非全裸离子-原子碰撞中的多重电离研究

利用加速器提供的非全裸重离子束 (q=1 - 4)轰击氦、氖和氩原子 ,研究了由非全裸离子引起原子多重电离的有效电荷效应和电荷交换效应 .提出用一个有效电荷来等价描述非全裸入射离子对靶原子的作用 ,将描述全裸离子 -原子碰撞过程的物理模型推广到处理非全裸离子 -原子碰撞过程 ,采用轨道贯穿模型对有效电荷的内在物理机制进行了解释 ,提出一种新的理论方法将多重电离中俄歇过程的贡献予以扣除 .通过研究发现 ,扣除俄歇过程贡献后 ,多重电离截面随入射离子q/ v的变化与多步过程的预言相符.The partially stripped C q+ , O q+ and F q+ ions (q=1-4) delivered by a 2×1.7 MV tandem accelerator were employed to bombard He, Ne and Ar targets. The cross section ratios of multiple ionization to single ionization were measured for different collision systems by using time of flight technique. The effective charge effects and charge exchange processes were studied. By using an effective charge q eff , the multiple ionization processes induced by partially stripped ions could...     

强扰动能区非全裸Cq+,Oq+(q=1-4)与He原子碰撞过程中截面比的实验研究

利用兰州大学2×1.7MV串列加速器离子-原子碰撞实验终端上产生的单核子能量为20-500 keV的Cq+和Oq+(q=1-4)离子与He原子碰撞.采用符合测量方法和多参数数据获取系统得到了散射离子与反冲离子电荷态的二维谱,从而分别得到直接电离、入射离子俘获电子和入射离子损失电子截面与总截面的截面比Rdirect,Rcapture和Rloss,并对强扰动能区的各个反应道之间竞争关系及同一反应道在不同碰撞体系中所表现出的实验规律进行了比较和定性分析.     

等电荷态离子与He原子碰撞中的转移电离过程研究

采用位置灵敏探测和飞行时间技术测量了等电荷态离子Cq+、Nq+、Oq+、Neq+(q=4,5,6,7)与He原子碰撞中,转移电离截面与单电子俘获截面的比值R.研究了相同q入射的情况下,R与入射离子核电荷数Z的依赖关系,在统计蒸发模型的基础上对实验结果进行了解释.     

高电荷态离子207Pbq+(24≤q≤36)与Si(110)固体表面作用的电子发射研究

报道了利用兰州重离子加速器国家实验室ECR源引出的高电荷态离子²⁰⁷Pb^q+(24≤q≤36)入射到Si(110)表面产生的电子发射的实验测量结果.结果表明,高电荷态离子与固体表面相互作用产生的电子发射产额Y与入射离子的电荷态q、入射角度ψ和入射能量E都有很强的关联.首次发现,电子发射产额Y与入射角度ψ间有接近1/tanψ的关系.理论分析认为,这些过程与基于经典过垒模型的势能电子发射过程密切相关. 关键词： 高电荷态离子 经典过垒模型 电子发射产额     

低能高电荷态离子(4≤q≤7)与He碰撞中双俘获与转移电离的截面反转效应

基于入射离子双俘获后势能沉积与双电离靶离子势能的比值定义了势能参数Ω,研究了低能高电荷态离子(q=4,5,6,7)与He原子碰撞系统中双俘获和转移电离反应道的选择规律.研究发现,在Ω坐标下,双俘获和转移电离存在截面反转效应,Ω1.0时双俘获为双电子转移过程主反应道,Ω≥1.0时转移电离成为双电子转移过程主反应道.     

中低能非全裸C离子与He原子的碰撞研究

采用反冲离子飞行时间-散射离子位置灵敏符合测量技术，测量了能量范围在0.7v₀—4.4v₀(v₀为玻尔速度)的碳离子C^q+(q=1—4)与He原子碰撞过程不同出射道靶原子的双电离与单电离截面比R，包括入射离子不损失电子(直接电离)的出射道(R_q,q),入射离子俘获一个电子的出射道(R_q,q-1)和入射离子损失一个电子的出射道(R_q,q+1)，并研究了R随入射C离子的能量及电荷态的变化关系.实验表明，对给定电荷态的入射离子，靶原子的双电离与单电离截面比R与出射道有很强的依赖关系，即R_q,q<R_q,q+1<R_q,q-1.直接电离出射道截面比R_q,q与入射离子电荷态几乎无关，而入射离子俘获一个电子的出射道和损失一个电子的出射道靶原子双电离与单电离截面比R_q,q-1和R_q,q+1却与入射离子电荷态有很强的关系.采用原子极化理论和电子屏蔽与反屏蔽作用对实验结果进行了解释. 关键词： 离子-原子碰撞 电离 截面比     

