Spectral Properties of Single BODIPY Dyes in Polystyrene Microspheres and in Solutions

The absorption, fluorescence, fluorescence quantum yield, and photostability of five BODIPY dyes are characterized and compared as single dyes in two environments, in 40-nm polystyrene spheres and in solution. The absorption and fluorescence spectra of the dyes in spheres are similar in profile but shifted to lower energies compared to those in solution. All the dyes are highly fluorescent, with three having fluorescence quantum yields of 1.0. For three of the five dyes, the yields were the same in spheres as in solution (1.00, 1.00, and 0.73). The high concentration of these dyes in spheres does not quench their fluorescence. For two other dyes the yields dropped, from 1.00 to 0.55 in one case and 0.83 to 0.50 in another, comparing the dyes in solution versus in spheres. The photodegradation of the dyes decreases in spheres compared to in solution in all but one case. For one dye, it decreases as much as 800-fold. Dyes overlooked because of low fluorescence or stability in solution could become useful fluorescent materials in the microsphere environment.     

Effect of ausforming temperature and strain on the bainitic transformation kinetics of a low carbon boron steel

The effect of ausforming temperature and strain on the bainitic transformation kinetics was investigated in a low carbon boron steel. A new mechanism, which is based on the competition between the increase in nucleation rate and the decrease in average volume of bainite sheaf after deformation, is proposed. The increase in nucleation rate is due to the decrease in boron concentration at the grain boundaries after small deformation and the formation of sub-grain boundaries at the grain interior after large deformation. The decrease in average volume of bainite sheaf is ascribed to the frequent impingement of bainite sub-units after deformation. The increase in nucleation rate after deformation results in the decrease in incubation time, which is confirmed from the experiment. The increase in nucleation rate overcomes the decrease in average volume of bainite sheaf, resulting in the increase in transformation velocity and volume fraction after small deformation. On the contrary, the decrease in the average volume of bainite sheaf overcomes the increase in nucleation rate after large deformation, leading to the decrease in transformation velocity and volume fraction of bainite.     

序列脉冲激光在不同大气模型下的热晕效应研究

考虑到大气中吸收系数随高度变化,通过内插法得到不同大气模型一定高度下大气的吸收系数,建立序列脉冲激光在地对空垂直传输的热晕模型。通过数值计算方法分析风场渡越时间内脉冲数为2时的序列脉冲在中纬度地区夏季和冬季、热带地区、近北极地区夏季和冬季5种大气模型下的热晕效应。结果表明:当光束孔径为0.25 m,初始功率为200 kW,波形为高斯状的激光束在近北极冬季传输10 km后沿横轴方向光强峰值偏移0.056 9 m,而热带光强峰值强度偏移最远为0.224 m,为近北极冬季时的4倍;脉冲激光在热带传输10 km后的靶面功率仅为15.06 kW,近北极冬季靶面功率为热带的10.5倍。热带地区的热晕效应最明显,中纬度地区次之,近北极地区最弱。激光在夏季传输要比冬季传输的热晕效应严重,而且近北极地区夏季要比中纬度地区冬季的热晕效应更严重。     

Contrastive analysis on tone between Putonghua and Taiwan Mandarin

The differences of the pitch and duration of Chinese syllables between Putonghua （PTH） and Taiwan Mandarin （TM） were studied. The speech materials to be used are not only isolated syllables, but also sentences. The results reveal that： For the isolated syllables, T1 and T2 in TM are influenced by Minnan dialect, therefore their pitch are lower than those in PTH. T3 is fall-rise in PTH, while it is fall in TM. Moreover, the syllable duration sequence for different tone is T3〉T2〉T1〉T4 in PTH, while it is T1〉T2〉T3〉T4 in TM. For the syllables in sentences, T2 is mid-rise in PTH, while it is mid-level in TM. And the T3 is longer than T4 but shorter than T1 or T2 in PTH, while it is the shortest in TM. Furthermore the effects of prosodic phrase boundary on duration for different tones are almost the same in PTH, but the lengthening part of T1 or T2 is longer than that of T3 or T4 in TM.     

石墨狭缝中甲烷吸附的分子动力学模拟

用分子动力学模拟研究石墨狭缝中甲烷的吸附,考察狭缝宽度和温度对甲烷吸附的影响.模拟发现甲烷在石墨狭缝中出现分层现象,吸附层中甲烷具有类液特征,第一吸附层内甲烷中总有两个氢原子的连线与另外两个氢原子的连线分别位于平行于狭缝壁的两个平面内,游离层中甲烷呈现气体的特征;碳原子间的平均作用势说明吸附层中甲烷分子间结合能力大于游离层,吸附态是甲烷在石墨狭缝中的主要赋存形式之一;伦敦力以及由吸附层净电荷产生的电场力是甲烷吸附和分层的主要原因;甲烷的吸附量随狭缝宽度增大或温度升高而减少,当狭缝宽度小于16.46Å时,甲烷仅以吸附形态存在.甲烷在第一吸附层中的扩散能力最弱、游离层中最强,甲烷扩散系数随狭缝宽度的增大或温度的升高而增大.     

