准分子激光束的喇曼整形

受激喇曼散射可以将紫外准分子激光辐射频移到特定的近紫外和可见光波长.采用喇曼整形技术还可以获得衍射极限发散角的斯托克斯输出.本文研究了注入光束质量对喇曼整形的影响,并求得不同氢压力下的喇曼增益系数和饱和参量.     

蛋白质结构和功能的紫外共振喇曼光谱研究

紫外共振喇曼光谱技术是研究复杂大分子结构的有力工具。结合作者在美国Pittsburgh University期间所做的工作，介绍了用紫外共振喇曼光谱研究肽和蛋白质结构与功能的现状和进展，N-methylacetamide和glycyglycine水溶液光化学异构过程的紫外共振喇曼光谱研究，简述了紫外共振喇曼光谱实验技术要点。本文还跟踪国际最新研究成果，介绍了利用紫外共振喇曼光谱技术研究蛋白质的折叠和去折叠过程。     

用受激喇曼散射方法产生紫外皮秒激光探针测量

 将波长1053nm、能量60～100mJ、脉冲宽度800ps的基频光,经二倍频、四倍频转换作为H₂喇曼池的泵浦光,基于后向喇曼散射光的压缩原理,获得了波长296nm、能量约2mJ、脉冲宽度81ps的紫外超短脉冲激光,可用于ICF物理诊断实验。     

单纵模Nd:YAG激光泵浦H2气中的受激喇曼散射

用单纵模Nd:YAG激光(波长1.06μm,脉宽9ns,线宽0.003cm-1)泵浦氢气中的受激喇曼散射,产生很强的后向一级斯托克斯.当泵浦能量为120mJ,压力为1.5MPaH2时,后向和前向喇曼的光子转化效率分别为66%和15%,而在4MPa时两个数值分别为46%和39%.由于后向喇曼与前向喇曼和泵浦光的传播方向相反,二者的相互竞争产生了张弛振荡,使得后向和前向喇曼的时间波形都分裂为两个峰,后向喇曼的两个峰都被压窄到1ns,使峰值功率达到了泵浦光功率的二倍,这在前向喇曼是不可能的.而且后向喇曼的光束质量要大大优于泵浦光和前向喇曼的光束质量,在4MPaH2和脉冲重复频率为10Hz时,喇曼过程的放热使前向喇曼的光束质量变坏,但对后向喇曼的光束质量影响不大.计算表明,该实验条件下受激喇曼过程没有达到稳态,所有实验结果都可以而且只能用相关的瞬态受激喇曼理论解释.     

光纤中的紫外受激喇曼散射

用YAG∶Nd激光的三次谐波作激励光,我们在光纤维中观测了紫外受激喇曼散射。测定了受激喇曼散射的峰值波长,它们是3610(?)、3722(?)和3791(?)。指出了各受激喇曼线相应的散射元.     

长短脉冲间自同步的光探针

一、引言 在六路激光系统中,我们采用从主激光输出中分出一部分进行喇曼频率变换和脉冲压缩,获得了最短脉宽为25ps的630nm的光,用此喇曼光我们进行了等离子体的阴影、纹影、干涉和磁场的测量,得到了一系列有用的信息。我们将此喇曼光用BBO晶体倍频,进一     

部分离化激光等离子体的受激喇曼散射不稳定性

由于部分离化激光等离子体中存在束缚电子，它可显著改变其参量不稳定性。本文分析了部分离化激光等离子体的受激喇曼散射的非线性色散关系，计算了钕玻璃倍频和三倍频激光受激喇曼散射的增长率，结果表明，前向受激喇曼散射显著增强，后向受激喇曼散射影响不大。     

皮秒激光瞬态受激光喇曼散射的实验研究

本文采用对撞脉冲锁模Ｎｄ：ＹＡＧ激光器输出１０ｐｓ脉冲串，经ＫＴＰ非线性晶体腔外倍频，泵浦喇曼介质为二甲亚砜（ＤＭＳＯ）液体。实验研究了不同透镜焦长，焦点位置不及不同喇曼介质长度对瞬态受激喇曼散射的影响，获得了能量转换效率分别为４５．６％和１０．５％的前，后和同阶斯托克斯－喇曼射光，，并以实验结果进行了讨论。     

