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1.
MoS2摩擦表面氧化与电子转移   总被引:2,自引:0,他引:2  
利用电子自旋共振谱(ESR)和X射线光电子谱(XPS)研究了MoS2摩擦表面的氧化行为和摩擦表面氧化的电子转移,发现Mo2在摩擦失效过程中Mo^4+与氧作用生成稳定的Mo^6+终态氧化物,其间经过Mo^5+过渡态。深入揭示了MoS2摩擦表面氧化过程的复杂性,指出Mo在摩擦表面氧化过程中以多种化学状态存在,Mo原子的氧化是Mo4d轨道上的单电子转移过程。  相似文献   

2.
采用XRD、EXAFS技术研究了不同Pd含量的Pd-Mo-K/Al2O3催化剂结构,并关联其合成低碳混合醇性能。结果表明,在氧化态Mo-K/Al2O3催化剂体系中添加Pd后,“K-Mo”物相晶粒变小,分散度提高,说明钯可能和钾钼物种发生了较强的相互作用。经硫化还原处理后,发生了氧硫交换,钼主要以MoS2物种形式存在,其粒度随着Pd含量的增加而明显减小。尺寸的显著变化可能导致MoS2与载体作用形式的  相似文献   

3.
采用等量分步浸渍法先后将Co与贵金属组份浸于CeO2上,经500℃焙烧2h,450℃氢气还原1h制得Co-Pt/CeO2和Co-Rh/CeO2催化剂。活性测试结果表明,贵金属与Co之间具有催化协同效应。对CO氧化,Pt与Co的协同效应较显著,而对富氧条件下CH4选择还原NO,Rh与Co的协同效应更为明显,XPS和EXAFS结果一致表明,经H2还原后,样品Co/CeO2、Co-Pt/CeO2和Co-  相似文献   

4.
氧化态K—MoO3/γ—Al2O3催化剂结构的EXAFS研究   总被引:1,自引:0,他引:1  
对Na2MoO4.2H2O,MoO3,(NH4)6Mo7O24.4H2O等结构典型的含钼化合物及氧化态K-MoO3/γ-Al2O3催化剂样品进行了EXAFS测试,并以Na2MoO4.2H2O为标样进行多层拟合计算,以研究各样品钼组分的配位结构。  相似文献   

5.
Mo2N催化剂的XPS研究   总被引:1,自引:0,他引:1  
用XPS考察了制备温度、钝化气氛和氢还原活化温度对Mo2N催化剂表面的影响,在400℃氨可将MoO3中的Mo还原到+4价;继续升温到700℃氨还原后,则Mo^2+成为主要组分,钝化样品的表面存在着来自氨的吸附氨和晶格氮两种不同的形式。而在表面钝化过程中引入的氧则在催化剂表面形成氧化薄层。经高温氢还原后,80%以上的氧物种可被除去,结合TDS,XRD和热分析等其它研究结果,对Mo2N表面的钝化的活化  相似文献   

6.
碳化钼催化剂的XPS研究   总被引:5,自引:0,他引:5  
用程序升温碳化法在CH4/H2气流中,由前驱体MoC2/C出发,制备了活性炭担载斩高分散Mo2C/C催化剂,并用XPS和XRD等方法考察了制备温度,钼含量,钝化处理和氢还原活化对催化剂表面状态的影响,680℃碳化制得的具有高甲烷活性的Mo2C/C催化剂表面钼中以Mo^4+组分为主,Cls单峰位于284.5eV未发现反映C-Mo键合的低结合能的Cls峰,600℃氢还原后,表面的O/Mo原子比仍在0.  相似文献   

7.
Ba,Sr,Ca在Co/γ—Al2O3催化剂上CO氧化的作用机制(II)   总被引:2,自引:0,他引:2  
用硝酸盐水溶液等量共浸法制备了分别在750℃和900℃焙烧的系列催化剂Co-M/γ-Al2O3(M=Ca,Sr,Ba,Co3O4/Al2O3=8wt%,M/Co=15mol%)测定了CO氧化转化率,用BET表面,XRD,XPS,DTA和TPR等手段研究了助剂Ba,Sr,Ca的作用,结果表明,加入助剂后,CO完全转化温度下降了20~60℃左右,助剂的作用顺序为Ca>Sr>Ba,实验表明,750℃和9  相似文献   