低电荷态离子原子碰撞过程中的转移电离机理的研究

介绍了使用位置灵敏技术和飞行时间方法研究中低能低电荷态离子-原子碰撞过程中转移电离与单电子俘获过程.对于确定的入射离子电荷态,通过理论分析及与实验数据对比给出了转移电离与单电子俘获截面比R_TS随着入射离子速度V_P的变化规律和转移电离过程中电离的电子主要来自靶原子的最外亚壳层. 关键词： 转移电离 逃离半径 电离半径 俘获半径     

等电荷态离子与He原子碰撞中的转移电离过程研究

采用位置灵敏探测和飞行时间技术测量了等电荷态离子C^q 、N^q 、O^q 、Ne^q (q=4，5，6，7)与He原子碰撞中，转移电离截面与单电子俘获截面的比值Ro研究了相同q入射的情况下，R与入射离子核电荷数Z的依赖关系。在统计蒸发模型的基础上对实验结果进行了解释。     

高电荷态离子207Pbq+(24≤q≤36)与Si(110)固体表面作用的电子发射研究

报道了利用兰州重离子加速器国家实验室ECR源引出的高电荷态离子207Pbq+(24≤q≤36)入射到Si(110)表面产生的电子发射的实验测量结果.结果表明,高电荷态离子与固体表面相互作用产生的电子发射产额Y与入射离子的电荷态q、入射角度ψ和入射能量E都有很强的关联.首次发现,电子发射产额Y与入射角度ψ间有接近1/tanψ的关系.理论分析认为,这些过程与基于经典过垒模型的势能电子发射过程密切相关.     

经典过垒模型在Xeq++He碰撞中的应用

采用位置灵敏探测和飞行时间技术研究了高电荷态Xe离子(q=15,17,19,21,23)与He原子碰撞中双电子转移截面与单俘获截面比随入射离子电荷态的变化规律.提出一步过程假定,对扩展的经典过垒(ECB)模型进行了修正,利用修正模型计算得到的单、双电子转移绝对截面与Andersson等人和Selberg等人的实验结果符合得很好,所得截面比与本实验得到的双电子转移截面与单电子俘获截面符合得比较好.     

The direct ionization processes in the collisions of partially stripped carbon and oxygen ions with helium atoms at low-to-intermediate energies

The values of direct double- to-single ionization ratio R of helium atoms induced by C^q＋, O^q＋ （q = 1 -4） ions at incident energies from 0.2 to 8.5MeV are measured. Based on the existing model （Shao J X, Chen X M and Ding B W 2007 Phys. Rev. A 75 012701） the effective charge of the projectile is introduced to theoretically estimate the value of R for the partially stripped ions impacting on helium atoms. The results calculated from our ＂effective charge＂ model are in good agreement with the experimental data, and the dependence of the effective charge on the ionization energy of the projectile is also discussed qualitatively.     

The effective charge effect in partially stripped ion-helium collisions

The double and single ionization cross section ratios of helium by partially stripped carbon, oxygen and fluorine ions are measured for projectile charge states ranging from +1 to +4 and impact energies from 1.5 MeV to 7.5 MeV. The effective charge effect in partially stripped ion-helium collisions is studied. It is found that the effective charge q_eff increases as the impinging energy increases and q _eff shows a modest dependence upon the projectile charge state in the present energy range. The projectile charge state, projectile energy, projectile and target electronic state dependences of the effective charge effect may be explained using orbital interpenetrating.     

The effective charge effect in partially stripped ion-helium collisions

The double and single ionization cross section ratios of helium by partially stripped carbon, oxygen and fluorine ions are measured for projectile charge states ranging from +1 to +4 and impact energies from 1.5 MeV to 7.5 MeV. The effective charge effect in partially stripped ion-helium collisions is studied. It is found that the effective chargeq _eff increases as the impinging energy increases andq _eff shows a modest dependence upon the projectile charge state in the present energy range. The projectile charge state, projectile energy, projectile and target electronic state dependences of the effective charge effect may be explained using orbital interpenetrating.     

