.4)1-xNdx(x=5,10,15)非晶态合金的晶化温度、晶化驱动力以及晶化焓.其中晶化温度和晶化焓的理论预测值与实验值的相对误差分别小于8%和7%.同时发现较高的晶化驱动力会降低 关键词: 非晶态合金 晶化温度 晶化驱动力  相似文献   

11.
Nonlinear structures of lower hybrid wave in collision plasmas are studied using the two-fluid theory.The oscillatory shock wave is observed due to the effects of the electron-neutral collision and the density inhomogeneity.In the cold electron limit,the oscillatory shock wave becomes the ordinary shock wave.In the collisionless limit,the dominated equation becomes Kd V equation and the lower hybrid solitons arise.The amplitude of the nonlinear structure is depressed by the plasma inhomogeneity,but is hardly affected by the electron-neutral collision.  相似文献   

12.
The modified CCW relation is applied to analyzing the shock, detonation wave converging and the role of chemical reactions in the process. Results indicate that the shock wave is strengthened faster than the detonation wave in the converging at the same initial Mach number. Euler equations implemented with a detailed chemical reaction model are solved to simulate toroidal shock and detonation wave converging. Gasdynamic characteristics of the converging are investigated, including wave interaction patterns, observable discrepancies and physical phenomena behind them. By comparing wave diffractions, converging processes and pressure evolutions in the focusing area, the different effects of chemical reactions on diffracting and converging processes are discussed and the analytic conclusion is demonstrated through the observation of numerical simulations.  相似文献   

13.
Gasdynamic characteristics of toroidal shock and detonation wave converging   总被引:3,自引:1,他引:2  
Shock wave focusing is a fundamental problem in the shock wave research and the instantaneous impulse of high temperature and pressure generated at the focal points has been applied recently in industrial and medical researches[1]. There are several methods to create shock wave focusing, among which the more commonly-used one is to make a planar shock wave reflect from a concave surface, such as the elliptical or parabolic re- flector. Toroidal shock wave focusing has been proposed and investi…  相似文献   

14.
于明  孙宇涛  刘全 《物理学报》2015,64(11):114702-114702
针对爆轰波在炸药-金属界面上折射时由实验获得的金属折射冲击波压力与经典爆轰波极曲线理论预测的压力存在显著差异这一问题, 本文展开了进一步的理论和数值模拟分析研究. 首先通过分析指出经典爆轰波极曲线理论的缺陷, 并对爆轰波极曲线理论进行了改进, 改进爆轰波极曲线理论给出了炸药爆轰波折射类型以及折射冲击作用点处的压力值. 然后发展了一个基于次特征理论来数值求解爆轰反应流动控制方程的二阶中心型Lagrange方法, 并数值模拟了一个典型的炸药爆轰波折射实验. 改进爆轰波极曲线理论和数值模拟分析结果表明, 爆轰波折射类型有三种:反射冲击波的正规折射、带Mach反射的非正规折射、无反射波的正规折射, 并且金属折射冲击波压力值随入射角增大而单调减小.  相似文献   

15.
本文从实际气体有粘流的激波厚度解,用分子运动论讨论了激波内部导热问题,并且通过重组范诺流和瑞利流的选加提出了激波中导热问题的物理模型和相应的定态激波非平衡态不可逆过程的模型。证明了激波是一种负熵流波,是依靠激波波速输运热流的热波。  相似文献   

16.
A shock wave that is characterized by sharp physical gradients always draws the medium out of equilibrium. In this work, both hydrodynamic and thermodynamic nonequilibrium effects around the shock wave are investigated using a discrete Boltzmann model. Via Chapman–Enskog analysis, the local equilibrium and nonequilibrium velocity distribution functions in one-, two-, and three-dimensional velocity space are recovered across the shock wave. Besides, the absolute and relative deviation degrees are defined in order to describe the departure of the fluid system from the equilibrium state. The local and global nonequilibrium effects, nonorganized energy, and nonorganized energy flux are also investigated. Moreover, the impacts of the relaxation frequency, Mach number, thermal conductivity, viscosity, and the specific heat ratio on the nonequilibrium behaviours around shock waves are studied. This work is helpful for a deeper understanding of the fine structures of shock wave and nonequilibrium statistical mechanics.  相似文献   

17.
This study is focused on the propagation behavior and attenuation characteristics of a planar incident shock wave when propagating through an array of perforated plates. Based on a density-based coupled explicit algorithm, combined with a third-order MUSCL scheme and the Roe averaged flux difference splitting method, the Navier–Stokes equations and the realizable k-ε turbulence model equations describing the air flow are numerically solved. The evolution of the dynamic wave and ring vortex systems is effectively captured and analyzed. The influence of incident shock Mach number, perforated-plate porosity, and plate number on the propagation and attenuation of the shock wave was studied by using pressure- and entropy-based attenuation rates. The results indicate that the reflection, diffraction, transmission, and interference behaviors of the leading shock wave and the superimposed effects due to the trailing secondary shock wave are the main reasons that cause the intensity of the leading shock wave to experience a complex process consisting of attenuation, local enhancement, attenuation, enhancement, and attenuation. The reflected shock interactions with transmitted shock induced ring vortices and jets lead to the deformation and local intensification of the shock wave. The formation of nearly steady jets following the array of perforated plates is attributed to the generation of an oscillation chamber for the inside dynamic wave system between two perforated plates. The vorticity diffusion, merging and splitting of vortex cores dissipate the wave energy. Furthermore, the leading transmitted shock wave attenuates more significantly whereas the reflected shock wave from the first plate of the array attenuates less significantly as the shock Mach number increases. The increase in the porosity weakens the suppression effects on the leading shock wave while increases the attenuation rate of the reflected shock wave. The first perforated plate in the array plays a major role in the attenuation of the shock wave.  相似文献   

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