8.
拉曼光谱研究Pt电极上欠电位沉积Sn对甲醇氧化的影响   总被引:2,自引:0,他引:2  
本文采用拉曼光谱研究Pt电极上欠电位沉积(亚)单原子层的Sn对甲醇氧化的影响,初步的结果表明,欠电位沉积Sn促进了Pt上甲醇的电催化氧化,与纯Pt电极体系相比较,作为表面毒性中间物的CO在较负电位下即可被氧化。本文对其可能的机理进行了初步的讨论  相似文献   

9.
通过比较多种杂多酸及铬酸盐等纯化剂的钝化效果,发现H3PMo12O40是一种优良的纯化剂。在55℃,pH1.0的条件下,A3钢在20g/L的H3PMo12O40溶液中能形成致密的耐蚀性保护膜。AES结合Ar^+溅射测得膜的元素组成为:P1.9%,Mo17.9%,O69.6%,Fe10.7%.XPS测得膜中Mo以Mo(Ⅵ)、Mo(V)t Mo(Ⅳ)三种氧化态存在。红外及Raman光谱表明,膜的主要振  相似文献   

10.
用XPS研究了紫青铜K0.9Mo6O17和蓝青铜K0.3MoO3的电子结构,根据测得的Mo3d芯级电子谱表明,紫,蓝青铜分别含有Mo^6+,Mo^5+,Mo^4+和Mo^6+,Mo^5+离子,其平均价态数分别为5.52和5.73,通过对两种晶体的芯电子谱和价带谱的比较认为,不同化学计量比的K离子对它们的电子结构影响是十分敏感的。  相似文献   

11.
The platinum-gold bimetallic nanoparticles supported poly(cyclotriphosphazene-co-benzidine)-grafted graphene oxide (poly(CP-co-BZ)-g-GO) composite has been prepared for electrochemical performance studies. Cyclic voltammetry and chronoamperometric studies were carried out to check the electrochemical properties of Pt-Au/poly(CP-co-BZ)-g-GO and Pt/poly(CP-co-BZ)-g-GO catalysts for methanol, ethylene glycol and glycerol in alkaline medium. The morphology and crystalline structure of the prepared Pt-Au/poly(CP-co-BZ)-g-GO and Pt/poly(CP-co-BZ)-g-GO and catalysts have been characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and fourier transform infrared spectroscopy (FT-IR). From the electrochemical results, it was concluded that Pt-Au/poly(CP-co-BZ)-g-GO catalyst shows higher catalytic activity and stability compared to Pt/poly(CP-co-BZ)-g-GO catalyst. The catalytic activity of Pt/poly(CP-co-BZ)-g-GO catalyst has been compared with Pt/poly(CP-co-BZ), Pt/GO and Pt/C catalysts. In addition, oxidation current of ethylene glycol is higher than the methanol and glycerol in alkaline medium on the prepared catalyst.  相似文献   

12.
一种软X射线多层膜界面粗糙度的计算方法   总被引:2,自引:2,他引:0  
提出一个利用多层膜小角X射线衍射谱衍射峰积分强度计算多层膜界面粗糙度的公式。用磁控溅射技术制备Mo/Si多层膜,用波长为0.154nm的硬X射线测量样品在小掠入射角区的衍射曲线,分别用本文公式和反射率曲线拟合方法计算了样品的界面粗糙度。实验结果表明:由本文公式获得的界面粗糙度近似于拟合方法获得的界面粗糙度,它们略等于多层膜界面实际粗糙度。  相似文献   

13.
In this work, boron doped multi-walled carbon nanotubes (BMWNTs) were introduced as a Pt catalyst support due to their unique physicochemical properties. The effect of BMWNTs on methanol oxidation was investigated with different Pt loading contents. The surface and structural properties of the modified MWNT supports were characterized by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD), respectively. The Pt loading contents in the catalysts were confirmed by inductive coupled plasma-mass spectrometer (ICP-MS) and the morphological structures of the catalysts were analyzed by transmission electron microscopy (TEM). The electrocatalytic activity of Pt/MWNTs was investigated by cyclic voltammetry measurement. As a result, the boron oxide vapor reacted with MWNTS to form BMWNTs, which led to enhancing the properties, such as graphitization and electrochemical behaviors. Moreover, Pt deposited on BMWNTs exhibited better electrocatalytic activity than on MWNTs for methanol oxidation. Consequently, it was found that partial boron doped MWNTs could influence on the properties of the MWNTs, resulting in enhancing the electrocatalytic activity of the catalysts for DMFCs.  相似文献   