Chromium(III) complexes as intermolecular probes

Metal ion complexes provide flexible paramagnetic centers that may be used to define intermolecular contacts in a variety of solution phase environments because both the charge and electronic relaxation properties of the complex may be varied. For most complex ions, there are several proton equilibria that may change the effective charge on the complex as a function of pH which in turn affects the efficacy of application for defining the electrostatic surfaces of co-solute molecules. We report here spectrophotometric and nuclear spin relaxation studies on aqueous solutions of chromium(III) complexes of EDTA, DTPA, and bis-amides of both. The effective charges available from these paramagnetic centers range from -3 to +1 and we report the pH ranges over which the effective charge is defined with confidence for application in magnetic relaxation experiments.     

电解质浓度对胶体粒子表面有效电荷的影响

胶体粒子的表面有效电荷是决定胶体性质的重要物理量,但溶液环境(如电解质溶液浓度)是否影响其数值至今尚无统一认识,近年来的一些研究工作给出了存在争议的不同结果和假设.在直接实验测量方面,由于电解质离子和胶体表面吸附离子的置换,粒子表面基团的不完全电离和胶体粒子对离子吸附的共同作用,使得对这类粒子在不同溶液环境下的表面有效电荷的测量和变化机理的认识极为困难.针对该问题,本文测定了羧基和磺酸基修饰的聚苯乙烯胶体颗粒在不同粒子浓度和HCl浓度下的电导率,由于两种粒子与HCl电离产生的阳离子相同(均为H+),可根据电导率-数密度法(迁移法)得到胶体颗粒表面有效电荷数.通过实验结果分析,明确了HCl浓度以及粒子数密度对胶体粒子表面电荷的影响规律以及表面电荷随HCl浓度增大的原因.除此之外,羧基修饰颗粒比磺酸基修饰颗粒的表面电荷随HCl浓度变化更快;对于同一HCl浓度,磺酸基修饰胶体表面电荷不受粒子数密度影响,而羧基修饰胶体颗粒却与之相关.基于粒子表面电荷的理论模型,对这些问题都给出了相应的解释.     

A suggestion for a parameter free model of strongly damped collisions

A parameter free model of strongly damped collisions is outlined. The proton and neutron drifts are determined by solving two coupled differential equations based on Einstein relations. The mass and charge variance are determined from an effective interaction time and an effective neck area both obtained from a dynamical calculation. We examine the reaction Xe + Bi at 1130 MeV. For all partial waves the theoretically predicted ratios of charge drift to charge variance agree very well with those obtained from recent experimental data.     

Nd L-shell x-ray emission induced by light ions

The L-shell x-ray of Nd has been obtained for 300-600 keV He²⁺ ions impacting, and compared with that produced by H⁺ and H₂⁺ ions. The threshold of projectile kinetic energy for L-shell ionization of Nd is crudely verified in the energy region of about 300-400 keV. It is found that the energy of the distinct L-subshell x-rays has a blue shift. The relative intensity ratios of Lβ_{1, 3, 4} and Lβ_{2, 15} to Lα_{1, 2} x-ray are enlarged compared to the atomic data, and they decrease with the increase of the incident energy, and increase with increasing the effective nuclear charge of the incident ions. That is interpreted by the multiple ionization of outer-shells induced by light ions.     

Single-and-double electron loss of O2+ in collisions with argon and helium

This paper reports that the ratios of double to single electron loss cross-section （R） of O^2＋ in collision with Ar and He at the velocity of 1 -4 vo（vo is the Bohr velocity） have been obtained by the coincidence technique. The trend of R - V in the experiment indicates that the effective charge varies with injected velocity. The effective charge can be obtained by the n-body classical trajectory Monte Carlo method, which is interpreted by the molecular Coulomb over barrier model.     

Study on the defect of sulfur substituting for phosphorus in potassium dihydrogen phosphate

The electronic structure and geometric distribution of neutral and charge states of the point defect sulfur substituting for phosphorus (S_p) in potassium dihydrogen phosphate (KH₂PO₄) have been investigated using a first-principles method. The energy gap is lowered to about 2.2 eV and 6.5 eV from the Density Function Theory (DFT) value of 7.3 eV by a -2 charge and neutral state, respectively. However, no defect states appear in the energy gap for the +1, -1, and +2 charge states of the S_p defect. The results show that the defects S_p with neutral and -2 charge states might contribute to the transient optical absorption under the high energy laser irradiation.