大气前向自发喇曼散射的距离积累效应

通过数值求解大气前向自发喇曼散射功率的传播方程，从理论上发现了大气前向自发散射喇曼距离的积累效应。     

全天时喇曼激光雷达探测大气水汽的技术实现及分光系统设计

为实现大气水汽的全天时测量,选用Nd∶YAG脉冲激光器的四倍频输出266.0nm作为激励光源,设计日盲紫外域喇曼激光雷达系统.由于低层大气污染造成的臭氧污染,通过增加大气氧气的振动喇曼散射信号测量通道,实时反演近地表臭氧浓度的分布,为修正激光雷达方程中的臭氧吸收提供解决方案.同时,选用高光谱分辨率光栅和窄带宽激光反射镜设计光栅光谱仪作为激光雷达的分光系统.仿真计算表明,入射角为10°时,设计的光栅光谱仪可有效分离并提取氧气、氮气和水汽的振动喇曼散射回波信号,日盲紫外喇曼激光雷达系统可实现全天时状态下2km高度范围内大气水汽的廓线探测.     

斯托克斯束的时空分布

基于在自由空间光束的分丰是已知的条件下，推导出适用于任意束分布的广义化的耦合波方程并得到一种计算受激拉曼散射过程中泵浦束与斯托克斯束的时、空分布的简单方法。所得结果清楚地示明受激拉曼散射过程既能使斯托克斯信号得到放大，又能使脉宽受到压缩。     

Cherenkov phase-matching in Raman-seeded four-wave mixing by a femtosecond Bessel beam

It is demonstrated experimentally that the angle vs. wavelength dependence of the emission generated by multi-step four-wave mixing process seeded by stimulated Raman scattering in water under femtosecond Bessel beam excitation is determined by the longitudinal phase-matching from IR to near UV. It is shown that if on-axis phase velocity of the pump Bessel beam is equal to the phase velocity of the Stokes axial wave, then, similar to Cherenkov radiation, all the other anti-Stokes beams too acquire that axial velocity.     

Influence of electron beam irradiation on structural and optical properties of α-Ag2WO4 nanoparticles

The influence of 8 MeV electron beam irradiation on the structural and optical properties of silver tungstate (α-Ag₂WO₄) nanoparticles synthesized by chemical precipitation method was investigated. The dose dependent effect of electron irradiation was investigated by various characterization techniques such as, X-ray diffraction, scanning electron microscopy, UV–vis absorption spectroscopy, photoluminescence and Raman spectroscopy. Systematic studies confirm that electron beam irradiation induces non-stoichiometry, defects and particle size variation on α-Ag₂WO₄, which in turn results changes in optical band gap, photoluminescence spectra and Raman bands.     

Measurement of nitric oxide concentrations in flames by using electronic-resonance-enhanced coherent anti-Stokes Raman scattering

We have measured nitric oxide (NO) concentrations in flames by using electronic-resonance-enhanced coherent anti-Stokes Raman spectroscopy (ERE-CARS). Visible pump and Stokes beams were tuned to a Q-branch vibrational Raman resonance of NO. A UV probe beam was tuned into resonance with specific rotational transitions in the (v"=1,v'=0) vibrational band in the A(2)Sigma(+)-X(2)Pi electronic transition, thus providing a substantial electronic-resonance enhancement of the resulting CARS signal. NO concentrations were measured at levels down to 50 parts in 10(6) in H(2)/air flames at atmospheric pressure. NO was also detected in heavily sooting C(2)H(2)/air flames at atmospheric pressure with minimal background interference.     