14.
介绍了软件X射线多层膜分束镜的制备,采用蚀基底法和氯化钠脱膜分离法制备且获得了大面积的Mo/Si多层膜分束镜。  相似文献   

15.
Ordered mesoporous carbons CMK-3 with various morphologies are synthesized by using various mesoporous silica SBA-15 as template and then support to prepare Pt/CMK-3 catalyst. The obtained catalysts are compared in terms of the electrocatalytic activity for methanol oxidation in sulfuric acidic solutions. The structure characterizations and electrochemical analysis reveal that Pt catalysts with the CMK-3 support of large particle size and long channel lengths possess larger electrochemical active surface area (ECSA) and higher activity toward methanol oxidation than those with the other two supports. The better performance of Pt/CMK-3 catalyst may be due to the larger area of electrode/electrolyte interface and larger ECSA value of Pt catalyst, which will provide better structure in favor of the mass transport and the electron transport.  相似文献   

16.
不同环境中X射线激光Yb靶表面氧化研究   总被引:1,自引:1,他引:0       下载免费PDF全文
 用电子束蒸发方法淀积制备X射线激光稀土元素Yb薄膜靶,将薄膜靶在不同的环境气氛中进行氧化。用X射线光电子谱(XPS)、俄歇电子谱(AES)和X射线衍射(XRD)方法研究了Yb薄膜靶表面氧化层的元素价态、组分和微观结构。发现薄膜表面氧化层中存在分层结构,干燥空气中储存的Yb薄膜表面氧化层由表及里的组分依次为化学吸附水、氢氧化物、氧化物及金属元素。表面氢氧化物和氧化物以非晶态形式存在。潮湿空气中水分是薄膜靶氧化速率增加的主要原因。  相似文献   

17.
A composite electrode of Pt nanoparticles coupled with tourmaline is prepared on glassy carbon (GC) disk electrode via electrodeposition. The nanocomposite of Pt/tourmaline is characterized by scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray powder diffraction, and transmission electron microscopy examinations linked with energy dispersive X-ray analysis. The electrocatalytic performance of the composite electrode (Pt/tourmaline/GC) is investigated in electrocatalysis oxidation of methanol at room temperature by cyclic voltammetry and chronoamperometry. It is indicated that Pt nanoparticles with size of ∼5 nm are uniformly assembled along the tourmaline particles and Pt exists in metallic and oxidated states confirmed by XPS. The results of electro-oxidation of methanol show that Pt/tourmaline catalyst is catalytically more active and stable than platinum-modified GC electrode, and the onset potential of Pt/tourmaline shifts 0.15 V to the negative side, and also the current density is significantly enhanced.  相似文献   

18.
本文利用光电子能谱(XPS)和质谱(MS)研究了12种有机锡化合物。通过XPS和MS讨论了化合物中取代基对锡内层电子的影响及对SnO键的影响。结果表明XPS和MS对有机锡化合物某些化学键性质的讨论具有互补性。  相似文献   

19.
The morphology of the platinum (Pt) nanoparticles has a significant effect on their activity for the catalytic oxidation of the volatile organic compounds (VOCs). In this work, the preparation of the dendritic and spherical Pt by a solution‐based approach is reported, which is supported on γ ‐ Al2O3 substrates, for decreasing the temperature of the complete conversion of benzene, one of the representative contaminants among the VOCs because of its carcinogenicity. The X‐ray photoelectron spectroscopy analyses reveal that the surface adsorbed oxygen is crucial for catalytic performance, and the electron transference from Pt to O is a benefit for the activation of oxygen. H2‐TPR results indicate that the reducibility of the catalyst has a significant effect on the catalytic activity for the catalytic oxidation. In general, the dendritic Pt/Al2O3 catalysts, which possess more abundant and active surface adsorbed oxygen, exhibit the higher activity for the complete catalytic conversion of benzene compared with the spherical one. Moreover, the addition of a small amount of Ag (or Au), which is in order to ensure the dendritic structure, has little influence on the catalytic activity. The versatile solution‐based synthesis will be a promising method for creating the highly efficient catalysts for environmental remediation.  相似文献   

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