ICP-AES测定云南楚雄糖尿病患者发样微量元素的研究

探讨微量元素与糖尿病间的关联性及临床意义。采用ICP-AES等离子体发射光谱仪测定了楚雄地区糖尿病患者人发中11种元素,采用2,3-二氨基萘荧光法测定发样中的硒元素。选取糖尿病患者120例,对照组35例。糖尿病组发样中常量元素Ca、Mg低于对照组,P高于对照组;除Cd、Cr、Fe外,微量元素Zn、Se、Ni、Mn、Cu等5种元素低于对照组,并有显著差异(P0.01)。糖尿病组间性别比较数据显示男性除发Ni、Mn、P外,其余元素含量均低于女性,其中发锌远低于女性。3个不同年龄段糖尿病人群的微量元素含量变化显示Fe、P2种元素随年龄增加含量增高;Mg、Cd2种元素随年龄增加含量减少;其余各元素变化情况为Fe、P元素在老年组中较高,Cu、Cd、Mg较低;Mn、Cr、Cu元素含量在中年组中较高,而Zn、Se略低;Zn、Se在青年组较高,而Mn、Cr低。城市人群发中Zn、Cd、Cu、Mg、Ca含量比农村人群高;Se元素含量二者间差别也不大,其余元素含量均低于农村人群。楚雄地区糖尿病患者发中Zn、Se、Mg、Mn4种元素水平低,楚雄地区糖尿病患者致病原因可能与地区属低Se水平和患者体内硒水平低有关。     

红外光谱法研究胆红素在溶液中的结构

本文详细地研究了胆红素在溶液中的结构,得到了很有实用价值的结果。     

Effect of the deletion of the C region on the structure and hydration of insulin-like growth factor 1: a molecular dynamics investigation

The structure and hydration of insulin-like growth factor 1 and an inactive mutant lacking the C region have been investigated in aqueous solution by molecular dynamics simulation. The overall structures of the two polypeptide resemble those determined by NMR spectroscopy. The deletion of the C region in the wild polypeptide introduces structural stability in the mutant, leading to a better definition of the secondary structure elements. A detailed hydration analysis was performed using the radial distribution functions and energy distributions. The backbone of the mutant is in general more solvent accessible than the wild polypeptide backbone. The structural rearrangements induced in the mutant led to changes in the solvent exposition of Tyr24 and Tyr60, which are residues important for ligand—receptor complex formation. Tyr24 exhibited a similar degree of solvent exposition in both IGF-I and in the mutant; however, its hydroxyl group in the wild polypeptide is better solvated than in the mutant. Tyr60 was found to be solvent exposed in the wild protein, while in the mutant the involvement of its hydroxyl group in intramolecular hydrogen bonds led to it being buried away from the solvent.     

Recent developments,challenges, and prospects of ultrasound-assisted oil technologies

There has been consistent drive towards research and innovation in oil production technologies in order to achieve improved effectiveness and efficiency in their operation. This drive has resulted in breakthrough in technologies such as the application of ultrasound (US) in demulsification and enhanced oil recovery (EOR), and usage of high-volume hydraulic fracturing and special horizontal well for shale oil and gas extraction. These can be observed in the increment in the number of commercial oil technologies such as EOR projects that rose from 237 in 1996 to 375 in 2017. This sustained expansion in EOR resulted in their total oil production rising from 1.5 million barrels per day in 2005 to 2.3 million barrels per day in 2020. And this is predicted to increase to about 4.7 million barrels per day in 2040, which represent about 4% of total production. Consequently, in this review, the developments in the utilization of US either as standalone or integrated with other technologies in EOR and dehydration of water in oil emulsions were analyzed. The studies include the optimization of fluid and US properties in EOR and demulsification. Reports on the treatment of formation damage resulting from inorganic salts, organic scales, drilling fluid plugs, condensate, paraffin wax and colloidal particle with US-assisted EOR were also highlighted. Moreover, the mechanisms were examined in order to gain insightful understanding and to aid research investigations in these areas. Technologies such as US assisted green demulsification, high intensity focused ultrasound, and potential pathways in field studies were assessed for their feasibilities. It is essential to evaluate these technologies due to the significant accrued benefits in them. The usage of green demulsifiers such as deep eutectic solvents, ionic liquids and bio-demulsifiers has promising future outlook and US could enhance their technical advancement. HiFU has been applied successfully in clinical research and developments in this area can potentiality improve demulsification and interfacial studies (fluid–fluid and solid–fluid interactions). As regards field studies, there is need to increase actual well investigations because present reports have few on-site measurements with most studies being in laboratory scale. Furthermore, there is need for more detailed modeling of these technologies as it would assist in conserving resources, saving research time and fast-tracking oil production. Additional evaluative studies of conditions such as the usage of Raschig rings, crude oil salinity and high temperature which have improved demulsification of crude oil emulsions should be pursued.     

Slowness surfaces, ray velocity surfaces and phonon focussing in highT c superconductor crystals

This paper reports the results of the study of anisotropy in elastic wave propagation in single crystal superconducting BSCCO. The inverse and group velocities of elastic waves propagating in different directions have been computed and the corresponding slowness and ray velocity surfaces plotted, taking elastic constant data from literature. In addition, the phenomenon of phonon focussing has been investigated in this material by computing the phonon enhancement factor along different directions in spherical polar coordinates. The abnormally high values in phonon enhancement factor exhibited in certain directions for the phonon modes are interpreted as due to caustics occurring in the geometrical acoustics approximation adopted in the computational analysis. The results in LSCO and YBCO are found to be similar to those in BSCCO.