紫外拉曼光谱及其在催化研究中的应用

本文介绍了紫外拉曼光谱及其在催化研究中的应用。研究内容包括积炭 ,担载型过渡金属氧化物 ,分子筛 ,杂原子分子筛中骨架杂原子的识别和有机物的单层分散等。由于避开荧光干扰和使用较短波长的激发线提高了拉曼光谱的灵敏度和信噪比 ,特别是利用拉曼共振效应 ,不但灵敏度大幅度提高 ,而且与紫外吸收相关的局部结构被选择地鉴别。紫外拉曼光谱拓宽了拉曼光谱在催化 ,生物化学和材料科学等领域的应用。     

Effect of boron concentration on the UV photosensitivity of silica glass film for planar lightwave circuit

The photosensitivity dynamics in SiO₂ glass with a composition similar to that of silica planar lightwave circuit (PLC) devices was investigated as a fundamental study prior to device fabrication. Silica bulk glasses with similar composition to the core layer of PLC devices were prepared with various concentrations of B₂O₃. The photosensitivity in boron and germanium co-doped amorphous SiO₂ yields a refractive index change Δn as high as 10⁻³ after irradiation with a KrF UV laser beam. The index modulation disappeared after thermal annealing. The result of annealing experiment and UV absorption/Raman spectra revealed that the molar volume change by UV irradiation is responsible for the index variation in the material.     

紫外拉曼光谱研究钇掺杂的氧化锆体系表面相变

本文用紫外拉曼 ,近可见拉曼光谱和XRD检测了不同焙烧温度下Y2 O3-ZrO2 的相变过程。紫外拉曼光谱对样品表面相变极其灵敏 ,而近可见拉曼光谱和XRD提供的主要是体相和表面的混合信息。在紫外拉曼谱图中 ,只观察到单斜相的谱峰 ,没有明显的四方晶相的信号 ,这表明样品的表面主要是单斜晶相。然而 ,XRD和近可见拉曼光谱的结果显示Y2 O3-ZrO2 体相是四方晶相。焙烧温度超过 40 0°时 ,紫外拉曼 ,近可见拉曼和XRD晶之间明显不同的结果表明Y2 O3-ZrO2 在表面区四方相很易转变为单斜相 ,体相中的四方相由于钇的添加而稳定存在。根据紫外拉曼和XRD结果 ,当升高温度时 ,在样品的表面形成一单斜相层 ,体相钇稳定的四方相 ,且由于Y2 O3的存在抑制了单斜相进一步向体相发展。     

Structural modification of fullerene thin films by highly charged iron ions

In this paper, the results of structural modification of fullerene thin films bombarded by highly charged iron ions (Fe⁶⁺) are presented. The properties of as-deposited and irradiated fullerene thin films have been investigated by Raman spectroscopy, UV/Vis spectrophotometry and atomic force microscopy (AFM). The results of Raman spectroscopy have indicated structural changes of irradiated thin films depending on fluences. It was found that iron doped fullerene films are dominated by sp³ rather than sp² after bombardment which might be due to formation of nanodiamond structures. AFM analysis showed that the ion beam had destroyed the surface ordering. The optical band gap was found to be in the range of 0.6 to 1.4 eV for irradiated films by Fe⁶⁺ ions at the highest fluences. PACS 61.48.+c; 78.30.-j; 79.20.Rf     

TiO_2/石墨烯/Ag复合结构SERS实验

基于氧化物半导体的光催化特性,能够降解有机物分子,使表面增强拉曼散射基底得以重复使用。提出了银纳米颗粒有效修饰覆盖有石墨烯的二氧化钛纳米棒阵列(TiO_2/石墨烯/Ag)复合结构作为表面增强拉曼散射基底,并对其进行了实验研究。利用水热法制备了二氧化钛纳米棒阵列;采用湿法转移石墨烯和光照还原方法制备了TiO_2/石墨烯/Ag复合结构。用罗丹明6G(R6G)分子作为探测分子,结果表明:随着紫外光照沉积时间增加,探针分子的拉曼信号先增强后减弱;计算得到最大增强因子值约为2.6×106。此外,还对TiO_2/石墨烯/Ag复合结构的紫外自清洁特性进行了初步实验,结果表明,紫外光照射20min后,其拉曼强度下降到42.3%,具有一定的紫外清洁效果。